arXiv subjects

Tian Xue

Publications and source records attributed to Tian Xue.

3 recordsLinked to original sources

arXiv2026

Factoring $2048$ bit RSA integers with a half-million-qubit modular atomic processor

Shor's algorithm is one of the most promising applications of quantum computers. However, since $\sim 10^6$ physical qubits are believed to be required for established approaches, the algorithm will need to be distributed across many modules. In this paper, we provide a distributed compilation of Shor's algorithm on a modular atomic processor. We present an end-to-end compilation and optimization strategy that focuses on the interplay between the inter-module communication and the intra-module clock rate. With a half-million-qubit modular atomic processor with a communication rate of $10^5$ Bell pairs per second and a measurement time of 1 ms in a CPU-inspired architecture, we demonstrate that 2048-bit RSA integers can be factored in only 16\% more time than a single-module architecture. Our work presents the first end-to-end analysis and simulation of large-scale integer factorization on modular atomic hardware and it provides a blueprint for the future design of other large-scale modular algorithms.

quant-ph↗

arXiv2025

Efficient algorithms for quantum chemistry on modular quantum processors

Quantum chemistry is a promising application of future quantum computers, but the requirements on qubit count and other resources suggest that modular computing architectures will be required. We introduce an implementation of a quantum chemistry algorithm that is distributed across several computational modules: the distributed unitary selective coupled cluster (dUSCC). We design a packing scheme using the pseudo-commutativity of Trotterization to maximize the parallelism while optimizing the scheduling of all inter-module gates around the buffering of inter-module Bell pairs. We demonstrate dUSCC on a 3-cluster (H$_4$)$_3$ chain and show that it naturally utilizes the molecule's structure to reduce inter-module latency. We show that the run time of dUSCC is unchanged with inter-module latency up to $\sim$20$\times$ slower than intra-module gates in the (H$_4$)$_3$ while maintaining chemical accuracy. dUSCC should be "free" in the weakly entangled systems, and the existence of "free" dUSCC can be found efficiently using classical algorithms. This new compilation scheme both leverages pseudo-commutativity and considers inter-module gate scheduling, and potentially provides an efficient distributed compilation of other Trotterized algorithms.

quant-ph↗

arXiv2022

Ultrafast X-ray Spectroscopy of Intersystem Crossing in Hexafluoroacetylacetone: Chromophore Photophysics and Spectral Changes in the Face of Electron Withdrawing Groups

Intersystem crossings between singlet and triplet states represent a crucial relaxation pathway in photochemical processes. Herein, we probe the intersystem crossing in hexafluoro-acetylacetone with ultrafast X-ray transient absorption spectroscopy at the carbon K-edge. We observe the excited state dynamics following excitation with 266 nm UV light to the $^1ππ^{*}$ (S$_2$) state with element and site-specificity using a broadband soft X-ray pulse produced by high harmonic generation. These results are compared to X-ray spectra computed from orbital optimized density functional theory methods. It is found that the electron withdrawing fluorine atoms decongest the X-ray absorption spectrum by enhancing separation between features originating from different carbon atoms. This facilitates the elucidation of structural and electronic dynamics at the chromophore. The evolution of the core-to-valence resonances at the carbon K-edge reveals an ultrafast population transfer between the $^1nπ^{*}$ (S$_1$) and $^3ππ^{*}$ (T$_1$) states on a $1.6\pm0.4$ ps timescale, which is similar to the 1.5 ps timescale earlier observed for acetylacetone [J. Am. Chem. Soc. 139, 16576 (2017)]. It therefore appears that terminal fluorination has little influence on the intersystem crossing rate of the acetylacetone chromophore. In addition, the significant role of hydrogen-bond opened and twisted rotational isomers is elucidated in the excited state dynamics by comparison of the experimental transient X-ray spectra with theory.

physics.chem-ph↗