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Udo Seifert

Publications and source records attributed to Udo Seifert.

At least 37 records · Page 2Linked to original sources

Time-resolved statistics of snippets as general framework for model-free entropy estimators

Irreversibility is commonly quantified by entropy production. An external observer can estimate it through measuring an observable that is antisymmetric under time-reversal like a current. We introduce a general framework that, inter alia, allows us to infer a lower bound on entropy production through measuring the time-resolved statistics of events with any symmetry under time-reversal, in particular, time-symmetric instantaneous events. We emphasize Markovianity as a property of certain events rather than of the full system and introduce an operationally accessible criterion for this weakened Markov property. Conceptually, the approach is based on snippets as particular sections of trajectories, for which a generalized detailed balance relation is discussed.

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Universal minimal cost of coherent biochemical oscillations

Biochemical clocks are essential for virtually all living systems. A biochemical clock that is isolated from an external periodic signal and subjected to fluctuations can oscillate coherently only for a finite number of oscillations. Furthermore, such an autonomous clock can oscillate only if it consumes free energy. What is the minimum amount of free energy consumption required for a certain number of coherent oscillations? We conjecture a universal bound that answers this question. A system that oscillates coherently for $\mathcal{N}$ oscillations has a minimal free energy cost per oscillation of $4π^2\mathcal{N} k_B T$. Our bound is valid for general finite Markov processes, is conjectured based on extensive numerical evidence, is illustrated with numerical simulations of a known model for a biochemical oscillator, and applies to existing experimental data.

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Thermodynamic inference in partially accessible Markov networks: A unifying perspective from transition-based waiting time distributions

The inference of thermodynamic quantities from the description of an only partially accessible physical system is a central challenge in stochastic thermodynamics. A common approach is coarse-graining, which maps the dynamics of such a system to a reduced effective one. While coarse-graining states of the system into compound ones is a well studied concept, recent evidence hints at a complementary description by considering observable transitions and waiting times. In this work, we consider waiting time distributions between two consecutive transitions of a partially observable Markov network. We formulate an entropy estimator using their ratios to quantify irreversibility. Depending on the complexity of the underlying network, we formulate criteria to infer whether the entropy estimator recovers the full physical entropy production or whether it just provides a lower bound that improves on established results. This conceptual approach, which is based on the irreversibility of underlying cycles, additionally enables us to derive estimators for the topology of the network, i.e., the presence of a hidden cycle, its number of states and its driving affinity. Adopting an equivalent semi-Markov description, our results can be condensed into a fluctuation theorem for the corresponding semi-Markov process. This mathematical perspective provides a unifying framework for the entropy estimators considered here and established earlier ones. The crucial role of the correct version of time-reversal helps to clarify a recent debate on the meaning of formal versus physical irreversibility. Extensive numerical calculations based on a direct evaluation of waiting-time distributions illustrate our exact results and provide an estimate on the quality of the bounds for affinities of hidden cycles.

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Anomalous relaxation from a non-equilibrium steady state: An isothermal analog of the Mpemba effect

The Mpemba effect denotes an anomalous relaxation phenomenon where a system initially at a hot temperature cools faster than a system that starts at a less elevated temperature. We introduce an isothermal analog of this effect for a system prepared in a non-equilibrium steady state that then relaxes towards equilibrium. Here, the driving strength, which determines the initial non-equilibrium steady state, takes the role of the temperature in the original version. As a paradigm, we consider a particle initially driven by a non-conservative force along a one-dimensional periodic potential. We show that for an asymmetric potential relaxation from a strongly driven initial state is faster than from a more weakly driven one at least for one of the two possible directions of driving. These results are first obtained through perturbation theory in the strength of the potential and then extended to potentials of arbitrary strength through topological arguments.

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Operationally Accessible Uncertainty Relations for Thermodynamically Consistent Semi-Markov Processes

Semi-Markov processes generalize Markov processes by adding temporal memory effects as expressed by a semi-Markov kernel. We recall the path weight for a semi-Markov trajectory and the fact that thermodynamic consistency in equilibrium imposes a crucial condition called direction-time independence for which we present an alternative derivation. We prove a thermodynamic uncertainty relation that formally resembles the one for a discrete-time Markov process. The result relates the entropy production of the semi-Markov process to mean and variance of steady-state currents. We prove a further thermodynamic uncertainty relation valid for semi-Markov descriptions of coarse-grained Markov processes that emerge by grouping states together. A violation of this inequality can be used as an inference tool to conclude that a given semi-Markov process cannot result from coarse-graining an underlying Markov one. We illustrate these results with representative examples.

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Thermodynamic Uncertainty Relation in Interacting Many-Body Systems

The thermodynamic uncertainty relation (TUR) has been well studied for systems with few degrees of freedom. While, in principle, the TUR holds for more complex systems with many interacting degrees of freedom as well, little is known so far about its behavior in such systems. We analyze the TUR in the thermodynamic limit for mixtures of driven particles with short-range interactions. Our main result is an explicit expression for the optimal estimate of the total entropy production in terms of single-particle currents and correlations between two-particle currents. Quantitative results for various versions of a driven lattice gas demonstrate the practical implementation of this approach.

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Coherence of oscillations in the weak-noise limit

In a noisy environment, oscillations loose their coherence which can be characterized by a quality factor. We determine this quality factor for oscillations arising from a driven Fokker-Planck dynamics along a periodic one-dimensional potential analytically in the weak noise limit. With this expression, we can prove for this continuum model the analog of an upper bound that has been conjectured for the coherence of oscillations in discrete Markov network models. We show that our approach can also be adapted to motion along a noisy two-dimensional limit cycle. Specifically, we apply our scheme to the noisy Stuart-Landau oscillator and the thermodynamically consistent Brusselator as a simple model for a chemical clock. Our approach thus complements the fairly sophisticated extant general framework based on techniques from Hamilton-Jacobi theory with which we compare our results numerically.

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Phase shift in periodically driven non-equilibrium systems: Its identification and a bound

Time-dependently driven stochastic systems form a vast and manifold class of non-equilibrium systems used to model important applications on small length scales such as bit erasure protocols or microscopic heat engines. One property that unites all these quite different systems is some form of lag between the driving of the system and its response. For periodic steady states, we quantify this lag by introducing a generalized phase difference and prove a tight upper bound for it. In its most general version, this bound depends only on the relative speed of the driving.

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The Two Scaling Regimes of the Thermodynamic Uncertainty Relation for the KPZ-Equation

We investigate the thermodynamic uncertainty relation for the $(1+1)$ dimensional Kardar-Parisi-Zhang equation on a finite spatial interval. In particular, we extend the results for small coupling strengths obtained previously to large values of the coupling parameter. It will be shown that, due to the scaling behavior of the KPZ equation, the TUR product displays two distinct regimes which are separated by a critical value of an effective coupling parameter. The asymptotic behavior below and above the critical threshold is explored analytically. For small coupling, we determine this product perturbatively including the fourth order; for strong coupling we employ a dynamical renormalization group approach. Whereas the TUR product approaches a value of $5$ in the weak coupling limit, it asymptotically displays a linear increase with the coupling parameter for strong couplings. The analytical results are then compared to direct numerical simulations of the KPZ equation showing convincing agreement.

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Quality of the Thermodynamic Uncertainty Relation for Fast and Slow Driving

The thermodynamic uncertainty relation originally proven for systems driven into a non-equilibrium steady state (NESS) allows one to infer the total entropy production rate by observing any current in the system. This kind of inference scheme is especially useful when the system contains hidden degrees of freedom or hidden discrete states, which are not accessible to the experimentalist. A recent generalization of the thermodynamic uncertainty relation to arbitrary time-dependent driving allows one to infer entropy production not only by measuring current-observables but also by observing state variables. A crucial question then is to understand which observable yields the best estimate for the total entropy production. In this paper we address this question by analyzing the quality of the thermodynamic uncertainty relation for various types of observables for the generic limiting cases of fast driving and slow driving. We show that in both cases observables can be found that yield an estimate of order one for the total entropy production. We further show that the uncertainty relation can even be saturated in the limit of fast driving.

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Optimality of non-conservative driving for finite-time processes with discrete states

An optimal finite-time process drives a given initial distribution to a given final one in a given time at the lowest cost as quantified by total entropy production. We prove that for system with discrete states this optimal process involves non-conservative driving, i.e., a genuine driving affinity, in contrast to the case of system with continuous states. In a multicyclic network, the optimal driving affinity is bounded by the number of states within each cycle. If the driving affects forward and backwards rates non-symmetrically, the bound additionally depends on a structural parameter characterizing this asymmetry.

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Thermodynamic uncertainty relation for time-dependent driving

Thermodynamic uncertainty relations yield a lower bound on entropy production in terms of the mean and fluctuations of a current. We derive their general form for systems under arbitrary time-dependent driving from arbitrary initial states and extend these relations beyond currents to state variables. The quality of the bound is discussed for various types of observables for an interacting pair of colloidal particles in a moving laser trap and for the dynamical unfolding of a small protein. Since the input for evaluating these bounds does not require specific knowledge of the system or its coupling to the time-dependent control, they should become widely applicable tools for thermodynamic inference in time-dependently driven systems.

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Numerical Study of the Thermodynamic Uncertainty Relation for the KPZ-Equation

A general framework for the field-theoretic thermodynamic uncertainty relation was recently proposed and illustrated with the $(1+1)$ dimensional Kardar-Parisi-Zhang equation. In the present paper, the analytical results obtained there in the weak coupling limit are tested via a direct numerical simulation of the KPZ equation with good agreement. The accuracy of the numerical results varies with the respective choice of discretization of the KPZ non-linearity. Whereas the numerical simulations strongly support the analytical predictions, an inherent limitation to the accuracy of the approximation to the total entropy production is found. In an analytical treatment of a generalized discretization of the KPZ non-linearity, the origin of this limitation is explained and shown to be an intrinsic property of the employed discretization scheme.

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Propagator for a driven Brownian particle in step potentials

Although driven Brownian particles are ubiquitous in stochastic dynamics and often serve as paradigmatic model systems for many aspects of stochastic thermodynamics, fully analytically solvable models are few and far between. In this paper, we introduce an iterative calculation scheme, similar to the method of images in electrostatics, that enables one to obtain the propagator if the potential consists of a finite number of steps. For the special case of a single potential step, this method converges after one iteration, thus providing an expression for the propagator in closed form. In all other cases, the iteration results in an approximation that holds for times smaller than some characteristic timescale that depends on the number of iterations performed. This method can also be applied to a related class of systems like Brownian ratchets, which do not formally contain step potentials in their definition, but impose the same kind of boundary conditions that are caused by potential steps.

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Exponential volume dependence of entropy-current fluctuations at first-order phase transitions in chemical reaction networks

In chemical reaction networks, bistability can only occur far from equilibrium. It is associated with a first-order phase transition where the control parameter is the thermodynamic force. At the bistable point, the entropy production is known to be discontinuous with respect to the thermodynamic force.We show that the fluctuations of the entropy production have an exponential volume-dependence when the system is bistable. At the phase transition, the exponential prefactor is the height of the effective potential barrier between the two fixed-points. Our results obtained for Schlögl's model can be extended to any chemical network.

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Stochastic thermodynamics of chemical reactions coupled to finite reservoirs: A case study for the Brusselator

Biomolecular processes are typically modeled using chemical reaction networks coupled to infinitely large chemical reservoirs. A difference in chemical potential between these reservoirs can drive the system into a non-equilibrium steady state (NESS). In reality, these processes take place in finite systems containing a finite number of molecules. In such systems, a NESS can be reached with the help of an externally driven pump for which we introduce a simple model. Crucial parameters are the pumping rate and the finite size of the chemical reservoir. We apply this model to a simple biochemical oscillator, the Brusselator, and quantify the performance using the number of coherent oscillations. As a surprising result, we find that higher precision can be achieved with finite-size reservoirs even though the corresponding current fluctuations are larger than in the ideal infinite case.

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Stochastic discrete time crystals: Entropy production and subharmonic synchronization

Discrete time crystals are periodically driven systems that display spontaneous symmetry breaking of time translation invariance in the form of indefinite subharmonic oscillations. We introduce a thermodynamically consistent model for a discrete time crystal and analyze it using the framework of stochastic thermodynamics. In particular, we evaluate the rate of energy dissipation of this many body system of interacting noisy subharmonic oscillators in contact with a heat bath. Our model displays the novel phenomena of subharmonic synchronization, which corresponds to collective subharmonic oscillations of the individual units.

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Free diffusion bounds the precision of currents in underdamped dynamics

The putative generalization of the thermodynamic uncertainty relation (TUR) to underdamped dynamics is still an open problem. So far, bounds that have been derived for such a dynamics are not particularly transparent and they do not converge to the known TUR in the overdamped limit. Furthermore, it was found that there are restrictions for a TUR to hold such as the absence of a magnetic field. In this article we first analyze the properties of driven free diffusion in the underdamped regime and show that it inherently violates the overdamped TUR for finite times. Based on numerical evidence, we then conjecture a bound for one-dimensional driven diffusion in a potential which is based on the result for free diffusion. This bound converges to the known overdamped TUR in the corresponding limit. Moreover, the conjectured bound holds for observables that involve higher powers of the velocity as long as the observable is odd under time-reversal. Finally, we address the applicability of this bound to underdamped dynamics in higher dimensions.

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