arXiv subjects

Tobias Junginger

Publications and source records attributed to Tobias Junginger.

18 recordsLinked to original sources

arXiv2026

Insight into SRF cavity performance from simulations of Nb's surface oxide dissolution and diffusion

We report simulations of the dissolution and diffusion of Nb's surface oxide layer in vacuum. While this chemical doping process is important for the surface preparation of Nb superconducting radio frequency (SRF) cavities - common components of particle accelerators - quantitatively linking the resulting oxygen distributions to superconducting performance remains challenging. In this work, we simulate the reaction-diffusion process numerically for treatment temperatures $T = 50^{\circ}$C to $200^{\circ}$C and times $t = 0.5$ h to $120$ h, and calculate the effect of the spatially inhomogeneous oxygen doping on Nb's superconducting properties. We find that oxygen doping redistributes the Meissner screening current, reducing its value at the surface and shifting its maximum several nanometres into the material. These results provide a microscopic link between oxygen diffusion profiles and the electromagnetic response of Nb relevant for SRF cavity operation. This work provides a quantitative framework linking oxygen diffusion profiles to superconducting performance and establishes a foundation for future studies involving time-dependent and multi-step heat treatment protocols.

cond-mat.supr-con↗

arXiv2026

Niobium's intrinsic coherence length and penetration depth revisited using low-energy muon spin spectroscopy and secondary-ion mass spectrometry

We report direct, simultaneous measurements of the London penetration depth ($λ_L$) and Bardeen-Cooper-Schrieffer (BCS) coherence length ($ξ_0$) in oxygen-doped niobium, with impurity concentrations spanning the "clean" to "dirty" limits. Two depth-resolved techniques - low-energy muon spin spectroscopy (LE-$μ$SR) and secondary-ion mass spectrometry (SIMS) - were used to quantify the element's Meissner screening profiles, analyzed within a framework that accounts for nonlocal electrodynamics. The analysis indicates intrinsic length scales of $λ_L = 29.1(10)$ nm and $ξ_0 = 39.9(25)$ nm, corresponding to a Ginzburg-Landau (GL) parameter of $κ= 0.70(5)$. The obtained $λ_L$ and $κ$ values, accurately quantified at the nanoscale, are smaller than values commonly used in applications and modeling, and indicate that clean niobium lies at the boundary between type-I and type-II superconductivity, supporting the contemporary view that its intrinsic state may be type-I.

cond-mat.supr-con↗

arXiv2025

Implantation studies of low-energy positive muons in niobium thin films

Here we study the range of keV positive muons $μ^+$ implanted in Nb$_2$O$_5$($x$ nm)/Nb($y$ nm)/SiO$_2$(300 nm)/Si [$x$ = 3.6 nm, 3.3 nm; $y$ = 42.0 nm, 60.1 nm] thin films using low-energy muon spin spectroscopy (LE-$μ$SR). At implantation energies 1.3 keV $\leq E \leq$ 23.3 keV, we compare the measured diamagnetic $μ^+$ signal fraction $f_{\mathrm{dia.}}$ against predictions derived from implantation profile simulations using the TRIM.SP Monte Carlo code. Treating the implanted $μ^+$ as light protons, we find that simulations making use of updated stopping cross section data are in good agreement with the LE-$μ$SR measurements, in contrast to parameterizations found in earlier tabulations. Implications for other studies relying on accurate $μ^+$ stopping information are discussed.

cond-mat.mtrl-sci↗

arXiv2025

Superconducting properties of thin film $\mathrm{Nb_{1-x}Ti_xN}$ studied via the NMR of implanted $^8$Li

We report measurements of the normal-state and superconducting properties of thin-film $\mathrm{Nb_{1-x}Ti_xN}$ using $^{8}$Li $β$-detected nuclear magnetic resonance ($β$-NMR). In these experiments, radioactive $^{8}$Li$^{+}$ probes were implanted $\sim21$ nm below the surface of a $\mathrm{Nb_{1-x}Ti_xN}$(91 nm) film in $\mathrm{Nb_{0.75}Ti_{0.25}N}$(91 nm)/AlN(4 nm)/Nb and its NMR response recorded (via $^{8}$Li's $β$-emissions) between 4.6 K and 270 K in a 4.1 T field applied normal to its surface. Resonance measurements reveal wide, symmetric lineshapes at all temperatures, with significant additional broadening below the film's superconducting transition temperature $T_\mathrm{c}(0 \; \mathrm{T}) = 15.4 \pm 0.7$ K due to vortex lattice formation. Fits to a broadening model find a magnetic penetration depth $λ(0 \; \mathrm{K})= 180.57 \pm 0.30$ nm and upper critical field $B_\mathrm{c2}(0 \; \mathrm{K})= 18 \pm 4$ T, consistent with literature estimates. Spin-lattice relaxation (SLR) measurements find a Korringa response at low temperatures, with dynamic (i.e., thermally activated) contributions dominating above $\sim100$ K. Below $T_\mathrm{c}$, we observe a small Hebel-Slichter coherence peak characterized by a superconducting energy gap $Δ(0 \; \mathrm{K}) = 2.60 \pm 0.12$ meV and modest Dynes-like broadening. Our measurements suggest a gap ratio $2Δ(0 \; \mathrm{K})/k_\mathrm{B}T_\mathrm{c}(0 \; \mathrm{T}) = 3.92 \pm 0.25$, consistent with strong-coupling behavior. Sources for the dynamic high-$T$ relaxation are suggested.

cond-mat.supr-con↗

arXiv2024

Search for inhomogeneous Meissner screening in Nb induced by low-temperature surface treatments

Empirical surface treatments, such as low-temperature baking (LTB) in a gaseous atmosphere or in vacuum, are important for the surface preparation of Nb superconducting radio frequency (SRF) cavities. These treatments inhomogeneously dope the first $\sim$50 nm of Nb's subsurface and are expected to impart depth-dependent characteristics to its Meissner response; however, direct evidence supporting this remains elusive, suggesting the effect is subtle. In this work, we revisit the Meissner profile data for several LTB treatments obtained from low-energy muon spin rotation (LE-$μ$SR) experiments [A. Romanenko et al., Appl. Phys. Lett. 104, 072601 (2014) and R. M. L. McFadden et al., Phys. Rev. Appl. 19, 044018 (2023)], and search for signatures of inhomogeneous field screening. Using a generalized London expression with a recently proposed empirical model for a depth-dependent magnetic penetration depth $λ(z)$, we obtain improved fits to the Meissner data, revealing that the presence of a non-superconducting surface "dead layer" $d \geq 25$ nm is a strong indicator of a reduced supercurrent density at shallow subsurface depths. Our analysis supports the notion that vacuum annealing at 120 $^{\circ}$C for 48 h induces a depth-dependent Meissner response, which has consequences for Nb's ability to maintain a magnetic-flux-free state. Evidence of similar behavior from a "nitrogen infusion" treatment is less compelling. Suggestions for further investigation into the matter are provided.

cond-mat.supr-con↗

arXiv2024

Measurements of the first-flux-penetration field in surface-treated and coated Nb: Distinguishing between surface pinning and an interface energy barrier

We report measurements of the first-flux-penetration field in surface-treated and coated Nb samples using muon spin rotation ($μ$SR). Using thin Ag foils as energy moderators for the implanted muon spin-probes, we "profile" the vortex penetration field $μ_{0} H_{\mathrm{vp}}$ at sub-surface depths on the order of $\sim 10$ $\mathrmμ$m to $\sim 100$ $\mathrmμ$m. In a coated sample [Nb$_3$Sn(2 $\mathrmμ$m)/Nb], we find that $μ_{0} H_{\mathrm{vp}}$ is depth-independent with a value of 234.5(35) mT, consistent with Nb's metastable superheating field and suggestive of surface energy barrier for flux penetration. Conversely, in a surface-treated sample [Nb baked in vacuum at 120 $^{\circ}$C for 48 h], vortex penetration onsets close to pure Nb's lower critical field $μ_{0}H_\mathrm{c1} \approx 170$ mT, but increases with increasing implantation depth, consistent with flux-pinning localized at the surface. The implication of these results for technical applications of superconducting Nb, such as superconducting radio frequency (SRF) cavities, is discussed.

cond-mat.supr-con↗

arXiv2024

Depth-resolved Characterization of Meissner Screening Breakdown in Surface Treated Niobium

We report direct measurements of the magnetic field screening at the limits of the Meissner phase for two superconducting Nb samples. The samples are processed with two different surface treatments that have been developed for superconducting radio-frequency cavity applications -- a "baseline" treatment and an oxygen-doping ("O-doping") treatment. The measurements show: 1) that the screening length is significantly longer in the "O-doping" sample compared to the "baseline" sample; 2) that the screening length near the limits of the Meissner phase increases with applied field; 3) the evolution of the screening profile as the material transitions from the Meissner phase to the mixed phase; and 4) a demonstration of the absence of any screening profile for the highest applied field, indicative of the full flux entering the sample. Measurements are performed utilizing the $β$-detected nuclear magnetic resonance ($β$-NMR) technique that allows depth resolved studies of the local magnetic field within the first 100 nm of the surface. The study takes advantage of the $β$-SRF beamline, a new facility at TRIUMF, Canada, where field levels up to 200 mT are available parallel to the sample surface to replicate radio frequency (RF) fields near the Meissner breakdown limits of Nb.

cond-mat.supr-con↗

arXiv2023

Depth-resolved measurement of the Meissner screening profile in a niobium thin film from spin-lattice relaxation of the implanted $β$-emitter $^{8}$Li

We report measurements of the Meissner screening profile in a Nb(300 nm)/Al$_{2}$O$_{3}$ thin film using $^{8}$Li $β$-detected nuclear magnetic resonance ($β$-NMR). The NMR probe $^{8}$Li was ion-implanted into the Nb film at energies $\leq$ 20 keV, corresponding to mean stopping depths comparable to Nb's magnetic penetration depth $λ$. $^{8}$Li's strong dipole-dipole coupling with the host $^{93}$Nb nuclei provided a "cross-relaxation" channel that dominated in low magnetic fields, which conferred indirect sensitivity to the local magnetic field via the spin-lattice relaxation (SLR) rate $1/T_{1}$. From a fit of the $1/T_{1}$ data to a model accounting for its dependence on temperature, magnetic field, and $^{8}$Li$^{+}$ implantation energy, we obtained a magnetic penetration depth $λ_{0}$ = 51.5(22) nm, consistent with a relatively short carrier mean-free-path $\ell$ = 18.7(29) nm typical of similarly prepared Nb films. The results presented here constitute an important step towards using $^{8}$Li $β$-NMR to characterize bulk Nb samples with engineered surfaces, which are often used in the fabrication of particle accelerators.

cond-mat.mtrl-sci↗

arXiv2023

Comment on "Strong Meissner screening change in superconducting radio frequency cavities due to mild baking" [Appl. Phys. Lett. 104, 072601 (2014)]

In a recent Letter by Romanenko et al., the authors used low-energy muon spin rotation (LE-$μ$SR) to measure the Meissner screening profile in cutouts from Nb superconducting radio frequency (SRF) cavities, systematically comparing how different surface treatments affect the screening properties of the elemental type-II superconductor. They reported a "strong" modification to the character of the screening profile upon mild baking at 120 $^{\circ}$C for 48 h, which was interpreted as a depth-dependent carrier mean-free-path resulting from a "gradient in vacancy concentration" near the surface. While this observation led to speculation that this surface treatment yields an "effective" superconducting bilayer, we suggest that its likeness to such is accidental and that the behavior is an artifact from the analysis.

cond-mat.supr-con↗

arXiv2023

Evidence for current suppression in superconductor-superconductor bilayers

Superconducting radio frequency (SRF) cavities, which are critical components in many particle accelerators, need to be operated in the Meissner state to avoid strong dissipation from magnetic vortices. For a defect-free superconductor, the maximum attainable magnetic field for operation is set by the superheating field, $B_{\mathrm{sh}}$, which directly depends on the surface current. In heterostructures composed of different superconductors, the current in each layer depends not only on the properties of the individual material, but also on the electromagnetic response of the adjacent layers through boundary conditions at the interfaces. Three prototypical bilayers [$\mathrm{Nb_{1-x}Ti_xN}$(50 nm)/Nb, $\mathrm{Nb_{1-x}Ti_xN}$(80 nm)/Nb, and $\mathrm{Nb_{1-x}Ti_xN}$(160 nm)/Nb] are investigated here by depth-resolved measurements of their Meissner screening profiles using low-energy muon spin rotation (LE-$μ$SR). From fits to a model based on London theory (with appropriate boundary and continuity conditions), a magnetic penetration depth for the thin $\mathrm{Nb_{1-x}Ti_xN}$ layers of $λ_\mathrm{Nb_{1-x}Ti_xN} =$ 182.5(31) nm is found, in good agreement with literature values for the bulk alloy. Using the measured $λ_\mathrm{Nb_{1-x}Ti_xN}$, the maximum vortex-free field, $B_{\mathrm{max}}$, of the superconductor-superconductor (SS) bilayer structure was estimated to be 610(40) mT. The strong suppression of the surface current in the $\mathrm{Nb_{1-x}Ti_xN}$ layer suggests an optimal thickness of $\sim 1.4 λ_{\mathrm{Nb_{1-x}Ti_xN}} =$ 261(14) nm.

cond-mat.supr-con↗

arXiv2023

Mid-T Heat Treatments on BCPed Coaxial Cavities at TRIUMF

Mid-T heat treatments in the range from 250 to 400 C on superconducting radio-frequency (SRF) cavities have been shown to provide high quality factors that rise with applied rf field strength in high frequency, electro-polished (EP), elliptical cavities operating at 2K, similar to nitrogen doped cavities. The rise in quality factor is attributed to a decrease in the temperature dependent part of the surface resistance $R_{BCS}$. Until now, no results have been reported for these new treatments on quarter-wave resonators (QWR) and half-wave resonators (HWR). The TRIUMF multi-mode coaxial cavities are dedicated test cavities that allow frequency and temperature resolved performance characterization of treatments without changing environments, therefore providing an excellent test vehicle to test these new treatments with rf frequencies ranging from 200 to 1200 MHz. In this paper, performance measurements from both QWR and HWR cavities are reported and their performance compared with four different treatments: baseline, a conventional 120C low temperature bake for 48 hours, and two mid-T bakes at 300 and 400C for 3 hours. In addition, sample analysis using SEM, EDX and SIMS of witness samples is also shown. It is found that the mid-T bakes are not directly transferable to low frequency cavities. In the fundamental modes of the two test cavities, no performance gain over the baseline treatment nor a decreasing temperature dependent component with rising rf amplitude was observed. At frequencies above 1GHz and low temperatures, the mid-T bakes show a reduced field dependence of $R_{BCS}$ compared to both the baseline and 120C treatments.

physics.acc-ph↗

arXiv2022

Depth-resolved measurements of the Meissner screening profile in surface-treated Nb

We report depth-resolved measurements of the Meissner screening profile in several surface-treated Nb samples using low-energy muon spin rotation (LE-$μ$SR). In these experiments, implanted positive muons, whose stopping depths below Nb's surface were adjusted between ~10 nm to ~150 nm, reveal the field distribution inside the superconducting element via their spin-precession (communicated through their radioactive decay products). We compare how the field screening is modified by different surface treatments commonly employed to prepare superconducting radio frequency (SRF) cavities used in accelerator beamlines. In contrast to an earlier report [A. Romanenko et al., Appl. Phys. Lett. 104 072601 (2014)], we find no evidence for any "anomalous" modifications to the Meissner profiles, with all data being well-described by a London model. Differences in screening properties between surface treatments can be explained by changes to the carrier mean-free-paths resulting from dopant profiles near the material's surface.

cond-mat.supr-con↗

arXiv2022

A New High Parallel-Field Spectrometer at TRIUMF's $β$-NMR Facility

A new high field spectrometer has been built to extend the capabilities of the $β$-detected nuclear magnetic resonance ($β$-NMR) facility at TRIUMF. This new beamline extension allows $β$-NMR spectroscopy to be performed with fields up to 200 mT parallel to a sample's surface (perpendicular to the ion beam), allowing depth-resolved studies of local electromagnetic fields with spin polarized probes at a much higher applied magnetic field than previously available in this configuration. The primary motivation and application is to allow studies of superconducting radio frequency (SRF) materials, close to the critical fields of Nb metal, which is extensively used to fabricate SRF cavities. The details of the design considerations and implementation of the ultra-high vacuum (UHV) system, ion optics, beam diagnostics are presented here. Commissioning of the beamline and spectrometer with radioactive ions are also reported here. Future capabilities and applications in other areas are also described.

cond-mat.mtrl-sci↗

arXiv2019

High Frequency Nonlinear Response of Superconducting Cavity-Grade Nb surfaces

Nb Superconducting Radio-Frequency (SRF) cavities are observed to break down and lose their high-Q superconducting properties at accelerating gradients below the limits imposed by theory. The microscopic origins of SRF cavity breakdown are still a matter of some debate. To investigate these microscopic issues temperature and power dependent local third harmonic response was measured on bulk Nb and Nb thin film samples using a novel near-field magnetic microwave microscope between 2.9K-10K and 2GHz-6GHz. Both periodic and non-periodic response as a function of applied RF field amplitude are observed. We attribute these features to extrinsic and intrinsic nonlinear responses of the sample. The RF-current-biased Resistively Shunted Junction (RSJ) model can account for the periodic response and fits very well to the data using reasonable parameters. The non-periodic response is consistent with vortex semi-loops penetrating into the bulk of the sample once sufficiently high RF magnetic field is applied, and the data can be fit to a Time-Dependent Ginzburg-Landau (TDGL) model of this process. The fact that these responses are measured on a wide variety of Nb samples suggests that we have captured the generic nonlinear response of air-exposed Nb surfaces.

cond-mat.supr-con↗

arXiv2017

Experimental evidence for electric surface resistance in niobium

Identifying the loss mechanisms of niobium cavities enables an accurate determination of applications for future accelerator projects and points to research topics required to mitigate current limitations. For several cavities an increasing surface resistance above a threshold field, saturating at higher field has been observed. Measurements on samples give evidence that this effect is caused by the surface electric field. The measured temperature and frequency dependence is consistent with a model that accounts for these losses by interface tunnel exchange between localized states in oxides formed along grain boundaries and the adjacent superconductor.

cond-mat.supr-con↗

arXiv2014

On the field dependent surface resistance of niobium on copper cavities

The surface resistance Rs of superconducting cavities prepared by sputter coating a thin niobium film on a copper substrate increases significantly stronger with the applied RF field compared to cavities of bulk material. A possible cause is that due to the thermal boundary resistance between the copper substrate and the niobium film Rs is enhanced due to global heating of the inner cavity wall. Introducing helium gas in the cavity and measuring its pressure as a function of applied field allowed to conclude that the inner surface of the cavity is heated up by only 60+/-60 mK when Rs increases with Eacc by 100 nOhm. This is more than one order of magnitude less than what one would expect from global heating. Additionally the effect of cooldown speed and low temperature baking have been investigated in the framework of these experiments. It is shown that for current state of the art niobium on copper cavities there is only a detrimental effect of low temperature baking. A fast cooldown results in a lowered Rs.

physics.acc-ph↗

arXiv2013

Losses in superconducting Niobium Films caused by Interface Tunnel Exchange

Identifying the loss mechanisms of niobium film cavities enables an accurate determination of applications for future accelerator projects and points to research topics required to mitigate their limitations. Measurements on samples show that the electric field is a dominant loss mechanism for niobium films, acting through interface tunneling between localized states in surface oxides and delocalized states in the superconducting niobium.

physics.acc-ph↗

arXiv2012

Extension of the Measurement Capabilities of the Quadrupole Resonator

The Quadrupole Resonator, designed to measure the surface resistance of superconducting samples at 400 MHz has been refurbished. The accuracy of its RF-DC compensation measurement technique is tested by an independent method. It is shown that the device enables also measurements at 800 and 1200 MHz and is capable to probe the critical RF magnetic field. The electric and magnetic field configuration of the Quadrupole Resonator are dependent on the excited mode. It is shown how this can be used to distinguish between electric and magnetic losses.

physics.acc-ph↗