arXiv subjects

Tong Wu

Publications and source records attributed to Tong Wu.

319 records · Page 18Linked to original sources

arXiv2017

Competition of Chiroptical Effect Caused by Nanostructure and Chiral Molecules

The theory to calculate circular dichroism (CD) of chiral molecules in a finite cluster with arbitrarily disposed objects has been developed by means of T-matrix method. The interactions between chiral molecules and nanostructures have been investigated. Our studies focus on the case of chiral molecules inserted into plasmonic hot spots of nanostructures. Our results show that the total CD of the system with two chiral molecules is not sum for two cases when two chiral molecules inserted respectively into the hot spots of nanoparticle clusters as the distances among nanoparticles are small, although the relationship is established at the case of large interparticle distances. The plasmonic CD arising from structure chirality of nanocomposites depends strongly on the relative positions and orientations of nanospheroids, and are much greater than that from molecule-induced chirality. However, the molecule-induced plasmonic CD effect from the molecule-NP nanocomposites with special chiral structures can be spectrally distinguishable from the structure chirality-based optical activity. Our results provide a new theoretical framework for understanding the two different aspects of plasmonic CD effect in molecule-NP nanocomposites, which would be helpful for the experimental design of novel biosensors to realize ultrasensitive probe of chiral information of molecules by plasmon-based nanotechnology.

physics.optics↗

arXiv2017

Multifrequency multi-qubit entanglement based on plasmonic hot spots

The theoretical method to study strong coupling between an ensemble of quantum emitters (QEs) and surface plasmons excited by the nanoparticle cluster has been presented by using a rigorous first-principles electromagnetic Green's tensor technique. We have demonstrated that multi-qubit entanglement for two-level QEs can be produced at different frequencies simultaneously, when they locate in hot spots of metallic nanoparticle clusters. The duration of quantum beats for such an entanglement can reach two orders longer than that for the entanglement in a photonic cavity. The phenomenon originates from collective coupling resonance excitation of the cluster. At the frequency of single scattering resonance, the entanglement cannot be produced although the single QE spontaneous decay rate is very big

quant-ph↗

arXiv2017

Engineering topological edge states in two dimensional magnetic photonic crystal

Based on a perturbative approach, we propose a simple and efficient method to engineer topological edge states in two dimensional magnetic photonic crystals. The topological edge states in the microstructures can be constructed and varied by altering the parameters of the microstructure according to the fieldenergy distributions of the Bloch states at the related Bloch wave vectors. The validity of the proposed method has been demonstrated by exact numerical calculations through three concrete examples. Our method makes the topological edge states 'designable'.

physics.optics↗

arXiv2017

Simultaneously giant enhancement of Forster resonance energy transfer rate and efficiency based on plasmonic excitations

We present a first-principles calculation on the rate and efficiency of Förster resonance energy transfer (FRET) from a donor to an acceptor when they are located in the hotspots of nanoparticle clusters. Nonlocal effect has been considered by using a hydrodynamic model. It is found that FRET rate and efficiency can be enhanced simultaneously by more than 9 and 3 orders of magnitude, respectively. The physical origins for these phenomena have been disclosed. Two opposite phenomena, the energy transfer rate is independent or dependent of the local density of optical states (LDOS), have been observed in the same system under different conditions. These findings not only help us to understand the unresolved debate on how the FRET rate depends on the LDOS, but also provide a new way to realize ultrafast energy transfer process with ultrahigh efficiency.

physics.optics↗

arXiv2017

Strongly Enhanced Raman Optical Activity in Molecules by Magnetic Response of Nanoparticles

An analytical theory for the surface-enhanced Raman optical activity (SEROA) with the magnetic response of the substrate particle has been presented. We have demonstrated that the SEROA signal is proportional to the magnetic polarizability of the substrate particle, which can be significantly enhanced due to the existence of the magnetic response. At the same time, a large circular intensity difference (CID) for the SEROA can also be achieved in the presence of the magnetic response. Taking Si nanoparticles as examples, we have found that the CID enhanced by a Si nanoparticle is 10 times larger than that of Au. Furthermore, when the molecule is located in the hotspot of a Si dimer, CID can be 60 times larger. The phenomena originate from large magnetic fields concentrated near the nanoparticle and boosted magnetic dipole emission of the molecule. The symmetric breaking of the electric fields caused by the magnetic dipole response of the nanoparticle also plays an important role. Our findings provide a new way to tailor theRaman optical activity by designing metamaterials with the strong magnetic response.

physics.optics↗

arXiv2017

Surface Enhanced Circular Dichroism of Oriented Chiral Molecules by Plasmonic Nanostructures

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule materials, which are regarded as anisotropic chiral media, and metallic nanostructures has been investigated. Our results show that the plasmon-induced CD is sensitive to the orientations of the molecules. In many cases, the contribution of molecular electric quadrupole transitions to the total CD signal can play a key role. More interesting, we have demonstrated that both the quadrupole- and dipole-based CD signals can be improved greatly by matching the phases for the electromagnetic fields and their gradients at different regions around the nanostructures, which are occupied by the oriented chiral molecules. Different regions might produce CD of opposite sign. When integrating over regions with only one side of the proposed nanostructure, we find that the CD-peak may be nearly hundreds-fold over the case of integrating both sides. We believe that these findings would be helpful for realizing ultrasensitive probing of chiral information for oriented molecules by plasmon-based nanotechnology.

physics.optics↗

arXiv2017

Giant chiroptical effect caused by the electric quadrupole

Recently, there is a great interest in studying ultrasensitive detection and characterization of biomolecules using plasmonic particles, because they are of considerable importance in biomedical science and pharmaceutics. So far, all the theories on plasmoninduced circular dichroism (CD) are based on the dipole approximation, the electric quadrupolar contribution is generally considered to be relatively small and neglected. Here we demonstrate that the electric quadrupolar contribution not only cannot be ignored, but also plays a key role in many cases. Particularly, for the chiral medium that possesses preferential molecular orientations and is located at the hotspot of plasmonic nanostructures, the plasmonic CD strength contributed by molecular electric quadrupoles (EQ) can be two orders of magnitude higher than that contributed by molecular electric/magnetic dipoles. Unlike the case of dipole approximation, molecular EQ associated plasmonic CD activity appears mainly at the plasmonic resonance absorptions that facilitate the optically enhanced near-field with steep electric filed gradients, and is correlated with the boosted emission rate of a molecular EQ. Based on such physical understandings, we can design nanostructures to realize giant chiroptical effect using the EQ contribution according to the requirements,2 which provide a new strategy for ultrasensitive detection and quantification of molecular chirality.

physics.optics↗

arXiv2017

Amplification of Molecular Chiroptical Effect by Low-loss Dielectric Nanoantennas

We report here chiroptical amplification effect occurring in the hybrid systems consisting of chiral molecules and Si nanostructures. Under resonant excitation of circularly polarized light, the hybrid systems show strong CD induction signals at optical frequency, which arise from both the electric and magnetic responses of the Si nanostructures. More interestingly, the induced CD signals from Si-based dielectric nanoantennas are always larger than that from Au-based plasmonic counterparts. The related physical origin was disclosed. Furthermore, compared to the Au-based high-loss plasmonic nanoantenas, Si-based low-loss structures would generate negligible photothermal effect, which makes Si nanoantennas become an optimized candidate to amplify molecular CD signals with ultralow thermal damages. Our findings may provide a guideline for the design of novel chiral nanosensors for applications in the fields of biomedicine and pharmaceutics.

physics.optics↗

arXiv2017

Quantum-trajectory analysis for charge transfer in solid materials induced by strong laser fields

We investigate the dependence of charge transfer on the intensity of driving laser field when SiO2 crystal is irradiated by an 800 nm laser. It is surprising that the direction of charge transfer undergoes a sudden reversal when the driving laser intensity exceeds critical values with different carrier envelope phases. By applying quantum-trajectory analysis, we find that the Bloch oscillation plays an important role in charge transfer in solid. Also, we study the interaction of strong laser with gallium nitride (GaN) that is widely used in optoelectronics. A pump-probe scheme is applied to control the quantum trajectories of the electrons in the conduction band. The signal of charge transfer is controlled successfully by means of theoretically proposed approach.

physics.optics↗

arXiv2016

Improvement on Fermionic properties and new isotope production in molecular dynamics simulations

By considering momentum transfer in the Fermi constraint procedure, the stability of the initial nuclei and fragments produced in heavy-ion collisions can be further improved in the quantum molecular dynamics simulations. The case of the phase space occupation probability larger than one is effectively reduced with the proposed procedure. Simultaneously, the energy conservation can be better described for both individual nuclei and heavy-ion reactions. With the revised version of the improved quantum molecular dynamics (ImQMD) model, the fusion excitation functions of $^{16}$O+$^{186}$W and the central collisions of Au+Au at 35 AMeV are re-examined. The fusion cross sections at sub-barrier energies and the charge distribution of fragments are relatively better reproduced due to the reduction of spurious nucleon emission. The charge and isotope distribution of fragments in Xe+Sn, U+U and Zr+Sn at intermediate energies are also predicted. More unmeasured extremely neutron-rich fragments with $Z=16-28$ are observed in the central collisions of $^{238}$U+$^{238}$U than that of $^{96}$Zr+$^{124}$Sn, which indicates that multi-fragmentation of U+U may offer a fruitful pathway to new neutron-rich isotopes.

nucl-th↗

arXiv2015

Learning the nonlinear geometry of high-dimensional data: Models and algorithms

Modern information processing relies on the axiom that high-dimensional data lie near low-dimensional geometric structures. This paper revisits the problem of data-driven learning of these geometric structures and puts forth two new nonlinear geometric models for data describing "related" objects/phenomena. The first one of these models straddles the two extremes of the subspace model and the union-of-subspaces model, and is termed the metric-constrained union-of-subspaces (MC-UoS) model. The second one of these models---suited for data drawn from a mixture of nonlinear manifolds---generalizes the kernel subspace model, and is termed the metric-constrained kernel union-of-subspaces (MC-KUoS) model. The main contributions of this paper in this regard include the following. First, it motivates and formalizes the problems of MC-UoS and MC-KUoS learning. Second, it presents algorithms that efficiently learn an MC-UoS or an MC-KUoS underlying data of interest. Third, it extends these algorithms to the case when parts of the data are missing. Last, but not least, it reports the outcomes of a series of numerical experiments involving both synthetic and real data that demonstrate the superiority of the proposed geometric models and learning algorithms over existing approaches in the literature. These experiments also help clarify the connections between this work and the literature on (subspace and kernel k-means) clustering.

stat.ML↗

arXiv2015

Tunable subwavelength strong absorption by graphene wrapped dielectric particles

The optical absorption properties of graphene wrapped dielectric particles have been investigated by using Mie scattering theory and exact multi-scattering method. It is shown that subwavelength strong absorption in infrared spectra can take place in such systems due to the excitation of plasmon resonance in graphene. The absorption characteristics and efficiency are tunable by varying Fermi level and damping constant of graphene, or by changing size and dielectric constant of small particles. For a cluster of these particles, the absorption characteristics are also affected by the separation distance between them. These extreme light resonances and absorptions in graphene wrapped nanostructures have great potential for opto-electronic devices.

physics.optics↗

arXiv2014

Painting Analysis Using Wavelets and Probabilistic Topic Models

In this paper, computer-based techniques for stylistic analysis of paintings are applied to the five panels of the 14th century Peruzzi Altarpiece by Giotto di Bondone. Features are extracted by combining a dual-tree complex wavelet transform with a hidden Markov tree (HMT) model. Hierarchical clustering is used to identify stylistic keywords in image patches, and keyword frequencies are calculated for sub-images that each contains many patches. A generative hierarchical Bayesian model learns stylistic patterns of keywords; these patterns are then used to characterize the styles of the sub-images; this in turn, permits to discriminate between paintings. Results suggest that such unsupervised probabilistic topic models can be useful to distill characteristic elements of style.

cs.CV↗