arXiv subjects

Tobias Schmitt

Publications and source records attributed to Tobias Schmitt.

9 recordsLinked to original sources

arXiv2026

Proximitized Topological Insulator Charge Island Fabricated via In Situ Multi-Angle Stencil Lithography

Hybrid superconductor-topological insulator (TI) nanostructures constitute a promising material platform for exploring proximity-induced superconductivity in systems with topologically protected surface states. A key obstacle has been the realization of clean and well-controlled superconductor-TI interfaces, as TI surfaces rapidly degrade under ambient conditions. Here, we introduce a fully in situ, multi-angle stencil lithography technique that enables the fabrication of proximitized charge islands in TIs. The approach combines selective area growth of (Bi,Sb)$_2$Te$_3$ nanoribbons with angle-controlled deposition of diffusion barriers, superconducting Al, and ultrathin oxide tunnel barriers, allowing scalable fabrication of hybrid nanostructures without post-growth processing. Low-temperature transport measurements reveal robust Coulomb blockade and a pronounced suppression of low-energy conductance, which vanishes with a magnetic field, consistent with proximity-induced superconductivity in the island. These results establish a versatile nanofabrication platform that enables access to previously unexplored TI-based hybrid quantum devices and opens new routes for investigating superconductivity in topological nanostructures.

cond-mat.mes-hall↗

arXiv2025

On-chip stencil lithography for superconducting qubits

Improvements in circuit design and more recently in materials and surface cleaning have contributed to a rapid development of coherent superconducting qubits. However, organic resists commonly used for shadow evaporation of Josephson junctions (JJs) pose limitations due to residual contamination, poor thermal stability and compatibility under typical surface-cleaning conditions. To provide an alternative, we developed an inorganic SiO$_2$/Si$_3$N$_4$ on-chip stencil lithography mask for JJ fabrication. The stencil mask is resilient to aggressive cleaning agents and it withstands high temperatures up to 1200°C, thereby opening new avenues for JJ material exploration and interface optimization. To validate the concept, we performed shadow evaporation of Al-based transmon qubits followed by stencil mask lift-off using vapor hydrofluoric acid, which selectively etches SiO$_2$. We demonstrate average $T_1 \approx 75 \pm 11 μ$s over a 200 MHz frequency range in multiple cool-downs for one device, and $T_1 \approx 44\pm 8 μ$s for a second device. These results confirm the compatibility of stencil lithography with state-of-the-art superconducting quantum devices and motivate further investigations into materials engineering, film deposition and surface cleaning techniques.

quant-ph↗

arXiv2022

Spin coherence of near-surface ionised $^{125}$Te$^+$ donors in silicon

Impurity spins in crystal matrices are promising components in quantum technologies, particularly if they can maintain their spin properties when close to surfaces and material interfaces. Here, we investigate an attractive candidate for microwave-domain applications, the spins of group-VI Impurity spins in crystal matrices are promising components in quantum technologies, particularly if they can maintain their spin properties when close to surfaces and material interfaces. Here, we investigate an attractive candidate for microwave-domain applications, the spins of group-VI $^{125}$Te$^+$ donors implanted into natural Si at depths as shallow as 20~nm. We show that surface band-bending can be used to ionise such near-surface Te to spin-active Te$^+$ state, and that optical illumination can be used further to control the Te donor charge state. We examine spin activation yield, spin linewidth, relaxation ($T_1$) and coherence times (\ttwo) and show how a zero-field 3.5~GHz `clock transition' extends spin coherence times to over 1~ms, which is about an order of magnitude longer than other near-surface spin systems.

cond-mat.mes-hall↗

arXiv2022

Microstructure-Resolved Degradation Simulation of Lithium-Ion Batteries in Space Applications

In-orbit satellite REIMEI, developed by the Japan Aerospace Exploration Agency, has been relying on off-the-shelf Li-ion batteries since its launch in 2005. The performance and durability of Li-ion batteries is impacted by various degradation mechanisms, one of which is the growth of the solid-electrolyte interphase (SEI). In this article, we analyse the REIMEI battery and parameterize a full-cell model with electrochemical cycling data, computer tomography images, and capacity fading experiments using image processing and surrogate optimization. We integrate a recent model for SEI growth into a full-cell model and simulate the degradation of batteries during cycling. To validate our model, we use experimental and in-flight data of the satellite batteries. Our combination of SEI growth model and microstructure-resolved 3D simulation shows, for the first time, experimentally observed inhomogeneities in the SEI thickness throughout the negative electrode for the degraded cells.

physics.chem-ph↗

arXiv2021

Magnetotransport signatures of three-dimensional topological insulator nanostructures

We study the magnetotransport properties of patterned 3D topological insulator nanostructures with several leads, such as kinks or Y-junctions, near the Dirac point with analytical as well as numerical techniques. The interplay of the nanostructure geometry, the external magnetic field and the spin-momentum locking of the topological surface states lead to a richer magnetoconductance phenomenology as compared to straight nanowires. Similar to straight wires, a quantized conductance with perfect transmission across the nanostructure can be realized across a kink when the input and output channels are pierced by a half-integer magnetic flux quantum. Unlike for straight wires, there is an additional requirement depending on the orientation of the external magnetic field. A right-angle kink shows a unique $π$-periodic magnetoconductance signature as a function of the in-plane angle of the magnetic field. For a Y-junction, the transmission can be perfectly steered to either of the two possible output legs by a proper alignment of the external magnetic field. These magnetotransport signatures offer new ways to explore topological surface states and could be relevant for quantum transport experiments on nanostructures which can be realized with existing fabrication methods.

cond-mat.mes-hall↗

arXiv2019

Derivation of a Local Volume-Averaged Model and a Stable Numerical Algorithm for Multi-Dimensional Simulations of Conversion Batteries

In this article, we derive a general form of local volume-averaging theory and apply it to a model of zinc-air conversion batteries. Volume-averaging techniques are frequently used for the macroscopic description of micro-porous electrodes. We extend the existing method by including reactions between different phases and time-dependent volume fractions of the solid phases as these are continuously dissolved and reconstructed during operation of conversion batteries. We find that the constraint of incompressibility for multi-component fluids causes numerical instabilities in simulations of zinc-air battery cells. Therefore, we develop a stable sequential semi-implicit algorithm which converges against the fully implicit solution. Our method reduces the coupling of the variables by splitting the system of equations and introducing an additional iteration step.

physics.chem-ph↗

arXiv2019

Zinc Electrode Shape-Change in Secondary Air Batteries: A 2D Modeling Approach

Zinc-air batteries offer large specific energy densities, while relying on abundant and non-toxic materials. In this paper, we present the first multi-dimensional simulations of zinc-air batteries. We refine our existing theory-based model of secondary zinc-air systems. The model comprises thermodynamically consistent multi-species transport in alkaline electrolytes, formation and dissolution of metallic zinc and passivating zinc oxide, as well as multi-phase coexistence in gas diffusion electrodes. For the first time, we simulate zinc shape-change during battery cycling by modeling convection of zinc solids. We validate our model with in-situ tomography of commercial button cells. Two-dimensional volume-averaged simulations of cell voltage and zinc electrode morphology during discharge agree with these measurements. Thus, we can study how electrolyte carbonation limits shelf-life and how zinc shape-change limits cycle-life. The charging current is found to be the major contributor to cycle-life limitations. Finally, we optimize initial anode structure and charge-discharge protocols for improved performance and cycle-ability.

physics.chem-ph↗

arXiv2018

Adsorption and Intermolecular Interaction of Cobalt Phthalocyanine on CoO(111) Ultrathin Films: An STM and DFT Study

We investigate the adsorption of cobalt phthalocyanine (CoPc) molecules on a thin layer of cobalt oxide grown on Ir(100). To that end we compare the results of low-temperature scanning tunneling microscopy (STM) with those of ab-initio density functional theory (DFT) calculations and reveal the adsorption geometry. We find that the CoPc molecules lie flat on the surface and that their central cobalt atom forms a chemical bond to a substrate oxygen ion. However, this bond contributes only modestly to the adsorption energy, while van-der-Waals forces dominate the potential landscape and determine to a large extend the geometry as well as the distortion of substrate and molecule. Furthermore they lead to attractive molecule-molecule interactions at higher molecular coverages. The DFT calculations predict energetic positions of the molecular orbitals which are compared to scanning tunneling spectroscopy (STS) measurements.

cond-mat.mes-hall↗

arXiv2018

Boosting Transparency in Topological Josephson Junctions via Stencil Lithography

Hybrid devices comprised of topological insulator (TI) nanostructures in proximity to s-wave superconductors (SC) are expected to pave the way towards topological quantum computation. Fabrication under ultra-high vacuum conditions is necessary to attain high quality of TI-SC hybrid devices, because the physical surfaces of V-VI three-dimensional TIs suffer from degradation at ambient conditions. Here, we present an in-situ process, which allows to fabricate such hybrids by combining molecular beam epitaxy and stencil lithography. As-prepared Josephson junctions show nearly perfect interface transparency and very large $I_CR_N$ products. The Shapiro response of radio frequency measurements indicates the presence of gapless Andreev bound states, so-called Majorana bound states.

cond-mat.supr-con↗