arXiv2017
This review work focuses on the milling process of titania (TiO2) nanopowder. TiO2 is a naturally available material. It is an inorganic semi-conducting oxide of titanium metal. Titanium oxide, titanium dioxide, and titanium (IV) oxide are the other names. TiO2 nanopowder is one of the well-known synthetic materials in the modern nanotechnology field. It has many interesting, lucrative and salient properties. These characters are attracting the researchers towards to exploit this material in variety of applications from energy to environmental. It is a highly sensitive and excellent photo-catalyst material. So, it can be used in gas sensors, in water splitting to generate hydrogen, and in waste water treatment to degrade the organic pollutants. It is soluble in ethanol, ethylene glycol and chloroform. TiO2 nanopowder is prepared by many methods such as sol-gel method, chemical vapour deposition, hydro-thermal, micro-emulsion etc. However, low cost and large scale synthesis of nanoparticles for commercial applications are the major challenges in the present day scenario. Mechanical milling is a simple method to prepare nanopowder where milling time plays very important role. The milling time may vary from 0 to 60 hour. The crystallinity, phase, size, shape and surface features are some of the factors affected by the milling process. For the preparation of TiO2 nanomaterial, the mechanical milling is more advantageous than other methods. It is a low cost, non toxic method which offers high chemical stability. The finely grinded TiO2 nano powder offers shiny surface and brilliant colours. Milling of TiO2 is done for size reduction. Doping of TiO2 is done to improve the efficiencies and to minimize drawbacks.