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Thomas Masseron

Publications and source records attributed to Thomas Masseron.

At least 37 records · Page 2Linked to original sources

Unveiling the chemical fingerprint of phosphorus-rich stars I. In the infrared region of APOGEE-2

The origin of phosphorus, one of the essential elements for life on Earth, is currently unknown. Prevalent models of Galactic chemical evolution (GCE) underestimate the amount of P compared to observations. The recently discovered P-rich ([P/Fe] > 1 dex) and metal-poor giants further challenge current theories on stellar nucleosynthesis. Since the observed stars are low-mass giants, our primary goal is to find clues on their progenitor. By increasing the number of known P-rich stars, we aim to narrow down a reliable chemical abundance pattern and to place robust constraints on the responsible nucleosynthetic mechanism. In the long term, identifying the progenitor of the P-rich stars may contribute to the search for the source of P in our Galaxy. We performed a detailed chemical abundance analysis based on the H-band spectra from APOGEE-2 (DR17). Employing the BACCHUS code, we measured the abundances of 13 elements in the sample, which is mainly composed of a recent collection of Si-enhanced giants. We also analyzed the orbital motions and compared the abundance results to possible nucleosynthetic formation scenarios, and also to detailed GCE models. We enlarged the sample of confirmed P-rich stars from 16 to 78 giants, which represents the largest sample of P-rich stars to date. Significant enhancements in O, Al, Si and Ce, as well as systematic correlations among the elements, unveil the chemical fingerprint of the P-rich stars. The high Mg and C+N found in some of the P-rich stars with respect to P-normal stars is not confirmed over the full sample. Strikingly, the strong over-abundance in the $α$-element Si is accompanied by normal Ca and S abundances. Our analysis of the orbital motion showed that the P-rich stars do not belong to a specific sub-population. In addition, we confirm that the majority of the sample stars are not part of binary systems.

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StarHorse results for spectroscopic surveys + Gaia DR3: Chrono-chemical populations in the solar vicinity, the genuine thick disk, and young-alpha rich stars

The Gaia mission has provided an invaluable wealth of astrometric data for more than a billion stars in our Galaxy. The synergy between Gaia astrometry, photometry, and spectroscopic surveys give us comprehensive information about the Milky Way. Using the Bayesian isochrone-fitting code StarHorse, we derive distances and extinctions for more than 10 million unique stars observed by both Gaia Data Release 3 as well as public spectroscopic surveys: GALAH DR3, LAMOST DR7 LRS, LAMOST DR7 MRS, APOGEE DR17, RAVE DR6, SDSS DR12 (optical spectra from BOSS and SEGUE), Gaia-ESO DR5 survey, and Gaia RVS part of Gaia DR3 release. We use StarHorse for the first time to derive stellar age for main-sequence turnoff and subgiant branch stars (MSTO-SGB), around 2.5 million stars with age uncertainties typically around 30%, 15% for only SGB stars, depending on the resolution of the survey. With the derived ages in hand, we investigate the chemical-age relations. In particular, the $α$ and neutron-capture element ratios versus age in the solar neighbourhood show trends similar to previous works, validating our ages. We use the chemical abundances from local subgiant samples of GALAH DR3, APOGEE DR17 and LAMOST MRS DR7 to map groups with similar chemical compositions and StarHorse ages with the dimensionality reduction technique t-SNE and the clustering algorithm HDBSCAN. We identify three distinct groups in all three samples. Their kinematic properties confirm them to be the genuine chemical thick disk, the thin disk and a considerable number of young alpha-rich stars. We confirm that the genuine thick disk's kinematics and age properties are radically different from those of the thin disk and compatible with high-redshift (z$\approx$2) star-forming disks with high dispersion velocities.

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BACCHUS Analysis of Weak Lines in APOGEE Spectra (BAWLAS)

Elements with weak and blended spectral features in stellar spectra are challenging to measure and require specialized analysis methods to precisely measure their chemical abundances. In this work, we have created a catalog of approximately 120,000 giants with high signal-to-noise APOGEE DR17 spectra, for which we explore weak and blended species to measure Na, P, S, V, Cu, Ce, and Nd abundances and $^{12}$C/$^{13}$C isotopic ratios. We employ an updated version of the BACCHUS (Brussels Automatic Code for Characterizing High accUracy Spectra) code to derive these abundances using the stellar parameters measured by APOGEE's DR17 ASPCAP pipeline, quality flagging to identify suspect spectral lines, and a prescription for upper limits. Combined these allow us to provide our BACCHUS Analysis of Weak Lines in APOGEE Spectra (BAWLAS) catalog of precise chemical abundances for these weak and blended species that agrees well with literature and improves upon APOGEE abundances for these elements, some of which are unable to be measured with APOGEE's current, grid-based approach without computationally expensive expansions. This new catalog can be used alongside APOGEE and provide measurements for many scientific applications ranging from nuclear physics to Galactic chemical evolution and Milky Way population studies. To illustrate this we show some examples of uses for this catalog, such as, showing that we observe stars with enhanced s-process abundances or that we can use the our $^{12}$C/$^{13}$C ratios to explore extra mixing along the red giant branch.

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The TESS-Keck Survey. XI. Mass Measurements for Four Transiting sub-Neptunes orbiting K dwarf TOI-1246

Multi-planet systems are valuable arenas for investigating exoplanet architectures and comparing planetary siblings. TOI-1246 is one such system, with a moderately bright K dwarf ($\rm{V=11.6,~K=9.9}$) and four transiting sub-Neptunes identified by TESS with orbital periods of $4.31~\rm{d},~5.90~\rm{d},~18.66~\rm{d}$, and $~37.92~\rm{d}$. We collected 130 radial velocity observations with Keck/HIRES and TNG/HARPS-N to measure planet masses. We refit the 14 sectors of TESS photometry to refine planet radii ($\rm{2.97 \pm 0.06~R_\oplus},\rm{2.47 \pm 0.08~R_\oplus}, \rm{3.46 \pm 0.09~R_\oplus}$, $\rm{3.72 \pm 0.16~R_\oplus}$), and confirm the four planets. We find that TOI-1246 e is substantially more massive than the three inner planets ($\rm{8.1 \pm 1.1 M_\oplus}$, $\rm{8.8 \pm 1.2 M_\oplus}$, $\rm{5.3 \pm 1.7 M_\oplus}$, $\rm{14.8 \pm 2.3 M_\oplus}$). The two outer planets, TOI-1246 d and TOI-1246 e, lie near to the 2:1 resonance ($\rm{P_{e}/P_{d}=2.03}$) and exhibit transit timing variations. TOI-1246 is one of the brightest four-planet systems, making it amenable for continued observations. It is one of only six systems with measured masses and radii for all four transiting planets. The planet densities range from $\rm{0.70 \pm 0.24}$ to $3.21 \pm 0.44 \rm{g/cm^3}$, implying a range of bulk and atmospheric compositions. We also report a fifth planet candidate found in the RV data with a minimum mass of 25.6 $\pm$ 3.6 $\rm{M_\oplus}$. This planet candidate is exterior to TOI-1246 e with a candidate period of 93.8 d, and we discuss the implications if it is confirmed to be planetary in nature.

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Estimation of Nitrogen-to-Iron Abundance Ratios From Low-Resolution Spectra

We present a method to determine nitrogen abundance ratios with respect to iron ([N/Fe]) from molecular CN-band features observed in low-resolution ($R \sim$ 2000) stellar spectra obtained by the Sloan Digital Sky Survey (SDSS) and the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST). Various tests are carried out to check the systematic and random errors of our technique, and the impact of signal-to-noise (S/N) ratios of stellar spectra on the determined [N/Fe]. We find that the uncertainty of our derived [N/Fe] is less than 0.3 dex for S/N ratios larger than 10 in the ranges $T_{eff}$ = [4000, 6000] K, log g = [0.0, 3.5], [Fe/H] = [--3.0, 0.0], [C/Fe] = [--1.0, +4.5], and [N/Fe] = [--1.0, +4.5], the parameter space that we are interested in to identify N-enhanced stars in the Galactic halo. A star-by-star comparison with a sample of stars with [N/Fe] estimates available from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) also suggests a similar level of uncertainty in our measured [N/Fe], after removing its systematic error. Based on these results, we conclude that our method is able to reproduce [N/Fe] from low-resolution spectroscopic data, with an uncertainty sufficiently small to discover N-rich stars that presumably originated from disrupted Galactic globular clusters.

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Detailed Chemical Abundances for a Benchmark Sample of M Dwarfs from the APOGEE Survey

Individual chemical abundances for fourteen elements (C, O, Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, and Ni) are derived for a sample of M-dwarfs using high-resolution near-infrared $H$-band spectra from the SDSS-IV/APOGEE survey. The quantitative analysis included synthetic spectra computed with 1-D LTE plane-parallel MARCS models using the APOGEE DR17 line list to determine chemical abundances. The sample consists of eleven M-dwarfs in binary systems with warmer FGK-dwarf primaries and ten measured interferometric angular diameters. To minimize atomic diffusion effects, [X/Fe] ratios are used to compare M-dwarfs in binary systems and literature results for their warmer primary stars, indicating good agreement ($<$0.08 dex) for all studied elements. The mean abundance differences in Primaries-this work M-dwarfs is -0.05$\pm$0.03 dex. It indicates that M-dwarfs in binary systems are a reliable way to calibrate empirical relationships. A comparison with abundance, effective temperature, and surface gravity results from the ASPCAP pipeline (DR16) finds a systematic offset of [M/H], $T_{\rm eff}$, log$g$ = +0.21 dex, -50 K, and 0.30 dex, respectively, although ASPCAP [X/Fe] ratios are generally consistent with this study. The metallicities of the M dwarfs cover the range of [Fe/H] = -0.9 to +0.4 and are used to investigate Galactic chemical evolution via trends of [X/Fe] as a function of [Fe/H]. The behavior of the various elemental abundances [X/Fe] versus [Fe/H] agrees well with the corresponding trends derived from warmer FGK-dwarfs, demonstrating that the APOGEE spectra can be used to Galactic chemical evolution using large samples of selected M-dwarfs.

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Ammonia-methane ratios from H-band near-infrared spectra of late-T and Y dwarfs

Gas cells containing ammonia and methane at atmospheric pressure were custom-made in our chemical laboratory. Low-resolution near-infrared spectroscopy of these gas cells were collected in our optical laboratory. They are compared with simulated spectra using the high-resolution transmission molecular absorption database (HITRAN) for temperatures of 300 K and 500 K, and with near-infrared spectra of late-T and Y dwarfs, Jupiter and Saturn. We selected for this investigation the spectral region between 1.5 and 1.7 microns (H-band) because it is covered by the Euclid red grism, it is particularly sensitive to the relative proportions of ammonia and methane opacity, and it is free from strong contributions of other abundant molecules such as water vapour. The laboratory spectra showed that the ammonia and methane features that are present in the simulations using the HITRAN database are incomplete. Using our laboratory spectra, we propose a modified version of the NH3-H spectral ratio with expanded integration limits that increases the amplitude of variation of the index with respect to spectral type. Combinations of our laboratory spectra were used to find the best fits to the observed spectra with the relative absorption ratio of ammonia to methane as a free parameter. A relationship was found between the T$\rm_{eff}$ and the ratio of ammonia to methane from spectral classes T5 to Y2 (1100 K -- 350 K), in qualitative fairly good agreement with theoretical predictions for high gravity objects and temperatures from 1100 K to 500 K. The ammonia to methane ratios in late-T and Y dwarfs are similar to that of Jupiter, suggesting a similar chemical composition. Simulations of the spectroscopic performance of Euclid suggest that it will yield T$\rm_{eff}$ values and ratios of ammonia to methane for over 10$^3$ late T dwarfs in the whole wide survey.

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Homogeneous Analysis of Globular Clusters from the APOGEE Survey with the BACCHUS Code $-$ III. $ω$ Cen

We study the multiple populations of $ω$ Cen by using the abundances of Fe, C, N, O, Mg, Al, Si, K, Ca, and Ce from the high-resolution, high signal-to-noise (S/N$>$70) spectra of 982 red giant stars observed by the SDSS-IV/APOGEE-2 survey. We find that the shape of the Al-Mg and N-C anticorrelations changes as a function of metallicity, continuous for the metal-poor groups, but bimodal (or unimodal) at high metallicities. There are four Fe populations, similar to what has been found in previously published investigations, but we find seven populations based on Fe, Al, and Mg abundances. The evolution of Al in $ω$ Cen is compared to its evolution in the Milky Way and in five representative globular clusters. We find that the distribution of Al in metal-rich stars of $ω$ Cen closely follows what is observed in the Galaxy. Other $α-$elements and C, N, O, and Ce are also compared to the Milky Way, and significantly elevated abundances are observed over what is found in the thick disk for almost all elements. However, we also find some stars with high metallicity and low [Al/Fe], suggesting that $ω$ Cen could be the remnant core of a dwarf galaxy, but the existence of these peculiar stars needs an independent confirmation. We also confirm the increase in the sum of CNO as a function of metallicity previously reported in the literature and find that the [C/N] ratio appears to show opposite correlations between Al-poor and Al-rich stars as a function of metallicity.

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The APOGEE Data Release 16 Spectral Line List

The updated H-band spectral line list (from λ15,000 - 17,000Å) adopted by the Apache Point Observatory Galactic Evolution Experiment (APOGEE) for the SDSS IV Data Release 16 (DR16) is presented here. The APOGEE line list is a combination of atomic and molecular lines with data from laboratory, theoretical, and astrophysical sources. Oscillator strengths and damping constants are adjusted using high signal-to-noise, high-resolution spectra of the Sun and alpha Boo (Arcturus) as "standard stars". Updates to the DR16 line list, when compared to the previous DR14 version, are the inclusion of molecular H_2O and FeH lines, as well as a much larger (by a factor of ~4) atomic line list, which includes significantly more transitions with hyperfine splitting. More recent references and line lists for the crucial molecules CO and OH were used, as well as for C_2 and SiH. In contrast to DR14, DR16 contains measurable lines from the heavy neutron-capture elements cerium (as Ce II), neodymium (as Nd II), and ytterbium (as Yb II), as well as one line from rubidium (as Rb I), that may be detectable in a small fraction of APOGEE red giants.

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Atomic data for the Gaia-ESO Survey

We describe the atomic and molecular data that were used for the abundance analyses of FGK-type stars carried out within the Gaia-ESO Survey. We present an unprecedented effort to create a homogeneous line list, which was used by several abundance analysis groups to calculate synthetic spectra and equivalent widths. The atomic data are accompanied by quality indicators and detailed references to the sources. The atomic and molecular data are made publicly available in electronic form. In general experimental transition probabilities were preferred but theoretical values were also used. Astrophysical gf-values were avoided due to the model-dependence of such a procedure. For elements whose lines are significantly affected by hyperfine structure or isotopic splitting a concerted effort has been made to collate the necessary data for the individual line components. We also performed a detailed investigation of available data for line broadening due to collisions with neutral hydrogen atoms. Synthetic spectra calculated for the Sun and Arcturus were used to assess the blending properties of the lines. Among a subset of over 1300 lines of 35 elements in the wavelength ranges from 475 nm to 685 nm and from 850 nm to 895 nm we identified about 200 lines of 24 species which have accurate gf-values and are free of blends in the spectra of the Sun and Arcturus. For the broadening due to collisions with neutral hydrogen we recommend data based on Anstee-Barklem-O'Mara theory, where available, and to avoid lines of neutral species otherwise. Theoretical broadening data by R.L. Kurucz should be used for Sc II, Ti II, and Y II lines. For ionised rare-earth species the Unsöld approximation with an enhancement factor of 1.5 for the line width can be used. Desirable improvements in atomic data were identified for a number of species, including Al I, S I, Cr II, Na I, Si I, Ca II, and Ni I.

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Characterizing the companion AGBs using surface chemical composition of barium stars

Barium stars are one of the important probes to understand the origin and evolution of slow neutron-capture process elements in the Galaxy. These are extrinsic stars, where the observed s-process element abundances are believed to have an origin in the now invisible companions that produced these elements at their Asymptotic Giant Branch phase of evolution. We have attempted to understand the s-process nucleosynthesis, as well as the physical properties of the companion stars through a detailed comparison of observed elemental abundances of 10 barium stars with the predictions from AGB nucleosynthesis models, FRUITY. For these stars, we have presented estimates of abundances of several elements, C, N, O, Na, Al, $α$-elements, Fe-peak elements and neutron-capture elements Rb, Sr, Y, Zr, Ba, La, Ce, Pr, Nd, Sm and Eu. The abundance estimates are based on high resolution spectral analysis. Observations of Rb in four of these stars have allowed us to put a limit to the mass of the companion AGB stars. Our analysis clearly shows that the former companions responsible for the surface abundance peculiarities of these stars are low-mass AGB stars. Kinematic analysis have shown the stars to be members of Galactic disk population.

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APOGEE Data and Spectral Analysis from SDSS Data Release 16: Seven Years of Observations Including First Results from APOGEE-South

The spectral analysis and data products in Data Release 16 (DR16; December 2019) from the high-resolution near-infrared APOGEE-2/SDSS-IV survey are described. Compared to the previous APOGEE data release (DR14; July 2017), APOGEE DR16 includes about 200000 new stellar spectra, of which 100000 are from a new southern APOGEE instrument mounted on the 2.5 m du Pont telescope at Las Campanas Observatory in Chile. DR16 includes all data taken up to August 2018, including data released in previous data releases. All of the data have been re-reduced and re-analyzed using the latest pipelines, resulting in a total of 473307 spectra of 437445 stars. Changes to the analysis methods for this release include, but are not limited to, the use of MARCS model atmospheres for calculation of the entire main grid of synthetic spectra used in the analysis, a new method for filling "holes" in the grids due to unconverged model atmospheres, and a new scheme for continuum normalization. Abundances of the neutron capture element Ce are included for the first time. A new scheme for estimating uncertainties of the derived quantities using stars with multiple observations has been applied, and calibrated values of surface gravities for dwarf stars are now supplied. Compared to DR14, the radial velocities derived for this release more closely match those in the Gaia DR2 data base, and a clear improvement in the spectral analysis of the coolest giants can be seen. The reduced spectra as well as the result of the analysis can be downloaded using links provided in the SDSS DR16 web page.

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Assessing Spectra and Thermal Inversions due to TiO in Hot Jupiter Atmospheres

Recent detections of thermal inversions in the dayside atmospheres of some hot Jupiters are motivating new avenues to understand the interplay between their temperature structures and other atmospheric conditions. In particular, TiO has long been proposed to cause thermal inversions in hot Jupiters, depending on other factors such as stellar irradiation, C/O, and vertical mixing. TiO also has spectral features in the optical and near-infrared that have been detected. However, interpretations of TiO signatures rely on the accuracy of TiO opacity used in the models. The recently reported Toto TiO line list provides a new opportunity to investigate these dependencies, which is the goal of the present work. First, we investigate how the Toto line list affects observable transmission and emission spectra of hot Jupiters at low and high resolution. The improvement in the Toto line list compared to a previous line list results in observable differences in the model spectra, particularly in the optical at high resolution. Secondly, we explore the interplay between temperature structure, irradiation and composition with TiO as the primary source of optical opacity, using 1D self-consistent atmospheric models. Among other trends, we find that the propensity for thermal inversions due to TiO peaks at C/O$\sim$0.9, consistent with recent studies. Using these models, we further assess metrics to quantify thermal inversions due to TiO, compared to frequently-used Spitzer photometry, over a range in C/O, irradiation, metallicity, gravity and stellar type.

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Homogeneous Analysis of Globular Clusters from the APOGEE Survey with the BACCHUS Code. II. The Southern Clusters and Overview

We investigate the Fe, C, N, O, Mg, Al, Si, K, Ca, Ce and Nd abundances of 2283 red giant stars in 31 globular clusters from high-resolution spectra observed in both the northern and southern hemisphere by the SDSS-IV APOGEE-2 survey. This unprecedented homogeneous dataset, largest to date, allows us to discuss the intrinsic Fe spread, the shape and statistics of Al-Mg and N-C anticorrelations as a function of cluster mass, luminosity, age and metallicity for all 31 clusters. We find that the Fe spread does not depend on these parameters within our uncertainties including cluster metallicity, contradicting earlier observations. We do not confirm the metallicity variations previously observed in M22 and NGC 1851. Some clusters show a bimodal Al distribution, while others exhibit a continuous distribution as has been previously reported in the literature. We confirm more than 2 populations in $ω$ Cen and NGC 6752, and find new ones in M79. We discuss the scatter of Al by implementing a correction to the standard chemical evolution of Al in the Milky Way. After correction, its dependence on cluster mass is increased suggesting that the extent of Al enrichment as a function of mass was suppressed before the correction. We observe a turnover in the Mg-Al anticorrelation at very low Mg in $ω$ Cen, similar to the pattern previously reported in M15 and M92. $ω$ Cen may also have a weak K-Mg anticorrelation, and if confirmed, it would be only the third cluster known to show such a pattern.

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Identification of a Group III CEMP-no Star in the Dwarf Spheroidal Galaxy Canes Venatici I

CEMP-no stars, a subclass of carbon-enhanced metal-poor (CEMP) stars, are one of the most significant stellar populations in Galactic Archaeology, because they dominate the low end of the metallicity distribution function, providing information on the early star-formation and chemical-evolution history of the Milky Way and its satellite galaxies. Here we present an analysis of medium-resolution ($R \sim 1,800$) optical spectroscopy for a CEMP giant, SDSS J132755.56+333521.7, observed with the Large Binocular Telescope (LBT), one of the brightest ($g \sim 20.5$) members of the classical dwarf spheroidal galaxy, Canes Venatici I (CVn I). Many CEMP stars discovered to date have very cool effective temperatures ($T_{\mathrm{eff}}< 4500$ K), resulting in strong veiling by molecular carbon bands over their optical spectra at low/medium spectral resolution. We introduce a technique to mitigate the carbon-veiling problem to obtain reliable stellar parameters and validate this method with the LBT medium-resolution optical spectra of the ultra metal-poor ([Fe/H] = $-4.0$) CEMP-no dwarf, G 77-61, and seven additional very cool CEMP stars, which have published high-resolution spectroscopic parameters. We apply this technique to the LBT spectrum of SDSS J132755.56+333521.7. We find that this star is well-described with parameters $T_{\mathrm{eff}}=4530$ K, log $g=$ 0.7, [Fe/H] $ = -3.38$, and absolute carbon abundance $A$(C) = 7.23, indicating that it is likely the first Group III CEMP-no star identified in CVn I. The Group III identification of this star suggests that it is a member of the extremely metal-poor population in CVn I, which may have been accreted into its halo.

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Stellar Characterization of M-dwarfs from the APOGEE Survey: A Calibrator Sample for the M-dwarf Metallicities

We present spectroscopic determinations of the effective temperatures, surface gravities and metallicities for 21 M-dwarfs observed at high-resolution (R $\sim$ 22,500) in the \textit{H}-band as part of the SDSS-IV APOGEE survey. The atmospheric parameters and metallicities are derived from spectral syntheses with 1-D LTE plane parallel MARCS models and the APOGEE atomic/molecular line list, together with up-to-date H$_{2}$O and FeH molecular line lists. Our sample range in $T_{\rm eff}$ from $\sim$ 3200 to 3800K, where eleven stars are in binary systems with a warmer (FGK) primary, while the other 10 M-dwarfs have interferometric radii in the literature. We define an $M_{K_{S}}$--Radius calibration based on our M-dwarf radii derived from the detailed analysis of APOGEE spectra and Gaia DR2 distances, as well as a mass-radius relation using the spectroscopically-derived surface gravities. A comparison of the derived radii with interferometric values from the literature finds that the spectroscopic radii are slightly offset towards smaller values, with $Δ$ = -0.01 $\pm$ 0.02 $R{\star}$/$R_{\odot}$. In addition, the derived M-dwarf masses based upon the radii and surface gravities tend to be slightly smaller (by $\sim$5-10\%) than masses derived for M-dwarf members of eclipsing binary systems for a given stellar radius. The metallicities derived for the 11 M-dwarfs in binary systems, compared to metallicities obtained for their hotter FGK main-sequence primary stars from the literature, shows excellent agreement, with a mean difference of [Fe/H](M-dwarf - FGK primary) = +0.04 $\pm$ 0.18 dex, confirming the APOGEE metallicity scale derived here for M-dwarfs.

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ExoMol Molecular linelists -- XXXIII. The spectrum of Titanium Oxide

Accurate line lists are crucial for correctly modelling a variety of astrophysical phenomena, including stellar photospheres and the atmospheres of extra-solar planets. This paper presents a new line database Toto for the main isotopologues of titanium oxide (TiO): $^{46}$Ti$^{16}$O, $^{47}$Ti$^{16}$O, $^{48}$Ti$^{16}$O, $^{49}$Ti$^{16}$O and $^{50}$Ti$^{16}$O. The TiO line list contains transitions with wave-numbers up to 30,000 cm$^{-1}$ ie long-wards of 0.33 $μ$m. The Toto line list includes all dipole-allowed transitions between 13 low-lying electronic states (X $^3Δ$, a $^1Δ$, d $^1Σ^+$, E $^3Π$, A $^3Φ$ B $^3Π$, C $^3Δ$, b $^1Π$, c $^1Φ$, f $^1Δ$, e $^1Σ^+$). Ab initio potential energy curves (PECs) are computed at the icMRCI level and combined with spin-orbit and other coupling curves. These PECs and couplings are iteratively refined to match known empirical energy levels. Accurate line intensities are generated using ab initio dipole moment curves. The Toto line lists are appropriate for temperatures below 5000 K and contain 30 million transitions for TiO; it is made available in electronic form via the CDS data centre and via www.exomol.com. Tests of the line lists show greatly improved agreement with observed spectra for objects such as M-dwarfs GJ876 and GL581.

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Chemical analysis of CH stars - III: Atmospheric parameters and elemental abundances

Elemental abundances of CH stars can provide observational constraints for theoretical studies on the nucleosynthesis and evolution of low- and intermediate-mass stars. However, available abundance data in literature are quite scanty. In our pursuit to generate a homogeneous database of elemental abundances of CH stars we have performed a detailed chemical abundance study for a sample of 12 potential CH star candidates based on high resolution spectroscopy. We present first time abundance analysis for the objects HE 0308-1612, CD-28 1082, HD 30443, and HD 87853. For the other objects, although limited information is available, detailed chemical composition studies are missing. Our analysis shows CD-28 1082 to be a very metal-poor object with [Fe/H] = -2.45 and enriched in carbon with [C/Fe] = 2.19. With a ratio of [Ba/Eu] ~ 0.02 the star satisfies the classification criteria of a CEMP-r/s star. The objects CD-38 2151 with [Fe/H] = -2.03 and HD 30443 with [Fe/H] ~ -1.68 are found to show the characteristic properties of CH stars. HE 0308-1612 and HD 87853 are found to be moderately metal-poor with [Fe/H]~ -0.73; while HE 0308-1612 is moderately enhanced with carbon ([C/Fe] ~ 0.78) and shows the spectral properties of CH stars, the abundance of carbon could not be estimated for HD 87853. Among the two moderately metal-poor objects, HD 87080 ([Fe/H] = -0.48) shows near solar carbon abundance, and HD 176021 ([Fe/H] = -0.63) is mildly enhanced in carbon with [C/Fe] = 0.52. HD 176021 along with HD 202020 a known binary, exhibit the characteristic properties of CH stars as far as the heavy element abundances are concerned. Five objects in our sample show spectral properties that are normally seen in barium stars.

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