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Thibault Cavalié

Publications and source records attributed to Thibault Cavalié.

At least 19 recordsLinked to original sources

Latitudinal variations in Neptune's temperature profile observed with ALMA

Despite the low solar irradiation it receives, Neptune shows a very active atmosphere with some of the most intense dynamics observed in Solar System atmospheres. Characterizing the atmospheric temperature profiles of the planet is a key to understand these observed processes. In this work, we derived the Neptune pressure-latitude thermal field, using 2016 ALMA measurements of the CO(3-2) spectral line at 345.796 GHz, with a spatial resolution of about 0.37" on Neptune's 2.24" disk. To analyse the data, we developed MCMC retrieval methods to derive both the temperature profiles and the CO abundance profile. We find that our data probes the upper troposphere and the lower stratosphere of the planet, between 2 bar and 0.1 mbar. Although temperature and CO profile are strongly correlated, simultaneous retrievals of both parameters for disk-integrated observations reveal a factor of 2-3 larger CO abundance in the stratosphere than in the troposphere, reinforcing the hypothesis of CO delivery by a recent cometary impact. CO retrievals with fixed temperature profile do not fit the spatially-resolved observations, implying underlying temperature variations. By performing temperature retrievals with spatially constant CO, we find distinct trends of the thermal profile between the southern polar region, mid-latitudes and the equator. At 10--100 mbar, this structure is consistent with that observed by Voyager 2 in 1989, i.e. colder mid-latitudes, with a warmer equator and south polar regions. At 300-600 mbar, however, we find a cold layer of about 45 K at Southern polar regions (-80°) which disappears towards mid-latitudes and the equator. By probing pressure levels not easily accessible to other observing methods e.g. infrared sounding, submillimeter observations offer a new view of the complex thermal structure in the upper troposphere and lower stratosphere of the Icy Giants.

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Surveying exogenous species in Saturn with ALMA I. Detecting and Mapping CO

The origin of carbon monoxide (CO) in Saturn's stratosphere remains uncertain, with proposed sources including internal thermochemical production, cometary impacts, and exogenic material from the rings and icy moons (i.e. Enceladus). We aim to constrain the vertical and meridional distribution of stratospheric CO and assess the relative contributions of these potential sources. Here, we analysed high-spectral-resolution ALMA observations of the CO (J=3-2) line obtained on 25 May 2018, sampling Saturn's limb from 20°S to 69°N. CO vertical profiles were retrieved using a line-by-line radiative transfer model combined with spectral inversion techniques, testing multiple prior scenarios representative of different source hypotheses. CO is confined to a narrow layer between 0.1 and 1 mbar, with a robust negative vertical gradient and mean abundances of (3.7+/- 0.8) x 10$^{-8}$ at 0.1 mbar and (7.2 +/- 0.9) x 10$^{-8}$ at 1 mbar. The meridional distribution is statistically homogeneous, with a marginal enhancement near 60° N plausibly related to Enceladus. No significant equatorial enhancement is detected. The absence of a strong equatorial enhancement rules out a long-lived steady source associated with ring infall. The observations are most consistent with a relatively recent ($\approx$200-year-old or younger) cometary impact whose material has since been horizontally mixed, while any Cassini Grand Finale ring influx was either too recent or inefficient to affect CO abundances at the probed pressure levels.

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Observations of the temporal evolution of Saturn's stratosphere following the Great Storm of 2010-2011 I. Temporal evolution of the water abundance in Saturn's hot vortex of 2011-2013

Water vapour is delivered to Saturn's stratosphere by Enceladus' plumes and subsequent diffusion in the planet system. It is expected to condense into a haze in the middle stratosphere. The hot stratospheric vortex (the `beacon') that formed as an aftermath of Saturn's Great Storm of 2010 significantly altered the temperature, composition, and circulation in Saturn's northern stratosphere. Previous photochemical models suggested haze sublimation and vertical winds as processes likely to increase the water vapour column density in the beacon. We aim to quantify the temporal evolution of stratospheric water vapour in the beacon during the storm. We mapped Saturn at 66.44 and 67.09 $μ$m on seven occasions from July 2011 to February 2013 with the PACS instrument of the Herschel Space Observatory. The observations probe the millibar levels, at which the water condensation region was altered by the warmer temperatures in the beacon. Using radiative transfer modelling, we tested several empirical and physically based models to constrain the cause of the enhanced water emission found in the beacon. The observations show an increased emission in the beacon that cannot be reproduced only accounting for the warmer temperatures. An additional source of water vapour is thus needed. We find a factor (7.5$\pm$1.6) increase in the water column in the beacon compared to pre-storm conditions using empirical models. Combining our results with a cloud formation model for July 2011, we evaluate the sublimation contribution to 45-85% of the extra column derived from the water emission increase in the beacon. The observations confirm that the storm conditions enhanced the water abundance at the millibar levels because of haze sublimation and vertical winds in the beacon. Future work on the haze temporal evolution during the storm will help to better constrain the sublimation contribution over time.

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The Polar Stratosphere of Jupiter

Observations of the Jovian upper atmosphere at high latitudes in the UV, IR and mm/sub-mm all indicate that the chemical distributions and thermal structure are broadly influenced by auroral particle precipitations. Mid-IR and UV observations have shown that several light hydrocarbons (up to 6 carbon atoms) have altered abundances near Jupiter's main auroral ovals. Ion-neutral reactions influence the hydrocarbon chemistry, with light hydrocarbons produced in the upper stratosphere, and heavier hydrocarbons as well as aerosols produced in the lower stratosphere. One consequence of the magnetosphere-ionosphere coupling is the existence of ionospheric jets that propagate into the neutral middle stratosphere, likely acting as a dynamical barrier to the aurora-produced species. As the ionospheric jets and the background atmosphere do not co-rotate at the same rate, this creates a complex system where chemistry and dynamics are intertwined. The ion-neutral reactions produce species with a spatial distribution following the SIII longitude system in the upper stratosphere. As these species sediment down to the lower stratosphere, and because of the progressive dynamical decoupling between the ionospheric flows and the background atmosphere, the spatial distribution of the auroral-related species progressively follows a zonal distribution with increasing pressures that ultimately produces a system of polar and subpolar hazes that extends down to the bottom of the stratosphere. This paper reviews the most recent work addressing different aspects of this environment.

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Storms and convection on Uranus and Neptune: impact of methane abundance revealed by a 3D cloud-resolving model

Uranus and Neptune have atmospheres dominated by molecular hydrogen and helium. In the upper troposphere, methane is the third main molecule and condenses, yielding a vertical gradient in CH4. This condensable species being heavier than H2 and He, the resulting change in mean molecular weight due to condensation comes as a factor countering dry and moist convection. As observations also show latitudinal variations in methane abundance, one can expect different vertical gradients from one latitude to another. In this paper, we investigate the impact of this methane vertical gradient on the atmospheric regimes, especially on the formation and inhibition of moist convective storms in the troposphere of ice giants. We develop a 3D cloud-resolving model to simulate convective processes. Using our simulations, we conclude that typical velocities of dry convection in the deep atmosphere are rather low (of the order of 1 m/s) but sufficient to sustain upward methane transport, and that moist convection at methane condensation level is strongly inhibited. Previous studies derived an analytical criterion on the methane vapor amount above which moist convection should be inhibited. We first validate this analytical criterion numerically. We then show that the critical methane abundance governs the inhibition and formation of moist convective storms, and we conclude that the intensity and intermittency of these storms should depend on the methane abundance and saturation. In ice giants, dry convection is weak, and moist convection is strongly inhibited. However, when enough methane is transported upwards, through dry convection and turbulent diffusion, sporadic moist convective storms can form. These storms should be more frequent on Neptune than on Uranus, because of Neptune's internal heat flow. Our results can explain the observed sporadicity of clouds in ice giants.

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The deep oxygen abundance in Solar System Giant Planets, with a new derivation for Saturn

Deep elemental composition is a challenging measurement to achieve in the giant planets of the solar system. Yet, knowledge of the deep composition offers important insights in the internal structure of these planets, their evolutionary history and their formation scenarios. A key element whose deep abundance is difficult to obtain is oxygen, because of its propensity for being in condensed phases such as rocks and ices. In the atmospheres of the giant planets, oxygen is largely stored in water molecules that condense below the observable levels. At atmospheric levels that can be investigated with remote sensing, water abundance can modify the observed meteorology, and meteorological phenomena can distribute water through the atmosphere in complex ways that are not well understood and that encompass deeper portions of the atmosphere. The deep oxygen abundance provides constraints on the connection between atmosphere and interior and on the processes by which other elements were trapped, making its determination an important element to understand giant planets. In this paper, we review the current constraints on the deep oxygen abundance of the giant planets, as derived from observations and thermochemical models.

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Evidence for auroral influence on Jupiter's nitrogen and oxygen chemistry revealed by ALMA

The localized delivery of new long-lived species to Jupiter's stratosphere by comet Shoemaker-Levy 9 in 1994 opened a window to constrain Jovian chemistry and dynamics by monitoring the evolution of their vertical and horizontal distributions. However, the spatial distributions of CO and HCN, two of these long-lived species, had never been jointly observed at high latitudinal resolution. Atacama large millimeter/submillimeter array observations of HCN and CO in March 2017 show that CO was meridionally uniform and restricted to pressures lower than 3 $\pm$ 1 mbar. HCN shared a similar vertical distribution in the low- to mid-latitudes, but was depleted at pressures between 2$^{+2}_ {-1}$ and 0.04$^{+0.07}_{-0.03}$ mbar in the aurora and surrounding regions, resulting in a drop by two orders of magnitude in column density. We propose that heterogeneous chemistry bonds HCN on large aurora-produced aerosols at these pressures in the Jovian auroral regions causing the observed depletion.

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Insights on the Formation Conditions of Uranus and Neptune from their Deep Elemental Compositions

This study, placed in the context of the preparation for the Uranus Orbiter Probe mission, aims to predict the bulk volatile compositions of Uranus and Neptune. Using a protoplanetary disk model, it examines the evolution of trace species through vapor and solid transport as dust and pebbles. Due to the high carbon abundance found in their envelopes, the two planets are postulated to have formed at the carbon monoxide iceline within the protosolar nebula. The time evolution of the abundances of the major volatile species at the location of the CO iceline is then calculated to derive the abundance ratios of the corresponding key elements, including the heavy noble gases, in the feeding zones of Uranus and Neptune. Supersolar metallicity in their envelopes likely results from accreting solids in these zones. Two types of solids are considered: pure condensates (Case 1) and a mixture of pure condensates and clathrates (Case 2). The model, calibrated to observed carbon enrichments, predicts deep compositions. In Case 1, argon is deeply depleted, while nitrogen, oxygen, krypton, phosphorus, sulfur, and xenon are significantly enriched relative to their protosolar abundances in the two planets. Case 2 predicts significant enrichments for all species, including argon, relative to their protosolar abundances. Consequently, Case 1 predicts near-zero Ar/Kr or Ar/Xe ratios, while Case 2 suggests these ratios are 0.1 and 0.5-1 times their protosolar ratios. Both cases predict a bulk sulfur-to-nitrogen ratio consistent with atmospheric measurements.

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Temperature and composition disturbances in the southern auroral region of Jupiter revealed by JWST/MIRI

Jupiters south polar region was observed by JWST Mid Infrared Instrument in December 2022. We used the Medium Resolution Spectrometer mode to provide new information about Jupiters South Polar stratosphere. The southern auroral region was visible and influenced the atmosphere in several ways. 1: In the interior of the southern auroral oval, we retrieved peak temperatures at two distinct pressure levels near 0.01 and 1 mbar, with warmer temperatures with respect to non auroral regions of 12 pm 2 K and 37 pm 4 K respectively. A cold polar vortex is centered at 65S at 10 mbar. 2: We found that the homopause is elevated to 590+25-118 km above the 1-bar pressure level inside the auroral oval compared to 460+60-50 km at neighboring latitudes and with an upper altitude of 350 km in regions not affected by auroral precipitation. 3: The retrieved abundance of C2H2 shows an increase within the auroral oval, and it exhibits high abundances throughout the polar region. The retrieved abundance of C2H6 increases towards the pole, without being localized in the auroral oval, in contrast with previous analysis. We determined that the warming at 0.01 mbar and the elevated homopause might be caused by the flux of charged particles depositing their energy in the South Polar Region. The 1 mbar hotspot may arise from adiabatic heating resulting from auroral driven downwelling. The cold region at 10 mbar may be caused by radiative cooling by stratospheric aerosols. The differences in spatial distribution seem to indicate that the hydrocarbons analyzed are affected differently by auroral precipitation.

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Recipes for forming a carbon-rich giant planet

The exploration of carbon-to-oxygen ratios has yielded intriguing insights into the composition of close-in giant exoplanets, giving rise to a distinct classification: carbon-rich planets, characterized by a carbon-to-oxygen ratio $\ge$ 1 in their atmospheres, as opposed to giant planets exhibiting carbon-to-oxygen ratios close to the protosolar value. In contrast, despite numerous space missions dispatched to the outer solar system and the proximity of Jupiter, Saturn, Uranus, and Neptune, our understanding of the carbon-to-oxygen ratio in these giants remains notably deficient. Determining this ratio is crucial as it serves as a marker linking a planet's volatile composition directly to its formation region within the disk. This article provides an overview of the current understanding of the carbon-to-oxygen ratio in the four gas giants of our solar system and explores why there is yet no definitive dismissal of the possibility that Jupiter, Saturn, Uranus, or Neptune could be considered carbon-rich planets. Additionally, we delve into the three primary formation scenarios proposed in existing literature to account for a bulk carbon-to-oxygen ratio $\ge$ 1 in a giant planet. A significant challenge lies in accurately inferring the bulk carbon-to-oxygen ratio of our solar system's gas giants. Retrieval methods involve integrating in situ measurements from entry probes equipped with mass spectrometers and remote sensing observations conducted at microwave wavelengths by orbiters. However, these methods fall short of fully discerning the deep carbon-to-oxygen abundance in the gas giants due to their limited probing depth, typically within the 10-100 bar range.

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Atacama Large Aperture Submillimeter Telescope (AtLAST) Science: Planetary and Cometary Atmospheres

The study of planets and small bodies within our Solar System is fundamental for understanding the formation and evolution the Earth and other planets. Compositional and meteorological studies of the giant planets provide a foundation for understanding the nature of the most commonly observed exoplanets, while spectroscopic observations of the atmospheres of terrestrial planets, moons, and comets provide insights into the past and present-day habitability of planetary environments, and the availability of the chemical ingredients for life. While prior and existing (sub)millimeter observations have led to major advances in these areas, progress is hindered by limitations in the dynamic range, spatial and temporal coverage, as well as sensitivity of existing telescopes and interferometers. Here, we summarize some of the key planetary science use cases that factor into the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST), a proposed 50-m class single dish facility: (1) to more fully characterize planetary wind fields and atmospheric thermal structures, (2) to measure the compositions of icy moon atmospheres and plumes, (3) to obtain detections of new, astrobiologically relevant gases and perform isotopic surveys of comets, and (4) to perform synergistic, temporally-resolved measurements in support of dedicated interplanetary space missions. The improved spatial coverage (several arcminutes), resolution ($\sim1.2''-12''$), bandwidth (several tens of GHz), dynamic range ($\sim10^5$) and sensitivity ($\sim1$ mK km s$^{-1}$) required by these science cases would enable new insights into the chemistry and physics of planetary environments, the origins of prebiotic molecules and the habitability of planetary systems in general.

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A 3D picture of moist-convection inhibition in hydrogen-rich atmospheres: Implications for K2-18 b

While small, Neptune-like planets are among the most abundant exoplanets, our understanding of their atmospheric structure and dynamics remains sparse. In particular, many unknowns remain on the way moist convection works in these atmospheres where condensable species are heavier than the non-condensable background gas. While it has been predicted that moist convection could shut-down above some threshold abundance of these condensable species, this prediction is based on simple linear analysis and relies on strong assumptions on the saturation of the atmosphere. To investigate this issue, we develop a 3D cloud resolving model for H2 atmospheres with large amounts of condensable species and apply this model to a prototypical temperate Neptune-like planet -- K2-18b. Our model confirms the shut-down of moist convection and the onset of a stably stratified layer in the atmosphere, leading to much hotter deep atmospheres and interiors. Our 3D simulations further provide quantitative estimates of the turbulent mixing in this stable layer, which is a key driver of the cycling of condensables in the atmosphere. This allows us to build a very simple, yet realistic 1D model that captures the most salient features of the structure of Neptune-like atmospheres. Our qualitative findings on the behavior of moist convection in hydrogen atmospheres go beyond temperate planets and should also apply to the regions where iron and silicates condense in the deep interior of H2-dominated planets. Finally, we use our model to investigate the likelihood of a liquid ocean beneath a H2 dominated atmosphere on K2-18b. We find that the planet would need to have a very high albedo (>0.5-0.6) to sustain a liquid ocean. However, due to the spectral type of the star, the amount of aerosol scattering that would be needed to provide such a high albedo is inconsistent with the latest observational data.

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Jupiter Science Enabled by ESA's Jupiter Icy Moons Explorer

ESA's Jupiter Icy Moons Explorer (JUICE) will provide a detailed investigation of the Jovian system in the 2030s, combining a suite of state-of-the-art instruments with an orbital tour tailored to maximise observing opportunities. We review the Jupiter science enabled by the JUICE mission, building on the legacy of discoveries from the Galileo, Cassini, and Juno missions, alongside ground- and space-based observatories. We focus on remote sensing of the climate, meteorology, and chemistry of the atmosphere and auroras from the cloud-forming weather layer, through the upper troposphere, into the stratosphere and ionosphere. The Jupiter orbital tour provides a wealth of opportunities for atmospheric and auroral science: global perspectives with its near-equatorial and inclined phases, sampling all phase angles from dayside to nightside, and investigating phenomena evolving on timescales from minutes to months. The remote sensing payload spans far-UV spectroscopy (50-210 nm), visible imaging (340-1080 nm), visible/near-infrared spectroscopy (0.49-5.56 $μ$m), and sub-millimetre sounding (near 530-625\,GHz and 1067-1275\,GHz). This is coupled to radio, stellar, and solar occultation opportunities to explore the atmosphere at high vertical resolution; and radio and plasma wave measurements of electric discharges in the Jovian atmosphere and auroras. Cross-disciplinary scientific investigations enable JUICE to explore coupling processes in giant planet atmospheres, to show how the atmosphere is connected to (i) the deep circulation and composition of the hydrogen-dominated interior; and (ii) to the currents and charged particle environments of the external magnetosphere. JUICE will provide a comprehensive characterisation of the atmosphere and auroras of this archetypal giant planet.

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A subsolar oxygen abundance or a radiative region deep in Jupiter revealed by thermochemical modelling

Jupiter's deep abundances help to constrain the formation history of the planet and the environment of the protoplanetary nebula. Juno recently measured Jupiter's deep oxygen abundance near the equator to be 2.2$_{-2.1}^{+3.9}$ times the protosolar value (2$σ$ uncertainties). Even if the nominal value is supersolar, subsolar abundances cannot be ruled out. Here we use a state-of-the-art one-dimensional thermochemical and diffusion model with updated chemistry to constrain the deep oxygen abundance with upper tropospheric CO observations. We find a value of 0.3$_{-0.2}^{+0.5}$ times the protosolar value. This result suggests that Jupiter could have a carbon-rich envelope that accreted in a region where the protosolar nebula was depleted in water. However, our model can also reproduce a solar/supersolar water abundance if vertical mixing is reduced in a radiative layer where the deep oxygen abundance is obtained. More precise measurements of the deep water abundance are needed to discriminate between these two scenarios and understand Jupiter's internal structure and evolution.

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Doppler wind measurements in Neptune's stratosphere with ALMA

Neptune's tropospheric winds are among the most intense in the Solar System, but the dynamical mechanisms that produce them remain uncertain. Measuring wind speeds at different pressure levels may help understand the atmospheric dynamics of the planet. The goal of this work is to directly measure winds in Neptune's stratosphere with ALMA Doppler spectroscopy. We derived the Doppler lineshift maps of Neptune at the CO(3-2) and HCN(4-3) lines at 345.8 GHz ($λ$~0.87 mm) and 354.5 GHz (0.85 mm), respectively. For that, we used spectra obtained with ALMA in 2016 and recorded with a spatial resolution of ~0.37" on Neptune's 2.24" disk. After subtracting the planet solid rotation, we inferred the contribution of zonal winds to the measured Doppler lineshifts at the CO and HCN lines. We developed an MCMC-based retrieval methodology to constrain the latitudinal distribution of wind speeds. We find that CO(3-2) and HCN(4-3) lines probe the stratosphere of Neptune at pressures of $2^{+12}_{-1.8}$ mbar and $0.4^{+0.5}_{-0.3}$ mbar, respectively. The zonal winds at these altitudes are less intense than the tropospheric winds based on cloud tracking from Voyager observations. We find equatorial retrograde (westward) winds of $-180^{+70}_{-60}$ m/s for CO, and $-190^{+90}_{-70}$ m/s for HCN. Wind intensity decreases towards mid-latitudes, and wind speeds at 40$^\circ$S are $-90^{+50}_{-60}$ m/s for CO, and $-40^{+60}_{-80}$ m/s for HCN. Wind speeds become 0 m/s at about 50$^\circ$S, and we find that the circulation reverses to a prograde jet southwards of 60$^\circ$S. Overall, our direct stratospheric wind measurements match previous estimates from stellar occultation profiles and expectations based on thermal wind equilibrium. These are the first direct Doppler wind measurements performed on the Icy Giants, opening a new method to study and monitor their stratospheric dynamics.

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A high spatial and spectral resolution study of Jupiter's mid-infrared auroral emissions and their response to a solar wind compression

We present mid-infrared spectroscopy of Jupiter's mid-to-high latitudes using Gemini-North/TEXES (Texas Echelon Cross Echelle Spectrograph) on March 17-19, 2017. These observations capture Jupiter's hydrocarbon auroral emissions before, during and after the arrival of a solar wind compression on March 18th, which highlights the coupling between the polar stratosphere and external space environment. In comparing observations on March 17th and 19th, we observe a brightening of the CH$_4$, C$_2$H$_2$ and C$_2$H$_4$ emissions in regions spatially coincident with the northern, duskside main auroral emission (henceforth, MAE). In inverting the spectra to derive atmospheric information, we determine that the duskside brightening results from an upper stratospheric (p < 0.1 mbar/z > 200 km) heating (e.g. $ΔT$ = 9.1 $\pm$ 2.1 K at 9 $μ$bar at 67.5$^\circ$N, 162.5$^\circ$W) with negligible heating at deeper pressures. Our interpretation is that the arrival of the solar wind enhancement drove magnetospheric dynamics through compression and/or viscous interactions on the flank. These dynamics accelerated currents and/or generated higher Poynting fluxes, which ultimately warmed the atmosphere through Joule heating and ion-neutral collisions. Poleward of the southern MAE, temperature retrievals demonstrate that auroral-related heating penetrates as deep as the 10-mbar level, in contrast to poleward of the northern MAE, where heating is only observed as deep as $\sim$3 mbar. We suggest this results from the south having higher Pedersen conductivities, and therefore stronger currents and acceleration of the neutrals, as well as the poleward heating overlapping with the apex of Jupiter's circulation thereby inhibiting efficient horizontal mixing/advection.

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Ice Giant Systems: The Scientific Potential of Orbital Missions to Uranus and Neptune

Uranus and Neptune, and their diverse satellite and ring systems, represent the least explored environments of our Solar System, and yet may provide the archetype for the most common outcome of planetary formation throughout our galaxy. Ice Giants will be the last remaining class of Solar System planet to have a dedicated orbital explorer, and international efforts are under way to realise such an ambitious mission in the coming decades. In 2019, the European Space Agency released a call for scientific themes for its strategic science planning process for the 2030s and 2040s, known as Voyage 2050. We used this opportunity to review our present-day knowledge of the Uranus and Neptune systems, producing a revised and updated set of scientific questions and motivations for their exploration. This review article describes how such a mission could explore their origins, ice-rich interiors, dynamic atmospheres, unique magnetospheres, and myriad icy satellites, to address questions at the heart of modern planetary science. These two worlds are superb examples of how planets with shared origins can exhibit remarkably different evolutionary paths: Neptune as the archetype for Ice Giants, whereas Uranus may be atypical. Exploring Uranus' natural satellites and Neptune's captured moon Triton could reveal how Ocean Worlds form and remain active, redefining the extent of the habitable zone in our Solar System. For these reasons and more, we advocate that an Ice Giant System explorer should become a strategic cornerstone mission within ESA's Voyage 2050 programme, in partnership with international collaborators, and targeting launch opportunities in the early 2030s.

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The deep composition of Uranus and Neptune from in situ exploration and thermochemical modeling

The distant ice giants of the Solar System, Uranus and Neptune, have only been visited by one space mission, Voyager 2. The current knowledge on their composition remains very limited despite some recent advances. A better characterization of their composition is however essential to constrain their formation and evolution, as a significant fraction of their mass is made of heavy elements, contrary to the gas giants Jupiter and Saturn. An in situ probe like Galileo would provide us with invaluable direct ground-truth composition measurements. However, some of the condensibles will remain out of the grasp of a shallow probe. While additional constraints could be obtained from a complementary orbiter, thermochemistry and diffusion modeling can further help us to increase the science return of an in situ probe.

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