arXiv subjects

Thorsten Kleine

Publications and source records attributed to Thorsten Kleine.

At least 19 recordsLinked to original sources

arXiv2026

The NC-CC dichotomy in ruthenium isotopes: Implications for the origin of the late veneer

High-precision mass-independent Ru isotope data for iron meteorites reveal that in three-isotope diagrams including the p-process Ru nuclides 96Ru or 98Ru, non-carbonaceous (NC) meteorites plot along an s-process mixing line, while the carbonaceous (CC) type irons plot as a cluster off the NC-line. As previously observed for Mo, this offset can be accounted for by an r-process excess in CC over NC materials. As a highly siderophile element, Ru in the bulk silicate Earth (BSE) is thought to predominantly derive from the late veneer, making the Ru isotope dichotomy a powerful genetic tracer of Earth's late accretionary epoch. The BSE and the isotopically anomalous Itsaq Gneiss Complex as defined in prior studies plot on the NC-line defined in this study, suggesting a predominantly NC late veneer that may have evolved over time from more s-process-enriched to more s-process-depleted compositions. However, more precise 96Ru and 98Ru measurements of the BSE's composition are needed to more reliably determine the genetic heritage of the late veneer and to quantify as to whether it contains CC material.

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arXiv2026

Origin of nucleosynthetic isotope variability in the NC reservoir: Evidence from Ti, Cr, and Mo isotopes

Nucleosynthetic isotope anomalies allow distinguishing between non-carbonaceous (NC) and carbonaceous (CC) type meteorites, and have revealed correlated isotope variations especially among NC bodies. Understanding the origin of this NC trend is important for identifying the processes that produced the NC isotope heterogeneity, and for using these isotope anomalies to reconstruct the early evolution of the solar protoplanetary disk. We report mass-independent Ti, Cr, and Mo isotope compositions for a comprehensive set of previously not or only poorly investigated meteorites, as well as acid leachates obtained from the sequential digestion of primitive ordinary chondrites. Some of the samples investigated in this study fill previously identified apparent gaps in the NC trend, suggesting these gaps reflect unrepresentative sampling of a more continuous isotopic trend. Bulk meteorites and leachates exhibit distinct isotope systematics, indicating that the NC isotope variability does not reflect selective thermal processing of presolar carriers in the disk. The NC trend also cannot reflect the continuous addition of CC dust from the outer to the inner disk, because early- and late-formed NC meteorites display largely overlapping isotopic compositions. Instead, we find that the NC isotope heterogeneity is best accounted for by fractionation and mixing among chemically and isotopically distinct dust components, similar to the processes that produced the isotopic variability among carbonaceous chondrites. On this basis we argue for the presence of substructures in the inner disk, which facilitated fractionation and mixing among distinct dust components, and helped preserve a long-lived dust reservoir from which NC planetesimals accreted over an extended period of time.

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arXiv2026

Carbonaceous Chondrites provide evidence for late-stage planetesimal formation in a pressure bump

Carbonaceous chondrites are samples from planetesimals that formed 2-4 million years after solar system formation began. They consist of distinct dust components formed at different times and locations in the accretion disk and whose abundances in carbonaceous chondrites vary over planetesimal formation time. The mechanism that led to this time-varied accretion is not understood, but is critical for understanding late-stage planetesimal formation. Using a two-dimensional Monte Carlo simulation of dust evolution, we show that differences in dust filtering and delivery rates of distinct dust components to a planet-induced pressure bump in the disk reproduce the observed compositions and formation ages of the carbonaceous chondrites. This implies that carbonaceous chondrites likely formed in a single, long-lived dust trap, most likely outside of Jupiter's orbit. Because differentiated meteorites, which sample an earlier generation of planetesimals, exhibit similar isotopic variability as the chondrites, they likely have also formed in dust traps, implying these structures were the dominant site for planetesimal formation in the solar system.

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arXiv2026

Iron isotope anomalies and the origin of the Earth

Understanding the origin of the Earth requires determining the original formation location of its building material. Based on the similar Fe isotopic composition of Earth's mantle and Ivuna-type (CI) chondrites, a prior study has argued that Earth formed by accretion of sunward-drifting pebbles from the outer Solar System. Here, using new high-precision Fe isotopic data, we show however that CI chondrites and Earth's mantle have distinct Fe isotopic composition when the neutron-rich 58Fe is also considered. This observation rules out that the Fe in Earth's mantle derives from CI chondrite-like material and demonstrates that Earth did not form by accretion of sunwards-drifting pebbles. We show that the Fe in Earth's mantle instead derives from the inner Solar System, and has been partly or wholly delivered by bodies from the innermost disk that remained unsampled among meteorites. This provenance of terrestrial Fe is consistent with the classical model of Earth's formation by hierarchical growth among inner Solar System planetesimals and planetary embryos.

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arXiv2025

Physicochemical Controls on the Compositions of the Earth and Planets

Despite the fact that the terrestrial planets formed from the protoplanetary disk, their compositions show marked departures from that of solar nebula condensates. Metallic cores fix oxygen fugacities ($f$O$_2$s) of the planets to 5 (Mercury) to 1 log units below the iron-w\"ustite (IW) buffer, orders of magnitude higher than the nebular gas. Their oxidised character is coupled with a lack of volatile elements with respect to the solar nebula. Condensates from a solar gas at different temperatures ($T_0$) have Fe/O (by mass) of 0.93 ($T_0$ = 1250 K) to 0.81 ($T_0$ = 400 K), far lower than that of Earth (1.06). Because the reaction Fe(s) + H2O(g) = FeO(s) + H2(g) proceeds <600 K, temperatures at which most moderately volatile elements (MVEs) have condensed, oxidised planets should be volatile-rich, and vice-versa. That this is not observed suggests that planets did not accrete from equilibrium nebular condensates and/or underwent additional volatile depletion/$f$O$_2$ changes. Indeed, MVEs in small telluric bodies (Moon, Vesta) indicate near equilibrium evaporation/condensation at IW-1 and 1400-1800 K. Volatile-depleted elemental yet near-chondritic isotopes of larger telluric bodies (Earth, Mars) reflect mixing of bodies of variable volatile depletion, overprinted by volatile-undepleted material. From the Cr- and Ti isotopes in the BSE, such undepleted matter has been proposed to be CI chondrites. 6% CI added late to an enstatite chondrite-like proto-Earth would match the Earth. However, because Earth is an end-member in isotopic anomalies of heavier elements, no combination of existing meteorites alone can account for its chemical- and isotopic composition. Instead, the Earth is made partially or essentially entirely from an NC-like missing component. If so, the oxidised-, yet volatile-poor nature of inner solar system bodies, including Earth and Mars, is intrinsic to the NC reservoir.

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arXiv2025

Origin of moderately volatile elements in Earth inferred from mass-dependent Ge isotope variations among chondrites

The bulk silicate Earth (BSE) is depleted in moderately volatile elements, indicating Earth formed from a mixture of volatile-rich and -poor materials. To better constrain the origin and nature of Earth's volatile-rich building blocks, we determined the mass-dependent isotope compositions of Ge in carbonaceous (CC) and enstatite chondrites. We find that, similar to other moderately volatile elements, the Ge isotope variations among the chondrites reflect mixing between volatile-rich, isotopically heavy matrix and volatile-poor, isotopically light chondrules. The Ge isotope composition of the BSE is within the chondritic range and can be accounted for as a ~2:1 mixture of CI and enstatite chondrite-derived Ge. This mixing ratio appears to be distinct from the ~1:2 ratio inferred for Zn, reflecting the different geochemical behavior of Ge (siderophile) and Zn (lithophile), and suggesting the late-stage addition of volatile-rich CC materials to Earth. On dynamical grounds it has been argued that Earth accreted CC material through a few Moon-sized embryos, in which case the Ge isotope results imply that these objects were volatile-rich, presumably because they were either undifferentiated or accreted volatile-rich objects themselves before being accreted by Earth.

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arXiv2025

Comparison of the earliest NC and CC planetesimals: Evidence from ungrouped iron meteorites

Isotope anomalies in meteorites reveal a fundamental dichotomy between non-carbonaceous- (NC) and carbonaceous-type (CC) planetary bodies. Until now, this dichotomy is established for the major meteorite groups, representing about 36 distinct parent bodies. Ungrouped meteorites represent an even larger number of additional and so far mostly unexplored parent bodies. Here, the genetics and chronology of 26 ungrouped iron meteorites are investigated. The ungrouped irons confirm the NC-CC dichotomy for Mo, where NC and CC meteorites define two distinct, subparallel s-process mixing lines. All ungrouped NC irons fall on the NC-line, which is now precisely defined for 41 distinct parent bodies. The ungrouped CC irons show scatter around the CC-line indicative of small r-process Mo heterogeneities among these samples. These r-process Mo isotope variations correlate with O isotope anomalies, most likely reflecting mixing of CI chondrite-like matrix, chondrule precursors and Ca-Al-rich inclusions. This implies that CC iron meteorite parent bodies accreted the same nebular components as the later-formed carbonaceous chondrites. The Hf-W model ages of core formation for the ungrouped irons reveal a narrow age peak at ~3.3 Ma after Ca-Al-rich inclusions for the CC irons. By contrast, the NC irons display more variable ages, including younger ages indicative of impact-induced melting events, which seem absent among the CC irons. This is attributed to the more fragile and porous nature of the CC bodies, making impact-induced melting on their surfaces difficult. The chemical characteristics of all iron meteorites together reveal slightly more oxidizing conditions during core formation for CC compared to NC irons. More strikingly, strong depletions in moderately volatile elements, typical of many iron meteorite parent bodies, predominantly occur among CC irons.

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arXiv2024

Did the terrestrial planets of the Solar System form by pebble accretion?

The dominant accretion process leading to the formation of the terrestrial planets of the Solar System is a subject of intense scientific debate. Two radically different scenarios have been proposed. The classic scenario starts from a disk of planetesimals which, by mutual collisions, produce a set of Moon to Mars-mass planetary embryos. After the removal of gas from the disk, the embryos experience mutual giant impacts which, together with the accretion of additional planetesimals, lead to the formation of the terrestrial planets on a timescale of tens of millions of years. In the alternative, pebble accretion scenario, the terrestrial planets grow by accreting sunward-drifting mm-cm sized particles from the outer disk. The planets all form within the lifetime of the disk, with the sole exception of Earth, which undergoes a single post-disk giant impact with Theia (a fifth protoplanet formed by pebble accretion itself) to form the Moon. To distinguish between these two scenarios, we revisit all available constraints: compositional (in terms of nucleosynthetic isotope anomalies and chemical composition), dynamical and chronological. We find that the pebble accretion scenario is unable to match these constraints in a self-consistent manner, unlike the classic scenario.

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arXiv2024

Mechanisms and timing of carbonaceous chondrite delivery to the Earth

The nucleosynthetic isotope signatures of meteorites and the bulk silicate Earth (BSE) indicate that Earth consists of a mixture of "carbonaceous" (CC) and "non-carbonaceous" (NC) materials. We show that the fration of CC material recorded in the isotopic composition of the BSE varies for different elements, and depends on the element's tendency to partition into metal and its volatility. The observed behaviour indicates that the majority of material accreted to the Earth was NC-dominated, but that CC-dominated material enriched in moderately-volatile elements by a factor of ~10 was delivered during the last ~2-10% of Earth's acccretion. The late delivery of CC material to Earth contrasts with dynamical evidence for the early implantation of CC objects into the inner solar system during the growth and migration of the giant planets. This, together with the NC-dominated nature of both Earth's late veneer and bulk Mars, suggests that material scattered inwards had the bulk of its mass concentrated in a few, large CC embryos rather than in smaller planetesimals. We propose that Earth accreted a few of these CC embryos while Mars did not, and that at least one of the CC embryos impacted Earth relatively late (when accretion was 90-90% complete). This scenario is consistent with the subsequent Moon-formign impact of a large NC body, as long as this impact did not re-homogenize the entire Earth's mantle.

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arXiv2024

The Ni isotopic composition of Ryugu reveals a common accretion region for carbonaceous chondrites

The isotopic compositions of samples returned from Cb-type asteroid Ryugu and Ivuna-type (CI) chondrites are distinct from other carbonaceous chondrites, which has led to the suggestion that Ryugu and CI chondrites formed in a different region of the accretion disk, possibly around the orbits of Uranus and Neptune. We show that, like for Fe, Ryugu and CI chondrites also have indistinguishable Ni isotope anomalies, which differ from those of other carbonaceous chondrites. We propose that this unique Fe and Ni isotopic composition reflects different accretion efficiencies of small FeNi metal grains among the carbonaceous chondrite parent bodies. The CI chondrites incorporated these grains more efficiently, possibly because they formed at the end of the disk's lifetime, when planetesimal formation was also triggered by photoevaporation of the disk. Isotopic variations among carbonaceous chondrites may thus reflect fractionation of distinct dust components from a common reservoir, implying CI chondrites and Ryugu may have formed in the same region of the accretion disk as other carbonaceous chondrites.

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arXiv2024

Condensate evolution in the solar nebula inferred from combined Cr, Ti, and O isotope analyses of amoeboid olivine aggregates

Refractory inclusions in chondritic meteorites, namely amoeboid olivine aggregates (AOAs) and Ca-Al-rich inclusions (CAIs), are among the first solids to have formed in the solar system. The isotopic composition of CAIs is distinct from bulk meteorites, which either results from extreme processing of presolar carriers in the CAI-forming region, or reflects an inherited heterogeneity from the Sun's parental molecular cloud. Amoeboid olivine aggregates are less refractory than CAIs and provide a record of how the isotopic composition of solid material in the disk may have changed in time and space. However, the isotopic composition of AOAs and how this composition relates to that of CAIs and later-formed solids is unknown. Here, using new O, Ti, and Cr isotopic data for eight AOAs from the Allende CV3 chondrite, we show that CAIs and AOAs share a common isotopic composition, indicating a close genetic link and formation from the same isotopic reservoir. Because AOAs are less refractory than CAIs, this observation is difficult to reconcile with a thermal processing origin of the isotope anomalies. Instead, the common isotopic composition of CAIs and AOAs is readily accounted for in a model in which the isotopic composition of infalling material from the Sun's parental molecular cloud changed over time. In this model, CAIs and AOAs record the isotopic composition of the early infall, while later-formed solids contain a larger fraction of the later, isotopically distinct infall. This model implies that CAIs and AOAs record the isotopic composition of the Sun and suggests that the nucleosynthetic isotope heterogeneity of the solar system is predominantly produced by mixing of solar nebula condensates, which acquired their distinct isotopic compositions as a result of time-varied infall from the protosolar cloud.

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arXiv2023

Age and genetic relationships among CB, CH and CR chondrites

The carbonaceous Bencubbin-like (CB), high-metal (CH), and Renazzo-like (CR) chondrites are metal-rich chondrites that have been suggested to be genetically linked and are sometimes grouped together as the CR chondrite clan. Of these, the CB and CH chondrites are thought to have formed in an impact-generated vapor-melt plume from material that may be isotopically akin to CR chondrites. We report Mo, Ti, Cr, and Hf-W isotopic data for CB and CH chondrites in order to determine their formation time, to assess whether these chondrites are genetically related, and to evaluate their potential link to CR chondrites. An internal Hf-W isochron for the CH chondrite Acfer 182 yields an age of 3.8 +- 1.2 Ma after the formation of Ca-Al-rich inclusions (CAIs), which is indistinguishable from the mean Hf-W model age for CB metal of 3.8 +- 1.3 Ma. The Mo isotopic data for CB and CH chondrites indicate that both contain some of the same metal and silicate components, which themselves are isotopically distinct. As such, the different Mo isotopic compositions of bulk CB and CH chondrites reflect their distinct metal-to-silicate ratios. CR metal exhibits the same Mo isotopic composition as CB and CH metal, but CR silicates have distinct Mo and Ti isotopic compositions compared to CB and CH silicates, indicating that CB/CH chondrites may be genetically related to CR metal, but not to CR silicates. Together, the new isotopic data are consistent with formation of CB and CH chondrites in different regions of a common impact-generated vapor- melt plume and suggest that the CB and CH metal may derive from a metal-rich precursor genetically linked to CR chondrites. The Hf-W systematics of CH and CB chondrites indicate that the impact occurred at 3.8 +- 0.8 Ma after the formation of Ca-Al-rich inclusions and, hence, up to ~1 Ma earlier than previously inferred based on Pb- Pb chronology.

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arXiv2023

Isotopic constraints on genetic relationships among group IIIF iron meteorites, Fitzwater Pass, and the Zinder pallasite

Complex interelement trends among magmatic IIIF iron meteorites are difficult to explain by fractional crystallization and have raised uncertainty about their genetic relationships. Nucleosynthetic Mo isotope anomalies provide a powerful tool to assess if individual IIIF irons are related to each other. However, while trace-element data are available for all nine IIIF irons, Mo isotopic data are limited to three samples. We present Mo isotopic data for all but one IIIF irons that help assess the genetic relationships among these irons, together with new Mo and W isotopic data for Fitzwater Pass (classified IIIF), and the Zinder pallasite (for which a cogenetic link with IIIF irons has been proposed). After correction for cosmic-ray exposure, the Mo isotopic compositions of the IIIF irons are identical within uncertainty and confirm their belonging to carbonaceous chondrite-type (CC) meteorites. The mean Mo isotopic composition of Group IIIF overlaps those Groups IIF and IID, but a common parent body for these groups is ruled out based on distinct trace element systematics. The new Mo isotopic data do not argue against a single parent body for the IIIF irons, and suggest a close genetic link among these samples. By contrast, Fitzwater Pass has distinct Mo and W isotopic compositions, identical to those of some non-magmatic IAB irons. The Mo and W isotope data for Zinder indicate that this meteorite is not related to IIIF irons, but belongs to the non-carbonaceous (NC) type and has the same Mo and W isotopic composition as main-group pallasites.

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arXiv2023

Distribution of s-, r-, and p-process nuclides in the early Solar System inferred from Sr isotope anomalies in meteorites

Nucleosynthetic isotope anomalies in meteorites allow distinguishing between the non-carbonaceous (NC) and carbonaceous (CC) meteorite reservoirs and show that correlated isotope anomalies exist in both reservoirs. It is debated, however, whether these anomalies reflect thermal processing of presolar dust in the disk or are primordial heterogeneities inherited from the Solar System's parental molecular cloud. Here, using new high-precision 84Sr isotope data, we show that NC meteorites, Mars, and the Earth and Moon are characterized by the same 84Sr isotopic composition. This 84Sr homogeneity of the inner Solar System contrasts with the well-resolved and correlated isotope anomalies among NC meteorites observed for other elements, and most likely reflects correlated s- and (r-, p-)-process heterogeneities leading to 84Sr excess and deficits of similar magnitude which cancel each other. For the same reason there is no clearly resolved 84Sr difference between NC and CC meteorites, because in some carbonaceous chondrites the characteristic 84Sr excess of the CC reservoir is counterbalanced by an 84Sr deficit resulting from s-process variations. Nevertheless, most carbonaceous chondrites exhibit 84Sr excesses, which reflect admixture of refractory inclusions and more pronounced s-process heterogeneities in these samples. Together, the correlated variations of s-, (r-, p-)-process nuclides revealed by the 84Sr data of this study refute an origin of these isotope anomalies solely by processing of presolar dust grains, but points to primordial mixing of isotopically distinct dust reservoirs as the dominant process producing the isotopic heterogeneity of the Solar System.

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arXiv2023

Origin of isotopic diversity among carbonaceous chondrites

Carbonaceous chondrites are some of the most primitive meteorites and derive from planetesimals that formed a few million years after the beginning of the solar system. Here, using new and previously published Cr, Ti, and Te isotopic data, we show that carbonaceous chondrites exhibit correlated isotopic variations that can be accounted for by mixing among three major constituents having distinct isotopic compositions, namely refractory inclusions, chondrules, and CI chondrite-like matrix. The abundances of refractory inclusions and chondrules are coupled and systematically decrease with increasing amount of matrix. We propose that these correlated abundance variations reflect trapping of chondrule precursors, including refractory inclusions, in a pressure maximum in the disk, which is likely related to the water ice line and the ultimate formation location of Jupiter. The variable abundance of refractory inclusions/chondrules relative to matrix is the result of their distinct aerodynamical properties resulting in differential delivery rates and their preferential incorporation into chondrite parent bodies during the streaming instability, consistent with the early formation of matrix-poor and the later accretion of matrix-rich carbonaceous chondrites. Our results suggest that chondrules formed locally from isotopically heterogeneous dust aggregates which themselves derive from a wide area of the disk, implying that dust enrichment in a pressure trap was an important step to facilitate the accretion of carbonaceous chondrite parent bodies or, more generally, planetesimals in the outer solar system.

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arXiv2022

Presolar stardust in asteroid Ryugu

We have conducted a NanoSIMS-based search for presolar material in samples recently returned from C-type asteroid Ryugu as part of JAXA's Hayabusa2 mission. We report the detection of all major presolar grain types with O- and C-anomalous isotopic compositions typically identified in carbonaceous chondrite meteorites: 1 silicate, 1 oxide, 1 O-anomalous supernova grain of ambiguous phase, 38 SiC, and 16 carbonaceous grains. At least two of the carbonaceous grains are presolar graphites, whereas several grains with moderate C isotopic anomalies are probably organics. The presolar silicate was located in a clast with a less altered lithology than the typical extensively aqueously altered Ryugu matrix. The matrix-normalized presolar grain abundances in Ryugu are 4.8$^{+4.7}_{-2.6}$ ppm for O-anomalous grains, 25$^{+6}_{-5}$ ppm for SiC grains and 11$^{+5}_{-3}$ ppm for carbonaceous grains. Ryugu is isotopically and petrologically similar to carbonaceous Ivuna-type (CI) chondrites. To compare the in situ presolar grain abundances of Ryugu with CI chondrites, we also mapped Ivuna and Orgueil samples and found a total of SiC grains and 6 carbonaceous grains. No O-anomalous grains were detected. The matrix-normalized presolar grain abundances in the CI chondrites are similar to those in Ryugu: 23 $^{+7}_{-6}$ ppm SiC and 9.0$^{+5.3}_{-4.6}$ ppm carbonaceous grains. Thus, our results provide further evidence in support of the Ryugu-CI connection. They also reveal intriguing hints of small-scale heterogeneities in the Ryugu samples, such as locally distinct degrees of alteration that allowed the preservation of delicate presolar material.

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arXiv2022

Terrestrial planet formation from lost inner solar system material

Two fundamentally different processes of rocky planet formation exist, but it is unclear which one built the terrestrial planets of the solar system. Either they formed by collisions among planetary embryos from the inner solar system, or by accreting sunward-drifting millimeter-sized 'pebbles' from the outer solar system. We show that the isotopic compositions of Earth and Mars are governed by two-component mixing among inner solar system materials, including material from the innermost disk unsampled by meteorites, whereas the contribution of outer solar system material is limited to a few percent by mass. This refutes a pebble accretion origin of the terrestrial planets, but is consistent with collisional growth from inner solar system embryos. The low fraction of outer solar system material in Earth and Mars indicates the presence of a persistent dust-drift barrier in the disk, highlighting the specific pathway of rocky planet formation in the solar system.

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arXiv2021

Contemporary formation of early solar system planetesimals at two distinct radial locations

The formation of planetesimals is expected to occur via particle-gas instabilities that concentrate dust into self-gravitating clumps. Triggering these instabilities requires the prior pileup of dust in the protoplanetary disk. Until now, this has been successfully modeled exclusively at the disk's snowline, whereas rocky planetesimals in the inner disk were obtained only by assuming either unrealistically large particle sizes or an enhanced global disk metallicity. However, planetesimal formation solely at the snowline is difficult to reconcile with the early and contemporaneous formation of iron meteorite parent bodies with distinct oxidation states and isotopic compositions, indicating formation at different radial locations in the disk. Here, by modeling the evolution of a disk with ongoing accretion of material from the collapsing molecular cloud, we show that planetesimal formation may have been triggered within the first 0.5 million years by dust pileup at both the snowline (at approximately 5 au) and the silicate sublimation line (at approximately 1 au), provided turbulent diffusion was low. Particle concentration at approximately 1 au is due to the early outward radial motion of gas and is assisted by the sublimation and recondensation of silicates. Our results indicate that, although the planetesimals at the two locations formed about contemporaneously, those at the snowline accreted a large fraction of their mass (approximately 60 percent) from materials delivered to the disk in the first few 10,000 yr, whereas this fraction is only 30 percent for the planetesimals formed at the silicate line. Thus, provided that the isotopic composition of the delivered material changed with time, these two planetesimal populations should have distinct isotopic compositions, consistent with observations.

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