arXiv subjects

Tongrui Li

Publications and source records attributed to Tongrui Li.

13 recordsLinked to original sources

arXiv2026

Orbital-selective band evolution and out-of-plane correlation in the FeGe-family kagome antiferromagnet ScFe$_6$Ge$_6$

In strongly correlated materials such as high-temperature superconductors, the relation between charge density wave (CDW) order and magnetism remains an important unresolved problem. FeGe is the first kagome metal known to exhibit CDW order deep within an antiferromagnetic state, accompanied by an unconventional evolution of lattice symmetry. To elucidate the general conditions governing such spin-correlated CDW order, we investigate ScFe$_6$Ge$_6$, which lacks CDW order and therefore exhibits reduced involvement of charge degrees of freedom while retaining other properties of FeGe. Instead of a CDW order, ScFe$_6$Ge$_6$ undergoes a magnetic transition at $T^*$ = 195 K. Across this transition, angle-resolved photoemission and Raman spectroscopy reveal orbital-selective behavior confined to a single kagome Dirac band, together with electron-phonon and magnetoelastic coupling to an out-of-plane phonon mode. These results suggest that orbital-selective physics and out-of-plane correlations play enhanced roles in realizing spin-correlated CDW order in magnetic kagome metals.

cond-mat.str-el↗

arXiv2026

Termination-Dependent Surface States and Magnetic Fingerprints of Chiral Helimagnet Cr1/3TaS2

Chiral helimagnets based on intercalated transition-metal dichalcogenides, characterized by nano-scale spin ordering, provide a powerful route to engineer chiral spin textures (e.g. the topologically protected magnetic solitons) and emergent electronic functionality at reduced dimensions, where surface and interface states often dominate device operation. However, despite growing interest, direct experimental studies of termination-dependent surface electronic structures and their temperature-driven magnetic evolution remain largely unexplored, hindering a microscopic understanding of the electronic states that is crucial for the development of low-dimensional spintronic devices. Here, for the first time, taking Cr1/3TaS2 as a representative example, we systematically investigate the termination-dependent surface electronic states of the chiral helimagnets and uncover their distinct temperature evolution across the magnetic transition (TC~142K) by combining high-resolution ARPES with a micro-focused beam and surface-state-resolved first-principles calculations. The TaS2-terminated surface hosts folded monolayer-like TaS2 bands under the $\sqrt3\times\sqrt3$ superlattice potential and a shallow triangular electron pocket at the superlattice $\bar K$ point arising from Cr-Ta orbital hybridization. In contrast, the Cr-terminated surface exhibits reconstructed hole pockets with pronounced magnetic band splitting. This splitting disappears above TC and closely follows the chiral helimagnetic order parameter, providing a direct spectroscopic fingerprint of chiral helimagnetic order. In addition, multiple ultranarrow Cr-d-derived surface flat bands are resolved. These findings establish Cr1/3TaS2 as a model system in which surface electronic states are strongly coupled to chiral magnetism, opening new opportunities for chiral spintronic and valleytronic micro/nanodevices.

cond-mat.mtrl-sci↗

arXiv2026

Multiple Topological States in LaAgAs2, a Failed Square-Net Semimetal

The rational design of new materials emerges as an important direction to explore new topological materials, which is based on the understanding of the correlation between crystal and electronic structures. In this paper, we perform a comprehensive study on the crystal and electronic structures in LaAgAs2 through a combination of single-crystal x-ray diffraction (XRD), quantum oscillation, and angle-resolved photoemission spectroscopy (ARPES) experimental measurements, and density functional theory (DFT) calculations. Single-crystal XRD measurements reveal that LaAgAs2 crystallizes into a HfCuSi2-derived structure with the square net distorted into cis-trans chains. Quantum oscillation measurements reveal two frequencies with small effective masses and quasi-two-dimensional (2D) characters. ARPES measurements reveal an electronic structure strikingly different from the square-net-based semimetals, such as LaAgAs2. The Fermi surface is quasi-two-dimensional (2D), with Dirac-like hole pockets at the zone center and a quasi-1D elliptical electron pocket at the zone boundary. Based on the DFT calculations, the measured electronic structure can be well understood regarding the cis-trans distortion, which transforms the two-dimensional square net-derived Dirac bands into quasi-1D trivial bands. Intriguingly, multiple topological states can be identified around the zone center, including a nontrivial Z2 topological surface state and a bulk Dirac state. Our study clarifies the impact of cis-trans distortion and identifies LaAgAs2 as a topological material with multiple topological states near the Fermi level, providing a guideline for intentionally designing new topological materials.

cond-mat.mtrl-sci↗

arXiv2026

Unusual Dual Flat Bands and two-dimensional Dirac-node Arc State in Kagome Metal Ni3In2S2

Kagome materials are at the frontier of condensed matter physics. An ideal kagome lattice features only one geometrically frustrated flat band spanning the entire momentum space and a single Dirac cone at the Brillouin-zone corners. However, for the first time, here we observe unusual flat-band and Dirac physics in the newly discovered "322" kagome material Ni3In2S2 by combining high-resolution synchrotron- and laser-based angle-resolved photoemission spectroscopy with a micro-focused beam, scanning tunneling microscopy, and first-principles calculations. We resolve two distinct electronic flat-band states located in close proximity to the Fermi level: a robust Topological Surface Flat Band at ~40 meV below the Fermi level on the Sulfur-terminated surface, originating from weak topological insulator states, and a kagome lattice-derived flat band at ~100 meV binding energy with an ultranarrow bandwidth (~5 meV). Instead of the single Dirac cone, the Indium-terminated surface hosts a rare two-dimensional Dirac-node arc state, where the gapless Dirac nodes extend along an open one-dimensional line crossing the Brillouin-zone boundary, exhibiting sharp linear dispersion, exceptionally high Fermi velocity, and pronounced circular dichroism. These findings establish Ni3In2S2 as a unique topological kagome metal in which multiple flat-band states of different physical origin coexist with an unusual Dirac-node arc, opening an avenue for discovering flat-band--driven and topology-enabled quantum phenomena.

cond-mat.mtrl-sci↗

arXiv2025

Surface reconstruction and orthogonal decoupling in SrAl4 and EuAl4

Surface-induced symmetry breaking in quantum materials can stabilize exotic electronic phases distinct from those in the bulk, yet its momentum-space manifestations remain elusive due to domain-averaging effects. Here, using angle-resolved photoemission spectroscopy (ARPES) and scanning tunneling microscopy (STM), we present a microscopic investigation of the electronic structures of SrAl4 and EuAl4, layered tetragonal intermetallic compounds that exhibit well-characterized incommensurate charge-density-wave (CDW) transitions. Below the CDW transition temperatures, we uncover linearly dispersing electronic states and pronounced unidirectional replica bands orthogonal to the bulk CDW wave vector, evidencing the emergence of an in-plane C4 symmetry-breaking electronic order that is not dictated by the bulk incommensurate CDW. STM measurements further reveal a 1 times 2 surface reconstruction with quasi-one-dimensional modulations and half-unit-cell steps, traced to ordered 50 percent Sr/Eu vacancies, which vanish irreversibly upon thermal cycling, indicating decoupled surface and bulk orders. These findings establish SrAl4 and EuAl4 as model platforms for exploring surface-confined nematicity and emergent low-dimensional phases in quantum materials.

cond-mat.mtrl-sci↗

arXiv2025

Orbital-selective charge transfer drives two-step negative thermal expansion structural transitions in PbTa2Se4

The negative thermal expansion (NTE) effect has been found generally combined with structural phase transitions. However, the charge and orbital freedoms of the NTE has not been well studied. This study employs angle-resolved photoemission spectroscopy and first-principles calculations to elucidate the charge and orbital kinetics of the anomalous two-step negative thermal expansion structural phase transitions in PbTa2Se4. As the temperature decreases, each transition undergoes a similar block-layer sliding, although the charge transfer behaviors differ significantly. During the first transition, charge is mainly transferred from the Pb 6pz orbital to an M-shaped band below the Fermi level, barely altering the Fermi surface. In contrast, the second transition involves modifications to both the Fermi surface and charge-transfer orbitals, with charge selectively transferred from Pb 6px/py orbitals to Ta 5dz2 orbitals and a decrease of the Fermi pockets formed by Pb 6px/py orbitals. Furthermore, a small pressure can easily tune the base structure phase among the three phases and the corresponding superconductivity. Therefore, our findings reveal that the orbital-selective charge transfer drives the unusual structure transition in PbTa2Se4, offering new insights into the NTE mechanisms and providing a unique window to study the pressure-tuned superconductivity in this metal-intercalated transition chalcogenides.

cond-mat.mtrl-sci↗

arXiv2025

Unconventional band splitting of CeSb in the devil's staircase transition

The interplay between magnetism and electronic band structure is a central theme in condensed matter physics. CeSb, with its complex devil's staircase antiferromagnetic transition, offers a unique opportunity to explore this interplay. Using angle-resolved photoemission spectroscopy (ARPES), we investigate the electronic structure evolution across the devil's staircase transition. Upon entering the antiferromagnetic phase, we observe an intriguing band splitting of the electron pocket around the X point. The energy separation between the split bands changes abruptly with temperature, consistent with the characteristics of the first-order phase transition. However, their respective spectral weights behave gradually with temperature. Combined with our density functional theory (DFT) calculations, we suggest that this atypical behavior deviates from conventional magnetically induced band splitting and potentially arises from the intricate modulation of paramagnetic and antiferromagnetic layers within the devil's staircase transition. Our results provide insights into the complex relationship between electronic structure and magnetism in correlated electron systems.

cond-mat.str-el↗

arXiv2024

Large band-splitting in $g$-wave type altermagnet CrSb

Altermagnetism (AM), a newly discovered magnetic state, ingeniously integrates the properties of ferromagnetism and antiferromagnetism, representing a significant breakthrough in the field of magnetic materials. Despite experimental verification of some typical AM materials, such as MnTe and MnTe$_2$, the pursuit of AM materials that feature larger spin splitting and higher transition temperature is still essential. Here, our research focuses on CrSb, which possesses N{é}el temperature of up to 700K and giant spin splitting near the Fermi level ($E_F$). Utilizing high-resolution angle-resolved photoemission spectroscopy and density functional theory calculations, we meticulously map the three-dimensional electronic structure of CrSb. Our photoemission spectroscopic results on both (0001) and (10$\overline{1}$0) cleavages of CrSb collaboratively reveal unprecedented details on AM-induced band splitting, and subsequently pin down its unique bulk $g$-wave symmetry through quantitative analysis of the angular and photon-energy dependence of spin splitting. Moreover, the observed spin splitting reaches the magnitude of 0.93~eV near $E_F$, the most substantial among all confirmed AM materials. This study not only validates the nature of CrSb as a prototype $g$-wave like AM material but also underscores its pivotal role in pioneering applications in spintronics.

cond-mat.mtrl-sci↗

arXiv2024

Absence of altermagnetic spin splitting character in rutile oxide RuO$_2$

Rutile RuO$_2$ has been posited as a potential $d$-wave altermagnetism candidate, with a predicted significant spin splitting up to 1.4 eV. Despite accumulating theoretical predictions and transport measurements, direct spectroscopic observation of spin splitting has remained elusive. Here, we employ spin- and angle-resolved photoemission spectroscopy to investigate the band structures and spin polarization of thin-film and single-crystal RuO$_2$. Contrary to expectations of altermagnetism, our analysis indicates that RuO$_2$'s electronic structure aligns with those predicted under non-magnetic conditions, exhibiting no evidence of the hypothesized spin splitting. Additionally, we observe significant in-plane spin polarization of the low-lying bulk bands, which is antisymmetric about the high-symmetry plane and contrary to the $d$-wave spin texture due to time-reversal symmetry breaking in altermagnetism. These findings definitively challenge the altermagnetic order previously proposed for rutile RuO$_2$, prompting a reevaluation of its magnetic properties.

cond-mat.mtrl-sci↗

arXiv2023

Direct observation of topological surface states in the layered kagome lattice with broken time-reversal symmetry

Magnetic topological quantum materials display a diverse range of fascinating physical properties which arise from their intrinsic magnetism and the breaking of time-reversal symmetry. However, so far, few examples of intrinsic magnetic topological materials have been confirmed experimentally, which significantly hinder our comprehensive understanding of the abundant physical properties in this system. The kagome lattices, which host diversity of electronic structure signatures such as Dirac nodes, flat bands, and saddle points, provide an alternative and promising platform for in-depth investigations into correlations and band topology. In this article, drawing inspiration from the stacking configuration of MnBi$_2$Te$_4$, we conceive and then synthesize a high-quality single crystal EuTi$_3$Bi$_4$, which is a unique natural heterostructure consisting of both topological kagome layers and magnetic interlayers. We investigate the electronic structure of EuTi$_3$Bi$_4$ and uncover distinct features of anisotropic multiple Van Hove singularitie (VHS) that might prevent Fermi surface nesting, leading to the absence of a charge density wave (CDW). In addition, we identify the topological nontrivial surface states that serve as connections between different saddle bands in the vicinity of the Fermi level. Combined with calculations, we establish that, the effective time-reversal symmetry S=$θ$$τ_{1/2}$ play a crucial role in the antiferromagnetic ground state of EuTi$_3$Bi$_4$, which ensures the stability of the topological surface states and gives rise to their intriguing topological nature. Therefore, EuTi$_3$Bi$_4$ offers the rare opportunity to investigate correlated topological states in magnetic kagome materials.

cond-mat.str-el↗

arXiv2023

Photoemission Evidence of a Novel Charge Order in Kagome Metal FeGe

A charge order has been discovered to emerge deep into the antiferromagnetic phase of the kagome metal FeGe. To study its origin, the evolution of the low-lying electronic structure across the charge order phase transition is investigated with angle-resolved photoemission spectroscopy. We do not find signatures of nesting between Fermi surface sections or van-Hove singularities in zero-frequency joint density of states, and there are no obvious energy gaps at the Fermi level, which exclude the nesting mechanism for the charge order formation in FeGe. However, two obvious changes in the band structure have been detected, i.e., one electron-like band around the K point and another one around the A point move upward in energy position when the charge order forms. These features can be well reproduced by our density-functional theory calculations, where the charge order is primarily driven by magnetic energy saving via large dimerizations of a quarter of Ge1-sites (in the kagome plane) along the c-axis. Our results provide strong support for this novel charge order formation mechanism in FeGe, in contrast to the conventional nesting mechanism.

cond-mat.str-el↗

arXiv2023

Origin of the exotic electronic states in antiferromagnetic NdSb

Using angle resolved photoemission spectroscopy measurements and first principle calculations, we report that the possible unconventional 2q antiferromagnetic (AFM) order in NdSb can induce unusual modulation on its electronic structure. The obvious extra bands observed in the AFM phase of NdSb are well reproduced by theoretical calculations, in which the Fermi-arc-like structures and sharp extra bands are originated from the in-gap surface states. However, they are demonstrated to be topological trivial. By tuning the chemical potential, the AFM phase of NdSb would go through a topological phase transition, realizing a magnetic topological insulator phase. Hence, our study sheds new light on the rare earth monopnictides for searching unusual AFM structure and the potential of intrinsic magnetic topological materials.

cond-mat.mtrl-sci↗

arXiv2021

OneVision: Centralized to Distributed Controller Synthesis with Delay Compensation

We propose a new algorithm to simplify the controller development for distributed robotic systems subject to external observations, disturbances, and communication delays. Unlike prior approaches that propose specialized solutions to handling communication latency for specific robotic applications, our algorithm uses an arbitrary centralized controller as the specification and automatically generates distributed controllers with communication management and delay compensation. We formulate our goal as nonlinear optimal control -- using a regret minimizing objective that measures how much the distributed agents behave differently from the delay-free centralized response -- and solve for optimal actions w.r.t. local estimations of this objective using gradient-based optimization. We analyze our proposed algorithm's behavior under a linear time-invariant special case and prove that the closed-loop dynamics satisfy a form of input-to-state stability w.r.t. unexpected disturbances and observations. Our experimental results on both simulated and real-world robotic tasks demonstrate the practical usefulness of our approach and show significant improvement over several baseline approaches.

cs.RO↗