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Tyler James

Publications and source records attributed to Tyler James.

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Thomas-Fermi screening of electrostatic fields in a type-I superconductor

The empirical London equations make distinct predictions for a superconductor's longitudinal and transverse electrodynamic response. Conventionally, this framework attributes the Meissner effect to the transverse component, with the longitudinal response predicted to remain unchanged on entering the superconducting state, i.e. a static electric field is screened over the Thomas-Fermi length ($\lambda_{\mathrm{TF}} \sim 1$~\AA), just as in the nonsupercondcuting metal. J.~E.~Hirsch~[\textit{Phys.~ Rev.~B}~\textbf{69},~214515~(2004)] has developed an alternative formalism, which predicts that the longitudinal screening length should instead be governed by the London penetration depth as the system is cooled below the superconducting transition temperature ($T_{\mathrm{c}}$). Here we use a combination of qPlus atomic force microscopy and scanning tunneling microscopy/spectroscopy of single-crystal Pb(111) at $\sim$~340~mK~ \mbox{($T/T_{\mathrm{c}}\sim0.05$)} in an attempt to detect any modifications in electrostatic screening of the longitudinal tip field upon entering the superconducting phase. We quench superconductivity using a magnetic field of 200 mT normal to the Pb(111) surface. By measuring force-distance curves and local field-emission resonance spectra at the same sample position in the presence and absence of the magnetic field, we constrain the change in screening between the normal and superconducting state to less than $\sim 1 \%$. This is between two to three orders of magnitude smaller than that predicted by Hirsch's theory, and entirely consistent with unmodified Thomas-Fermi screening across the superconducting transition.

cond-mat.supr-con

Timing the Escape of a Caged Electron

Charge transfer is fundamentally dependent on the overlap of the orbitals comprising the transport pathway. This has key implications for molecular, nanoscale, and quantum technologies, for which delocalization (and decoherence) rates are essential figures of merit. Here, we apply the core hole clock technique - an energy-domain variant of ultrafast spectroscopy - to probe the delocalization of a photoexcited electron inside a closed molecular cage, namely the Ar 2p54s1 state of Ar@C60. Despite marginal frontier orbital mixing in the ground configuration, almost 80% of the excited state density is found outside the buckyball due to the formation of a markedly diffuse hybrid orbital. Far from isolating the intracage excitation, the surrounding fullerene is instead a remarkably efficient conduit for electron transfer: we measure characteristic delocalization times of 6.6 $\pm$ 0.3 fs and $\lesssim$ 500 attoseconds, respectively, for a 3D Ar@C60 film and a 2D monolayer on Ag(111).

physics.chem-ph