arXiv subjects

T. Saitoh

Publications and source records attributed to T. Saitoh.

14 recordsLinked to original sources

arXiv2016

Quasi-particles ultrafastly releasing kink bosons to form Fermi arcs in a cuprate superconductor

In a conventional framework, superconductivity is lost at a critical temperature (T_c) because, at higher temperatures, gluing bosons can no longer bind two electrons into a Cooper pair. In high-T_c cuprates, it is still unknown how superconductivity vanishes at T_c. We provide evidence that the so-called <~70-meV kink bosons that dress the quasi-particle excitations are playing a key role in the loss of superconductivity in a cuprate. We irradiated a 170-fs laser pulse on Bi2Sr2CaCu2O8+δand monitored the responses of the superconducting gap and dressed quasi-particles by time- and angle-resolved photoemission spectroscopy. We observe an ultrafast loss of superconducting gap near the d-wave node, or light-induced Fermi arcs, which is accompanied by spectral broadenings and weight redistributions occurring within the kink binding energy. We discuss that the underlying mechanism of the spectral broadening that induce the Fermi arc is the undressing of quasi-particles from the kink bosons. The loss mechanism is beyond the conventional framework, and can accept the unconventional phenomena such as the signatures of Cooper pairs remaining at temperatures above T_c.

cond-mat.supr-con↗

arXiv2015

Hybridization gap formation in the Kondo insulator YbB$_{12}$ observed using time-resolved photoemission spectroscopy

A detailed low-energy electronic structure of a Kondo insulator YbB$_{12}$ was revealed by a synergetic combination of ultrahigh-resolution laser photoemission spectroscopy (PES) and time-resolved PES. The former confirmed a 25-meV pseudogap corresponding to the Kondo temperature of this material, and more importantly, it revealed that a 15-meV gap and a Kondo-peak feature developed below a crossover temperature $T^\ast \sim 110$ K. In harmony with this, the latter discovered a very long recombination time exceeding 100 ps below $\sim$$T^\ast$. This is a clear manifestation of photoexcited carriers due to the bottleneck in the recovery dynamics, which is interpreted as a developing hybridization gap of a hard gap.

cond-mat.str-el↗

arXiv2013

Empirical relationship between x-ray photoemission spectra and electrical conductivity in a colossal magnetoresistive manganite La_{1-x}Sr_{x}MnO_{3}

By using laboratory x-ray photoemission spectroscopy (XPS) and hard x-ray photoemission spectroscopy (HX-PES) at a synchrotron facility, we report an empirical semi-quantitative relationship between the valence/core-level x-ray photoemission spectral weight and electrical conductivity in La_{1-x}Sr_{x}MnO_{3} as a function of x. In the Mn 2p_{3/2} HX-PES spectra, we observed the shoulder structure due to the Mn^{3+} well-screened state. However, the intensity at x=0.8 was too small to explain its higher electrical conductivity than x=0.0, which confirms our recent analysis on the Mn 2p_{3/2} XPS spectra. The near-Fermi level XPS spectral weight was found to be a measure of the variation of electrical conductivity with x in spite of a far lower energy resolution compared with the energy scale of the quasiparticle (coherent) peak because of the concurrent change of the coherent and incoherent spectral weight.

cond-mat.str-el↗

arXiv2013

Electronic structure of hole-doped delafossite oxides CuCr_{1-x}Mg_{x}O_{2}

We report the detailed electronic structure of a hole-doped delafossite oxide CuCr_{1-x}Mg_{x}O_{2} (0 <= x <= 0.03) studied by photoemission spectroscopy (PES), soft x-ray absorption spectroscopy (XAS), and band-structure calculations within the local-density approximation +U (LDA+U) scheme. Cr/Cu 3p-3d resonant PES reveals that the near-Fermi-level leading structure has primarily the Cr 3d character with a minor contribution from the Cu 3d through Cu 3d-O 2p-Cr 3d hybridization, having good agreement with the band-structure calculations. This indicates that a doped hole will have primarily the Cr 3d character. Cr 2p PES and L-edge XAS spectra exhibit typical Cr^{3+} features for all x, while the Cu L-edge XAS spectra exhibited a systematic change with x. This indicates now that the Cu valence is monovalent at x=0 and the doped hole should have Cu 3d character. Nevertheless, we surprisingly observed two types of charge-transfer satellites that should be attributed to Cu^{+} (3d^{10}) and Cu^{2+} (3d^{9}) like initial states in Cu 2p-3d resonant PES spectrum for at x=0, while Cu 2p PES spectra with no doubt shows the Cu^{+} character even for the lightly doped samples. We propose that these contradictory results can be understood by introducing no only the Cu 4s state, but also finite Cu 3d,4s-Cr 3d charge transfer via O 2p states in the ground-state electronic configuration.

cond-mat.str-el↗

arXiv2013

Hidden relationship between the electrical conductivity and the Mn 2p core-level photoemission spectra in La1-xSrxMnO3

Core-level electronic structure of La1-xSrxMnO3 has been studied by x-ray photoemission spectroscopy (XPS). We first report, by the conventional XPS, the well-screened shoulder structure in Mn 2p3/2 peak, which had been observed only by hard x-ray photoemission spectroscopy so far. Multiple-peak analysis revealed that the Mn4+ spectral weight was not proportional to the nominal hole concentration x, indicating that a simple Mn3+/Mn4+ intensity ratio analysis may result in a wrong quantitative elemental analysis. Considerable weight of the shoulder at x=0.0 and the fact that the shoulder weight was even slightly going down from x=0.2 to 0.4 were not compatible with the idea that this weight simply represents the metallic behavior. Further analysis found that the whole Mn 2p3/2 peak can be decomposed into four portions, the Mn4+, the (nominal) Mn3+, the shoulder, and the other spectral weight located almost at the Mn3+ location. We concluded that this weight represents the well-screened final state at Mn4+ sites, whereas the shoulder is known as that of the Mn3+ states. We found that the sum of these two spectral weight has an empirical relationship to the conductivity evolution with x.

cond-mat.str-el↗

arXiv2010

Femtosecond core level photoemision spectroscopy on 1T-TaS2 using 60 eV laser source

Time-resolved photoelectron spectroscopy (trPES) can directly detect transient electronic structure, thus bringing out its promising potential to clarify nonequilibrium processes arising in condensed matters. Here we report the result of core-level (CL) trPES on 1T-TaS2, realized by developing a high-intensity 60 eV laser obtained by high-order harmonic (HH) generation. Ta4f CL-trPES offers the transient amplitude of the charge-density-wave (CDW), via the site-selective and real-time observation of Ta electrons. The present result indicates an ultrafast photoinduced melting and recovery of CDW amplitude, followed by a peculiar long-life oscillation (i.e. collective amplitudon excitation) accompanying the transfer of 0.01 electrons among adjacent Ta atoms. CL-trPES offers a broad range of opportunities for investigating the ultrafast atom-specific electron dynamics in photo-related phenomena of interest.

cond-mat.str-el↗

arXiv2009

Superconducting electronic state in optimally doped YBa2Cu3O7-d observed with laser-excited angle-resolved photoemission spectroscopy

Low energy electronic structure of optimally doped YBa2Cu3O7-d is investigated using laser-excited angle-resolved photoemission spectroscopy. The surface state and the CuO chain band that usually overlap the CuO2 plane derived bands are not detected, thus enabling a clear observation of the bulk superconducting state. The observed bilayer splitting of the Fermi surface is ~0.08 angstrom^{-1} along the (0,0)-(pi,pi) direction, significantly larger than Bi2Sr2CaCu2O8+d. The kink structure of the band dispersion reflecting the renormalization effect at ~60 meV shows up similarly as in other hole-doped cuprates. The momentum-dependence of the superconducting gap shows d_{x^2-y^2}-wave like amplitude, but exhibits a nonzero minimum of ~12 meV along the (0,0)-(pi,pi) direction. Possible origins of such an unexpected "nodeless" gap behavior are discussed.

cond-mat.supr-con↗

arXiv2008

An Isotopic Fingerprint of Electron-Phonon Coupling in High-Tc Cuprates

Angle-resolved photoemission spectroscopy with low-energy tunable photons along the nodal direction of oxygen isotope substituted Bi2Sr2CaCu2O8+delta reveals a distinct oxygen isotope shift near the electron-boson coupling "kink" in the electronic dispersion. The magnitude (a few meV) and direction of the kink shift are as expected due to the measured isotopic shift of phonon frequency, which are also in agreement with theoretical expectations. This demonstrates the participation of the phonons as dominant players, as well as pinpointing the most relevant of the phonon branches.

cond-mat.supr-con↗

arXiv2006

Electronic Structure of Charge- and Spin-controlled Sr_{1-(x+y)}La_{x+y}Ti_{1-x}Cr_{x}O_{3}

We present the electronic structure of Sr_{1-(x+y)}La_{x+y}Ti_{1-x}Cr_{x}O_{3} investigated by high-resolution photoemission spectroscopy. In the vicinity of Fermi level, it was found that the electronic structure were composed of a Cr 3d local state with the t_{2g}^{3} configuration and a Ti 3d itinerant state. The energy levels of these Cr and Ti 3d states are well interpreted by the difference of the charge-transfer energy of both ions. The spectral weight of the Cr 3d state is completely proportional to the spin concentration x irrespective of the carrier concentration y, indicating that the spin density can be controlled by x as desired. In contrast, the spectral weight of the Ti 3d state is not proportional to y, depending on the amount of Cr doping.

cond-mat.str-el↗

arXiv2005

Orbital selectivity of the kink in the dispersion of Sr2RuO4

We present detailed energy dispersions near the Fermi level on the monolayer perovskite ruthenate Sr2RuO4, determined by high-resolution angle-resolved photoemission spectroscopy. An orbital selectivity of the kink in the dispersion of Sr2RuO4 has been found: A kink for the Ru 4d_xy orbital is clearly observed, but not for the Ru 4d_yz and 4d_zx ones. The result provides insight into the origin of the kink.

cond-mat.supr-con↗

arXiv2005

Unusual electron-doping effects in Sr$_{2-x}$La$_x$FeMoO$_6$ observed by photoemission spectroscopy

We have investigated the electronic structure of electron-doped Sr$_{2-x}$La$_x$FeMoO$_6$ ($x$=0.0 and 0.2) by photoemission spectroscopy and band-structure calculations within the local-density approximation+$U$ (LDA+$U$) scheme. A characteristic double-peak feature near the Fermi level ($E_{\rm F}$) has been observed in the valence-band photoemission spectra of both $x$=0.0 and 0.2 samples. A photon-energy dependence of the spectra in the Mo 4$d$ Cooper minimum region compared with the band-structure calculations has shown that the first peak crossing $E_{\rm F}$ consists of the (Fe+Mo) $t_{2g\downarrow}$ states (feature A) and the second peak well below $E_{\rm F}$ is dominated by the Fe $e_{g\uparrow}$ states (feature B). Upon La substitution, the feature A moves away from $E_{\rm F}$ by $\sim$50 meV which is smaller than the prediction of our band theory, 112 meV. In addition, an intensity enhancement of $both$ A and B has been observed, although B is not crossing $E_{\rm F}$. Those two facts are apparently incompatible with the simple rigid-band shift due to electron doping. We point out that such phenomena can be understood in terms of the strong Hund's rule energy stabilization in the 3$d^5$ configuration at the Fe sites in this compound. From an observed band-narrowing, we have also deduced a mass enhancement of $\sim$2.5 with respect to the band theory, in good agreement with a specific heat measurement.

cond-mat.str-el↗

arXiv2004

Strong correlation effects of the Re 5$d$ electrons on the metal-insulator transition in Ca$_2$FeReO$_6$

We have investigated the electronic structure of polycrystalline Ca$_2$FeReO$_6$ using photoemission spectroscopy and band-structure calculations within the local-density approximation+$U$ (LDA+$U$) scheme. In valence-band photoemission spectra, a double-peak structure which is characteristic of the metallic double perovskite series has been observed near the Fermi level ($E_{\rm F}$), although it is less distinct compared to the Sr$_2$FeMoO$_6$ case. The leading near-$E_{\rm F}$ structure has a very weak spectral weight at $E_{\rm F}$ above the metal-insulator transition (MIT) temperature $T_{\rm MI}$ of $\sim$140 K, and it loses the $E_{\rm F}$ weight below $T_{\rm MI}$, forming a small energy gap. To reproduce this small energy gap in the calculation, we require a very large effective $U$ ($U_{\rm eff}$) for Re (4 eV) in addition to a relatively large $U_{\rm eff}$ for Fe (4 eV). Although the most of the experimental features can be interpreted with the help of the band theory, the overall agreement between the theory and the experiment was not satisfactory. We demonstrate that the effective transfer integral between Fe and Re is actually smaller than that between Fe and Mo in Ca$_2$FeMoO$_6$, which can explain both MIT and very high ferrimagnetic transition temperature.

cond-mat.str-el↗

arXiv1999

Temperature-Dependent Pseudogaps in Colossal Magnetoresistive Oxides

Direct electronic structure measurements of a variety of the colossal magnetoresistive oxides show the presence of a pseudogap at the Fermi energy E_F which drastically suppresses the electron spectral function at E_F. The pseudogap is a strong function of the layer number of the samples (sample dimensionality) and is strongly temperature dependent, with the changes beginning at the ferromagnetic transition temperature T_c. These trends are consistent with the major transport trends of the CMR oxides, implying a direct relationship between the pseudogap and transport, including the "colossal" conductivity changes which occur across T_c. The k-dependence of the temperature-dependent effects indicate that the pseudogap observed in these compounds is not due to the extrinsic effects proposed by Joynt.

cond-mat.str-el↗

arXiv1999

63Cu NQR evidence of dimensional crossover to anisotropic 2d regime in S= 1/2 three-leg ladder Sr2Cu3O5

We probed spin-spin correlations up to 725 K with 63Cu NQR in the S= 1/2 three-leg ladder Sr2Cu3O5. We present experimental evidence that below 300 K, weak inter-ladder coupling causes dimensional crossover of the spin-spin correlation length ξfrom quasi-1d (ξ~ 1/T) to anisotropic 2d regime (ξ\~ exp[2πρ_{s}/T], where 2πρ_{s} = 290 +/- 30 K is the effective spin stiffness). This is the first experimental verification of the renormalized classical behavior of the anisotropic non-linear sigma model in 2d, which has been recently proposed for the striped phase in high T_{c} cuprates.

cond-mat.supr-con↗