arXiv subjects

Tomohiro Matsui

Publications and source records attributed to Tomohiro Matsui.

14 recordsLinked to original sources

arXiv2026

Unconventional thermal conductivity of suspended zigzag graphene nanomesh

Compared to the study of graphene itself, the study of nano-structured graphene is rather limited because it is difficult to prepare atomically ordered edges. In this study, we have fabricated a periodically patterned mesh structure of graphene with atomically precise zigzag edges (zGNM: zigzag graphene nanomesh) and studied its thermal conductivity ($\kappa$) by opto-thermal Raman measurement. Unintuitively, it is found that the $\kappa$ of zGNM of 2,3 monolayers (MLs) thick is inversely proportional to the nanoribbon width ($W$), while that of zGNM of 5$\sim$10 MLs thick is independent of $W$ down to 30 nm. Since the $\kappa$ of suspended zigzag graphene nanoribbons (zGNRs) is suppressed by decreasing $W$, this nonclassical behavior of zGNM is due to the mesh structure. In addition, zGNRs show a higher $\kappa$ than GNRs with atomically rough edges. This is probably due to the atomically ordered zigzag edges.

cond-mat.mes-hall↗

arXiv2024

Introducing Corrections to the Reflectance of Graphene by Light Emission

Monolayer graphene absorbs 2.3 percent of the incident visible light. This 'small' absorption has been used to emphasize the visual transparency of graphene, but it in fact means that multilayer graphene absorbs a sizable fraction of incident light, which causes non-negligible fluorescence. In this paper, we formulate the light emission properties of multilayer graphene composed of tens to hundreds of layers using a transfer matrix method and confirm the method's validity experimentally. We could quantitatively explain the measured contrasts of multilayer graphene on SiO$_2$/Si substrates and found sizable corrections, which cannot be classified as incoherent light emissions, to the reflectance of visible light. The new component originates from coherent emission caused by absorption at each graphene layer. Multilayer graphene thus functions as a partial coherent light source of various wavelengths, and it may have surface-emitting laser applications.

cond-mat.mtrl-sci↗

arXiv2022

Termination of Graphene Edges Created by Hydrogen and Deuterium Plasmas

Edge engineering is important for both fundamental research and applications as the device size decreases to nanometer scale. This is especially the case for graphene because a graphene edge shows totally different electronic properties depending on the atomic structure and the termination. It has recently been shown that an atomically precise zigzag edge can be obtained by etching graphene and graphite using hydrogen (H) plasma. However, edge termination had not been studied directly. In this study, termination of edges created by H-plasma is studied by high-resolution electron energy loss spectroscopy (HREELS) to show that the edge is $\mathrm{sp}^{2}$ bonded and the edge carbon atom is terminated by only one H atom. This suggests that an ideal zigzag edge, which is not only atomically precise but also $\mathrm{sp}^{2}$ bonding, can be obtained by H-plasma etching. Etching of the graphite surface with plasma of a different isotope, deuterium (D), is also studied by scanning tunneling microscopy (STM) to show that D-plasma anisotropically etches graphite less efficiently, although it can make defects more efficiently, than H-plasma.

cond-mat.mes-hall↗

arXiv2022

Nanoscale Fabrication of Graphene by Hydrogen-Plasma Etching

Graphene is attracting vast interest due to its superior electronic and mechanical properties. However, structure and electronic properties of its edge are often neglected, although they are important for nanoscale devices because the edge ratio becomes larger by decreasing the device size. In this study, we suggest a way to fabricate a graphene with atomically aligned zigzag edges by applying hydrogen-plasma etching (HPE) technique. By patterning a graphene prior to HPE, it is succeeded to shape a graphene in desired structure. Both atomic force microscopy and Raman spectroscopy confirm that the graphene shaped by this technique preserves its honeycomb structure even on the edge, which is aligned with zigzag structure. Although the mechanism of the anisotropic etching by hydrogen-plasma have not been clarified yet, the sample position dependence of the etching rate suggests that the hydrogen-radicals are responsible for the anisotropic etching.

cond-mat.mes-hall↗

arXiv2021

Two-dimensional superconductivity of the Ca-intercalated graphene on SiC: vital role of the interface between monolayer graphene and the substrate

Ca-intercalation has opened a way for superconductivity in graphene on SiC. However, the atomic and electronic structures being critical for superconductivity are still under discussion. We find the essential role of the interface between monolayer graphene and the SiC substrate for superconductivity. In the Ca-intercalation process, at the interface a carbon layer terminating SiC changes to graphene by Ca-termination of SiC (monolayer graphene becomes bilayer) with inducing more carriers than a free-standing model. Then, Ca is intercalated in-between graphene layers, which shows superconductivity with the updated critical temperature ($T_{C}$) of up to 5.7 K. In addition, the relation between $T_{C}$ and the normal-state conductivity is unusual, "dome-shape". These findings are beyond the simple C6CaC6 model in which s-wave BCS superconductivity is theoretically predicted. This work proposes a general picture of the intercalation-induced superconductivity in graphene on SiC, and shed the light on the potential of superconductivity induced by other intercalants.

cond-mat.mes-hall↗

arXiv2021

A Simple Experimental Setup for Simultaneous Superfluid-response and Heat-capacity Measurements for Helium in Confined Geometries

Torsional oscillator (TO) is an experimental technique which is widely used to investigate superfluid responses in helium systems confined in porous materials or adsorbed on substrates. In these systems, heat capacity (HC) is also an important quantity to study the local thermodynamic properties. We have developed a simple method to incorporate the capability of HC measurement into an existing TO without modifying the TO itself. By inserting a rigid thermal isolation support made of alumina and a weak thermal link made of fine copper wires between a standard TO and the mixing chamber of a dilution refrigerator in parallel, we were able to carry out simultaneous TO and HC measurements on exactly the same helium sample, i.e., four atomic layers of $^4$He adsorbed on graphite, with good accuracies down to 30 mK. The data reproduced very well the previous workers' results obtained independently using setups optimized for individual measurements. This method is conveniently applicable to a variety of experiments where careful comparisons between results of TO and HC measurements are crucial. We describe how to design the thermal isolation support and the weak thermal link to manage conflicting requirements in the two techniques.

cond-mat.other↗

arXiv2020

Superconducting Niobium Calorimeter for Studies of Adsorbed Helium Monolayers

We developed a calorimeter with a vacuum container made of superconducting niobium (Nb) to study monolayers of helium adsorbed on graphite which are prototypical two-dimensional quantum matters below 1 K. Nb was chosen because of its small specific heat in the superconducting state. It is crucially important to reduce the addendum heat capacity ($C_{\rm{ad}}$) when the specific surface area of substrate is small. Here we show details of design, construction and results of $C_{\rm{ad}}$ measurements of the Nb calorimeter down to 40 mK. The measured $C_{\rm{ad}}$ was sufficiently small so that we can use it for heat capacity measurements on helium monolayers in a wide temperature range below 1 K. We found a relatively large excess heat capacity in $C_{\rm{ad}}$, which was successfully attributed to atomic tunneling of hydrogen (H) and deuterium (D) between trap centers near oxygen or nitrogen impurities in Nb. The tunnel frequencies of H and D deduced by fitting the data to the tunneling model are consistent with the previous experiments on Nb doped with H or D.

cond-mat.other↗

arXiv2019

Hexagonal Nanopits with the Zigzag Edge State on Graphite Surfaces Synthesized by Hydrogen-Plasma Etching

We studied, by scanning tunneling microscopy, the morphology of nanopits of monolayer depth created at graphite surfaces by hydrogen plasma etching under various conditions such as H$_2$ pressure, temperature, etching time, and RF power of the plasma generation. In addition to the known pressure-induced transition of the nanopit morphology, we found a sharp temperature-induced transition from many small rather round nanopits of ~150 nm size to few large hexagonal ones of 300-600 nm within a narrow temperature range. The remote and direct plasma modes switching mechanism, which was proposed to explain the pressure-induced transition, is not directly applicable to this newly found transition. Scanning tunneling spectroscopy (STS) measurements of edges of the hexagonal nanopits fabricated at graphite surfaces by this method show clear signatures of the peculiar electronic state localized at the zigzag edge (edge state), i.e., a prominent peak near the Fermi energy accompanied by suppressions on either side in the local density of states. These observations indicate that the hexagonal nanopits consist of a high density of zigzag edges. The STS data also revealed a domain structure of the edge state in which the electronic state varies over a length scale of ~3 nm along the edge. The present study will pave the way for microscopic understanding of the anisotropic etching mechanism and of spin polarization in zigzag nanoribbons which are promising key elements for future graphene nanoelectronics.

cond-mat.mes-hall↗

arXiv2018

STM/S Observations of Graphene on SiC(0001) Etched by H-plasma

Monolayer graphene epitaxially grown on SiC(0001) was etched by H-plasma and studied by scanning tunneling microscopy and spectroscopy. The etching created partly hexagonal nanopits of monatomic depth as well as elevated regions with a height of about 0.12 nm which are stable at $T$ = 78 K. The symmetric tunnel spectrum about the Femi energy and the absence of a $6\times6$ corrugation on the elevated regions suggest that in these regions the carbon buffer layer is decoupled from the SiC substrate and quasi-free-standing bilayer graphene appears at originally monolayer graphene on the buffer layer. This is a result of passivation of the SiC substrate by intercalated hydrogen as in previous reports for graphene on SiC(0001) heat treated in atomic hydrogen.

cond-mat.mes-hall↗

arXiv2018

The Role of Substrate Roughness in Superfluid Film Flow Velocity

It is known that the apparent film flow rate $j_0$ of superfluid $^4$He increases significantly when the container wall is contaminated by a thin layer of solid air. However, its microscopic mechanism has not yet been clarified enough. We have measured $j_0$ under largely different conditions for the container wall in terms of surface area (0.77-6.15 m$^2$) and surface morphology using silver fine powders (particle size: $0.10$ μm) and porous glass (pore size: 0.5, 1 μm). We could increase $j_0$ by more than two orders of magnitude compared to non-treated smooth glass walls, where liquid helium flows down from the bottom of container as a continuous stream rather than discrete drips. By modeling the surface morphology, we estimated the effective perimeter of container $L_{\mathrm{eff}}$ and calculated the flow rate $j~(= j_0L_0/L_{\mathrm{eff}})$, where $L_0$ is the apparent perimeter without considering the microscopic surface structures. The resultant $j$ values for the various containers are constant each other within a factor of four, suggesting that the enhancement of $L_{\mathrm{eff}}$ plays a major role to change $j_0$ to such a huge extent and that the superfluid critical velocity, $v_{\mathrm{c}}$, does not change appreciably. The measured temperature dependence of $j$ revealed that $v_{\mathrm{c}}$ values in our experiments are determined by the vortex depinning model of Schwarz (Phys. Rev. B $\textbf{31}$, 5782 (1986)) with several nm size pinning sites.

cond-mat.other↗

arXiv2018

Pyrolytic Graphite Sheet, a New Adsorption Substrate for Superfluid Thin Films

We have measured surface morphology and gas adsorption characteristics of uncompressed pyrolytic graphite sheet (uPGS) which is a candidate substrate for AC and DC superflow experiments on monolayers of 4He below T = 1 K. The PGS is a mass-produced thin graphite sheet with various thicknesses between 10 and 100 μm. We employed a variety of measuring techniques such as imagings with optical microscope, SEM and STM, Raman spectroscopy, and adsorption isotherm. PGS has smooth and atomically-flat external surfaces with high crystallinity. Although the specific surface area (<0.1 m$^2$/g) is rather small, by making use of its smooth external surface, the thinnest uPGS of 10 μm thick is found to be suitable for the superflow experiments on the strictly two-dimensional helium systems.

cond-mat.mtrl-sci↗

arXiv2017

Low temperature transport properties of pyrolytic graphite sheet

We have made thermal and electrical transport measurements of uncompressed pyrolytic graphite sheet (uPGS), a mass-produced thin graphite sheet with various thicknesses between 10 and 100 μm, at temperatures between 2 and 300 K. Compared to exfoliated graphite sheets like Grafoil, uPGS has much higher conductivities by an order of magnitude because of its high crystallinity confirmed by X-ray diffraction and Raman spectroscopy. This material is advantageous as a thermal link of light weight in a wide temperature range particularly above 60 K where the thermal conductivity is much higher than common thermal conductors such as copper and aluminum alloys. We also found a general relationship between thermal and electrical conductivities in graphite-based materials which have highly anisotropic conductivities. This would be useful to estimate thermal conductance of a cryogenic part made of these materials from its electrical conductance more easily measurable at low temperature.

cond-mat.mtrl-sci↗

arXiv2007

Imaging correlated wave functions of few-electron quantum dots: Theory and scanning tunneling spectroscopy experiments

We show both theoretically and experimentally that scanning tunneling spectroscopy (STS) images of semiconductor quantum dots may display clear signatures of electron-electron correlation. We apply many-body tunneling theory to a realistic model which fully takes into account correlation effects and dot anisotropy. Comparing measured STS images of freestanding InAs quantum dots with those calculated by the full configuration interaction method, we explain the wave function sequence in terms of images of one- and two-electron states. The STS map corresponding to double charging is significantly distorted by electron correlation with respect to the non-interacting case.

cond-mat.mes-hall↗

arXiv2007

Correlation Effects in Wave Function Mapping of Molecular Beam Epitaxy Grown Quantum Dots

We investigate correlation effects in the regime of a few electrons in uncapped InAs quantum dots by tunneling spectroscopy and wave function (WF) mapping at high tunneling currents where electron-electron interactions become relevant. Four clearly resolved states are found, whose approximate symmetries are roughly s and p, in order of increasing energy. Because the major axes of the p-like states coincide, the WF sequence is inconsistent with the imaging of independent-electron orbitals. The results are explained in terms of many-body tunneling theory, by comparing measured maps with those calculated by taking correlation effects into account.

cond-mat.mes-hall↗