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Thomas P. Greene

Publications and source records attributed to Thomas P. Greene.

At least 55 records · Page 3Linked to original sources

Spectroscopic Time-series Performance of JWST/NIRSpec from Commissioning Observations

We report on JWST commissioning observations of the transiting exoplanet HAT-P-14 b, obtained using the Bright Object Time Series (BOTS) mode of the NIRSpec instrument with the G395H/F290LP grating/filter combination ($3-5μ$m). While the data were used primarily to verify that the NIRSpec BOTS mode is working as expected, and to enable it for general scientific use, they yield a precise transmission spectrum which we find is featureless down to the precision level of the instrument, consistent with expectations given HAT-P-14~b's small scale-height and hence expected atmospheric features. The exquisite quality and stability of the \emph{JWST/NIRSpec} transit spectrum -- almost devoid of any systematic effects -- allowed us to obtain median uncertainties of 50-60 ppm in this wavelength range at a resolution of $R=100$ in a single exposure, which is in excellent agreement with pre-flight expectations and close to the (or at the) photon-noise limit for a $J = 9.094$, F-type star like HAT-P-14. These observations showcase the ability of NIRSpec/BOTS to perform cutting-edge transiting exoplanet atmospheric science, setting the stage for observations and discoveries to be made in Cycle 1 and beyond.

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JWST/NIRCam Coronagraphy: Commissioning and First On-Sky Results

In a cold and stable space environment, the James Webb Space Telescope (JWST or "Webb") reaches unprecedented sensitivities at wavelengths beyond 2 microns, serving most fields of astrophysics. It also extends the parameter space of high-contrast imaging in the near and mid-infrared. Launched in late 2021, JWST underwent a six month commissioning period. In this contribution we focus on the NIRCam Coronagraphy mode which was declared "science ready" on July 10 2022, the last of the 17 JWST observing modes. Essentially, this mode will allow to detect fainter/redder/colder (less massive for a given age) self-luminous exoplanets as well as other faint astrophysical signal in the vicinity of any bright object (stars or galaxies). Here we describe some of the steps and hurdles the commissioning team went through to achieve excellent performances. Specifically, we focus on the Coronagraphic Suppression Verification activity. We were able to produce firm detections at 3.35$μ$m of the white dwarf companion HD 114174 B which is at a separation of $\simeq$ 0.5" and a contrast of $\simeq$ 10 magnitudes ($10^{4}$ fainter than the K$\sim$5.3 mag host star). We compare these first on-sky images with our latest, most informed and realistic end-to-end simulations through the same pipeline. Additionally we provide information on how we succeeded with the target acquisition with all five NIRCam focal plane masks and their four corresponding wedged Lyot stops.

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First Peek with JWST/NIRCam Wide-Field Slitless Spectroscopy: Serendipitous Discovery of a Strong [O III]/H$α$ Emitter at $z=6.11$

We report the serendipitous discovery of an [O III] $λλ$4959/5007 and H$α$ line emitter in the Epoch of Reionization (EoR) with the JWST commissioning data taken in the NIRCam wide field slitless spectroscopy (WFSS) mode. Located $\sim$55" away from the flux calibrator P330-E, this galaxy exhibits bright [O III] $λλ$4959/5007 and H$α$ lines detected at 3.7, 9.9 and 5.7$σ$, respectively, with a spectroscopic redshift of $z=6.112\pm0.001$. The total H$β$+[O III] equivalent width is 664$\pm$98 Å (454$\pm$78 Å from the [O III] $λ$5007 line). This provides direct spectroscopic evidence for the presence of strong rest-frame optical lines (H$β$+[O III] and H$α$) in EoR galaxies as inferred previously from the analyses of Spitzer/IRAC spectral energy distributions. Two spatial and velocity components are identified in this source, possibly indicating that this system is undergoing a major merger, which might have triggered the ongoing starburst with strong nebular emission lines over a timescale of $\sim$2 Myr as our SED modeling suggests. The tentative detection of He II $λ$4686 line ($1.9σ$), if real, may indicate the existence of very young and metal-poor star-forming regions with a hard UV radiation field. Finally, this discovery demonstrates the power and readiness of the JWST/NIRCam WFSS mode, and marks the beginning of a new era for extragalactic astronomy, in which EoR galaxies can be routinely discovered via blind slitless spectroscopy through the detection of rest-frame optical emission lines.

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A Mirage or an Oasis? Water Vapor in the Atmosphere of the Warm Neptune TOI-674 b

We report observations of the recently discovered warm Neptune TOI-674 b (5.25 \rearth{}, 23.6 \mearth{}) with the Hubble Space Telescope's Wide Field Camera 3 instrument. TOI-674 b is in the Neptune desert, an observed paucity of Neptune-size exoplanets at short orbital periods. Planets in the desert are thought to have complex evolutionary histories due to photoevaporative mass loss or orbital migration, making identifying the constituents of their atmospheres critical to understanding their origins. We obtained near-infrared transmission spectroscopy of the planet's atmosphere with the G141 grism. After extracting, detrending, and fitting the spectral lightcurves to measure the planet's transmission spectrum, we used the petitRADTRANS atmospheric spectral synthesis code to perform retrievals on the planet's atmosphere to identify which absorbers are present. These results show moderate evidence for increased absorption at 1.4 $μ$m due to water vapor at 2.9$σ$ (Bayes factor = 15.8), as well as weak evidence for the presence of clouds at 2.2$σ$ (Bayes factor = 4.0). TOI-674 b is a strong candidate for further study to refine the water abundance, which is poorly constrained by our data. We also incorporated new TESS short-cadence optical photometry, as well as Spitzer/IRAC data, and re-fit the transit parameters for the planet. We find the planet to have the following transit parameters: $R_p/R_* = 0.1135\pm0.0006$, $T_0 = 2458544.523792\pm0.000452$ BJD, and $P = 1.977198\pm0.00007$ d. These measurements refine the planet radius estimate and improve the orbital ephemerides for future transit spectroscopy observations of this highly intriguing warm Neptune.

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Densified pupil spectrograph as high-precision radial velocimetry: From direct measurement of the Universe's expansion history to characterization of nearby habitable planet candidates

The direct measurement of the Universe's expansion history and the search for terrestrial planets in habitable zones around solar-type stars require extremely high-precision radial velocity measures over a decade. This study proposes an approach for enabling high-precision radial velocity measurements from space. The concept presents a combination of a high-dispersion densified pupil spectrograph and a novel telescope line-of-sight monitor. The precision of the radial velocity measurements is determined by combining the spectrophotometric accuracy and the quality of the absorption lines in the recorded spectrum. Therefore, a highly dispersive densified pupil spectrograph proposed to perform stable spectroscopy can be utilized for high-precision radial velocity measures. A concept involving the telescope line-of-sight monitor is developed to minimize the change of the telescope line-of-sight over a decade. This monitor allows the precise measurement of a long-term telescope drift without any significant impact on the Airy disk when the densified pupil spectra are recorded. We analytically derive the uncertainty of the radial velocity measurements, which is caused by the residual offset of the line-of-sights at two epochs. We find that the error could be reduced down to approximately 1 $cm/s$, and the precision will be limited by another factor (e.g., wavelength calibration uncertainty). A combination of the high precision spectrophotometry and the high spectral resolving power could open a new path toward the characterization of nearby non-transiting habitable planet candidates orbiting late-type stars. We present two simple and compact high-dispersed densified pupil spectrograph designs for the cosmology and exoplanet sciences.

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Detecting Biosignatures in the Atmospheres of Gas Dwarf Planets with the James Webb Space Telescope

Exoplanets with radii between those of Earth and Neptune have stronger surface gravity than Earth, and can retain a sizable hydrogen-dominated atmosphere. In contrast to gas giant planets, we call these planets gas dwarf planets. The James Webb Space Telescope (JWST) will offer unprecedented insight into these planets. Here, we investigate the detectability of ammonia (NH$_{3}$, a potential biosignature) in the atmospheres of seven temperate gas dwarf planets using various JWST instruments. We use petitRadTRANS and PandExo to model planet atmospheres and simulate JWST observations under different scenarios by varying cloud conditions, mean molecular weights (MMWs), and NH$_{3}$ mixing ratios. A metric is defined to quantify detection significance and provide a ranked list for JWST observations in search of biosignatures in gas dwarf planets. It is very challenging to search for the 10.3--10.8 $μ$m NH$_{3}$ feature using eclipse spectroscopy with MIRI in the presence of photon and a systemic noise floor of 12.6 ppm for 10 eclipses. NIRISS, NIRSpec, and MIRI are feasible for transmission spectroscopy to detect NH$_{3}$ features from 1.5 $μ$m to 6.1 $μ$m under optimal conditions such as a clear atmosphere and low MMWs for a number of gas dwarf planets. We provide examples of retrieval analyses to further support the detection metric that we use. Our study shows that searching for potential biosignatures such as NH$_{3}$ is feasible with a reasonable investment of JWST time for gas dwarf planets given optimal atmospheric conditions.

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The Pandora SmallSat: Multiwavelength Characterization of Exoplanets and their Host Stars

Pandora is a SmallSat mission designed to study the atmospheres of exoplanets, and was selected as part of NASA's Astrophysics Pioneers Program. Transmission spectroscopy of transiting exoplanets provides our best opportunity to identify the makeup of planetary atmospheres in the coming decade. Stellar brightness variations due to star spots, however, can impact these measurements and contaminate the observed spectra. Pandora's goal is to disentangle star and planet signals in transmission spectra to reliably determine exoplanet atmosphere compositions. Pandora will collect long-duration photometric observations with a visible-light channel and simultaneous spectra with a near-IR channel. The broad-wavelength coverage will provide constraints on the spot and faculae covering fractions of low-mass exoplanet host stars and the impact of these active regions on exoplanetary transmission spectra. Pandora will subsequently identify exoplanets with hydrogen- or water-dominated atmospheres, and robustly determine which planets are covered by clouds and hazes. Pandora will observe at least 20 exoplanets with sizes ranging from Earth-size to Jupiter-size and host stars spanning mid-K to late-M spectral types. The project is made possible by leveraging investments in other projects, including an all-aluminum 0.45-meter Cassegrain telescope design, and a NIR sensor chip assembly from the James Webb Space Telescope. The mission will last five years from initial formulation to closeout, with one-year of science operations. Launch is planned for the mid-2020s as a secondary payload in Sun-synchronous low-Earth orbit. By design, Pandora has a diverse team, with over half of the mission leadership roles filled by early career scientists and engineers, demonstrating the high value of SmallSats for developing the next generation of space mission leaders.

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JWST Noise Floor II: Systematic Error Sources in JWST NIRCam Time Series

JWST holds great promise in characterizing atmospheres of transiting exoplanets, potentially providing insights into Earth-sized planets within the habitable zones of M dwarf host stars if photon-limited performance can be achieved. Here, we discuss the systematic error sources that are expected to be present in grism time series observations with the NIRCam instrument. We find that pointing jitter and high gain antenna moves on top of the detectors' subpixel crosshatch patterns will produce relatively small variations (less than 6 parts per million, ppm). The time-dependent aperture losses due to thermal instabilities in the optics can also be kept to below 2 ppm. To achieve these low noise sources, it is important to employ a sufficiently large (more than 1.1 arcseconds) extraction aperture. Persistence due to charge trapping will have a minor (less than 3 ppm) effect on time series 20 minutes into an exposure and is expected to play a much smaller role than it does for the HST WFC3 detectors. We expect temperature fluctuations to be less than 3 ppm. In total, our estimated noise floor from known systematic error sources is only 9 ppm per visit. We do however urge caution as unknown systematic error sources could be present in flight and will only be measurable on astrophysical sources like quiescent stars. We find that reciprocity failure may introduce a perennial instrument offset at the 40 ppm level, so corrections may be needed when stitching together a multi-instrument multi-observatory spectrum over wide wavelength ranges.

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Transmission spectroscopy for the warm sub-Neptune HD3167c: evidence for molecular absorption and a possible high metallicity atmosphere

We present a transmission spectrum for the warm (500-600K) sub-Neptune HD3167c obtained using the Hubble Space Telescope Wide Field Camera 3 infrared spectrograph. We combine these data, which span the 1.125-1.643 micron wavelength range, with broadband transit measurements made using Kepler/K2 (0.6-0.9 micron) and Spitzer/IRAC (4-5 micron). We find evidence for absorption by at least one of H2O, HCN, CO2, and CH4 (Bayes factor 7.4; 2.5-sigma significance), although the data precision does not allow us to unambiguously discriminate between these molecules. The transmission spectrum rules out cloud-free hydrogen-dominated atmospheres with metallicities <100x solar at >5.8-sigma confidence. In contrast, good agreement with the data is obtained for cloud-free models assuming metallicities >700x solar. However, for retrieval analyses that include the effect of clouds, a much broader range of metallicities (including subsolar) is consistent with the data, due to the degeneracy with cloud-top pressure. Self-consistent chemistry models that account for photochemistry and vertical mixing are presented for the atmosphere of HD3167c. The predictions of these models are broadly consistent with our abundance constraints, although this is primarily due to the large uncertainties on the latter. Interior structure models suggest the core mass fraction is >40%, independent of a rock or water core composition, and independent of atmospheric envelope metallicity up to 1000x solar. We also report abundance measurements for fifteen elements in the host star, showing that it has a very nearly solar composition.

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JWST Noise Floor I: Random Error Sources in JWST NIRCam Time Series

JWST transmission and emission spectra will provide invaluable glimpses of transiting exoplanet atmospheres, including possible biosignatures. This promising science from JWST, however, will require exquisite precision and understanding of systematic errors that can impact the time series of planets crossing in front of and behind their host stars. Here, we provide estimates of the random noise sources affecting JWST NIRCam time-series data on the integration-to-integration level. We find that 1/f noise can limit the precision of grism time series for 2 groups (230 ppm to 1000 ppm depending on the extraction method and extraction parameters), but will average down like the square root of N frames/reads. The current NIRCam grism time series mode is especially affected by 1/f noise because its GRISMR dispersion direction is parallel to the detector fast-read direction, but could be alleviated in the GRISMC direction. Care should be taken to include as many frames as possible per visit to reduce this 1/f noise source: thus, we recommend the smallest detector subarray sizes one can tolerate, 4 output channels and readout modes that minimize the number of skipped frames (RAPID or BRIGHT2). We also describe a covariance weighting scheme that can significantly lower the contributions from 1/f noise as compared to sum extraction. We evaluate the noise introduced by pre-amplifier offsets, random telegraph noise, and high dark current RC pixels and find that these are correctable below 10 ppm once background subtraction and pixel masking are performed. We explore systematic error sources in a companion paper.

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Tentative Evidence for Water Vapor in the Atmosphere of the Neptune-Size Exoplanet HD 106315 c

We present a transmission spectrum for the Neptune-size exoplanet HD 106315 c from optical to infrared wavelengths based on transit observations from the Hubble Space Telescope/Wide Field Camera 3, K2, and Spitzer. The spectrum shows tentative evidence for a water absorption feature in the $1.1 - 1.7μ$m wavelength range with a small amplitude of 30 ppm (corresponding to just $0.8 \pm 0.04$ atmospheric scale heights). Based on an atmospheric retrieval analysis, the presence of water vapor is tentatively favored with a Bayes factor of 1.7 - 2.6 (depending on prior assumptions). The spectrum is most consistent with either enhanced metallicity, high altitude condensates, or both. Cloud-free solar composition atmospheres are ruled out at $>5σ$ confidence. We compare the spectrum to grids of cloudy and hazy forward models and find that the spectrum is fit well by models with moderate cloud lofting or haze formation efficiency, over a wide range of metallicities ($1 - 100\times$ solar). We combine the constraints on the envelope composition with an interior structure model and estimate that the core mass fraction is $\gtrsim0.3$. With a bulk composition reminiscent of that of Neptune and an orbital distance of 0.15 AU, HD 106315 c hints that planets may form out of broadly similar material and arrive at vastly different orbits later in their evolution.

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Water Vapor and Clouds on the Habitable-Zone Sub-Neptune Exoplanet K2-18b

Results from the Kepler mission indicate that the occurrence rate of small planets ($<3$ $R_\oplus$) in the habitable zone of nearby low-mass stars may be as high as 80%. Despite this abundance, probing the conditions and atmospheric properties on any habitable-zone planet is extremely difficult and has remained elusive to date. Here, we report the detection of water vapor and the likely presence of liquid and icy water clouds in the atmosphere of the $2.6$ $R_\oplus$ habitable-zone planet K2-18b. The simultaneous detection of water vapor and clouds in the mid-atmosphere of K2-18b is particularly intriguing because K2-18b receives virtually the same amount of total insolation from its host star ($1368_{-107}^{+114}$ W m$^{-2}$) as the Earth receives from the Sun (1361 W m$^{-2}$), resulting in the right conditions for water vapor to condense and explain the detected clouds. In this study, we observed nine transits of K2-18b using HST/WFC3 in order to achieve the necessary sensitivity to detect the water vapor, and we supplement this data set with Spitzer and K2 observations to obtain a broader wavelength coverage. While the thick hydrogen-dominated envelope we detect on K2-18b means that the planet is not a true Earth analog, our observations demonstrate that low-mass habitable-zone planets with the right conditions for liquid water are accessible with state-of-the-art telescopes.

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Photometric precision of a Si:As impurity band conduction mid-infrared detector and application to transit spectroscopy

Transit spectroscopy is the most promising path toward characterizing nearby terrestrial planets at mid-infrared wavelengths in the next 20 years. The Spitzer Space telescope has achieved moderately good mid-infrared photometric precision in observations of transiting planets, but the intrinsic photometric stability of mid-IR detectors themselves has not been reported in the scientific or technical literature. Here, we evaluated the photometric precision of a JWST MIRI prototype mid-infrared Si:As impurity band conduction detector, using time-series data taken under flood illumination. These measurements of photometric precision were conducted over periods of 10 hours, representative of the time required to observe an exoplanet transit. After selecting multiple sub-regions with a size of 10x10 pixels and compensating for a gain change caused by our warm detector control electronics for the selected sub-regions, we found that the photometric precision was limited to 26.3ppm at high co-added signal levels due to a gain variation caused by our warm detector control electronics. The photometric precision was improved up to 12.8ppm after correcting for the gain drift. We also translated the photometric precision to the expected spectro-photometric precision, assuming that an optimized densified pupil spectrograph is used in transit observations. We found that the spectro-photometric precision of an optimized densified pupil spectrograph when used in transit observations is expected to be improved by the square root of the number of pixels per a spectral resolution element. At the high co-added signal levels, the total noise could be reduced down to 7ppm, which was larger by a factor of 1.3 than the ideal performance that was limited by the Poisson noise and readout noise. The systematic noise hidden behind the simulated transit spectroscopy was 1.7ppm.

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Revisiting the HIP41378 system with K2 and Spitzer

We present new observations of the multi-planet system HIP~41378, a bright star ($V$ = 8.9, $K_s$ = 7.7) with five known transiting planets. Observations in Campaign 5 of the K2 mission showed multiple transits of two Neptune-sized bodies and single transits of three larger planets ($R_P= 0.33R_J, 0.47R_J, 0.88 R_J$). K2 recently observed the system again in Campaign 18. We observe one new transit each of two of the larger planets, HIP41378~d and~f, giving maximal possible orbital periods of 1114 and 1084 days, respectively. Other possible periods include integer divisions of these maximum values down to a lower limit of about 50 days. We use all available photometry to determine the eccentricity distributions of HIP41378~d \& f, finding that periods $\lesssim$300 days require non-zero eccentricity. We also perform a stability analysis on the orbits of planets d and f to assess the likelihood of their different possible periods, finding that short periods (P $<$ 300 days) are disfavored. In addition, we observe transits of the inner two planets b and c with Spitzer/IRAC, which we combine with the new K2 observations of these planets to search for transit timing variations (TTVs). We find a linear ephemeris for planet b, but see a significant TTV signal for planet c that could be induced by planet d, e, or f. The ability to recover the two smaller planets with Spitzer shows that the several planets in this fascinating system will continue to be detectable with Spitzer, CHEOPS, TESS, and other observatories. This will allow us to precisely determine the periods of d and f, characterize the TTVs of planet~c, recover the transits of planet~e, and further enhance our view of this remarkable dynamical laboratory.

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The Transiting Exoplanet Community Early Release Science Program for JWST

The James Webb Space Telescope (JWST) presents the opportunity to transform our understanding of planets and the origins of life by revealing the atmospheric compositions, structures, and dynamics of transiting exoplanets in unprecedented detail. However, the high-precision, time-series observations required for such investigations have unique technical challenges, and prior experience with other facilities indicates that there will be a steep learning curve when JWST becomes operational. In this paper we describe the science objectives and detailed plans of the Transiting Exoplanet Community Early Release Science (ERS) Program, which is a recently approved program for JWST observations early in Cycle 1. The goal of this project, for which the obtained data will have no exclusive access period, is to accelerate the acquisition and diffusion of technical expertise for transiting exoplanet observations with JWST, while also providing a compelling set of representative datasets that will enable immediate scientific breakthroughs. The Transiting Exoplanet Community ERS Program will exercise the time-series modes of all four JWST instruments that have been identified as the consensus highest priorities, observe the full suite of transiting planet characterization geometries (transits, eclipses, and phase curves), and target planets with host stars that span an illustrative range of brightnesses. The observations in this program were defined through an inclusive and transparent process that had participation from JWST instrument experts and international leaders in transiting exoplanet studies. Community engagement in the project will be centered on a two-phase Data Challenge that culminates with the delivery of planetary spectra, time-series instrument performance reports, and open-source data analysis toolkits in time to inform the agenda for Cycle 2 of the JWST mission.

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Detection of Photospheric Features in the Near-Infrared Spectrum of a Class 0 Protostar

We present a near-infrared $K$-band $R \simeq 1500$ Keck spectrum of S68N, a Class 0 protostar in the Serpens molecular cloud. The spectrum shows a very red continuum, CO absorption bands, weak or non-existent atomic metal absorptions, and H$_2$ emission lines. The near-IR H$_2$ emission is consistent with excitation in shocks or by X-rays but not by UV radiation. We model the absorption component as a stellar photosphere plus circumstellar continuum emission with wavelength-dependent extinction. A Markov Chain Monte Carlo analysis shows that the most likely model parameters are consistent with a low-temperature, low-gravity photosphere with significant extinction and no more than modest continuum veiling. Its $T_{\mathrm{eff}} \simeq 3260$ K effective temperature is similar to that of older, more evolved pre-main-sequence stars, but its surface gravity log $g \simeq 2.4$ cm s$^{-2}$ is approximately 1 dex lower. This implies that the radius of this protostar is a factor of $\sim 3$ larger than that of $10^6$ yr old T Tauri stars. Its low veiling is consistent with a circumstellar disk having intrinsic near-IR emission that is less than or equal to that of more evolved Class I protostars. Along with the high extinction, this suggests that most of the circumstellar material is in a cold envelope, as expected for a Class 0 protostar. This is the first known detection and analysis of a Class 0 protostar absorption spectrum.

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Clear and Cloudy Exoplanet Forecasts for JWST: Maps, Retrieved Composition and Constraints on Formation with MIRI and NIRCam

The James Webb Space Telescope (JWST) will measure exoplanet transmission and eclipse spectroscopy at un-precedented precisions to better understand planet structure, dynamics, chemistry and formation. These are essential tools on the march towards biosignature searches on potentially habitable planets. We explore a range of exoplanet atmospheric conditions and forecast the expected results with JWST. We take realistic CHIMERA models that match existing Spitzer and HST results and simulate the spectra achievable with the JWST MIRI + NIRCam Guaranteed Time Observations (GTO) survey. We then retrieve atmospheric parameters from these spectra to estimate the precision to which the planets' atmospheric compositions can be measured. We find that emission spectra have well-constrained unimodal solutions but transmission spectra near 10X solar abundance and solar C/O ratios can suffer from bimodal solutions. Broad wavelength coverage as well as higher precision data can resolve bimodal solutions and provide dramatically better atmospheric parameter constraints. We find that metallicities can be measured to within 20% to 170%, which approaches the precisions on Solar System planets, and C/O ratios can be constrained to ~10% to 60%, assuming that observers can leverage short wavelength data to select the correct solution from the bimodal posteriors. These compositional precisions are sufficient to validate or refute predictions from disk formation models on final atmospheric abundances as long as their history is not erased by planet evolution processes. We also show the extent to which eclipse mapping with JWST is possible on our brightest system HD 189733 b.

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Three's Company: An additional non-transiting super-Earth in the bright HD 3167 system, and masses for all three planets

HD 3167 is a bright (V = 8.9), nearby K0 star observed by the NASA K2 mission (EPIC 220383386), hosting two small, short-period transiting planets. Here we present the results of a multi-site, multi-instrument radial velocity campaign to characterize the HD 3167 system. The masses of the transiting planets are 5.02+/-0.38 MEarth for HD 3167 b, a hot super-Earth with a likely rocky composition (rho_b = 5.60+2.15-1.43 g/cm^3), and 9.80+1.30-1.24 MEarth for HD 3167 c, a warm sub-Neptune with a likely substantial volatile complement (rho_c = 1.97+0.94-0.59 g/cm^3). We explore the possibility of atmospheric composition analysis and determine that planet c is amenable to transmission spectroscopy measurements, and planet b is a potential thermal emission target. We detect a third, non-transiting planet, HD 3167 d, with a period of 8.509+/-0.045 d (between planets b and c) and a minimum mass of 6.90+/-0.71 MEarth. We are able to constrain the mutual inclination of planet d with planets b and c: we rule out mutual inclinations below 1.3 degrees as we do not observe transits of planet d. From 1.3-40 degrees, there are viewing geometries invoking special nodal configurations which result in planet d not transiting some fraction of the time. From 40-60 degrees, Kozai-Lidov oscillations increase the system's instability, but it can remain stable for up to 100Myr. Above 60 degrees, the system is unstable. HD 3167 promises to be a fruitful system for further study and a preview of the many exciting systems expected from the upcoming NASA TESS mission.

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