arXiv subjects

Tuson Park

Publications and source records attributed to Tuson Park.

At least 37 records · Page 2Linked to original sources

arXiv2022

Emergent nematicity and intrinsic vs. extrinsic electronic scattering processes in the kagome metal CsV$_3$Sb$_5$

Fermi surface fluctuations and lattice instabilities in the 2D metallic kagome superconductor CsV$_3$Sb$_5$ are elucidated via polarization-resolved Raman spectroscopy. The presence of a weak electronic continuum in high-quality samples marks the cross-over into the charge-density-wave (CDW) ordered phase, while impurity-rich samples promote strong defect-induced electronic scattering processes that affect the coherence of the CDW phase. CDW-induced phonon anomalies appear below $T_{\mathrm{CDW}}$, with emergent $C2$ symmetry for one of the CDW amplitude modes, alluding to nematicity. In conjunction with symmetry-breaking lattice distortions, a kink-like hardening of the A$_{1g}$ phonon energy at $T_{\mathrm{CDW}}$ signifies a concerted interplay of electronic correlations and electron-phonon coupling in the exotic CDW order.

cond-mat.str-el↗

arXiv2021

Magnetic-order-driven metal-insulator transitions in the quasi-one-dimensional spin-ladder compounds BaFe$_2$S$_3$ and BaFe$_2$Se$_3$

The quasi-one-dimensional spin ladder compounds, BaFe$_2$S$_3$ and BaFe$_2$Se$_3$, are investigated by infrared spectroscopy and density functional theory (DFT) calculations. We observe strong anisotropic electronic properties and an optical gap in the leg direction that is gradually filled above the antiferromagnetic (afm) ordering temperature, turning the systems into a metallic phase. Combining the optical data with the DFT calculations we associate the optical gap feature with the $p$-$d$ transition that appears only in the afm ordered state. Hence, the insulating ground state along the leg direction is attributed to Slater physics rather than Mott-type correlations.

cond-mat.str-el↗

arXiv2020

Crystalline symmetry-dependent magnon formation in itinerant ferromagnet SrRuO3

SrRuO3 (SRO) is an itinerant ferromagnet with strong coupling between the charge, spin, and lattice degrees of freedom. This strong coupling suggests that the electronic and magnetic behaviors of SRO are highly susceptible to changes in the lattice distortion. Here we show how the spin interaction and resultant magnon formation change with the modification in the crystallographic orientation. We fabricated SRO epitaxial thin films with (100), (110), and (111) surface orientations, to systematically modulate the spin interaction and spin dimensionality. The reduced spin dimensionality and enhanced exchange interaction in the (111)-oriented SRO thin film significantly suppresses magnon formation. Our study comprehensively demonstrates the facile tunability of magnon formation and spin interaction in correlated oxide thin films.

cond-mat.str-el↗

arXiv2020

Structural and optical properties of single- and few-layer magnetic semiconductor CrPS4

Atomically thin binary 2-dimensional (2D) semiconductors exhibit diverse physical properties depending on their composition, structure and thickness. By adding another element in those materials, which will lead to formation of ternary 2D materials, the property and structure would greatly change and significantly expanded applications could be explored. In this work, we report structural and optical properties of atomically thin chromium thiophosphate (CrPS4), a ternary antiferromagnetic semiconductor. Its structural details were revealed by X-ray and electron diffractions. Transmission electron microscopy showed that preferentially-cleaved edges are parallel to diagonal Cr atom rows, which readily identified their crystallographic orientations. Strong in-plane optical anisotropy induced birefringence that also enabled efficient determination of crystallographic orientation using polarized microscopy. The lattice vibrations were probed by Raman spectroscopy for the first time and exhibited significant dependence on thickness of crystals exfoliated down to single layer. Optical absorption determined by reflectance contrast was dominated by d-d type transitions localized at Cr3+ ions, which was also responsible for the major photoluminescence peak at 1.31 eV. The spectral features in the absorption and emission spectra exhibited noticeable thickness-dependence and hinted a high photochemical activity for single layer CrPS4. The current structural and optical investigation will provide a firm basis for future study and application of this novel magnetic semiconductor.

cond-mat.mtrl-sci↗

arXiv2019

Artificially Engineered Nanostrain in Iron Chalcogenide Superconductor Thin Film for Enhancing Supercurrent

Although nanoscale deformation, such as nanostrain in iron chalcogenide (FeSexTe1-x, FST) thin films, has attracted attention owing to the enhancement of general superconducting properties, including critical current density (Jc) and critical transition temperature, its formation has proven to be an extremely challenging and complex process thus far. Herein, we successfully fabricated an epitaxial FST thin film with uniformly distributed nanostrain by injection of a trace amount of CeO2 inside FST matrix using sequential pulsed laser deposition. Using transmission electron microscopy and geometrical phase analysis, we verified that a trace amount of CeO2 injection forms nanoscale fine defects with a nanostrained region, which has a tensile strain (ezz ~ 0.02) along the c-axis of the FST matrix. The nanostrained FST thin film achieves a remarkable Jc of 3.5 MA/cm2 for a self-field at 6 K and a highly enhanced Jc under the entire magnetic field with respect to a pristine FST thin film.

cond-mat.supr-con↗

arXiv2019

Tunable quantum critical point and detached superconductivity in Al-doped CrAs

The origin of unconventional superconductivity and its relationship to a T=0 K continuous quantum phase transition (a quantum critical point, QCP), which is hidden inside the dome of a superconducting state, have long been an outstanding puzzle in correlated superconductors. The observation and tuning of the hidden QCP, which is critical in resolving the mystery, however, has been rarely reported due to lack of ideal systems. The helical antiferromagnet CrAs provides an example in which a dome of superconductivity appears at a pressure where its magnetic transition goes to zero temperature. Here we report the tuning of a projected critical point in CrAs via Al chemical doping (Al-CrAs) and separation of the magnetic critical point from the pressure-induced superconducting phase. When CrAs is doped with Al, its AFM ordering temperature TN increases from 260 K to 270 K. With applied pressure, TN decreases and extrapolates to zero Kelvin near 4.5 kbar, which is shifted from 8 kbar for undoped CrAs. A funnel of anomalously enhanced electron scattering and a non-Fermi liquid resistivity underscore an AFM QCP near 4.5 kbar in Al-CrAs. Pressure-induced superconductivity, in contrast, is almost independent of Al doping and forms a dome with essentially the identical maximum Tc and same optimal pressure as in pure CrAs. The clear separation between the tuned AFM QCP and Tc maximum in Al-CrAs suggests that superconductivity is independent of the AFM QCP, illustrating subtleties in the interplay between superconductivity and quantum criticality in correlated electron systems.

cond-mat.supr-con↗

arXiv2018

Influence of carbon-ion irradiation on the superconducting critical properties of MgB$_2$ thin films

We investigate the influence of carbon-ion irradiation on the superconducting critical properties of MgB$_2$ thin films. MgB$_2$ films of two thicknesses viz. 400 nm (MB400nm) and 800 nm (MB800nm) were irradiated by 350 keV C ions having a wide range of fluence, 1 x 10$^{13}$ - 1 x 10$^{15}$ C atoms/cm$^2$. The mean projected range ($R_p$) of 350 keV C ions in MgB$_2$ is 560 nm, thus the energetic C ions will pass through the MB400nm, whereas the ions will remain into the MB800nm. The superconducting transition temperature ($T_c$), upper critical field ($H_{c2}$), $c$-axis lattice parameter, and corrected residual resistivity ($ρ_{corr}$) of both the films showed similar trends with the variation of fluence. However, a disparate behavior in the superconducting phase transition was observed in the MB800nm when the fluence was larger than 1 x 10$^{14}$ C atoms/cm$^2$ because of the different Tcs between the irradiated and non-irradiated parts of the film. Interestingly, the superconducting critical properties, such as $T_c$, $H_{c2}$, and $J_c$, of the irradiated MgB$_2$ films, as well as the lattice parameter, were almost restored to those in the pristine state after a thermal annealing procedure. These results demonstrate that the atomic lattice distortion induced by C-ion irradiation is the main reason for the change in the superconducting properties of MgB$_2$ films.

cond-mat.supr-con↗

arXiv2018

Enhanced magnetic and thermoelectric properties in epitaxial polycrystalline SrRuO3 thin film

Transition metal oxide thin films show versatile electrical, magnetic, and thermal properties which can be tailored by deliberately introducing macroscopic grain boundaries via polycrystalline solids. In this study, we focus on the modification of the magnetic and thermal transport properties by fabricating single- and polycrystalline epitaxial SrRuO3 thin films using pulsed laser epitaxy. Using epitaxial stabilization technique with atomically flat polycrystalline SrTiO3 substrate, epitaxial polycrystalline SrRuO3 thin film with crystalline quality of each grain comparable to that of single-crystalline counterpart is realized. In particular, alleviated compressive strain near the grain boundaries due to coalescence is evidenced structurally, which induced enhancement of ferromagnetic ordering of the polycrystalline epitaxial thin film. The structural variations associated with the grain boundaries further reduce the thermal conductivity without deteriorating the electronic transport, and lead to enhanced thermoelectric efficiency in the epitaxial polycrystalline thin films, compared with their single-crystalline counterpart.

cond-mat.mtrl-sci↗

arXiv2018

A peak in the critical current for quantum critical superconductors

Generally, studies of the critical current Ic are necessary if superconductors are to be of practical use because Ic sets the current limit below which there is a zero-resistance state. Here, we report a peak in the pressure dependence of the zero-field Ic, Ic(0), at a hidden quantum critical point (QCP), where a continuous antiferromagnetic transition temperature is suppressed by pressure toward 0 K in CeRhIn5 and 4.4% Sn-doped CeRhIn5. The Ic(0)s of these Ce-based compounds under pressure exhibit a universal temperature dependence, underlining that the peak in zero-field Ic(P) is determined predominantly by critical fluctuations associated with the hidden QCP. The dc conductivity is a minimum at the QCP, showing anti-correlation with Ic(0). These discoveries demonstrate that a quantum critical point hidden inside the superconducting phase in strongly correlated materials can be exposed by the zero-field Ic, therefore providing a direct link between a QCP and unconventional superconductivity.

cond-mat.supr-con↗

arXiv2018

Hard magnetic properties in nanoflake van der Waals Fe3GeTe2

Two dimensional (2D) van der Waals (vdW) materials have demonstrated fascinating optical, electrical and thickness-dependent characteristics. These have been explored by numerous authors but reports on magnetic properties and spintronic applications of 2D vdW materials are scarce by comparison. By performing anomalous Hall effect transport measurements, we have characterised the thickness dependent magnetic properties of single crystalline vdW Fe3GeTe2. The nanoflakes of this vdW metallic material exhibit a single hard magnetic phase with a near square-shaped magnetic loop, large coercivity (up to 550 mT at 2 K), a Curie temperature near 200 K and strong perpendicular magnetic anisotropy. Using criticality analysis, we confirmed the existence of magnetic coupling between vdW atomic layers and obtained an estimated coupling length of ~ 5 vdW layers in Fe3GeTe2. Furthermore, the hard magnetic behaviour of Fe3GeTe2 can be well described by a proposed model. The magnetic properties of Fe3GeTe2 highlight its potential for integration into vdW magnetic heterostructures, paving the way for spintronic research and applications based on these devices.

cond-mat.mtrl-sci↗

arXiv2016

Pressure dependence of upper critical fields in FeSe single crystals

We investigate the pressure dependence of the upper critical fields (μ$_0$$H$$_{c2}$) for FeSe single crystals with pressure up to 2.57 GPa. The superconducting (SC) properties show a disparate behavior across a critical pressure where the pressure-induced antiferromagnetic phase coexists with superconductivity. The magnetoresistance for $H//ab$ and $H//c$ is very different: for $H//c$, magnetic field induces and enhances a hump in the resistivity close to the $T_c$ for pressures higher than 1.2 GPa, while it is absent for $H//ab$. Since the measured μ$_0$$H$$_{c2}$ for FeSe samples is smaller than the orbital limited upper critical field ($H$$^{orb}$$_{c2}$) estimated by the Werthamer Helfand and Hohenberg (WHH) model, the Maki parameter (α) related to Pauli spin-paramagnetic effects is additionally considered to describe the temperature dependence of μ$_0$$H$$_{c2}$($T$). Interestingly, the α value is hardly affected by pressure for $H//ab$, while it strongly increases with pressure for $H//c$. The pressure evolution of the μ$_0$$H$$_{c2}$(0)s for the FeSe single crystals is found to be almost similar to that of $T_c$($P$), suggesting that the pressure-induced magnetic order adversely affects the upper critical fields as well as the SC transition temperature.

cond-mat.supr-con↗

arXiv2015

Enhanced critical current density in the pressure-induced magnetic state of the high-temperature superconductor FeSe

We investigate the relation of the critical current density (Jc) and the remarkably increased superconducting transition temperature (Tc) for the FeSe single crystals under pressures up to 2.43 GPa, where the Tc is increased by ~8 K/GPa. The critical current density corresponding to the free flux flow is monotonically enhanced by pressure which is due to the increase in Tc, whereas the depinning critical current density at which the vortex starts to move is more influenced by the pressure-induced magnetic state compared to the increase of Tc. Unlike other high-Tc superconductors, FeSe is not magnetic, but superconducting at ambient pressure. Above a critical pressure where magnetic state is induced and coexists with superconductivity, the depinning Jc abruptly increases even though the increase of the zero-resistivity Tc is negligible, directly indicating that the flux pinning property compared to the Tc enhancement is a more crucial factor for an achievement of a large Jc. In addition, the sharp increase in Jc in the coexisting superconducting phase of FeSe demonstrates that vortices can be effectively trapped by the competing antiferromagnetic order, even though its antagonistic nature against superconductivity is well documented. These results provide new guidance toward technological applications of high-temperature superconductors.

cond-mat.supr-con↗

arXiv2015

Pressure-tuned quantum criticality in the antiferromagnetic Kondo semi-metal CeNi$_{2-δ}$As$_2$

The easily tuned balance among competing interactions in Kondo-lattice metals allows access to a zero-temperature, continuous transition between magnetically ordered and disordered phases, a quantum-critical point (QCP). Indeed, these highly correlated electron materials are prototypes for discovering and exploring quantum-critical states. Theoretical models proposed to account for the strange thermodynamic and electrical transport properties that emerge around the QCP of a Kondo lattice assume the presence of an indefinitely large number of itinerant charge carriers. Here, we report a systematic transport and thermodynamic investigation of the Kondo-lattice system CeNi$_{2-δ}$As$_2$ ($δ$$\thickapprox$0.28) as its antiferromagnetic order is tuned by pressure and magnetic field to zero-temperature boundaries. These experiments show that the very small but finite carrier density of $\sim$0.032 $e^-$/f.u. in CeNi$_{2-δ}$As$_2$ leads to unexpected transport signatures of quantum criticality and the delayed development of a fully coherent Kondo lattice state with decreasing temperature. The small carrier density and associated semi-metallicity of this Kondo-lattice material favor an unconventional, local-moment type of quantum criticality and raise the specter of Nozières exhaustion idea that an insufficient number of conduction-electron spins to separately screen local moments requires collective Kondo screening.

cond-mat.str-el↗

arXiv2015

Hidden non-Fermi liquid behavior caused by magnetic phase transition in Ni-doped Ba-122 pnictides

We studied two BaFe2-xNixAs2 (Ni-doped Ba-122) single crystals at two dfferent doping levels (underdoped and optimally doped) using an optical spectroscopic technique. The underdoped sample shows a magnetic phase transition around 80 K. We analyze the data with a Drude-Lorentz model with two Drude components (D1 and D2). It is known that the narrow D1 component originates from electron carriers in the electron-pockets and the broad D2 mode is from hole carriers in the hole-pockets. While the plasma frequencies of both Drude components and the static scattering rate of the broad D2 component show negligible temperature dependencies, the static scattering rate of the D1 mode shows strong temperature dependence for the both samples. We observed a hidden quasi-linear temperature dependence in the scattering rate of the D1 mode above and below the magnetic transition temperature while in the optimally doped sample the scattering rate shows a more quadratic temperature dependence. The hidden non-Fermi liquid behavior in the underdoped sample seems to be related to the magnetic phase of the material.

cond-mat.supr-con↗

arXiv2015

Superconductivity at 7.4 K in Few Layer Graphene by Li-intercalation

Superconductivity in graphene has been highly sought after for its promise in various device applications and for general scientific interest. Ironically, the simple electronic structure of graphene, which is responsible for novel quantum phenomena, hinders the emergence of superconductivity. Theory predicts that doping the surface of the graphene effectively alters the electronic structure, thus promoting propensity towards Cooper pair instability. Here we report the emergence of superconductivity at 7.4 K in Li-intercalated few-layer-graphene (FLG). The absence of superconductivity in three-dimensional Li-doped graphite underlines that superconductivity in Li-FLG arises from the novel electronic properties of the two-dimensional graphene layer. These results are expected to guide future research on graphene-based superconductivity, both in theory and experiments. In addition, easy control of the Li-doping process holds promise for various device applications.

cond-mat.supr-con↗

arXiv2015

Spectroscopic evidence for two-gap superconductivity in the quasi-one dimensional chalcogenide Nb$_{2}$Pd$_{0.81}$S$_{5}$

We present the first direct evidence for two-band superconductivity in the quasi-one dimensional chalcogenide Nb$_{2}$Pd$_{0.81}$S$_{5}$. Soft point contact spectroscopic measurements reveal Andreev reflection in the differential conductance $G$ in the zero-resistance superconducting (SC) state below $T_c$(=6.6~K). Multiple peaks in $G$ were clearly observed at 1.8~K and were successfully explained by the two-band Blonder-Tinkham-Klapwijk model with two gaps $Δ_{1}=0.48$~meV and $Δ_{2}=1.05$~meV. Their evolution in temperature and magnetic field is consistent with the conventional BCS theory. The SC gap to $T_c$ ratio for $Δ_1$ and $Δ_2$ is 1.7 and 3.7, which is similar to the weak coupling BCS prediction of 3.5. These results demonstrate that the newly discovered niobium chalcogenide is a two-gap superconductor in the weak coupling limit.

cond-mat.supr-con↗

arXiv2014

Disorder in a Quantum Critical Superconductor

In four classes of materials, the layered copper-oxides, organics, iron-pnictides and heavy-fermion compounds, an unconventional superconducting state emerges as a magnetic transition is tuned toward absolute zero temperature, that is, toward a magnetic quantum-critical point (QCP). In most materials, the QCP is accessed by chemical substitutions or applied pressure. CeCoIn5 is one of the few materials that are born as a quantum-critical superconductor and, therefore, offers the opportunity to explore the consequences of chemical disorder. Cadmium-doped crystals of CeCoIn5 are a particularly interesting case where Cd substitution induces long-range magnetic order, as in Zn-doped copper-oxides. Applied pressure globally supresses the Cd-induced magnetic order and restores bulk superconductivity. Here we show, however, that local magnetic correlations, whose spatial extent decreases with applied pressure, persist at the extrapolated QCP. The residual droplets of impurity-induced magnetic moments prevent the reappearance of conventional signatures of quantum criticality, but induce a heterogeneous electronic state. These discoveries show that spin droplets can be a source of electronic heterogeneity in classes of strongly correlated electron systems and emphasize the need for caution when interpreting the effects of tuning a correlated system by chemical substitution.

cond-mat.supr-con↗

arXiv2012

Pressure effects on the superconducting thin film Ba$_{1-x}$K$_{x}$Fe$_{2}$As$_{2}$

We report electrical resistivity measurements on a high-quality Ba$_{1-x}$K$_{x}$Fe$_{2}$As$_{2}$ thin film ($x=0.4$) under pressure. The superconducting transition temperature (=39.95 K) of the optimally-doped thin film shows a dome shape with pressure, reaching a maximal value 40.8 K at 11.8 kbar. The unusually high superconducting transition temperature and its anomalous pressure dependence are ascribed to a lattice mismatch between the LaAlO$_3$ substrate and the thin film. The local temperature exponent of the resistivity ($n=d\text{ln}Δρ/d\text{ln}T$) shows a funnel shape around the optimal pressure, suggesting that fluctuations associated with the anomalous normal state are responsible for high-temperature superconductivity.

cond-mat.supr-con↗