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Takeshi Sakai

Publications and source records attributed to Takeshi Sakai.

At least 55 records · Page 3Linked to original sources

The Perseus ALMA Chemistry Survey (PEACHES). I. The Complex Organic Molecules in Perseus Embedded Protostars

To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of 50 embedded protostars surveyed, 58% of them have emission from COMs. A 56%, 32%, and 40% of the protostars have CH$_3$OH, CH$_3$OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H$_2$ column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH$_3$OH has a tight correlation with CH$_3$CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH$_3$OH and CH$_3$CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, hinting at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH$_3$OCHO and CH$_3$OCH$_3$) relative to that of smaller COMs (CH$_3$OH and CH$_3$CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes.

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The ALMA Survey of 70$μ$m Dark High-mass Clumps in Early Stages (ASHES) III. A Young Molecular Outflow Driven by a Decelerating Jet

We present a spatio-kinematical analysis of the CO~($J$=2$\rightarrow$1) line emission, observed with the Atacama Large Millimter/submillimter Array (ALMA), of the outflow associated with the most massive core, ALMA1, in the 70 $μ$m dark clump G010.991$-$00.082. The position-velocity (P-V) diagram of the molecular outflow exhibits a peculiar $\mathsf{S}$-shaped morphology that has not been seen in any other star forming region. We propose a spatio-kinematical model for the bipolar molecular outflow that consists of a decelerating high-velocity component surrounded by a slower component whose velocity increases with distance from the central source. The physical interpretation of the model is in terms of a jet that decelerates as it entrains material from the ambient medium, which has been predicted by calculations and numerical simulations of molecular outflows in the past. One side of the outflow is shorter and shows a stronger deceleration, suggesting that the medium through which the jet moves is significantly inhomogeneous. The age of the outflow is estimated to be $τ$$\approx$1300 years, after correction for a mean inclination of the system of $\approx$57$^{\circ}$.

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Spectrometer Using superconductor MIxer Receiver (SUMIRE) for Laboratory Submillimeter Spectroscopy

Recent spectroscopic observations by sensitive radio telescopes require accurate molecular spectral line frequencies to identify molecular species in a forest of lines detected. To measure rest frequencies of molecular spectral lines in the laboratory, an emission-type millimeter and submillimeter-wave spectrometer utilizing state-of-the-art radio-astronomical technologies is developed. The spectrometer is equipped with a 200 cm glass cylinder cell, a two sideband (2SB) Superconductor-Insulator-Superconductor (SIS) receiver in the 230 GHz band, and wide-band auto-correlation digital spectrometers. By using the four 2.5 GHz digital spectrometers, a total instantaneous bandwidth of the 2SB SIS receiver of 8 GHz can be covered with a frequency resolution of 88.5 kHz. Spectroscopic measurements of CH$_3$CN and HDO are carried out in the 230 GHz band so as to examine frequency accuracy, stability, sensitivity, as well as intensity calibration accuracy of our system. As for the result of CH$_3$CN, we confirm that the frequency accuracy for lines detected with sufficient signal to noise ratio is better than 1 kHz, when the high resolution spectrometer having a channel resolution of 17.7 kHz is used. In addition, we demonstrate the capability of this system by spectral scan measurement of CH$_3$OH from 216 GHz to 264 GHz. We assign 242 transitions of CH$_3$OH, 51 transitions of $^{13}$CH$_3$OH, and 21 unidentified emission lines for 295 detected lines. Consequently, our spectrometer demonstrates sufficient sensitivity, spectral resolution, and frequency accuracy for in-situ experimental-based rest frequency measurements of spectral lines on various molecular species.

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Digging into the Interior of Hot Cores with ALMA (DIHCA). I. Dissecting the High-mass Star-Forming Core G335.579-0.292 MM1

We observed the high-mass star-forming region G335.579-0.292 with the Atacama Large Millimeter/submillimeter Array (ALMA) at 226 GHz with an angular resolution of 0.3'' ($\sim 1000$ au resolution at the source distance). G335.579-0.292 hosts one of the most massive cores in the Galaxy (G335-MM1). The continuum emission shows that G335-MM1 fragments into at least five sources, while molecular line emission is detected in two of the continuum sources (ALMA1 and ALMA3). We found evidence of large and small scale infall in ALMA1 revealed by an inverse P-Cygni profile and the presence of a blue-shifted spot at the center of the first moment map of the CH$_3$CN emission. In addition, hot gas expansion in the innermost region is unveiled by a red-shifted spot in the first moment map of HDCO and (CH$_3$)$_2$CO (both with $E_u > 1100$ K). Our modeling reveals that this expansion motion originates close to the central source, likely due to reversal of the accretion flow induced by the expansion of the HII region, while infall and rotation motions originate in the outer regions. ALMA3 shows clear signs of rotation, with a rotation axis inclination with respect to the line of sight close to $90^\circ$, and a system mass (disk + star) in the range of 10-30 M$_\odot$.

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FAUST II. Discovery of a Secondary Outflow in IRAS 15398-3359: Variability in Outflow Direction during the Earliest Stage of Star Formation?

We have observed the very low-mass Class 0 protostar IRAS 15398-3359 at scales ranging from 50 au to 1800 au, as part of the ALMA Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source along a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398-3359, by 1200 au. The arc-like structure is blue-shifted with respect to the systemic velocity. A velocity gradient of 1.2 km/s over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398-3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.

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The ALMA Survey of 70 $μ\rm m$ Dark High-mass Clumps in Early Stages (ASHES). II: Molecular Outflows in the Extreme Early Stages of Protocluster Formation

We present a study of outflows at extremely early stages of high-mass star formation obtained from the ALMA Survey of 70 $μ\rm m$ dark High-mass clumps in Early Stages (ASHES). Twelve massive 3.6$-$70 $μ\rm m$ dark prestellar clump candidates were observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6. Forty-three outflows are identified toward 41 out of 301 dense cores using the CO and SiO emission lines, yielding a detection rate of 14%. We discover 6 episodic molecular outflows associated with low- to high-mass cores, indicating that episodic outflows (and therefore episodic accretion) begin at extremely early stages of protostellar evolution for a range of core masses. The time span between consecutive ejection events is much smaller than those found in more evolved stages, which indicates that the ejection episodicity timescale is likely not constant over time. The estimated outflow dynamical timescale appears to increase with core masses, which likely indicates that more massive cores have longer accretion timescales than less massive cores. The lower accretion rates in these 70 $μ\rm m$ dark objects compared to the more evolved protostars indicate that the accretion rates increase with time. The total outflow energy rate is smaller than the turbulent energy dissipation rate, which suggests that outflow induced turbulence cannot sustain the internal clump turbulence at the current epoch. We often detect thermal SiO emission within these 70 $μ\rm m$ dark clumps that is unrelated to CO outflows. This SiO emission could be produced by collisions, intersection flows, undetected protostars, or other motions.

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HCN $J$=4-3, HNC $J$=1-0, $\mathrm{H^{13}CN}$ $J$=1-0, and $\mathrm{HC_3N}$ $J$=10-9 Maps of Galactic Center Region II.: Physical Properties of Dense Gas Clumps and Probability of Star Formation

We report a statistical analysis exploring the origin of the overall low star formation efficiency (SFE) of the Galactic central molecular zone (CMZ) and the SFE diversity among the CMZ clouds using a wide-field HCN $J$=4-3 map, whose optically thin critical density ($\sim10^7\,\mathrm{cm}^{-3}$) is the highest among the tracers ever used in CMZ surveys. Logistic regression is performed to empirically formulate star formation probability of 195 HCN clumps, 13 of which contain star formation signatures. The explanatory parameters in the best-fit model are reduced into the virial parameter $α_{\mathrm{vir}}$ without significant contribution from other parameters, whereas the performance of the model without $α_{\mathrm{vir}}$ is no better than that using randomly generated data. The threshold $α_{\mathrm{vir}}$ is 6, which translates into a volume density ($n_{\mathrm{H_2}}$) of $10^{4.6}\,\mathrm{cm}^{-3}$ with the $n_{\mathrm{H_2}}$-$α_{\mathrm{vir}}$ correlation. The scarcity of the low-$α_{\mathrm{vir}}$ clumps, whose fraction to all HCN clumps is 0.1, can be considered as one of the immediate causes of the suppressed SFE. No correlation between the clump size or mass and star formation probability is found, implying that HCN $J$=4-3 does not immediately trace the mass of star-forming gas above a threshold density. Meanwhile, star-forming and non-star-forming clouds are degenerate in the physical parameters of the CS $\mathit{J}$=1-0 clouds, highlighting the efficacy of the HCN $\mathit{J}$=4-3 line to probe star-forming regions in the CMZ. The time scale of the high-$α_{\mathrm{vir}}$ to low-$α_{\mathrm{vir}}$ transition is $\lesssim2$ Myr, which is consistent with the tidal compression and X1/X2 orbit transition models but possibly does not fit the cloud-cloud collision picture.

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Molecular Cloud Cores with High Deuterium Fraction: Nobeyama Single-Pointing Survey

We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($λ$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense cores on the verge of star formation for the study of the initial conditions of star formation. We observed these cores in eight molecular lines at 76-94 GHz using the Nobeyama 45-m telescope. We find that early-type molecules (e.g., CCS) have low detection rates and that late-type molecules (e.g., N$_2$H$^+$, c-C$_3$H$_2$) and deuterated molecules (e.g., N$_2$D$^+$, DNC) have high detection rates, suggesting that most of the cores are chemically evolved. The deuterium fraction (D/H) is found to decrease with increasing distance, indicating that it suffers from differential beam dilution between the D/H pair of lines for distant cores ($>$1 kpc). For $λ$ Orionis, Orion A, and B located at similar distances, D/H is not significantly different, suggesting that there is no systematic difference in the observed chemical properties among these three regions. We identify at least eight high D/H cores in the Orion region and two at high latitudes, which are most likely to be close to the onset of star formation. There is no clear evidence of the evolutionary change in turbulence during the starless phase, suggesting that the dissipation of turbulence is not a major mechanism for the beginning of star formation as judged from observations with a beam size of 0.04 pc.

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ALMA ACA and Nobeyama observations of two Orion cores in deuterated molecular lines

We mapped two molecular cloud cores in the Orion A cloud with the ALMA ACA 7-m Array and with the Nobeyama 45-m radio telescope. These cores have bright N$_2$D$^+$ emission in single-pointing observations with the Nobeyama 45-m radio telescope, have relatively high deuterium fraction, and are thought to be close to the onset of star formation. One is a star-forming core, and the other is starless. These cores are located along filaments observed in N$_2$H$^+$, and show narrow linewidths of 0.41 km s$^{-1}$ and 0.45 km s$^{-1}$ in N$_2$D$^+$, respectively, with the Nobeyama 45-m telescope. Both cores were detected with the ALMA ACA 7m Array in the continuum and molecular lines at Band 6. The starless core G211 shows clumpy structure with several sub-cores, which in turn show chemical differences. Also, the sub-cores in G211 have internal motions that are almost purely thermal. The starless sub-core G211D, in particular, shows a hint of the inverse P Cygni profile, suggesting infall motion. The star-forming core G210 shows an interesting spatial feature of two N$_2$D$^+$ peaks of similar intensity and radial velocity located symmetrically with respect to the single dust continuum peak. One interpretation is that the two N$_2$D$^+$ peaks represent an edge-on pseudo-disk. The CO outflow lobes, however, are not directed perpendicular to the line connecting both N$_2$D$^+$ peaks.

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A new off-point-less observing method for millimeter and submillimeter spectroscopy with a frequency-modulating local oscillator (FMLO)

We propose a new observing method for single-dish millimeter and submillimeter spectroscopy using a heterodyne receiver equipped with a frequency-modulating local oscillator (FMLO). Unlike conventional switching methods, which extract astronomical signals by subtracting the reference spectra of off-sources from those of on-sources, the FMLO method does not need to obtain any off-source spectra; rather, it estimates them from the on-source spectra themselves. The principle is a high dump-rate (10 Hz) spectroscopy with radio frequency modulation (FM) achieved by fast sweeping of a local oscillator (LO) of a heterodyne receiver: Because sky emission (i.e., off-source) fluctuates as $1/f$-type and is spectrally correlated, it can be estimated and subtracted from time-series spectra (a timestream) by principal component analysis. Meanwhile astronomical signals remain in the timestream since they are modulated to a higher time-frequency domain. The FMLO method therefore achieves (1) a remarkably high observation efficiency, (2) reduced spectral baseline wiggles, and (3) software-based sideband separation. We developed an FMLO system for the Nobeyama 45-m telescope and a data reduction procedure for it. Frequency modulation was realized by a tunable and programmable first local oscillator. With observations of Galactic sources, we demonstrate that the observation efficiency of the FMLO method is dramatically improved compared to conventional switching methods. Specifically, we find that the time to achieve the same noise level is reduced by a factor of 3.0 in single-pointed observations and by a factor of 1.2 in mapping observations. The FMLO method can be applied to observations of fainter ($\sim$mK) spectral lines and larger ($\sim$deg$^{2}$) mapping. It would offer much more efficient and baseline-stable observations compared to conventional switching methods.

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The ALMA Survey of 70 $μ$m dark High-mass clumps in Early Stages (ASHES). I. Pilot Survey: Clump Fragmentation

(Abridged) ASHES has been designed to systematically characterize the earliest stages and to constrain theories of high-mass star formation. A total of 12 massive (>500 $M_{\odot}$), cold (<15 K), 3.6-70 $μ$m dark prestellar clump candidates, embedded in IRDCs, were carefully selected in the pilot survey to be observed with ALMA. We mosaiced each clump (~1 arcmin^2) in dust and line emission with the 12m/7m/TP arrays at 224 GHz, resulting in ~1.2" resolution (~4800 AU). As the first paper of the series, we concentrate on the dust emission to reveal the clump fragmentation. We detect 294 cores, from which 84 (29%) are categorized as protostellar based on outflow activity or 'warm core' line emission. The remaining 210 (71%) are considered prestellar core candidates. The number of detected cores is independent of the mass sensitivity range of the observations. On average, more massive clumps tend to form more cores. We find a large population of low-mass (<1 M) cores and no high-mass (>30 $M_{\odot}$) prestellar cores. The most massive prestellar core has a mass of 11 $M_{\odot}$. From the prestellar CMF, we derive a power law index of 1.17+-0.1, slightly shallower than Salpeter (1.35). We use the MST technique to characterize the separation between cores and their spatial distribution, and derive mass segregation ratios. While there is a range of core masses and separations detected in the sample, the mean separation and mass of cores are well explained by thermal fragmentation and are inconsistent with turbulent Jeans fragmentation. The core spatial distribution is well described by hierarchical subclustering rather than centrally peaked clustering. There is no conclusive evidence of mass segregation. We test several theoretical conditions, and conclude that overall, competitive accretion and global hierarchical collapse scenarios are favored over the turbulent core accretion scenario.

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Sulfur-Bearing Species Tracing the Disk/Envelope System in the Class I Protostellar Source Elias 29

We have observed the Class I protostellar source Elias 29 with Atacama Large Millimeter/submillimeter Array (ALMA). We have detected CS, SO, $^{34}$SO, SO$_2$, and SiO line emissions in a compact component concentrated near the protostar and a ridge component separated from the protostar by 4\arcsec\ ($\sim 500$ au). The former component is found to be abundant in SO and SO$_2$ but deficient in CS. The abundance ratio SO/CS is as high as $3^{+13}_{-2} \times 10^2$ at the protostar, which is even higher than that in the outflow-shocked region of L1157 B1. However, organic molecules (HCOOCH$_3$, CH$_3$OCH$_3$, CCH, and c-C$_3$H$_2$) are deficient in Elias 29. We attribute the deficiency in organic molecules and richness in SO and SO$_2$ to the evolved nature of the source or the relatively high dust temperature (\protect\raisebox{-0.7ex}{$\:\stackrel{\textstyle >}{\sim}\:$} 20 K) in the parent cloud of Elias 29. The SO and SO$_2$ emissions trace rotation around the protostar. Assuming a highly inclined configuration ($i \geq 65$\degr; 0\degr\ for a face-on configuration) and Keplerian motion for simplicity, the protostellar mass is estimated to be (0.8 -- 1.0) \Msun. The $^{34}$SO and SO$_2$ emissions are asymmetric in their spectra; the blue-shifted components are weaker than the red-shifted ones. Although this may be attributed to the asymmetric molecular distribution, other possibilities are also discussed.

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An unbiased spectral line survey observation toward the low-mass star-forming region L1527

An unbiased spectral line survey toward a solar-type Class 0/I protostar, IRAS04368+2557, in L1527 has been carried out in the 3 mm band with the Nobeyama 45 m telescope. L1527 is known as a warm carbon-chain chemistry (WCCC) source, which harbors abundant unsaturated organic species such as C$_n$H ($n = 3,\ 4,\ 5,\ldots$) in a warm and dense region near the protostar. The observation covers the frequency range from 80 to 116 GHz. A supplementary observation has also been conducted in the 70 GHz band to observe fundamental transitions of deuterated species. In total, 69 molecular species are identified, among which 27 species are carbon-chain species and their isomers, including their minor isotopologues. This spectral line survey provides us with a good template of the chemical composition of the WCCC source.

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Series-connected array of superconductor-insulator-superconductor junctions in the 100-GHz band heterodyne mixer for FOREST on the Nobeyama 45-m telescope

In this study, we designed and experimentally evaluated a series-connected array of superconductor-insulator-superconductor (SIS) junctions in the 100-GHz band mixer for the multi-beam receiver FOREST on the Nobeyama 45-m millimeter-wave telescope. The construction of the junction chip comprised a waveguide probe antenna, impedance matching circuit, SIS array junction, and choke filter, which were made from a superconducting niobium planar circuit on a quartz substrate. The multi-stage impedance matching circuit between the feed point and the SIS junction was designed as a capacitively loaded transmission line, and it comprised two sections with high (~90 Ohm) and low (~10 Ohm) characteristic impedance transmission lines. The structure of this tuning line was simple and easy to fabricate, and the feed impedance matched with the SIS junction in a wide frequency range. The signal coupling efficiency was more than 92% and the expected receiver noise temperature was approximately two times the quantum limit for 75-125 GHz based on quantum theory. The array junction devices with 3-6 connected junctions were fabricated and we measured their performance in terms of the receiver noise temperature and gain compression in the laboratory. We successfully developed an array junction device with a receiver noise temperature of ~15-30 K and confirmed that the improvement in the saturation power corresponded to the number of junctions. The newly developed array junction mixer was installed in the FOREST receiver and it successfully detected the 12CO (J = 1-0) molecular line toward IRC+10216 with the Nobeyama 45-m telescope.

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Rotation in the NGC 1333 IRAS 4C Outflow

We report molecular line observations of the NGC 1333 IRAS 4C outflow in the Perseus Molecular Cloud with the Atacama Large Millimeter/Submillimeter Array. The CCH and CS emission reveal an outflow cavity structure with clear signatures of rotation with respect to the outflow axis. The rotation is detected from about 120 au up to about 1400 au above the envelope/disk mid-plane. As the distance to the central source increases, the rotation velocity of the outflow decreases while the outflow radius increases, which gives a flat specific angular momentum distribution along the outflow. The mean specific angular momentum of the outflow is about 100 au km/s. Based on reasonable assumptions on the outward velocity of the outflow and the protostar mass, we estimate the range of outflow launching radii to be 5-15 au. Such a launching radius rules out that this outflow is launched as an X-wind, but rather, it is more consistent to be a slow disk wind launched from relatively large radii on the disk. The radius of the centrifugal barrier is roughly estimated, and the role of the centrifugal barrier in the outflow launching is discussed.

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Depletion of 15N in the center of L1544: Early transition from atomic to molecular nitrogen?

We performed sensitive observations of the N15ND+(1-0) and 15NND+(1-0) lines toward the prestellar core L1544 using the IRAM 30m telescope. The lines are not detected down to 3 sigma levels in 0.2 km/s channels of around 6 mK. The non-detection provides the lower limit of the 14N/15N ratio for N2D+ of ~700-800, which is much higher than the elemental abundance ratio in the local ISM of ~200-300. The result indicates that N2 is depleted in 15N in the central part of L1544, because N2D+ preferentially traces the cold dense gas, and because it is a daughter molecule of N2. In-situ chemistry is unlikely responsible for the 15N depletion in N2; neither low-temperature gas phase chemistry nor isotope selective photodissociation of N2 explains the 15N depletion; the former prefers transferring 15N to N2, while the latter requires the penetration of interstellar FUV photons into the core center. The most likely explanation is that 15N is preferentially partitioned into ices compared to 14N via the combination of isotope selective photodissociation of N2 and grain surface chemistry in the parent cloud of L1544 or in the outer regions of L1544 which are not fully shielded from the interstellar FUV radiation. The mechanism is the most efficient at the chemical transition from atomic to molecular nitrogen. In other words, our result suggests that the gas in the central part of L1544 already went trough the transition from atomic to molecular nitrogen in the earlier evolutionary stage, and that N2 is currently the primary form of gas-phase nitrogen.

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Infall Signatures in a Prestellar Core embedded in the High-Mass 70 $μ$m Dark IRDC G331.372-00.116

Using Galactic Plane surveys, we have selected a massive (1200 M$_\odot$), cold (14 K) 3.6-70 $μ$m dark IRDC G331.372-00.116. This IRDC has the potential to form high-mass stars and, given the absence of current star formation signatures, it seems to represent the earliest stages of high-mass star formation. We have mapped the whole IRDC with the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.1 and 1.3 mm in dust continuum and line emission. The dust continuum reveals 22 cores distributed across the IRDC. In this work, we analyze the physical properties of the most massive core, ALMA1, which has no molecular outflows detected in the CO (2-1), SiO (5-4), and H$_2$CO (3-2) lines. This core is relatively massive ($M$ = 17.6 M$_\odot$), subvirialized (virial parameter $α_{vir}=M_{vir}/M=0.14$), and is barely affected by turbulence (transonic Mach number of 1.2). Using the HCO$^+$ (3-2) line, we find the first detection of infall signatures in a relatively massive, prestellar core (ALMA1) with the potential to form a high-mass star. We estimate an infall speed of 1.54 km s$^{-1}$ and a high accretion rate of 1.96 $\times$ 10$^{-3}$ M$_\odot$ yr$^{-1}$. ALMA1 is rapidly collapsing, out of virial equilibrium, more consistent with competitive accretion scenarios rather than the turbulent core accretion model. On the other hand, ALMA1 has a mass $\sim$6 times larger than the clumps Jeans mass, being in an intermediate mass regime ($M_{J}=2.7<M\lesssim$ 30 M$_\odot$), contrary to what both the competitive accretion and turbulent core accretion theories predict.

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Chemical survey toward young stellar objects in the Perseus molecular cloud complex

Chemical diversity of the gas in low-mass protostellar cores is widely recognized. In order to explore its origin, a survey of chemical composition toward 36 Class 0/I protostars in the Perseus molecular cloud complex, which are selected in an unbiased way under certain physical conditions, has been conducted with IRAM 30 m and NRO 45 m telescope. Multiple lines of C2H, c-C3H2 and CH3OH have been observed to characterize the chemical composition averaged over a 1000 au scale around the protostar. The derived beam-averaged column densities show significant chemical diversity among the sources, where the column density ratios of C2H/CH3OH are spread out by 2 orders of magnitude. From previous studies, the hot corino sources have abundant CH3OH but deficient C2H, their C2H/CH3OH column density ratios being relatively low. In contrast, the warm-carbon-chain chemistry (WCCC) sources are found to reveal the high C2H/CH3OH column density ratios. We find that the majority of the sources have intermediate characters between these two distinct chemistry types. A possible trend is seen between the C2H/CH3OH ratio and the distance of the source from the edge of a molecular cloud. The sources located near cloud edges or in isolated clouds tend to have a high C2H/CH3OH ratio. On the other hand, the sources having a low C2H/CH3OH ratio tend to be located in inner regions of the molecular cloud complex. This result gives an important clue to an understanding of the origin of the chemical diversity of protostellar cores in terms of environmental effects.

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