arXiv subjects

T. J. Millar

Publications and source records attributed to T. J. Millar.

At least 19 recordsLinked to original sources

arXiv2026

Ca-bearing cyanopolyynes in IRC+10216

In recent years, a number of metal-containing, carbon-chain species have been detected in the external circumstellar envelope of the carbon-rich AGB star IRC+10216. The most common metal detected in such species is Mg, for which molecules as large as MgC$_5$N, MgC$_5$N$^+$, MgC$_6$H and MgC$_6$H$^+$ have been observed. In this paper, we calculate the likely abundances of the Ca-bearing cyanopolyynes, CaC$_{2n+1}$N for n = 1-4, drawing the conclusion that the observed abundance of CaNC must be made from much larger Ca-terminated cyanopolyyne ions, which requires considerable rearrangement in their dissociative recombination. We pay particular attention to the detectability of CaC$_3$N whose rotational spectrum has recently been measured.

astro-ph.SR↗

arXiv2026

Charting circumstellar chemistry of carbon-rich asymptotic giant branch stars. III. SiO and SiS abundances

The present understanding of C-rich AGB chemistry largely relies on observations of the archetypal carbon star IRC+10216. Current molecular abundance estimates for carbon stars are based either on single-dish spectra sampling a range of excitation conditions, or on interferometric mapping of a few lines. We aim to estimate the circumstellar abundances of SiO, SiS, and their most abundant isotopologues ($^{29}$SiO, $^{30}$SiO, $^{29}$SiS, $^{30}$SiS, and Si$^{34}$S) for a sample of five carbon stars. We derived molecular abundances using detailed 1D non-local thermodynamic equilibrium (non-LTE) radiative transfer (RT) modelling, constrained by both morphological and excitation information obtained from spatially resolved ALMA maps and single-dish observations. We further compared the derived abundances to chemical modelling results. We obtain good fits to the SiO and SiS line profiles, and derived well-constrained abundance profiles and reliable isotopic ratios for all sources except AFGL 3068. While the SiS peak abundances are very similar across the sample (2.0$\times$10$^{-6}-4.7\times$10$^{-6}$), we find that the SiO peak abundances of the rest of the stars are a factor of $\sim$5 larger than that of IRC+10216. The $e$-folding radii ($R_\mathrm{e}$) are in the range 1.3$\times$10$^{16}-7.0\times$10$^{16}$ cm for SiO and 6.0$\times$10$^{15}-1.0\times$10$^{17}$ cm for SiS. The $R_\mathrm{e}$ increases with gas density for both SiO and SiS. Chemical models reproduce the derived SiO abundance profiles well, while over-predicting the SiS $R_\mathrm{e}$ values. Our models highlight the necessity of having spatially resolved observations across a broad range of excitation conditions, while also making evident the limitations inherent in 1D RT modelling using simplified (circum)stellar models. We find that the currently assumed SiS photodissociation rate in chemical models is underestimated.

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arXiv2025

Isotopomer-Specific Carbon Isotope Ratio of Complex Organic Molecules in Star-Forming Cores

The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the synthesis of COMs. In this study, we investigate the formation and carbon isotope fractionation of COMs by constructing a new astrochemical reaction network that distinguishes the position of $^{13}$C within species (e.g., H$^{13}$COOCH$_3$ and HCOO$^{13}$CH$_3$ are distinguished). We take into account the position of $^{13}$C in each species in gas and solid phase chemistry. This new model allows us to resolve isotopomer-specific $^{12}$C/$^{13}$C ratios of COMs formed in the star-forming cores. We consider thermal diffusion-driven radical-radical reactions on the ice surface and non-thermal radiolysis chemistry in the bulk (surface + mantle) ice. We find that carbon isotope fractionation of the functional groups in COMs appears through both non-thermal radiolysis in cold environments and thermal diffusion in warm environments, depending on the COMs. In particular, COMs containing methyl groups show isotopomer differences in $^{12}$C/$^{13}$C ratios that reflect their formation pathways and environments. These isotopomer-resolved fractionation patterns provide a diagnostic tool to probe the origins of COMs in star-forming cores. Our results suggest that future comparisons between high-sensitivity isotopic observations and isotopomer-specific models will be helpful for constraining the relative contributions of thermal and non-thermal formation processes of COMs.

astro-ph.GA↗

arXiv2025

Sense and Sensitivity - I. Uncertainty analysis of the gas-phase chemistry in AGB outflows

Chemical reaction networks are central to all chemical models. Each rate coefficient has an associated uncertainty, which is generally not taken into account when calculating the chemistry. We performed the first uncertainty analysis of a chemical model of C-rich and O-rich AGB outflows using the Rate22 reaction network. Quantifying the error on the model predictions enables us to determine the need for adding complexity to the model. Using a Monte Carlo sampling method, we quantified the impact of the uncertainties on the chemical kinetic data on the predicted fractional abundances and column densities. The errors are caused by a complex interplay of reactions forming and destroying each species. Parent species show an error on their envelope sizes, which is not caused by the uncertainty on their photodissociation rate, but rather the chemistry reforming the parent after its photodissociation. Using photodissociation models to estimate the envelope size might be an oversimplification. The error on the CO envelope impacts retrieved mass-loss rates by up to a factor of two. For daughter species, the error on the peak fractional abundance ranges from a factor of a few to three orders of magnitude, and is on average about 10\% of its value. This error is positively correlated with the error on the column density. The standard model suffices for many species, e.g., the radial distribution of cyanopolyynes and hydrocarbon radicals around IRC +10216. However, including spherical asymmetries, dust-gas chemistry, and photochemistry induced by a close-by stellar companion are still necessary to explain certain observations.

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arXiv2025

ATOMIUM: Continuum emission and evidence of dust enhancement from binary motion

Low- and intermediate-mass stars on the asymptotic giant branch (AGB) account for a significant portion of the dust and chemical enrichment in their host galaxy. Here we present ALMA observations of the continuum emission at 1.24 mm around a sample of 17 stars from the ATOMIUM survey. From our analysis of the stellar contributions to the continuum flux, we find that the semi-regular variables all have smaller physical radii and fainter monochromatic luminosities than the Mira variables. Comparing these properties with pulsation periods, we find a positive trend between stellar radius and period only for the Mira variables with periods above 300 days and a positive trend between the period and the monochromatic luminosity only for the red supergiants and the most extreme AGB stars with periods above 500 days. We find that the continuum emission at 1.2 mm can be classified into four groups. "Featureless" continuum emission is confined to the (unresolved) regions close to the star for five stars in our sample, relatively uniform extended flux is seen for four stars, tentative elongated features are seen for three stars, and the remaining five stars have unique or unusual morphological features in their continuum maps. These features can be explained by binary companions to 10 out of the 14 AGB stars in our sample. Based on our results we conclude that there are two modes of dust formation: well established pulsation-enhanced dust formation and our newly proposed companion-enhanced dust formation. If the companion is located close to the AGB star, in the wind acceleration region, then additional dust formed in the wake of the companion can increase the mass lost through the dust driven wind. This explains the different dust morphologies seen around our stars and partly accounts for a large scatter in literature mass-loss rates, especially among semiregular stars with small pulsation periods.

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arXiv2025

Charting circumstellar chemistry of carbon-rich asymptotic giant branch stars. II. Abundances and spatial distributions of CS

The circumstellar envelopes (CSEs) of asymptotic giant branch (AGB) stars harbour a rich variety of molecules and are sites of complex chemistry. Our current understanding of the circumstellar chemical processes of carbon-rich AGB stars is predominantly based on observations of a single star, IRC+10216, often regarded as an archetypical carbon star. We aim to estimate stellar and circumstellar properties for five carbon stars, and constrain their circumstellar CS abundances. This study compares the CS abundances among the sources, informs circumstellar chemical models, and helps to assess if IRC+10216 is a good representative of the physics and chemistry of carbon star CSEs. We modelled the spectral energy distributions (SEDs) and CO line emission to derive the stellar and outflow properties. Using these, we then retrieved CS abundance profiles with detailed radiative transfer modelling, imposing spatial and excitation constraints from ALMA and single-dish observations. We obtain good fits to the SEDs and CO lines for all sources and reproduce the CS line emission across various transitions and apertures, yielding robust estimates of the CS abundance profiles. Peak CS fractional abundances range from 1$\times$10$^{-6}$ - 4$\times$10$^{-6}$, with e-folding radii of 1.8$\times$10$^{16}$ - 6.8$\times$10$^{16}$ cm. We also derive reliable $^{12}$C/$^{13}$C and $^{32}$S/$^{34}$S ratios from CS isotopologue modelling. Our results refine previous single-dish CS abundance estimates and improve the relative uncertainty on the CS e-folding radius for IRAS 07454$-$7112 by a factor of $\sim$2.5. Chemical models reproduce our estimates of the CS radial extent, corroborating the CS photodissociation framework used therein. We find no significant differences between the derived CS abundance profiles for IRC+10216 and the rest of the sample, apart from the expected density-driven variations.

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arXiv2024

Chemical tracers of a highly eccentric AGB-main sequence star binary

Binary interactions have been proposed to explain a variety of circumstellar structures seen around evolved stars, including asymptotic giant branch (AGB) stars and planetary nebulae. Studies resolving the circumstellar envelopes of AGB stars have revealed spirals, discs and bipolar outflows, with shaping attributed to interactions with a companion. For the first time, we have used a combined chemical and dynamical analysis to reveal a highly eccentric and long-period orbit for W Aquilae, a binary system containing an AGB star and a main sequence companion. Our results are based on anisotropic SiN emission, the first detections of NS and SiC towards an S-type star, and density structures observed in the CO emission. These features are all interpreted as having formed during periastron interactions. Our astrochemistry-based method can yield stringent constraints on the orbital parameters of long-period binaries containing AGB stars, and will be applicable to other systems.

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arXiv2023

Charting Circumstellar Chemistry of Carbon-rich AGB Stars: I. ALMA 3 mm spectral surveys

AGB stars are major contributors to the chemical enrichment of the ISM through nucleosynthesis and extensive mass loss. Most of our current knowledge of AGB atmospheric and circumstellar chemistry, in particular in a C-rich environment, is based on observations of the carbon star IRC+10216. We aim to obtain a more generalised understanding of the chemistry in C-rich AGB CSEs by studying a sample of three carbon stars, IRAS15194-5115, IRAS15082-4808, and IRAS07454-7112, and test the archetypal status often attributed to IRC+10216. We performed spatially resolved, unbiased spectral surveys in ALMA Band 3. We identify a total of 132 rotational transitions from 49 molecular species. There are two main morphologies of the brightness distributions: centrally-peaked (e.g. HCN) and shell-like (e.g. C$_2$H). We estimated the sizes of the molecular emitting regions using azimuthally-averaged radial profiles of the line brightness distributions, and derived abundance estimates. Of the shell distributions, the cyanopolyynes peak at slightly smaller radii than the hydrocarbons, and CN and HNC show the most extended emission. The emitting regions for each species are the smallest for IRAS07454-7112. We find that, within the uncertainties of the analysis, the three stars present similar abundances for most species, also compared to IRC+10216. We find that SiO is more abundant in our three stars compared to IRC+10216. Our estimated isotopic ratios match well the literature values for the sources. The observed circumstellar chemistry appears very similar across our sample and compared to that of IRC+10216, both in terms of the relative location of the emitting regions and molecular abundances. This implies that, to a first approximation, the chemical models tailored to IRC+10216 are able to reproduce the observed chemistry in C-rich envelopes across roughly an order of magnitude in wind density.

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arXiv2023

ATOMIUM: Molecular inventory of 17 oxygen-rich evolved stars observed with ALMA

The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02"-1.4". Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v=1, SO2 v1=1 and v2=2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2=2,3 and SiS v=4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql...

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arXiv2023

Concluding remarks: Faraday Discussion on astrochemistry at high resolution

Fifty years on from the first detailed chemical kinetic modelling of astronomical sources, I provide some introductory comments on the history of astrochemistry, summarise some personal views on the topics covered in this discussion meeting, and conclude with some thoughts on its future development. I have left out the jokes.

astro-ph.GA↗

arXiv2023

Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

astro-ph.GA↗

arXiv2023

ATOMIUM: Probing the inner wind of evolved O-rich stars with new, highly excited H$_2$O and OH lines

Water and the hydroxyl radical are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are highly excited have been observed in both H$_2$O and OH. These and more recently discovered transitions can now be observed at a high sensitivity and angular resolution with the ALMA Array. Spectra and maps of H$_2$O and OH observed with an angular resolution of 20 to $\sim$200 mas were obtained at two epochs with the ALMA array. Observations with the Compact Array were also used to check for time variability of water transitions. Radiative transfer models of water were revisited to characterize masing conditions and up-to-date chemical models were used for comparison with our observations. Ten rotational transitions of H$_2$O with energies up to 9000 K were observed in various vibrational states. All but one are new detections in space, and from these we have derived accurate rest frequencies. Hyperfine split $Λ$-doubling transitions in v = 0, J = 27/2 and 29/2 levels of the $^2Π_{3/2}$ state and, $J = 33/2$ and 35/2 of the $^2Π_{1/2}$ state of OH with excitation energies up to 8900 K were also observed. Four of these transitions are new detections in space. Combining our measurements with earlier observations of OH, the v = 0 and v = 1 $Λ$-doubling frequencies have been improved. Our H$_2$O maps show compact emission and extensions up to twelve stellar radii or more. The 268.149 GHz emission line of water in the v$_2$ = 2 state is time variable, tends to be masing with dominant radiative pumping, and is widely excited. The widespread but weaker 262.898 GHz water line in v$_2$ = 1 also shows signs of maser emission. Emission and absorption of both H$_2$O and OH reveal an infall of matter and complex kinematics influenced by binarity. From our observed column densities, we derived OH/H$_2$O abundance ratios in a few stars.

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arXiv2023

The VLT/SPHERE view of the ATOMIUM cool evolved star sample. I. Overview: Sample characterization through polarization analysis

Aims. Through the ATOMIUM project, based on an ALMA large program, we aim to present a consistent view of a sample of 17 nearby cool evolved stars (Aymptotic Giant Branch and red supergiant stars). Methods. Here we present VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function, and in or near the plane of the sky, with a total optical depth close to unity in the line of sight, representing only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03-0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of common dust species. The spatial structure of the DoLP shows a diverse set of shapes. Only for three sources do we note a correlation between the ALMA CO and SiO lines, which trace the gas density, and the DoLP, which traces the dust. Conclusion. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner circumstellar environment (CSE), dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the CSE. Except for $π^1$~Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky.

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arXiv2021

ATOMIUM: ALMA tracing the origins of molecules in dust forming oxygen rich M-type stars: Motivation, sample, calibration, and initial results

This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter-submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. 17 oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (0.025-0.050 arcsec), medium (0.13-0.24 arcsec), and low (about 1 arcsec) angular resolution. The sensitivity per 1.3 km/s channel was 1.5-5 mJy/beam. 13 molecules were designated as primary molecules in the survey: CO, SiO, AlO, AlOH, TiO, TiO2, HCN, SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described; and we highlight one scientific result - the wind kinematics of the ATOMIUM sources. The ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion, and the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In 15 sources, some molecular transitions other than 12CO v=0 J=2-1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. Binary interaction with a (sub)stellar companion might (partly) explain the non-monotonic behaviour of the projected velocity field.

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arXiv2021

The impact of stellar companion UV photons on the chemistry of the circumstellar environments of AGB stars

Spherical asymmetries are prevalent within the outflows of AGB stars. Since binary interaction with a stellar or planetary companion is thought to be the underlying mechanism behind large-scale structures, we included the effects of UV radiation originating from a stellar companion in our chemical kinetics model. The one-dimensional model provides a first approximation of its effects on the chemistry throughout the outflow. The presence of a close-by stellar companion can strongly influence the chemistry within the entire outflow. Its impact depends on the intensity of the radiation (set by the stellar radius and blackbody temperature) and on the extinction the UV radiation experiences (set by the outflow density, density structure, and assumed radius of dust formation). Parent species can be photodissociated by the companion, initiating a rich photon-driven chemistry in the inner parts of the outflow. The outcome depends on the balance between two-body reactions and photoreactions. If two-body reactions dominate, chemical complexity within the outflow increases. This can make the abundance profiles of daughters appear like those of parents, with a larger inner abundance and a gaussian decline. If photoreactions dominate, the outflow can appear molecule-poor. We model three stellar companions. The impact of a red dwarf companion is limited. Solar-like companions show the largest effect, followed by a white dwarf. A stellar companion can also lead to the formation of unexpected species. The outflow's molecular content, especially combined with abundance profiles, can indicate a stellar companion's presence. Our results pave the way for further outflow-specific (three-dimensional) model development.

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arXiv2021

ATOMIUM: Halide molecules around the S-type AGB star W Aquilae

S-type asymptotic giant branch (AGB) stars are thought to be intermediates in the evolution of oxygen- to carbon-rich AGB stars. The chemical compositions of their circumstellar envelopes are also intermediate, but have not been studied in as much detail as their carbon- and oxygen-rich counterparts. We aim to determine the abundances of AlCl and AlF from rotational lines, which have been observed for the first time towards an S-type AGB star, W Aql. In combination with models based on PACS observations, we aim to update our chemical kinetics network based on these results. We analyse ALMA observations towards W Aql of AlCl in the ground and first two vibrationally excited states and AlF in the ground vibrational state. Using radiative transfer models, we determine the abundances and spatial abundance distributions of Al$^{35}$Cl, Al$^{37}$Cl, and AlF. We also model HCl and HF emission and compare these models to PACS spectra to constrain the abundances of these species. AlCl is found in clumps very close to the star, with emission confined within 0.1$^{\prime\prime}$ of the star. AlF emission is more extended, with faint emission extending 0.2$^{\prime\prime}$ to 0.6$^{\prime\prime}$ from the continuum peak. We find peak abundances, relative to H$_2$, of $1.7\times 10^{-7}$ for Al$^{35}$Cl, $7\times 10^{-8}$ for Al$^{37}$Cl and $1\times 10^{-7}$ for AlF. From the PACS spectra, we find abundances of $9.7\times 10^{-8}$ and $\leq 10^{-8}$, relative to H$_2$, for HCl and HF, respectively. The AlF abundance exceeds the solar F abundance, indicating that fluorine synthesised in the AGB star has already been dredged up to the surface of the star and ejected into the circumstellar envelope. From our analysis of chemical reactions in the wind, we conclude that AlF may participate in the dust formation process, but we cannot fully explain the rapid depletion of AlCl seen in the wind.

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arXiv2021

High Spatial Resolution Observations of Molecular Lines towards the Protoplanetary Disk around TW Hya with ALMA

We present molecular line observations of 13CO and C18O J=3-2, CN N = 3 - 2, and CS J=7-6 lines in the protoplanetary disk around TW Hya at a high spatial resolution of ~9 au (angular resolution of 0.15''), using the Atacama Large Millimeter/Submillimeter Array. A possible gas gap is found in the deprojected radial intensity profile of the integrated C18O line around a disk radius of ~58 au, slightly beyond the location of the au-scale dust clump at ~52 au, which resembles predictions from hydrodynamic simulations of planet-disk interaction. In addition, we construct models for the physical and chemical structure of the TW Hya disk, taking account of the dust surface density profile obtained from high spatial resolution dust continuum observations. As a result, the observed flat radial profile of the CN line intensities is reproduced due to a high dust-to-gas surface density ratio inside ~20 au. Meanwhile, the CO isotopologue line intensities trace high temperature gas and increase rapidly inside a disk radius of ~30 au. A model with either CO gas depletion or depletion of gas-phase oxygen elemental abundance is required to reproduce the relatively weak CO isotopologue line intensities observed in the outer disk, consistent with previous atomic and molecular line observations towards the TW Hya disk. {Further observations of line emission of carbon-bearing species, such as atomic carbon and HCN, with high spatial resolution would help to better constrain the distribution of elemental carbon abundance in the disk gas.

astro-ph.EP↗

arXiv2020

The Role of Ultraviolet Photons in Circumstellar Astrochemistry

Stars with masses between 1 and 8 solar masses (M$_\odot$) lose large amounts of material in the form of gas and dust in the late stages of stellar evolution, during their Asymptotic Giant Branch phase. Such stars supply up to 35% of the dust in the interstellar medium and thus contribute to the material out of which our solar system formed. In addition, the circumstellar envelopes of these stars are sites of complex, organic chemistry with over 80 molecules detected in them. We show that internal ultraviolet photons, either emitted by the star itself or from a close-in, orbiting companion, can significantly alter the chemistry that occurs in the envelopes particularly if the envelope is clumpy in nature. At least for the cases explored here, we find that the presence of a stellar companion, such as a white dwarf star, the high flux of UV photons destroys H$_2$O in the inner regions of carbon-rich AGB stars to levels below those observed and produces species such as C$^+$ deep in the envelope in contrast to the expectations of traditional descriptions of circumstellar chemistry.

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