arXiv subjects

Thomas Thundat

Publications and source records attributed to Thomas Thundat.

10 recordsLinked to original sources

arXiv2020

High-temperature and Abrasion Resistant Selective Solar Absorber under Ambient Environment

Selective solar absorbers (SSAs) with high performance are the key to concentrated solar power systems. Optical metamaterials are emerging as a promising strategy to enhance selective photon absorption, however, the high-temperature resistance (>500C) remains as one of the main challenges for their practical applications. Here, a multilayered metamaterial system (Al2O3/W/SiO2/W) based on metal-insulator-metal (MIM) resonance effect has been demonstrated with high solar absorptance over 92%, low thermal emittance loss below 6%, and significant high-temperature resistance: it has been proved that the optical performance remains 93.6% after 1-hour thermal annealing under ambient environment up to 500C, and 94.1% after 96-hour thermal cycle test at 400C, which is also confirmed by the microscopic morphology characterization. The spectral selectivity of fabricated SSAs is angular independent and polarization insensitive. Outdoor tests demonstrate that a peak temperature rise (193.5C) can be achieved with unconcentrated solar irradiance and surface abrasion resistance test yields that SSAs have a robust resistance to abrasion attack for engineering applications.

physics.app-ph↗

arXiv2019

Experimental and Theoretical Realization of Zenneck Wave-based Non-Radiative, Non-Coupled Wireless Power Transmission

A decade ago, non-radiative wireless power transmission re-emerged as a promising alternative to deliver electrical power to devices where a physical wiring proved to be unfeasible. However, existing approaches are neither scalable nor efficient when multiple devices are involved, as they are restricted by factors like coupling and external environments. Zenneck waves are excited at interfaces, like surface plasmons and have the potential to deliver electrical power to devices placed on a conducting surface. Here, we demonstrate, efficient and long range delivery of electrical power by exciting nonradiative waves over metal surfaces to multiple loads. Our modeling and simulation using Maxwells equation with proper boundary conditions shows Zenneck type behavior for the excited waves and are in excellent agreement with experimental results. In conclusion, we physically realize a radically different power transfer system, based on a wave, whose existence has been fiercely debated for over a century.

physics.app-ph↗

arXiv2018

Nanomechanical resonance captures pre-melting transition in DNA unravelling

A double-stranded DNA unravels thermally through intermediate denatured bubble segments. Intrinsically, fluctuations ensue at the bubble boundaries from non-equilibrium (NE) energy exchanges with the environment. However, such details gets obscured by large population kinetics at the macroscale, associating equilibrium pathway to the unravelling landscape. In this work, we capture evidence of fluctuation energetics with picoliter samples in a microfluidic cantilever. We exploit nanomechanical resonance to measure the NE energy exchanges through dissipation, revealing a crucial pre-melting transition at T~42C . This signifies that unravelling possibly proceeds via intermediate collapsed-bubble conformations releasing energy, sufficient to unbind bubble ends, assisting further unbinding. Fluctuation theorem explains the observations opening further avenues to investigate fluctuation kinetics in other biological phenomena that also proceed through similar NE energetics.

cond-mat.soft↗

arXiv2018

Interfacial friction-induced electronic excitation mechanism for tribo-tunneling current generation

Direct-current (d.c.) electricity generation using moving Schottky contact is emerging as a new strategy for mechanical energy conversion. Here, we demonstrate the generation of d.c.tunneling current with a density of ~35 A/m2 at a metal-insulator-semiconductor (MIS) sliding system using micro-tips. The measured current densities were found to be three to four orders of magnitude higher than that observed with the conventional polymer-based triboelectric nanogenerators (TENGs). The electromotive force for the tribo-tunneling transport comes from the dynamic electronic excitation at the frictional interface rather than from the electrostatically trapped surface charges as in the case of conventional TENGs. The strong electronic excitation can give rise to a non-equilibrium interfacial charge variation. Depending on the energy distribution of the excited electrons/holes, the charge variation subsequently dissipates non-adiabatically into tunneling current and trapped surface charges, or adiabatically into heat. These fundamental results not only enhance our understanding of the triboelectric phenomenon, but also open up new paths for the development of next-generation mechanical energy harvesting and sensing techniques.

physics.app-ph↗

arXiv2017

Abiotic streamers in a microfluidic system

In this work, we report the phenomenon of formation of particle aggregates in the form of thin slender strings when a polyacrylamide (PAM) solution, laden with polystyrene (PS) particles is introduced into a microfluidic device containing an array of micropillars. PAM and dilute solution of PS beads is introduced into the microfluidic channel through two separate inlets and localized particle aggregation is found to occur under certain conditions. The particle aggregates initially have a string-like morphology that remain tethered at their ends to the micropillar walls, while the rest of the structure remains suspended in the fluid medium. It is this morphology that inspired us to name these structures streamers. The flow regime under which streamer formation is observed is quantified using through a phase diagram. We discuss the streamer formation time-scales and also show that streamer formation is likely the result of flocculation of the PS beads. These streamers can serve as excellent model systems to study a biological phenomenon by the same name.

physics.flu-dyn↗

arXiv2017

Thermal graphene metamaterials and epsilon-near-zero high temperature plasmonics

The key feature of a thermophotovoltaic (TPV) emitter is the enhancement of thermal emission corresponding to energies just above the bandgap of the absorbing photovoltaic cell and simultaneous suppression of thermal emission below the bandgap. We show here that a single layer plasmonic coating can perform this task with high efficiency. Our key design principle involves tuning the epsilon-near-zero frequency (plasma frequency) of the metal acting as a thermal emitter to the electronic bandgap of the semiconducting cell. This approach utilizes the change in reflectivity of a metal near its plasma frequency (epsilon-near-zero frequency) to lead to spectrally selective thermal emission and can be adapted to large area coatings using high temperature plasmonic materials. We provide a detailed analysis of the spectral and angular performance of high temperature plasmonic coatings as TPV emitters. We show the potential of such high temperature plasmonic thermal emitter coatings (p-TECs) for narrowband near-field thermal emission. We also show the enhancement of near-surface energy density in graphene-multilayer thermal metamaterials due to a topological transition at an effective epsilon-near-zero frequency. This opens up spectrally selective thermal emission from graphene multilayers in the infrared frequency regime. Our design paves the way for the development of single layer p-TECs and graphene multilayers for spectrally selective radiative heat transfer applications.

physics.optics↗

arXiv2016

A nanostructured surface increases friction exponentially at the solid-gas interface

According to Stokes' law, a moving solid surface experiences dissipation that is linearly related to its velocity and the viscosity of the medium. This linear dependence on viscosity forms the basis for many characterization techniques for liquids. Unlike viscosities of different liquids, viscosities of gases vary only in a narrow range which limits their use as an effective characterization parameter using moving structures. Here we report experimental results of dissipation showing exponential dependence on viscosity for oscillating surfaces modified with nanostructures. The surface nanostructures alter solid-gas interplay greatly, amplifying the dissipation response exponentially for even minute variations in viscosity. Nanostructured resonator thus allows discrimination of otherwise narrow range of gaseous viscosity making it an ideal detection parameter for analysis. We attribute the observed exponential enhancement to the stochastic nature of interactions of many coupled nanostructures with the gas media.

physics.chem-ph↗

arXiv2016

Effect of interface on mid-infrared photothermal response of MoS2 thin film grown by pulsed laser deposition

Here we report mid infrared (mid-IR) photothermal response of multi layer MoS2 thin film grown on crystalline (p-type silicon and c-axis oriented single crystal sapphire) and amorphous substrates (Si/SiO2 and Si/SiN) by pulsed laser deposition (PLD) technique. The photothermal response of the MoS2 films was measured as changes in the resistance of MoS2 films when irradiated with mid IR (7 to 8.2 μm) source. We show that it is possible to enhance the temperature coefficient of resistance (TCR) of the MoS2 thin film by controlling the interface through proper choice of substrate and growth conditions. The thin films grown by PLD were characterized using XRD, Raman, AFM, XPS and TEM. High-resolution transmission electron microscopy (HRTEM) images show that the MoS2 films grow on sapphire substrate in a layer-by-layer manner with misfit dislocations. Layer growth morphology is disrupted when grown on substrates with diamond cubic structure such as silicon due to growth twin formation. The growth morphology is very different on amorphous substrates such as Si/SiO2 or Si/SiN. The MoS2 film grown on silicon shows a very high TCR (-2.9% K-1), mid IR sensitivity (delR/R=5.2 %) and responsivity (8.7 V/W) as compared to films on other substrates.

cond-mat.mtrl-sci↗

arXiv2015

Universal Spin-Momentum Locked Optical Forces

Evanescent electromagnetic waves possess spin-momentum locking, where the direction of propagation (momentum) is locked to the inherent polarization of the wave (transverse spin). We study the optical forces arising from this universal phenomenon and show that the fundamental origin of recently reported non-trivial optical chiral forces is spin-momentum locking. For evanescent waves, we show that the direction of energy flow, direction of decay, and direction of spin follow a right hand rule for three different cases of total internal reflection, surface plasmon polaritons, and $HE_{11}$ mode of an optical fiber. Furthermore, we explain how the recently reported phenomena of lateral optical force on chiral and achiral particles is caused by the transverse spin of the evanescent field and the spin-momentum locking phenomenon. Finally, we propose an experiment to identify the unique lateral forces arising from the transverse spin in the optical fiber and point to fundamental differences of the spin density from the well-known orbital angular momentum of light. Our work presents a unified view on spin-momentum locking and how it affects optical forces on chiral and achiral particles.

physics.optics↗

arXiv2015

Bacterial floc mediated rapid streamer formation in creeping flows

One of the central puzzles concerning the interaction of low Reynolds number (Re<<1) fluid transport with bacterial biomass is the formation of filamentous structures called streamers. In this manuscript, we report our discovery of a new kind of low Re bacterial streamers, which appear from pre-formed bacterial flocs. In sharp contrast to the biofilm-mediated streamers, these streamers form over extremely small timescales (less than a second). Our experiments, carried out in a microchannel with micropillars rely on fluorescence microscopy techniques to illustrate that floc-mediated streamers form when a freely-moving floc adheres to the micropillar wall and gets rapidly sheared by the background flow. We also show that at their inception the deformation of the flocs is dominated by recoverable large strains indicating significant elasticity. These strains subsequently increase tremendously to produce filamentous streamers. Interestingly, we find that these fully formed streamers are not static structures and show viscous response at time scales larger than their formation time scales. Finally we show that such novel streamer formation can lead to rapid clogging of microfluidic devices.

physics.flu-dyn↗