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Thomas E. O'Brien

Publications and source records attributed to Thomas E. O'Brien.

At least 19 recordsLinked to original sources
arXiv2026

Towards verifiable quantum advantage with random circuits: Observables that survive concentration

Demonstrating quantum advantage on current quantum hardware is a central goal of quantum computing, and random quantum circuits underpin many leading proposals. Yet sampling-based demonstrations are often difficult to verify, while observable-based approaches face a different challenge: concentration can suppress differences between circuit instances. Recent experiments have put forward the estimation of out-of-time-order correlators (OTOCs) in random circuits as a promising task for verifiable quantum advantage, yet whether their circuit-to-circuit fluctuations survive concentration as system size grows has remained open. Here we show that they do. For broad classes of local random circuits in any fixed spatial dimension, we prove inverse-polynomial fluctuations of fixed-order OTOCs at system-scale depths. In one-dimensional Haar-random brickwork circuits, we further show that macroscopically many gates contribute to these fluctuations, yet in each layer they remain confined to a sublinear-width region. As a byproduct, we develop a classical algorithm exhibiting the first rigorous improvement over brute-force classical simulation of OTOCs in 1D. Although classical hardness remains open, our results rule out strong concentration as an obstruction to OTOC-based proposals for verifiable quantum advantage.

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arXiv2026

Quantum error mitigation from information dynamics

Overcoming experimental errors is a central challenge in quantum science. This challenge is particularly acute in large and complex quantum circuits, where quantum information spreads into exponentially many paths, foiling any direct attempt to understand errors' impact. In this work, we present a novel approach to understanding and mitigating experimental errors, based on a surprisingly compact representation of a quantum circuit's information dynamics, the reactivity function. The shape of a circuit's reactivity function governs its noise response, and its amenability to different error mitigation methods. From this viewpoint, we introduce two complementary such methods. The first, Pauli-path zero-noise extrapolation, fits a parameterized model to a circuit's reactivity function and uses it to accurately extrapolate to zero noise. The second, tunable error cancellation, filters a circuit's reactivity function to cancel noise on all information up to a threshold locality. Crucially, both methods feature a tuning parameter that allows one to systematically improve their accuracy until convergence. Across three circuit families from published experiments, our methods overcome conventional zero-noise extrapolation biases as large as 30%; at $\sim$$10^{-2}$ root-mean-square error, they reduce sampling cost relative to probabilistic error cancellation by up to a factor of $10^3$.

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arXiv2026

Accurate ground state energy estimation with noise and imperfect state preparation

We introduce a classical estimator for the post-processing of quantum phase estimation (QPE) data when a single target phase is isolated within a known interval, as is typical of ground state energy estimation of gapped systems. Our estimator filters the QPE signal within this promise region and recovers the phase through a moment-projection routine, which is robust to both external spurious phases and experimental noise. In the noiseless case this achieves an exponential suppression of bias with respect to a naive mean estimator. In the presence of global depolarizing noise the bias is exponentially small in the circuit depth $t$, and the variance is $O(t^{-2}F^{-2})$ for circuit fidelity $F$. This improves by a factor of $t^2$ over a naive shifted-and-rescaled-mean approach. To mitigate realistic circuit-level noise, we combine our method with the explicit unbiasing scheme described in [Dutkiewicz et al., 2025]. This yields an overhead interpolating between the $F^{-4}$ scaling typical of explicitly unbiased error mitigation and a reduced $F^{-2}$ scaling when the noise samples fall outside the promise interval. We validate our estimators on a small-scale simulation of the Ising model, observing better-than-expected performance for a global depolarizing noise approximation. This robustness to both multiple eigenvalues and realistic noise makes limited-depth phase estimation practical for early fault tolerant quantum experiments.

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arXiv2026

When is randomization advantageous in quantum simulation?

We study the regimes in which Hamiltonian simulation benefits from randomization. We introduce a sparse-QSVT construction based on composite stochastic decompositions, where dominant terms are treated deterministically and smaller contributions are sampled stochastically. Crucially, we analyze how stochastic and approximation errors propagate through block-encoding and QSVT procedures. To benchmark this approach, we construct ensembles of random Hamiltonians with controlled coefficient dispersion, locality, and number of terms, designed to favor randomization, and therefore providing an upper bound on its practical advantage. For Hamiltonians with many terms and highly inhomogeneous coefficient distributions, randomized methods reduce gate counts by up to an order of magnitude. However, this advantage is confined to moderate-precision regimes: as the target error decreases, deterministic methods become more efficient, with a crossover near $\varepsilon \sim 10^{-3}$. Although this regime partially overlaps with quantum chemistry Hamiltonians, realistic systems exhibit additional structure, such as commutation patterns, not captured by our model, which are expected to further favor deterministic approaches.

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arXiv2025

A simplified version of the quantum OTOC$^{(2)}$ problem

This note presents a simplified version of the OTOC$^{(2)}$ problem that was recently experimentally implemented by Google Quantum AI and collaborators. We present a formulation of the problem for growing input size and hope this spurs further theoretical work on the problem.

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arXiv2025

Error mitigation and circuit division for early fault-tolerant quantum phase estimation

As fully fault-tolerant quantum computers capable of solving useful problems remain a distant goal, we anticipate an era of "early fault tolerance" where limited error correction is available. We propose a framework for designing early fault-tolerant algorithms by trading between error correction overhead and residual logical noise, and apply it to quantum phase estimation (QPE). We develop a quantum-Fourier-transform (QFT)-based QPE technique that is robust to global depolarising noise and outperforms the previous state of the art at low and moderate noise rates. We further introduce the Explicitly Unbiased Maximum Likelihood Estimation (EUMLE), a data processing technique that mitigates arbitrary errors in QFT-based QPE schemes. EUMLE provides consistent, asymptotically normal error-mitigated estimates, addressing the open problem of extending error mitigation beyond expectation value estimation. Applying this scheme to the ground state problem of the two-dimensional Hubbard model and various molecular Hamiltonians, we find we can roughly halve the number of physical qubits with a $\sim 10\times$ wall-clock time overhead, but further reduction causes a steep runtime increase. This work provides an end-to-end analysis of early fault-tolerance cost reductions and space-time trade-offs, and identifies which areas can be improved in the future.

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arXiv2024

The advantage of quantum control in many-body Hamiltonian learning

We study the problem of learning the Hamiltonian of a many-body quantum system from experimental data. We show that the rate of learning depends on the amount of control available during the experiment. We consider three control models: one where time evolution can be augmented with instantaneous quantum operations, one where the Hamiltonian itself can be augmented by adding constant terms, and one where the experimentalist has no control over the system's time evolution. With continuous quantum control, we provide an adaptive algorithm for learning a many-body Hamiltonian at the Heisenberg limit: $T = \mathcal{O}(ε^{-1})$, where $T$ is the total amount of time evolution across all experiments and $ε$ is the target precision. This requires only preparation of product states, time-evolution, and measurement in a product basis. In the absence of quantum control, we prove that learning is standard quantum limited, $T = Ω(ε^{-2})$, for large classes of many-body Hamiltonians, including any Hamiltonian that thermalizes via the eigenstate thermalization hypothesis. These results establish a quadratic advantage in experimental runtime for learning with quantum control.

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arXiv2024

A hybrid quantum algorithm to detect conical intersections

Conical intersections are topologically protected crossings between the potential energy surfaces of a molecular Hamiltonian, known to play an important role in chemical processes such as photoisomerization and non-radiative relaxation. They are characterized by a non-zero Berry phase, which is a topological invariant defined on a closed path in atomic coordinate space, taking the value $π$ when the path encircles the intersection manifold. In this work, we show that for real molecular Hamiltonians, the Berry phase can be obtained by tracing a local optimum of a variational ansatz along the chosen path and estimating the overlap between the initial and final state with a control-free Hadamard test. Moreover, by discretizing the path into $N$ points, we can use $N$ single Newton-Raphson steps to update our state non-variationally. Finally, since the Berry phase can only take two discrete values (0 or $π$), our procedure succeeds even for a cumulative error bounded by a constant; this allows us to bound the total sampling cost and to readily verify the success of the procedure. We demonstrate numerically the application of our algorithm on small toy models of the formaldimine molecule (\ce{H2C=NH}).

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arXiv2023

Quantum Error Mitigation

For quantum computers to successfully solve real-world problems, it is necessary to tackle the challenge of noise: the errors which occur in elementary physical components due to unwanted or imperfect interactions. The theory of quantum fault tolerance can provide an answer in the long term, but in the coming era of `NISQ' machines we must seek to mitigate errors rather than completely remove them. This review surveys the diverse methods that have been proposed for quantum error mitigation, assesses their in-principle efficacy, and then describes the hardware demonstrations achieved to date. We identify the commonalities and limitations among the methods, noting how mitigation methods can be chosen according to the primary type of noise present, including algorithmic errors. Open problems in the field are identified and we discuss the prospects for realising mitigation-based devices that can deliver quantum advantage with an impact on science and business.

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arXiv2023

Compilation of product-formula Hamiltonian simulation via reinforcement learning

Hamiltonian simulation is believed to be one of the first tasks where quantum computers can yield a quantum advantage. One of the most popular methods of Hamiltonian simulation is Trotterization, which makes use of the approximation $e^{i\sum_jA_j}\sim \prod_je^{iA_j}$ and higher-order corrections thereto. However, this leaves open the question of the order of operations (i.e. the order of the product over $j$, which is known to affect the quality of approximation). In some cases this order is fixed by the desire to minimise the error of approximation; when it is not the case, we propose that the order can be chosen to optimize compilation to a native quantum architecture. This presents a new compilation problem -- order-agnostic quantum circuit compilation -- which we prove is NP-hard in the worst case. In lieu of an easily-computable exact solution, we turn to methods of heuristic optimization of compilation. We focus on reinforcement learning due to the sequential nature of the compilation task, comparing it to simulated annealing and Monte Carlo tree search. While two of the methods outperform a naive heuristic, reinforcement learning clearly outperforms all others, with a gain of around 12% with respect to the second-best method and of around 50% compared to the naive heuristic in terms of the gate count. We further test the ability of RL to generalize across instances of the compilation problem, and find that a single learner is able to solve entire problem families. This demonstrates the ability of machine learning techniques to provide assistance in an order-agnostic quantum compilation task.

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arXiv2023

Optimizing the information extracted by a single qubit measurement

We consider a quantum computation that only extracts one bit of information per $N$-qubit quantum state preparation. This is relevant for error mitigation schemes where the remainder of the system is measured to detect errors. We optimize the estimation of the expectation value of an operator by its linear decomposition into bitwise-measurable terms. We prove that optimal decompositions must be in terms of reflections with eigenvalues $\pm1$. We find the optimal reflection decomposition of a fast-forwardable operator, and show a numerical improvement over a simple Pauli decomposition by a factor $N^{0.7}$

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arXiv2023

Quantum digital cooling

We introduce a method for digital preparation of ground states of simulated Hamiltonians, inspired by cooling in nature and adapted to leverage the capabilities of digital quantum hardware. The cold bath is simulated by a single ancillary qubit, which is reset periodically and coupled to the system non-perturbatively. Studying this cooling method on a 1-qubit system toy model, we optimize two cooling protocols based on weak-coupling and strong-coupling approaches. Extending the insight from the 1-qubit system model, we develop two scalable protocols for larger systems. The LogSweep protocol extends the weak-coupling approach by sweeping energies to resonantly match any targeted transition. We test LogSweep on the 1D tranverse-field Ising model, demonstrating approximate ground state preparation with an error that can be made polynomially small in the computation time for all three phases of the system. The BangBang protocol extends the strong-coupling approach, and exploits a heuristics for local Hamiltonians to maximise the probability of de-exciting system transitions in the shortest possible time. Although this protocol does not promise long-time convergence, it allows for a rapid cooling to an approximation of the ground state, making this protocol appealing for near-term demonstrations.

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arXiv2023

Simulating prethermalization using near-term quantum computers

Quantum simulation is one of the most promising scientific applications of quantum computers. Due to decoherence and noise in current devices, it is however challenging to perform digital quantum simulation in a regime that is intractable with classical computers. In this work, we propose an experimental protocol for probing dynamics and equilibrium properties on near-term digital quantum computers. As a key ingredient of our work, we show that it is possible to study thermalization even with a relatively coarse Trotter decomposition of the Hamiltonian evolution of interest. Even though the step size is too large to permit a rigorous bound on the Trotter error, we observe that the system prethermalizes in accordance with previous results for Floquet systems. The dynamics closely resemble the thermalization of the model underlying the Trotterization up to long times. We extend the reach of our approach by developing an error mitigation scheme based on measurement and rescaling of survival probabilities. To demonstrate the effectiveness of the entire protocol, we apply it to the two-dimensional XY model and numerically verify its performance with realistic noise parameters for superconducting quantum devices. Our proposal thus provides a route to achieving quantum advantage for relevant problems in condensed matter physics.

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arXiv2023

Performance comparison of optimization methods on variational quantum algorithms

Variational quantum algorithms (VQAs) offer a promising path toward using near-term quantum hardware for applications in academic and industrial research. These algorithms aim to find approximate solutions to quantum problems by optimizing a parametrized quantum circuit using a classical optimization algorithm. A successful VQA requires fast and reliable classical optimization algorithms. Understanding and optimizing how off-the-shelf optimization methods perform in this context is important for the future of the field. In this work, we study the performance of four commonly used gradient-free optimization methods: SLSQP, COBYLA, CMA-ES, and SPSA, at finding ground-state energies of a range of small chemistry and material science problems. We test a telescoping sampling scheme (where the accuracy of the cost-function estimate provided to the optimizer is increased as the optimization converges) on all methods, demonstrating mixed results across our range of optimizers and problems chosen. We further hyperparameter tune two of the four optimizers (CMA-ES and SPSA) across a large range of models and demonstrate that with appropriate hyperparameter tuning, CMA-ES is competitive with and sometimes outperforms SPSA (which is not observed in the absence of hyperparameter tuning). Finally, we investigate the ability of an optimizer to beat the `sampling noise floor' given by the sampling noise on each cost-function estimate provided to the optimizer. Our results demonstrate the necessity for tailoring and hyperparameter-tuning known optimization techniques for inherently-noisy variational quantum algorithms and that the variational landscape that one finds in a VQA is highly problem- and system-dependent. This provides guidance for future implementations of these algorithms in the experiment.

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arXiv2022

Noise-resilient Edge Modes on a Chain of Superconducting Qubits

Inherent symmetry of a quantum system may protect its otherwise fragile states. Leveraging such protection requires testing its robustness against uncontrolled environmental interactions. Using 47 superconducting qubits, we implement the one-dimensional kicked Ising model which exhibits non-local Majorana edge modes (MEMs) with $\mathbb{Z}_2$ parity symmetry. Remarkably, we find that any multi-qubit Pauli operator overlapping with the MEMs exhibits a uniform late-time decay rate comparable to single-qubit relaxation rates, irrespective of its size or composition. This characteristic allows us to accurately reconstruct the exponentially localized spatial profiles of the MEMs. Furthermore, the MEMs are found to be resilient against certain symmetry-breaking noise owing to a prethermalization mechanism. Our work elucidates the complex interplay between noise and symmetry-protected edge modes in a solid-state environment.

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arXiv2022

Nearly Optimal Quantum Algorithm for Estimating Multiple Expectation Values

Many quantum algorithms involve the evaluation of expectation values. Optimal strategies for estimating a single expectation value are known, requiring a number of state preparations that scales with the target error $\varepsilon$ as $\mathcal{O}(1/\varepsilon)$. In this paper, we address the task of estimating the expectation values of $M$ different observables, each to within additive error $\varepsilon$, with the same $1/\varepsilon$ dependence. We describe an approach that leverages Gilyén et al.'s quantum gradient estimation algorithm to achieve $\mathcal{O}(\sqrt{M}/\varepsilon)$ scaling up to logarithmic factors, regardless of the commutation properties of the $M$ observables. We prove that this scaling is worst-case optimal in the high-precision regime if the state preparation is treated as a black box, even when the operators are mutually commuting. We highlight the flexibility of our approach by presenting several generalizations, including a strategy for accelerating the estimation of a collection of dynamic correlation functions.

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arXiv2022

Heisenberg-limited quantum phase estimation of multiple eigenvalues with few control qubits

Quantum phase estimation is a cornerstone in quantum algorithm design, allowing for the inference of eigenvalues of exponentially-large sparse matrices.The maximum rate at which these eigenvalues may be learned, --known as the Heisenberg limit--, is constrained by bounds on the circuit complexity required to simulate an arbitrary Hamiltonian. Single-control qubit variants of quantum phase estimation that do not require coherence between experiments have garnered interest in recent years due to lower circuit depth and minimal qubit overhead. In this work we show that these methods can achieve the Heisenberg limit, {\em also} when one is unable to prepare eigenstates of the system. Given a quantum subroutine which provides samples of a `phase function' $g(k)=\sum_j A_j e^{i ϕ_j k}$ with unknown eigenphases $ϕ_j$ and overlaps $A_j$ at quantum cost $O(k)$, we show how to estimate the phases $\{ϕ_j\}$ with (root-mean-square) error $δ$ for total quantum cost $T=O(δ^{-1})$. Our scheme combines the idea of Heisenberg-limited multi-order quantum phase estimation for a single eigenvalue phase [Higgins et al (2009) and Kimmel et al (2015)] with subroutines with so-called dense quantum phase estimation which uses classical processing via time-series analysis for the QEEP problem [Somma (2019)] or the matrix pencil method. For our algorithm which adaptively fixes the choice for $k$ in $g(k)$ we prove Heisenberg-limited scaling when we use the time-series/QEEP subroutine. We present numerical evidence that using the matrix pencil technique the algorithm can achieve Heisenberg-limited scaling as well.

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arXiv2022

Simulating groundstate and dynamical quantum phase transitions on a superconducting quantum computer

We optimise a translationally invariant, sequential quantum circuit on a superconducting quantum device to simulate the groundstate of the quantum Ising model through its quantum critical point. We further demonstrate how the dynamical quantum critical point found in quenches of this model across its quantum critical point can be simulated. Our approach avoids finite-size scaling effects by using sequential quantum circuits inspired by infinite matrix product states. We provide efficient circuits and a variety of error mitigation strategies to implement, optimise and time-evolve these states.

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