arXiv subjects

Uma Gorti

Publications and source records attributed to Uma Gorti.

At least 19 recordsLinked to original sources

arXiv2026

Ammonium salt formation and abundance in protoplanetary disks

Ammonium salts may represent an important reservoir of volatile species in Solar system primitive bodies, but the question of how and when these salts can form during the star formation process remains unknown. In this paper, we use thermo-chemical models to study the formation of ammonium salts during the protoplanetary disk stage. We show that ammonium salts form efficiently in the inner disk midplane (i.e. $r \lesssim 50 $ au), inside the comet forming region. In this region, our model predicts that almost all the available nitrogen is in the form of salts (i.e. mainly in ammonium cyanate) at the surface of grains after evolving for 10 Myrs. For sulfur, we show that almost all the available S is in the form of ammonium hydrosulfide in the inner disk midplane. We show that inside $r\sim 30$ au, ammonium salt formation is enhanced by a cosmic-ray-driven sink effect that progressively converts gas-phase CO and N$_2$ into carbon dioxide and salts, respectively, at the surface of grains on a timescale $\gtrsim 1$ Myr. This impacts the location of the CO and N$_2$ radial snowlines which both shift closer to the star as a function of time.

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arXiv2026

JWST/MIRI Reveals the Evolution from Molecular to Atomic Disk Winds

The evolution and dispersal of protoplanetary disks--governed by accretion, magnetically launched jets and winds, and photoevaporative winds--fundamentally shape planetary systems. Determining how these mass-loss processes co-evolve is crucial for constraining planet formation pathways. We analyze archival JWST/MIRI/IFU data of 72 inclined (i>40deg) mostly ClassII disks to identify and characterize spatially resolved jets and winds, focusing on [NeII] and H2 lines. Extended emission in H2 S(1), S(3), S(5), S(7) and/or [NeII] is detected toward 66 disks, revealing diverse morphologies. We develop a framework to identify conical H2 winds and high-velocity [NeII] jets perpendicular to the disk, detecting them toward 46 and 40 disks, respectively. All sources with [NeII] jets exhibit a corresponding wind traced in either H2 (85%) or [OI], establishing a connection between jets and winds. The detection fractions of [NeII]-jets and H2-winds correlate positively with mass accretion rate, with no dependence on disk inclination or stellar mass. Conversely, marginally resolved low-velocity [NeII] winds are found preferentially toward lower accretors. Among sources with H2 winds, detection of hotter winds traced by S(7) and S(5) declines more rapidly with decreasing accretion rate than the colder S(1) component. Comparison with high-resolution [OI]6300\text{\AA} spectroscopy reveals [OI] LVC and extended H2 wind detections preferentially toward moderate-to-high accretors (>~10^{-8.5}~Msun/yr), whereas lower accretors exhibit only [OI] and [NeII] winds. Together, these results indicate that atomic jets and atomic+molecular winds, consistent with an MHD disk-wind origin, dominate during early, actively accreting disk phases, while at lower accretion rates, jets weaken and winds become predominantly atomic.

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arXiv2026

Project Hephaistos -- IV. James Webb Space Telescope Observations of Two Dyson Sphere Candidates

We report on JWST/MIRI imaging and spectroscopy of two M-dwarf stars previously singled out by project Hephaistos as potential Dyson-sphere candidates (their candidates D and E) due to the presence of excess flux at mid-infrared wavelengths. We find that the infrared excess does not originate from Dysonian megastructures, or other radiation mechanisms close to these stars, but from background galaxies projected within $\sim 1$ arcsec of the M dwarfs, thereby confusing previous mid-infrared photometry obtained with the WISE telescope. The candidate D background galaxy lies at redshift $z\approx 0.9$, appears point-source dominated in imaging and has a mid-infrared spectrum consistent with being a Hot Dust Obscured Galaxy (Hot DOG). The candidate E background galaxy lies at $z\approx 0.4$, displays an extended morphology with bright knots and a spectrum consistent with a dusty starburst.

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arXiv2026

From Young to Older Disks: JWST/MIRI Evidence for Fading Molecular Emission and Hints for Elevated C/O in Upper Scorpius

We present JWST/MIRI spectroscopy of 14 disks in the older (~5-10 Myr) Upper Scorpius (USco) association and use slab of gas in local thermal equilibrium to infer basic gas properties. We find that half of these disks are molecular rich, with detections of H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and H$_2$, while the other half are molecular poor, showing no molecular emission other than H$_2$. We further combine this sample with 10 other USco disks from the AGE-PRO program and compare the combined older sample to young (~1-3 Myr) JDISCS Cycle~1 systems, which are analyzed in a similar manner. We find that USco disks have lower detection rates of major molecular species but a significantly higher detection rate of rarer C-bearing molecules such as C$_4$H$_2$. At a given accretion luminosity, molecular line luminosities are systematically lower in USco than in young disks, and the scaling relations with accretion luminosity differ between the two populations. Moreover, we find that about half of the older disks, preferentially the millimeter faint, and likely more compact disks, have observable mass ratios of C- to O-bearing molecules that are higher than the maximum values in the young sample. These results point to reduced inner-disk molecular gas masses, cooler emitting layers, and higher inner gas C/O ratios in older disks, the latter being consistent with pebble drift. Taken together, our findings provide evidence for chemical evolution of inner disk gas from young to older systems, with important implications for the accretion of primordial planetary atmospheres.

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arXiv2026

DiskMINT-GARDEN: Self-consistent Models to Estimate Disk Masses

We present DiskMINT-GARDEN, a grid of self-consistent models together with a fast, open source inference tool for disk masses. The grid is built on DiskMINT, a tool which couples hydrostatic disk structure, continuum/line radiative transfer, and a reduced CO chemical network including freeze-out, grain-surface conversion, and isotope-selective photodissociation. DiskMINT-GARDEN model grid spans a large range of stellar mass ($0.1-2.0\,M_\odot$), gas disk mass ($10^{-5}-10^{-1}\,M_\star$), dust-to-gas ratio ($0.003-0.1$), and characteristic radius ($10-300\,{\rm au}$), and provides synthetic ALMA observables. We train a machine-learning regression model to infer the disk mass, dust-to-gas mass ratio, and disk size from the dust continuum and $\mathrm{C^{18}O}$ line observations. Applying DiskMINT-GARDEN to archival ALMA data of 34 disks, we find gas masses in good agreement with dynamical and HD-based estimates. Comparing our results with estimates from chemical modeling using DALI, we find that their need for large-scale elemental or CO depletion can be accounted for by grain-surface chemistry implemented in DiskMINT, with CO conversion to CO$_2$ being one of the main reactions. Therefore, extant data suggest little chemical processing due to disk evolutionary processes.

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arXiv2026

Evidence for Systematically Larger Dust Grains in Upper Scorpius Relative to Taurus Disks

Infrared spectroscopy provides a powerful diagnostic for probing the mineralogical properties of dust grains in the terrestrial planet-forming regions of protoplanetary disks. The Upper Scorpius association offers an excellent laboratory for studying disk evolution because it represents an evolved stage (5-10 Myr) compared with younger star-forming regions such as the Taurus Molecular Cloud (1-3 Myr). In this work, we present mid-infrared spectra of 11 disks in Upper Scorpius that were obtained with the Mid-Infrared Instrument aboard the James Webb Space Telescope. We derive emission feature indices for crystalline olivine and pyroxene centered at about 9.2 micron and 11.1 micron, as well as perform spectral decomposition to quantify dust crystallinity and characteristic grain size. These results are compared with those measured from Spitzer/IRS spectra of 31 disks in Taurus with similar stellar types. We find no significant difference in dust crystallinity between the two groups, suggesting that crystallization is largely established at early stages of disk evolution. Our analysis indicates that the average grain size in Upper Scorpius disks is systematically larger than that in Taurus disks, aligning with theories of dust evolution. We also observe a trend of increasing grain size towards later-type stars, as well as a correlation between crystallinity, grain size and the flux ratio F24/F8, which serves as a measure of dust settling. These results suggest that dust processing proceeds in tandem with disk evolution.

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arXiv2025

DiskMINT: Self-Consistent Thermochemical Disk Models with Radially Varying Gas and Dust -- Application to the Massive, CO-Rich Disk of IM Lup

Disks around young stars are the birthplaces of planets, and the spatial distribution of their gas and dust masses is critical for understanding where and what types of planets can form. We present self-consistent thermochemical disk models built with DiskMINT, which extends its initial framework to allow for spatially decoupled gas and dust distributions. DiskMINT calculates the gas temperature based on thermal equilibrium with dust grains, solves vertical gas hydrostatic equilibrium, and includes key processes for the CO chemistry, specifically selective photodissociation, and freeze-out with conversion CO/CO$_2$ ice. We apply DiskMINT to study the IM Lup disk, a large massive disk, yet with an inferred CO depletion of up to 100 based on earlier thermochemical models. By fitting the multi-wavelength SED along with the millimeter continuum, ${\rm C^{18}O}$ radial emission profiles, we find $0.02-0.08\,{\rm M_\odot}$ for the gas disk mass, which are consistent with the dynamical-based mass within the uncertainties. We further compare the derived surface densities for dust and gas and find that the outer disk is drift-dominated, with a dust-to-gas mass ratio of approximately 0.01-0.02, which is likely insufficient to meet the conditions for the streaming instability to occur. Our results suggest that when interpreted with self-consistent thermochemical models, ${\rm C^{18}O}$ alone can serve as a reliable tracer of both the total gas mass and its radial distribution. This approach enables gas mass estimates in lower-mass disks, where dynamical constraints are not available, and in fainter systems where rare species like ${\rm N_2H^+}$ are too weak to detect.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): III. Dust and Gas Disk Properties in the Lupus Star-forming Region

We present Band 6 and Band 7 observations of 10 Lupus disks around M3-K6 stars from the ALMA survey of Gas Evolution in PROtoplanetary disks (AGE-PRO) Large Program. In addition to continuum emission in both bands, our Band 6 setup covers the $\mathrm{{}^{12}CO}$, $\mathrm{{}^{13}CO}$ and $\mathrm{C^{18}O}\,J$=2-1 lines, while our Band 7 setup covers the $\mathrm{N_2H^+}\,J$=3-2 line. All of our sources are detected in $\mathrm{{}^{12}CO}$ and $\mathrm{{}^{13}CO}$, 7 out of 10 are detected in $\mathrm{C^{18}O}$, and 3 are detected in $\mathrm{N_2H^+}$. We find strong correlations between the CO isotopologue line fluxes and the continuum flux densities. With the exception of one disk, we also identify a strong correlation between the $\mathrm{C^{18}O}\,J$=2-1 and $\mathrm{N_2H^+}\,J$=3-2 fluxes, indicating similar CO abundances across this sample. For the two sources with well-resolved continuum and $\mathrm{{}^{12}CO}\,J$=2-1 images, we find that their gas-to-dust size ratio is consistent with the median value of $\sim 2$ inferred from a larger sample of Lupus disks. We derive dust disk masses from continuum flux densities. We estimate gas disk masses by comparing $\mathrm{C^{18}O}\,J$=2-1 line fluxes with those predicted by the limited grid of self-consistent disk models of Ruaud et al. (2022). A comparison of these mass estimates with those derived by Trapman et al. (2025), using a combination of CO isotopologue and $\mathrm{N_2H^+}$ line emission, shows that the masses are consistent with each other. Some discrepancies appear for small and faint disks, but they are still within the uncertainties. Both methods find gas disk masses increase with dust disk masses, and gas-to-dust mass ratios are between $10-100$ in the AGE-PRO Lupus sample.

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arXiv2025

Class I/II Jets with JWST: Mass loss rates, Asymmetries, and Binary induced Wigglings

We present JWST NIRSpec spectro-imaging observations of jets from four edge-on protoplanetary disks that exhibit clear signatures of MHD disk winds. Bipolar jets are detected and spatially resolved in over 30 shock-excited forbidden lines, multiple Paschen and Brackett series lines of atomic hydrogen, and the high-energy excitation line of atomic helium (1.083 um). This helium line is the brightest jet-tracer towards HH 30 and FS TauB, which also exhibit asymmetric intensity between their red- and blue-shifted lobes in all tracers, including the [Fe II] and [He I] lines. Extinction maps reveal no significant differences across the lobes, suggesting an asymmetric jet-launching mechanism rather than environmental effects. Diagnostic line ratios yield consistent shock speeds of 50-60 km/s, jet ionization fractions of 0.1-0.2, and pre-shock electron densities of 1000 /cm^3. Combined with pixel-by-pixel electron density maps and [Fe II] line luminosities, we estimate jet mass-loss rates using three independent methods, averaging around a few 10^(-9) solar masses/yr. We estimate the accretion rates for these sources as 10 times the jet mass loss rates and find them to match well with the independently derived accretion estimates of other Class II sources in the Taurus star-forming region. Owing to JWST's high precision, we also investigate jet wiggling and find Tau 042021 to showcase the perfect case of mirror-symmetric wiggling, which can only be explained by the motion of the jet source around a stellar companion. Modeling this wiggling suggests Tau 042021 to host 0.33 and 0.07 solar masses binary at the center with binary separation of 1.35 au and an orbital period of 2.5 years.

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arXiv2024

JWST/NIRSpec Reveals the Nested Morphology of Disk Winds from Young Stars

Radially extended disk winds could be the key to unlocking how protoplanetary disks accrete and how planets form and migrate. A distinctive characteristic is their nested morphology of velocity and chemistry. Here we report JWST/NIRSpec spectro-imaging of four young stars with edge-on disks in the Taurus star-forming region that demonstrate the ubiquity of this structure. In each source, a fast collimated jet traced by [Fe II] is nested inside a hollow cavity within wider lower-velocity H2 and, in one case, also CO ro-vibrational (v=1-0) emission. Furthermore, in one of our sources, ALMA CO(2-1) emission, paired with our NIRSpec images, reveals the nested wind structure extends further outward. This nested wind morphology strongly supports theoretical predictions for wind-driven accretion and underscores the need for theoretical work to assess the role of winds in the formation and evolution of planetary systems

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arXiv2024

JWST captures a sudden stellar outburst and inner disk wall destruction

We present JWST/MIRI observations of T~Cha, a highly variable ($\Delta V \sim$3-5\,mag) accreting Sun-like star surrounded by a disk with a large ($\sim 15$\,au) dust gap. We find that the JWST mid-infrared spectrum is signiticantly different from the {\it Spitzer} spectrum obtained 17 years before, where the emission at short wavelengths ($5-10 \mu m$) has decreased by $\sim 2/3$ while at longer wavelengths ($15-25 \mu m$) it increased by up to a factor of $\sim 3$. This 'seesaw' behavior is contemporary with a fairly constant higher optical emission captured by the All Sky Automated Survey. By analyzing and modelling both SEDs, we propose that JWST caught the star during an outburst that destructed the asymmetric inner disk wall responsible for the high optical variability and lower $15-25$\,micron\ emission during the {\it Spitzer} time. The dust mass lost during this outburst is estimated to be comparable ($\sim 1/5$) to the upper limit of the total micron-sized dust mass in the inner disk of T~Cha now. Monitoring this system during possible future outbursts and more observations of its quiescent state will reveal if the inner disk can be replenished or will continue to be depleted and vanish.

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arXiv2024

Simultaneous FUV and NUV observations of T Tauri stars with UVIT/AstroSat: probing accretion process in young stars

We present results from simultaneous FUV and NUV observations of T-Tauri stars (TTSs) in the Taurus molecular cloud with UVIT/AstroSat. This is the very first UVIT study of TTSs. From the spectral energy distribution of TTSs from FUV to near-IR, we show that classical TTSs (CTTSs) emit significantly higher UV excess compared to weak-line TTSs (WTTSs). The equivalent black-body temperatures corresponding to the UV excess in CTTSs ($>10^4$ K) are also found to be relatively higher than that in WTTSs ($<9250$ K). From the UV excess, we have re-classified two WTTSs (BS Tau, V836 Tau) as CTTSs, which has been supported by the follow-up optical spectroscopic study using the Himalayan Chandra Telescope (HCT), showing strong H$α$ line emission. We find that CTTSs show strong excess emission in both FUV ($>$10$^7$) and NUV ($>$10$^3$) bands, while WTTSs show strong excess only in the FUV ($\lesssim$10$^5$), suggesting that excess emission in NUV can be used as a tool to classify the TTSs. We also find a linear correlation between UV luminosity (a primary indicator of mass accretion) and H$α$ luminosity (a secondary indicator of mass accretion) with a slope of 1.20$\pm$0.22 and intercept of 2.16$\pm$0.70.

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arXiv2024

Cold water emission cannot be used to infer depletion of bulk elemental oxygen [O/H] in disks

We re-examine the constraints provided by Herschel Space Observatory data regarding cold water emission from protoplanetary disks. Previous disk models that were used to interpret observed water emission concluded that oxygen (O/H) is depleted by at least 2 orders of magnitude if a standard, interstellar gas/dust mass ratio is assumed in the disk. In this work, we use model results from a recent disk parameter survey and show that most of the \textit{Herschel} constraints obtained for cold water (i.e. for transitions with an upper energy level $E_\mathrm{up}<200$ K, where the bulk of the disk water lies) can be explained with disk models adopting ISM-like oxygen elemental abundance (i.e. O/H=$3.2\times10^{-4}$) and the canonical gas/dust mass ratio of 100. We show that cold water vapor is mainly formed by photodesorption of water ice at the interface between the molecular layer and the midplane, and that its emission is relatively independent of the main disk properties like the disk gas mass and gas/dust mass ratio. We find that the abundance of water vapor in the outer disk is set by photoprocesses and depends on the (constant) vertical column density of water ice needed to attenuate the FUV photon flux, resulting in roughly constant emission for the parameters (gas mass, dust mass, disk radius) varied in our survey. Importantly, water line emission is found to be optically thick and hence sensitive to temperature more than abundance, possibly driving previous inferences of large scale oxygen depletion.

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arXiv2024

Applications of Fast Magnetic Reconnection Models to the Atmospheres of the Sun and Protoplanetary Disks

Partially-ionized plasmas consist of charged and neutral particles whose mutual collisions modify magnetic reconnection compared with the fully-ionized case. The collisions alter the rate and locations of the magnetic dissipation heating and the distribution of energies among the particles accelerated into the non-thermal tail. We examine the collisional regimes for the onset of fast reconnection in two environments: the partially-ionized layers of the solar atmosphere and the protoplanetary disks that are the birthplaces for planets around young stars. In both these environments, magnetic nulls readily develop into resistive current sheets in the regime where the charged and neutral particles are fully coupled by collisions, but the current sheets quickly break down under the ideal tearing instability. The current sheets collapse repeatedly, forming magnetic islands at successively smaller scales, till they enter a collisionally-decoupled regime where the magnetic energy is rapidly turned into heat and charged-particle kinetic energy. Small-scale, decoupled fast reconnection in the solar atmosphere may lead to preferential heating and energization of ions and electrons that escape into the corona. In protoplanetary disks such reconnection causes localized heating in the atmospheric layers that produce much of the infrared atomic and molecular line emission observed with the Spitzer and James Webb Space Telescopes.

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arXiv2024

Modeling JWST MIRI-MRS Observations of T Cha: Mid-IR Noble Gas Emission Tracing a Dense Disk Wind

[Ne II] 12.81 $\mu\mathrm{m}$ emission is a well-used tracer of protoplanetary disk winds due to its blueshifted line profile. MIRI-MRS recently observed T Cha, detecting this line along with lines of [Ne III], [Ar II] and [Ar III], with the [Ne II] and [Ne III] lines found to be extended while the [Ar II] was not. In this complementary work, we use these lines to address long-debated questions about protoplanetary disk winds regarding their mass-loss rate, the origin of their ionization, and the role of magnetically-driven winds as opposed to photoevaporation. To this end, we perform photoionization radiative transfer on simple hydrodynamic wind models to map the line emission. We compare the integrated model luminosities to those observed with MIRI-MRS to identify which models most closely reproduce the data and produce synthetic images from these to understand what information is captured by measurements of the line extents. Along with the low degree of ionization implied by the line ratios, the relative compactness of [Ar II] compared to [Ne II] is particularly constraining. This requires Ne II production by hard X-rays and Ar II production by soft X-rays (and/or EUV) in an extended ($\gtrsim 10$ au) wind that is shielded from soft X-rays - necessitating a dense wind with material launched on scales down to ~1 au. Such conditions could be produced by photoevaporation, whereas an extended MHD wind producing equal shielding would likely underpredict the line fluxes. However, a tenuous inner MHD wind may still contribute to shielding the extended wind. This picture is consistent with constraints from spectrally-resolved line profiles.

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arXiv2024

JWST MIRI/MRS Observations of T Cha: Discovery of a Spatially Resolved Disk Wind

Understanding when and how circumstellar disks disperse is crucial to constrain planet formation and migration. Thermal winds powered by high-energy stellar photons have long been theorized to drive disk dispersal. However, evidence for these winds is currently based only on small (~3-6 km/s) blue-shifts in [Ne II] 12.81 um lines, which does not exclude MHD winds. We report JWST MIRI MRS spectro-imaging of T Cha, a disk with a large dust gap (~30 au in radius) and blue-shifted [Ne II] emission. We detect four forbidden noble gas lines, [Ar II], [Ar III], [Ne II], and [Ne III], of which [Ar III] is the first detection in any protoplanetary disk. We use line flux ratios to constrain the energy of the ionizing photons and find that Argon is ionized by EUV whereas Neon is most likely ionized by X-rays. After performing continuum and Point Spread Function (PSF) subtraction on the IFU cube, we discover a spatial extension in the [Ne II] emission off the disk continuum emission. This is the first spatially resolved [Ne II] disk wind emission. The mostly ionic spectrum of T Cha, in combination with the extended [Ne II] emission, points to an evolved stage for any inner MHD wind and is consistent with the existence of an outer thermal wind ionized and driven by high-energy stellar photons. This work acts as a pathfinder for future observations aiming at investigating disk dispersal using JWST.

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arXiv2023

DiskMINT: A Tool to Estimate Disk Masses with CO Isotopologues

CO is one of the most abundant molecules in protoplanetary disks, and optically thin emission from its isotopologues has been detected in many of them. However, several past works have argued that reproducing the relatively low emission of CO isotopologues requires a very low disk mass or significant CO depletion. Here, we present a Python code, DiskMINT, which includes gas density and temperature structures that are both consistent with the thermal pressure gradient, isotope-selective chemistry, and conversion of CO into $\mathrm{CO_2}$ ice on grain-surfaces. The code generates a self-consistent disk structure, where the gas disk distribution is obtained from a Spectral Energy Distribution (SED)-derived dust disk structure with multiple grain sizes. We use DiskMINT to study the disk of RU~Lup, a high-accreting star whose disk was previously inferred to have a gas mass of only $\sim 1.5\times10^{-3}\,M_\odot$ and gas-to-dust mass ratio of $\sim 4$. Our best-fit model to the long-wavelength continuum emission can explain the total $\mathrm{C^{18}O}$ luminosity as well as the $\mathrm{C^{18}O}$ velocity and radial intensity profiles, and obtains a gas mass of $\sim 1.2\times10^{-2}\,M_\odot$, an order of magnitude higher than previous results. A disk model with parametric Gaussian vertical distribution that better matches the IR-SED can also explain the observables above with a similarly high gas mass $\sim 2.1\times10^{-2}\,M_\odot$. We confirm the conclusions of Ruaud et al. (2022) that optically thin $\mathrm{C^{18}O}$ rotational lines provide reasonable estimates of the disk mass and can therefore be used as gas disk tracers.

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arXiv2023

Large Myr-old Disks are Not Severely Depleted of gas-phase CO or carbon

We present an ACA search for [CI] emission at 492GHz toward large T Tauri disks (gas radii $\gtrsim 200$au) in the $\sim 1-3$Myr-old Lupus star-forming region. Combined with ALMA 12-m archival data for IM Lup, we report [CI] detections in 6 out of 10 sources, thus doubling the known detections toward T Tauri disks. We also identify four Keplerian double-peaked profiles and demonstrate that [CI] fluxes correlate with $^{13}$CO, C$^{18}$O, and $^{12}$CO(2-1) fluxes, as well as with the gas disk outer radius measured from the latter transition. These findings are in line with the expectation that atomic carbon traces the disk surface. In addition, we compare the carbon and CO line luminosities of the Lupus and literature sample with [CI] detections with predictions from the self-consistent disk thermo-chemical models of Ruaud et al. (2022). These models adopt ISM carbon and oxygen elemental abundances as input parameters. With the exception of the disk around Sz 98, we find that these models reproduce all available line luminosities and upper limits with gas masses comparable to or higher than the minimum mass solar nebula and gas-to-dust mass ratios $\geq 10$. Thus, we conclude that the majority of large Myr-old disks conform to the simple expectation that they are not significantly depleted in gas, CO, or carbon.

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