arXiv subjects

U. Zülicke

Publications and source records attributed to U. Zülicke.

At least 19 recordsLinked to original sources

arXiv2026

Standard model of electromagnetism and chirality in crystals

We present a general, quantitative theory of electromagnetism and chirality in crystals. Symmetry is its guiding principle, enabling us to consider macroscopic multipole densities without reference to specific microscopic configurations. We use a formal analogy between space inversion $i$ and time inversion $θ$ to identify two complementary, comprehensive classifications of crystals, based on five categories of electric and magnetic multipole order---called polarizations---and five categories of chirality. The five categories of polarizations (parapolar, electropolar, magnetopolar, antimagnetopolar, and multipolar) embody the ways in which multipole order can be realized in solids, thus expanding the familiar notion of electric dipolarization in ferroelectrics and magnetization in ferromagnets to higher-rank multipole densities characterizing, e.g., altermagnets and alterelectrics. Group theory also permits the absolute, gauge-invariant quantification of these multipole densities. The five categories of chirality (parachiral, electrochiral, magnetochiral, antimagnetochiral, and multichiral) extend the notion of enantiomorphism---conventionally associated with the lack of spatial mirror symmetries---to include all possibilities for creating non-superposable images by applying the inversions $i$, $θ$, and $iθ$. In particular, multichiral systems lack all inversion symmetries and thus have four different enantiomorphs. Each category of chirality arises from particular superpositions of electric and magnetic multipole densities. Our theory has great predictive power by relating electric and magnetic multipolar order with, e.g., distinctive features in the crystal structure, the electronic band structure, and property tensors of quantum materials. These findings are critical for a large community working on fundamental and applied aspects of novel quantum materials.

cond-mat.mtrl-sci↗

arXiv2025

Gauge-invariant absolute quantification of electric and magnetic multipole densities in crystals

Electric and magnetic multipole densities in crystalline solids, including the familiar electric dipole density in ferroelectrics and the magnetic dipole density in ferromagnets, are of central importance for our understanding of ordered phases in matter. However, determining the magnitude of these quantities has proven to be conceptually and technically difficult. Here we present a universally applicable approach, based on projection operators, that yields gauge-invariant absolute measures for all types of electric and magnetic order in crystals. We demonstrate the utility of the general theory using concrete examples of electric and magnetic multipole order in variants of lonsdaleite and diamond structures. Besides the magnetic dipole density in ferromagnets, we also consider, e.g., the magnetic octupole density in altermagnets. The robust method developed in this work lends itself to be incorporated into the suite of computational materials-science tools. The multipole densities can be used as thermodynamic state variables including Landau order parameters.

cond-mat.mtrl-sci↗

arXiv2025

Time inversion symmetry in the Dirac and Schrödinger-Pauli theories

The Schrödinger-Pauli theory is generally believed to give a faithful representation of the nonrelativistic and weakly relativistic limit of the Dirac theory. However, the Schrödinger-Pauli theory is fundamentally incomplete in its account of broken time inversion symmetry, e.g., in magnetically ordered systems. In the Dirac theory of the electron, magnetic order breaks time inversion symmetry even in the nonrelativistic limit, whereas time inversion symmetry is effectively preserved in the Schrödinger-Pauli theory in the absence of spin-orbit coupling. In the Dirac theory, the Berry curvature $1/(2m^2c^2)$ is thus an intrinsic property of nonrelativistic electrons similar to the well-known spin magnetic moment $e\hbar/(2m)$, while this result is missed by the nonrelativistic or weakly relativistic Schrödinger-Pauli equation. In ferromagnetically ordered systems, the intrinsic Berry curvature yields a contribution to the anomalous Hall conductivity independent of spin-orbit coupling.

cond-mat.mtrl-sci↗

arXiv2024

Odd-frequency superfluidity from a particle-number-conserving perspective

We investigate odd-in-time - or odd-frequency - pairing of fermions in equilibrium systems within the particle-number-conserving framework of Penrose, Onsager and Yang, where superfluid order is defined by macroscopic eigenvalues of reduced density matrices. We show that odd-frequency pair correlations are synonymous with even fermion-exchange symmetry in a time-dependent correlation function that generalises the two-body reduced density matrix. Macroscopic even-under-fermion-exchange pairing is found to emerge from conventional Penrose-Onsager-Yang condensation in two-body or higher-order reduced density matrices through the symmetry-mixing properties of the Hamiltonian. We identify and characterise a transformer matrix responsible for producing macroscopic even fermion-exchange correlations that coexist with a conventional Cooper-pair condensate, while a generator matrix is shown to be responsible for creating macroscopic even fermion-exchange correlations from hidden orders such as a multi-particle condensate. The transformer scenario is illustrated using the spin-balanced s-wave superfluid with Zeeman splitting as an example. The generator scenario is demonstrated by the composite-boson condensate arising for itinerant electrons coupled to magnetic excitations. Structural analysis of the transformer and generator matrices is shown to provide general conditions for odd-frequency pairing order to arise in a given system. Our formalism facilitates a fully general derivation of the Meissner effect for odd-frequency superconductors that holds also beyond the regime of validity for mean-field theory.

cond-mat.supr-con↗

arXiv2023

Theory of electric, magnetic, and toroidal polarizations in crystalline solids with applications to hexagonal lonsdaleite and cubic diamond

Multipolar order in bulk crystalline solids is characterized by multipole densities -- denoted as polarizations in this work -- that cannot be cleanly defined using the concepts of classical electromagnetism. Here we use group theory to overcome this difficulty and present a systematic study of electric, magnetic and toroidal multipolar order in crystalline solids. Based on our symmetry analysis, we identify five categories of polarized matter, each of which is characterized by distinct features in the electronic band structure. For example, Rashba spin splitting in electropolar bulk materials like wurtzite represents the electric dipolarization in these materials. We also develop a general formalism of indicators for individual multipole densities that provide a physical interpretation and quantification of multipolar order. Our work clarifies the relation between patterns of localized multipoles and macroscopic multipole densities they give rise to. To illustrate the general theory, we discuss its application to polarized variants of hexagonal lonsdaleite and cubic diamond structures. Our work provides a general framework for classifying and expanding current understanding of multipolar order in complex materials.

cond-mat.mtrl-sci↗

arXiv2022

Coexistence of topological and nontopological Fermi-superfluid phases

The two-dimensional spin-imbalanced Fermi gas subject to s-wave pairing and spin-orbit coupling is considered a promising platform for realizing a topological chiral-p-wave superfluid. In the BCS limit of s-wave pairing, i.e., when Cooper pairs are only weakly bound, the system enters the topological phase via a second-order transition driven by increasing the Zeeman spin-splitting energy. Stronger attractive two-particle interactions cause the system to undergo the BCS-BEC crossover, in the course of which the topological transition becomes first-order. As a result, topological and nontopological superfluids coexist in spatially separated domains in an extended region of phase space spanned by the strength of s-wave interactions and the Zeeman energy. Here we investigate this phase-coexistence region theoretically using a zero-temperature mean-field approach. Exact numerical results are presented to illustrate basic physical characteristics of the coexisting phases and to validate an approximate analytical description derived for weak spin-orbit coupling. Besides extending our current understanding of spin-imbalanced superfluid Fermi systems, the present approach also provides a platform for future studies of unconventional Majorana excitations that, according to topology, should be present at the internal interface between coexisting topological and nontopological superfluid parts of the system.

cond-mat.quant-gas↗

arXiv2020

Collinear Orbital Antiferromagnetic Order and Magnetoelectricity in Quasi-2D Itinerant-Electron Paramagnets, Ferromagnets and Antiferromagnets

We develop a comprehensive theory for magnetoelectricity in magnetically ordered quasi-2D systems whereby in thermal equilibrium an electric field can induce a magnetization $m$ and a magnetic field can induce a polarization. This effect requires that both space-inversion and time-reversal symmetry are broken. Antiferromagnetic (AFM) order plays a central role in this theory. We define a Néel operator $τ$ such that a nonzero expectation value $\langle τ\rangle$ signals AFM order, in the same way $m$ signals ferromagnetic (FM) order. While $m$ is even under space inversion and odd under time reversal, $τ$ describes a toroidal moment that is odd under both symmetries. Thus $m$ and $\langle τ\rangle$ quantify complementary aspects of magnetic order in solids. In quasi-2D systems FM order can be attributed to dipolar equilibrium currents that give rise to $m$. In the same way, AFM order arises from quadrupolar currents that generate the moment $\langle τ\rangle$. The electric-field-induced magnetization can then be attributed to the electric manipulation of the quadrupolar currents. We develop a $k \cdot p$ envelope-function theory for AFM diamond structures that allows us to derive explicit expressions for the operator $τ$. Considering FM zincblende and AFM diamond, we derive quantitative expressions for the magnetoelectric responses due to electric and magnetic fields that reveal explicitly the inherent duality of these responses required by thermodynamics. Magnetoelectricity is found to be small in realistic calculations for quasi-2D electron systems. The magnetoelectric response of quasi-2D hole systems turns out to be sizable, however, with moderate electric fields being able to induce a magnetic moment of one Bohr magneton per charge carrier. Our theory provides a broad framework for the manipulation of magnetic order by means of external fields.

cond-mat.mes-hall↗

arXiv2019

Chiral twodimensional p-wave superfluid from s-wave pairing in the BEC regime

Twodimensional spin-orbit-coupled Fermi gases subject to s-wave pairing can be driven into a topological phase by increasing the Zeeman spin splitting beyond a critical value. In the topological phase, the system exhibits the hallmarks of chiral p-wave superfluidity, including exotic Majorana excitations. Previous theoretical studies of this realization of a twodimensional topological Fermi superfluid have focused on the BCS regime where the s-wave Cooper pairs are only weakly bound and, hence, the induced chiral p-wave order parameter has a small magnitude. Motivated by the goal to identify potential new ways for the experimental realization of robust topological superfluids in ultra-cold atom gases, we study the BCS-to-BEC crossover driven by increasing the Cooper-pair binding energy for this system. In particular, we obtain phase diagrams in the parameter space of two-particle bound-state energy and Zeeman spin-splitting energy. Ordinary characteristics of the BCS-to-BEC crossover, in particular the shrinking and eventual disappearance of the Fermi surface, are observed in the nontopological phase. In contrast, the topological phase retains all features of chiral p-wave superfluidity, including a well-defined underlying Fermi surface, even for large s-wave pair-binding energies. Compared to the BCS limit, the topological superfluid in the BEC regime turns out to be better realizable even for only moderate magnitude of spin-orbit coupling because the chiral p-wave order parameter is generally larger and remnants of s-wave pairing are suppressed. We identify optimal parameter ranges that can aid further experimental investigations and elucidate the underlying physical reason for the persistence of the chiral p-wave superfluid.

cond-mat.quant-gas↗

arXiv2019

Spherical topological-insulator nanoparticles: Quantum size effects and optical transitions

We have investigated the interplay between band inversion and size quantization in spherically shaped nanoparticles made from topological-insulator (TI) materials. A general theoretical framework is developed based on a versatile continuum-model description of the TI bulk band structure and the assumption of a hard-wall mass confinement. Analytical results are obtained for the wave functions of single-electron energy eigenstates and the matrix elements for optical transitions between them. As expected from spherical symmetry, quantized levels in TI nanoparticles can be labeled by quantum numbers $j$ and $m=-j, -j+1, \dots, j$ for total angular momentum and its projection on an arbitrary axis. The fact that TIs are narrow-gap materials, where the charge-carrier dynamics is described by a type of two-flavor Dirac model, requires $j$ to assume half-integer values and also causes a doubling of energy-level degeneracy where two different classes of states are distinguished by being parity eigenstates with eigenvalues $(-1)^{j\mp 1/2}$. The existence of energy eigenstates having the same $j$ but opposite parity enables optical transitions where $j$ is conserved, in addition to those adhering to the familiar selection rule where $j$ changes by $\pm 1$. All optical transitions satisfy the usual selection rule $Δm = 0, \pm 1$. We treat intra- and inter-band optical transitions on the same footing and establish ways for observing unusual quantum-size effects in TI nanoparticles, including oscillatory dependences of the band gap and of transition amplitudes on the nanoparticle radius. Our theory also provides a unified perspective on multi-band models for charge carriers in semiconductors and Dirac fermions from elementary-particle physics.

cond-mat.mes-hall↗

arXiv2019

Ex-ante measure of patent quality reveals intrinsic fitness for citation-network growth

We have constructed a fitness parameter, characterizing the intrinsic attractiveness for patents to be cited, from attributes of the associated inventions known at the time a patent is granted. This exogenously obtained fitness is shown to determine the temporal growth of the citation network in conjunction with mechanisms of preferential attachment and obsolescence-induced ageing that operate without reference to characteristics of individual patents. Our study opens a window on understanding quantitatively the interplay of the rich-gets-richer and fit-gets-richer paradigms that have been suggested to govern the growth dynamics of real-world complex networks.

physics.soc-ph↗

arXiv2019

Community structure in co-inventor networks affects time to first citation for patents

We have investigated community structure in the co-inventor network of a given cohort of patents and related this structure to the dynamics of how these patents acquire their first citation. A statistically significant difference in the time lag until first citation is linked to whether or not this citation comes from a patent whose listed inventors share membership in the same communities as the inventors of the cited patent. Although the inventor-community structures identified by different community-detection algorithms differ in several aspects, including the community-size distribution, the magnitude of the difference in time to first citation is robustly exhibited. Our work is able to quantify the expected acceleration of knowledge flow within inventor communities and thereby further establishes the utility of network-analysis tools for studying innovation dynamics.

cs.SI↗

arXiv2018

Accurate projective two-band description of topological superfluidity in spin-orbit-coupled Fermi gases

The interplay of spin-orbit coupling and Zeeman splitting in ultracold Fermi gases gives rise to a topological superfluid phase in two spatial dimensions that can host exotic Majorana excitations. Theoretical models have so far been based on a four-band Bogoliubov-de Gennes formalism for the combined spin-1/2 and particle-hole degrees of freedom. Here we present a simpler, yet accurate, two-band description based on a well-controlled projection technique that provides a new platform for exploring analogies with chiral p-wave superfluidity and detailed future studies of spatially non-uniform situations.

cond-mat.quant-gas↗

arXiv2018

Dirac electrons in quantum rings

We consider quantum rings realized in materials where the dynamics of charge carriers mimics that of two-dimensional (2D) Dirac electrons. A general theoretical description of the ring-subband structure is developed that applies to a range of currently available 2D systems, including graphene, transition-metal dichalcogenides, and narrow-gap semiconductor quantum wells. We employ the scattering-matrix approach to calculate the electronic two-terminal conductance through the ring and investigate how it is affected by Dirac-electron interference. The interplay of pseudo-spin chirality and hard-wall confinement is found to distinctly affect the geometric phase that is experimentally accessible in mesoscopic-conductance measurements. We derive an effective Hamiltonian for the azimuthal motion of charge carriers in the ring that yields deeper insight into the physical origin of the observed transport effects, including the unique behavior exhibited by the lowest ring subband in the normal and topological (i.e., band-inverted) regimes. Our work provides a unified approach to characterizing confined Dirac electrons, which can be used to explore the design of valley- and spintronic devices based on quantum interference and the confinement-tunable geometric phase.

cond-mat.mes-hall↗

arXiv2017

Unraveling the dynamics of growth, aging and inflation for citations to scientific articles from specific research fields

We analyze the time evolution of citations acquired by articles from journals of the American Physical Society (PRA, PRB, PRC, PRD, PRE and PRL). The observed change over time in the number of papers published in each journal is considered an exogenously caused variation in citability that is accounted for by a normalization. The appropriately inflation-adjusted citation rates are found to be separable into a preferential-attachment-type growth kernel and a purely obsolescence-related (i.e., monotonously decreasing as a function of time since publication) aging function. Variations in the empirically extracted parameters of the growth kernels and aging functions associated with different journals point to research-field-specific characteristics of citation intensity and knowledge flow. Comparison with analogous results for the citation dynamics of technology-disaggregated cohorts of patents provides deeper insight into the basic principles of information propagation as indicated by citing behavior.

cs.DL↗

arXiv2017

Universal Spin Dynamics in Quantum Wires

We discuss the universal spin dynamics in quasi one-dimensional systems including the real spin in narrow-gap semiconductors like InAs and InSb, the valley pseudospin in staggered single-layer graphene, and the combination of real spin and valley pseudospin characterizing single-layer transition metal dichalcogenides (TMDCs) such as MoS$_2$, WS$_2$, MoSe$_2$, and WSe$_2$. All these systems can be described by the same Dirac-like Hamiltonian. Spin-dependent observable effects in one of these systems thus have counterparts in each of the other systems. Effects discussed in more detail include equilibrium spin currents, current-induced spin polarization (Edelstein effect), and spin currents generated via adiabatic spin pumping. Our work also suggests that a long-debated spin-dependent correction to the position operator in single-band models should be absent.

cond-mat.mes-hall↗

arXiv2017

Manipulating topological-insulator properties using quantum confinement

Recent discoveries have spurred the theoretical prediction and experimental realization of novel materials that have topological properties arising from band inversion. Such topological insulators are insulating in the bulk but have conductive surface or edge states. Topological materials show various unusual physical properties and are surmised to enable the creation of exotic Majorana-fermion quasiparticles. How the signatures of topological behavior evolve when the system size is reduced is interesting from both a fundamental and an application-oriented point of view, as such understanding may form the basis for tailoring systems to be in specific topological phases. This work considers the specific case of quantum-well confinement defining two-dimensional layers. Based on the effective-Hamiltonian description of bulk topological insulators, and using a harmonic-oscillator potential as an example for a softer-than-hard-wall confinement, we have studied the interplay of band inversion and size quantization. Our model system provides a useful platform for systematic study of the transition between the normal and topological phases, including the development of band inversion and the formation of massless-Dirac-fermion surface states. The effects of bare size quantization, two-dimensional-subband mixing, and electron-hole asymmetry are disentangled and their respective physical consequences elucidated.

cond-mat.mes-hall↗

arXiv2017

Unconventional superconductivity from magnetism in transition metal dichalcogenide

We investigate proximity-induced superconductivity in monolayers of transition metal dichalcogenides (TMDs) in the presence of an externally generated exchange field. A variety of superconducting order parameters is found to emerge from the interplay of magnetism and superconductivity, covering the entire spectrum of possibilities to be symmetric or antisymmetric with respect to the valley and spin degrees of freedom, as well as even or odd in frequency. More specifically, when a conventional \emph{s}-wave superconductor with singlet Copper pairs is tunnel-coupled to the TMD layer, both spin-singlet and triplet pairings between electrons from the same and opposite valleys arise due to the combined effects of intrinsic spin-orbit coupling and a magnetic-substrate-induced exchange field. As a key finding, we reveal the existence of an exotic even-frequency triplet pairing between equal-spin electrons from different valleys, which arises whenever the spin orientations in the two valleys are noncollinear. All types of superconducting order turn out to be highly tunable via straightforward manipulation of the external exchange field.

cond-mat.supr-con↗

arXiv2017

Fame and Obsolescence: Disentangling growth and ageing dynamics of patent citations

We present an analysis of citations accrued over time by patents granted by the United States Patent and Trademark Office in 1998. In contrast to previous studies, a disaggregation by technology category is performed, and exogenously caused citation-number growth is controlled for. Our approach reveals an intrinsic citation rate that clearly separates into an -- in the long run, exponentially time-dependent -- ageing function and a completely time-independent preferential-attachment-type growth kernel. For the general case of such a separable citation rate, we obtain the time-dependent citation distribution analytically in a form that is valid for any functional form of its ageing and growth parts. Good agreement between theory and long-time characteristics of patent-citation data establishes our work as a useful framework for addressing still open questions about knowledge-propagation dynamics, such as the observed excess of citations at short times.

physics.soc-ph↗