arXiv subjects

Tobias Baier

Publications and source records attributed to Tobias Baier.

17 recordsLinked to original sources

arXiv2026

Solutocapillary bubble centering in a confined ethanol plume in water

This study investigates the radial centering of gas bubbles within a buoyant plume of ethanol injected into a co-flowing water sheath flow in a vertical capillary. Bubbles nucleate in the ethanol stream due to CO$_2$ supersaturation and rapidly migrate toward the plume axis via solutocapillary (Marangoni) forces driven by interfacial tension gradients in the ethanol-water mixture. Experiments reveal that bubbles of varying sizes reliably align along the plume centerline, facilitated by steep radial concentration gradients near the plume boundary. A reduced-order model supports robust centering across a wide range of bubble radii. For larger bubbles, axial Marangoni effects modulate ascent velocities and can even induce upstream migration under transient conditions, highlighting the complex feedback between bubble dynamics and plume distortion. The results demonstrate that solutocapillary migration provides a reliable mechanism for contact-free bubble focusing, with implications for bubble manipulation in microfluidics, reactors, and phase-separation processes.

physics.flu-dyn↗

arXiv2025

Upstream motion of oil droplets in co-axial Ouzo flow due to Marangoni forces

To explore the physicochemical hydrodynamics of phase-separating ternary liquids (Ouzo-type), a binary oil-ethanol mixture is introduced into a co-flowing stream of water. Oil droplets nucleate at the interface between the two liquids, leading to a larger oil droplet interacting with the ethanol-rich jet. Although buoyancy forces and hydrodynamic drag forces push the droplet in downstream direction, we observe an upstream motion. Using computational fluid dynamics simulations of a simplified model system, we identify the nucleation zone for oil droplets and uncover Marangoni forces to be responsible for the upstream motion of the droplet. A semi-analytical model allows us to identify the key parameters governing this effect. A general conclusion is that Marangoni stresses can reverse the motion of droplets through channels, where the surrounding liquid is a multi-component mixture. The insights from this work are not only relevant for channel flow, but more generally, for the physicochemical hydrodynamics of multiphase, multi-component systems.

physics.flu-dyn↗

arXiv2023

The influence of incompressible surfactant on drag in flow along an array of gas-filled grooves

Surfactants can have a detrimental effect on the drag reduction in shear flow over superhydrophobic surfaces in Cassie state. While surfactant-free gas-liquid interfaces are often well approximated as shear-free, surfactants can impede the flow by stacking up in front of obstacles. We study shear-flow along an array of narrow gas-filled grooves of finite length embedded in an otherwise planar surface, with the gas-liquid interface protruding slightly above or below the plane. Assuming immiscible surfactants forming an incompressible, inviscid surfactant phase at the gas-liquid interfaces we employ a recently proposed model [Baier and Hardt, J.Fluid Mech., 949 (2022)] for addressing this situation. Using a domain perturbation technique together with the Lorentz reciprocal theorem we obtain the slip length characterizing the flow over such surfaces to second order in the maximal interface deflection as a small parameter. We find that within the range of moderate interface deflections studied, the slip length for flow over such surfaces is negative (positive) for surfaces protruding above (below) the surface and is much smaller than for flow over a corresponding surfactant-free interface. Thus, contrary to expectations of reduced drag in flow over superhydrophobic surfaces in Cassie state, surfactant covered interfaces can even be detrimental for drag reduction in the limit where surfactants act as an effectively incompressible surface-fluid. This has important implications for the appropriate design of superhydrophobic surfaces for reducing flow resistance.

physics.flu-dyn↗

arXiv2022

Shear flow over a surface containing a groove covered by an incompressible surfactant phase

We study shear-driven liquid flow over a planar surface with an embedded gas-filled groove, with the gas-liquid interface protruding slightly above or below the planar surface. The flow direction is along the groove, taken to be much longer than wide, and the gas-liquid interface is assumed to be covered by an incompressible surface fluid, representing a surfactant phase. Using the incompressiblity condition for the surface fluid, the equations of motion and corresponding boundary conditions for the liquid phase are obtained by minimizing the dissipation rate. Assuming a moderate deformation of the interface, a domain perturbation technique with the maximal deformation as the small parameter is employed. The Stokes equation in the liquid phase under corresponding boundary conditions is solved to second order in the deformation using the Keldysh-Sedov formalism. The obtained analytical results are compared with numerical calculations of the same problem, allowing an assessment of the limits of validity of the expansion. While on a planar gas-liquid interface no flow is induced, a recirculating flow is observed on an interface protruding slightly above or below the planar surface. The study sheds light onto the mobility of curved gas-liquid interfaces in the presence of surfactants acting as an incompressible surface fluid.

physics.flu-dyn↗

arXiv2018

Thermophoresis of Janus particles at large Knudsen numbers

The force and torque on a Janus sphere moving in a rarefied gas with a thermal gradient are calculated. The regime of large Knudsen number is considered, with the momenta of impinging gas molecules either obtained from a Chapman-Enskog distribution or from a binary Maxwellian distribution between two opposing parallel plates at different temperature. The reflection properties at the surface of the Janus particle are characterized by accommodation coefficients having constant but dissimilar values on each hemisphere. It is shown that the Janus particle preferentially orients such that the hemisphere with a larger accommodation coefficient points towards the lower temperature. The thermophoretic velocity of the particle is computed, and the influence of the thermophoretic motion on the magnitude of the torque responsible for the particle orientation is studied. The analytical calculations are supported by Direct Simulation Monte Carlo results, extending the scope of the study towards smaller Knudsen numbers. The results shed light on the efficiency of oriented deposition of nanoparticles from the gas phase onto a cold surface.

physics.flu-dyn↗

arXiv2017

Knudsen pump inspired by Crookes radiometer with a specular wall

A rarefied gas is considered in a channel consisting of two infinite parallel plates between which an evenly spaced array of smaller plates is arranged normal to the channel direction. Each of these smaller plates is assumed to possess one ideally specularly reflective and one ideally diffusively reflective side. When the temperature of the small plates differs from the temperature of the sidewalls of the channel, these boundary conditions result in a temperature profile around the edges of each small plate which breaks the reflection symmetry along the channel direction. This in turn results in a force on each plate and a net gas flow along the channel. The situation is analysed numerically using the direct simulation Monte Carlo (DSMC) method and compared with analytical results where available. The influence of the ideally specularly reflective wall is assessed by comparing with simulations using a finite accommodation coefficient at the corresponding wall. The configuration bears some similarity with a Crookes radiometer, where a non-symmetric temperature profile at the radiometer vanes is generated by different temperatures on each side of the vane, resulting in a motion of the rotor. The described principle may find applications in pumping gas on small scales driven by temperature gradients.

physics.flu-dyn↗

arXiv2016

Energy conversion by surface-tension driven charge separation

In this work, the shear-induced electrokinetic streaming potential present in free-surface electrolytic flows subjected to a gradient in surface tension is assessed. Firstly, for a Couette flow with fully resolved electric double layer (EDL), the streaming potential per surface stress as a function of the Debye parameter and surface potential is analyzed. By contrast to the Smoluchowski limit in pressure-driven channel flow, the shear-induced streaming potential vanishes for increasing Debye parameter (infinitely thin EDL), unless the free surface contains (induced) surface charge or the flow at the charged, solid wall is permitted to slip. Secondly, a technical realization of surface-tension induced streaming is proposed, with surface stress acting on the free (slipping) surfaces of a micro-structured, superhydrophobic wall. The streaming potential is analyzed with respect to the slip parameter and surface charge. Finally, the surface tension is assumed to vary with temperature (thermocapillarity) or with surfactant concentration (destillocapillarity). The maximal thermal efficiency is derived and compared to the Carnot efficiency. For large thermal Marangoni number, the efficiency is severely limited by the large heat capacity of aqueous solvents. By contrast, destillocapillary flows may reach conversion efficiencies similar to pressure-driven flow.

physics.flu-dyn↗

arXiv2014

Energy harvesting through gas dynamics in the free molecular flow regime between structured surfaces at different temperatures

For a gas confined between surfaces held at different temperatures the velocity distribution shows a significant deviation from the Maxwell distribution when the mean free path of the molecules is comparable to or larger than the channel dimensions. If one of the surfaces is suitably structured, this non-equilibrium distribution can be exploited for momentum transfer in tangential direction between the two surfaces. This opens up the possibility to extract work from the system which operates as a heat engine. Since both surfaces are held at constant temperatures, the mode of momentum transfer is different from thermal creep flow that has gained more attention so far. This situation is studied in the limit of free-molecular flow for the case that an unstructured surface is allowed to move tangentially with respect to a structured surface. Parameter studies are conducted, and configurations with maximum thermodynamic efficiency are identified. Overall, it is shown that significant efficiencies can be obtained by tangential momentum transfer between structured surfaces.

physics.flu-dyn↗

arXiv2013

Influence of the enclosed fluid on the flow over a microstructured surface in the Cassie state

Analytical expressions for the flow field as well as for the effective slip length of a shear flow over a surface with periodic rectangular grooves are derived. The primary fluid is in the Cassie state with the grooves being filled with a secondary immiscible fluid. The coupling of both fluids is reflected in a locally varying slip distribution along the fluid-fluid interface, which models the effect of the secondary fluid on the outer flow. The obtained closed-form analytical expressions for the flow field and effective slip length of the primary fluid explicitly contain the influence of the viscosities of the two fluids as well as the magnitude of the local slip, which is a function of the surface geometry. They agree well with results from numerical computations of the full geometry. The analytical expressions allow investigating the influence of the viscous stresses inside the secondary fluid for arbitrary geometries of the rectangular grooves. For classic superhydrophobic surfaces, the deviations in the effective slip length compared to the case of inviscid gas flow are are pointed out. Another important finding with respect to an accurate modeling of flow over microstructured surfaces is that the local slip length of a grooved surface is anisotropic.

physics.flu-dyn↗

arXiv2013

Effect of Electro-Osmotic Flow on Energy Conversion on Superhydrophobic Surfaces

It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in micro-energy harvesting devices. In this paper, we show using analytical and numerical methods, that when a streaming potential is generated in such superhydrophobic geometries, the reverse electro-osmotic flow and hence current generated by this, is significant. A decrease in streaming potential compared to what was earlier predicted is expected. We also show that, due to the electro-osmotic streaming-current, a saturation in both the power extracted and efficiency of energy conversion is achieved in such systems for large values of the free surface charge densities. Nevertheless, under realistic conditions, such microstructured devices with superhydrophobic surfaces have the potential to even reach energy conversion efficiencies only achieved in nanostructured devices so far.

physics.flu-dyn↗

arXiv2013

Propulsion Mechanisms for Leidenfrost Solids on Ratchets

We propose a model for the propulsion of Leidenfrost solids on ratchets based on viscous drag due to the flow of evaporating vapor. The model assumes pressure-driven flow described by the Navier-Stokes equations and is mainly studied in lubrication approximation. A scaling expression is derived for the dependence of the propulsive force on geometric parameters of the ratchet surface and properties of the sublimating solid. We show that the model results as well as the scaling law compare favorably with experiments and are able to reproduce the experimentally observed scaling with the size of the solid.

physics.flu-dyn↗

arXiv2013

Sample dispersion in isotachophoresis with Poiseuille counterflow

A particular mode of isotachophoresis (ITP) employs a pressure-driven flow opposite to the sample electromigration direction in order to anchor a sample zone at a specific position along a channel or capillary. We investigate this situation using a two-dimensional finite-volume model based on the Nernst-Planck equation. The imposed Poiseuille flow profile leads to a significant dispersion of the sample zone. This effect is detrimental for the resolution in analytical applications of ITP. We investigate the impact of convective dispersion, characterized by the area-averaged width of a sample zone, for various values of the sample Péclet-number, as well as the relative mobilities of the sample and the adjacent electrolytes. A one-dimensional model for the area-averaged concentrations based on a Taylor-Aris-type effective axial diffusivity is shown to yield good agreement with the finite-volume calculations. This justifies the use of such simple models and opens the door for the rapid simulation of ITP protocols with Poiseuille counterflow.

physics.flu-dyn↗

arXiv2012

Thermally-driven flows between a Leidenfrost solid and a ratchet surface

The significance of thermally-driven flows for the propulsion of Leidenfrost solids on a ratchet surface is studied based on a numerical solution of the Boltzmann equation. In contrast to a previous analysis, it is found that no significant thermal creep flow is established. Instead, the flow pattern is dominated by thermal edge and thermal-stress slip flow, the latter being directed opposite to thermal creep flow. However, in total thermally-induced flows only make a minor contribution to the propulsion of Leidenfrost solids on ratchet surfaces which is dominated by the pressure-driven flow due to the sublimating solid.

physics.flu-dyn↗

arXiv2011

Non-equilibrium electric double layers at the interface between two electrolytes

The charge distribution at the interface between two electrolytes is studied for the case of non-vanishing ion fluxes. The analysis is an extension of the established Verwey-Niessen theory to non-equilibrium situations. Applying matched asymptotic expansions for the region of the electric double layer and the bulk electrolytes, analytical expressions for the ion concentrations and the electrostatic potential are derived. It is found that the electric double layer is surprisingly stable. Even in cases where the applied electric field is so strong that it completely cancels the field of the charge clouds at the interface, two opposing space charge regions are formed. This phenomenon is qualitatively explained using a simple model incorporating ion partitioning and diffusive ion transport. Another notable phenomenon is that the interface acquires a net charge in the presence of an applied electric field, being of relevance for the hydrodynamic stability of interfacial flows.

cond-mat.soft↗

arXiv2010

Thermocapillary Flow on Superhydrophobic Surfaces

A liquid in Cassie-Baxter state above a structured superhydrophobic surface is ideally suited for surface driven transport due to its large free surface fraction in close contact to a solid. We investigate thermal Marangoni flow over a superhydrophobic array of fins oriented parallel or perpendicular to an applied temperature gradient. In the Stokes limit we derive an analytical expression for the bulk flow velocity above the surface and compare it with numerical solutions of the Navier-Stokes equation. Even for moderate temperature gradients comparatively large flow velocities are induced, suggesting to utilize this principle for microfluidic pumping.

physics.flu-dyn↗

arXiv2001

Correlation functions for composite operators in the Hubbard model

We compute the correlation functions for antiferromagnetic and d-wave superconducting fermion bilinears in a generalized mean field type approximation for the Hubbard model. For high temperature our explicit expressions show that homogeneous field configurations are preferred for these composite bosons. Below a critical temperature we find spontaneous symmetry breaking with homogeneous expectation values of the composite fields. Our results can be used to device a nonperturbative flow equation for the exploration of the low temperature regime.

cond-mat.str-el↗

arXiv2000

Spontaneous symmetry breaking in the colored Hubbard model

The Hubbard model is reformulated in terms of different ``colored'' fermion species for the electrons or holes at different lattice sites. Antiferromagnetic ordering or d-wave superconductivity can then be described in terms of translationally invariant expectation values for colored composite scalar fields. A suitable mean field approximation for the two dimensional colored Hubbard model shows indeed phases with antiferromagnetic ordering or d-wave superconductivity at low temperature. At low enough temperature the transition to the antiferromagnetic phase is of first order. The present formulation also allows an easy extension to more complicated microscopic interactions.

cond-mat.str-el↗