arXiv subjects

T. W. Darling

Publications and source records attributed to T. W. Darling.

4 recordsLinked to original sources

arXiv2004

Direct observation of the formation of polar nanoregions in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ using neutron pair distribution function analysis

Using neutron pair distribution function (PDF) analysis over the temperature range from 1000 K to 15 K, we demonstrate the existence of local polarization and the formation of medium-range, polar nanoregions (PNRs) with local rhombohedral order in a prototypical relaxor ferroelectric Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$. We estimate the volume fraction of the PNRs as a function of temperature and show that this fraction steadily increases from 0 % to a maximum of $\sim$ 30% as the temperature decreases from 650 K to 15 K. Below T$\sim$200 K the PNRs start to overlap as their volume fraction reaches the percolation threshold. We propose that percolating PNRs and their concomitant overlap play a significant role in the relaxor behavior of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$.

cond-mat.dis-nn↗

arXiv2003

Anisotropic Elastic Properties of CeRhIn$_{5}$

The structure of the quasi two dimensional heavy fermion antiferromagnet CeRhIn$_{5}$ has been investigated as a function of pressure up to 13 GPa using a diamond anvil cell under both hydrostatic and quasihydrostatic conditions at room (T=295 K) and low (T=10 K) temperatures. Complementary resonant ultrasound measurements were performed to obtain the complete elastic moduli. The bulk modulus ($B\approx 78$ GPa) and uniaxial compressibilities ($κ_{a}$ $=3.96\times $ $10^{-3}$ GPa$^{-1}$ and $% κ_{c}$ $=4.22\times $ $10^{-3}$ GPa$^{-1}$) found from pressure-dependent x-ray diffraction are in good agreement with the ultrasound measurements. Unlike doping on the Rh site where $T_{c}$ increases linearly with the ratio of the tetragonal lattice parameters $c/a,$ no such correlation is observed under pressure; instead, a double peaked structure with a local minimum around 4-5 GPa is observed at both room and low temperatures.

cond-mat.str-el↗

arXiv2003

The role of the lattice in the $γ\to α$ phase transition of Ce: a high pressure neutron and x-ray diffraction study

The temperature and pressure dependence of the thermal displacements and lattice parameters were obtained across the $γ\to α$ phase transition of Ce using high-pressure, high-resolution neutron and synchrotron x-ray powder diffraction. The estimated vibrational entropy change per atom in the $γ\to α$ phase transition, $ΔS^{γ- α}_{\rm vib} \approx (0.75 \pm 0.15)$k$_{\rm B}$, is about half of the total entropy change. The bulk modulus follows a power-law pressure dependence which is well described using the framework of electron-phonon coupling. These results clearly demonstrate the importance of lattice vibrations, in addition to the spin and charge degrees of freedom, for a complete description of the $γ\to α$ phase transition in elemental Ce.

cond-mat.str-el↗

arXiv2001

Elastic and thermodynamic properties of the shape-memory alloy AuZn

The current work reports on the elastic shear moduli, internal friction, and the specific heat of the B2 cubic ordered alloy AuZn as a function of temperature. Measurements were made on single-crystal and polycrystalline samples using Resonant Ultrasound Spectroscopy (RUS), semi-adiabatic calorimetry and stress-strain measurements. Our results confirm that this alloy exhibits the shape-memory effect and a phase transition at 64.75 K that appears to be continuous (second-order) from the specific heat data. It is argued that the combination of equiatomic composition and a low transformation temperature constrain the chemical potential and its derivatives to exhibit behavior that lies at the borderline between that of a first-order (discontinuous) and a continuous phase transition. The acoustic dissipation does not peak at the transtion temperature as expected, but shows a maximum well into the low-temperature phase. The Debye temeprature value of 219 K, obtained from the low-temperature specific heat data is in favorable agreement with that determined from the acoustic data (207 K) above the transition.

cond-mat.mtrl-sci↗