arXiv subjects

Upendra Harbola

Publications and source records attributed to Upendra Harbola.

At least 19 recordsLinked to original sources

arXiv2025

Light-matter interaction inside an optical cavity: A perspective

Light-matter interaction inside an optical cavity and formation of polaritonic states have gained interest in the past decades as it has direct applications in many research fields. Different regimes of light-matter coupling have been studied using different approximations, one of which is rotating wave approximation(RWA), which is said to be valid for weak coupling and near resonant regimes. In this study, we have categorized the light-matter coupling into four regimes depending on the validity of the RWA as moderate, $λ/ω_c\leq 0.1$, strong, $0.1 \leq λ/ω_c\leq 0.5$, ultra-strong, $0.5 \leqλ/ω_c\leq 1.0$ and deep-strong, $λ/ω_c\geq 1.0$ coupling, where $λ$ is the coupling strength and $ω_c$ is the cavity frequency. In experiments, vacuum Rabi-splitting has been observed which is a clear indication of formation of polaritonic states. It is a common misunderstanding that the cavity remains in vacuum state when the coupled system is in the ground state. Here we show that upon coupling, the cavity has non-zero excitation even in the ground state, which is not captured by RWA. In fact, RWA breaks down completely to predict the ground state properties as it fails to capture the interaction between the matter and the cavity field.

quant-ph↗

arXiv2025

Pump-intensity-scaling of Two-Photon-Absorption and Photon Statistics of Entangled-Photon Fields

We use a non-perturbative theoretical approach to the parametric down-conversion (PDC) process, which generates entangled-photon field for an arbitrarily strong pump-pulse. This approach can be used to evaluate multi-point field correlation functions to compute nonlinear spectroscopic signals induced by a strong pump. The entangled-photon statistics is studied using Glauber's $g^{(2)}$ function, which helps understand the significance of the photon entanglement-time and the pump-pulse intensity on spectroscopic signals. Under the non-perturbative treatment of the entangled field, the two-photon absorption (TPA) signal shows linear to strongly non-linear growth with the pump intensity, rather than linear to quadratic scaling reported previously. An increase in the range of pump intensity for the linear scaling is observed as the pump band-width is increased. We propose an experimental scheme that can select contributions to the TPA signal that arise solely from interactions with the entangled photons, and filter out unentangled photon contributions, which are dominant at higher pump intensities, paving a way to explore the entanglement effects at higher intensities.

physics.chem-ph↗

arXiv2025

Frequency-dependent specific heat in quantum supercooled liquids: A mode-coupling study

Frequency-dependence of specific heat in supercooled hard sphere liquid is computed using quantum mode-coupling theory (QMCT). Mode-coupling equations are solved using recently proposed perturbative method that allows to study relaxation in the moderate quantum regime where quantum effects assist liquid to glass transition. Zwanzig's formulation is used to compute the frequency-dependent specific heat in supercooled state using dynamical information from QMCT. Specific heat shows strong variation as the quantumness of the liquid is changed, which becomes more significant as density is increased. It is found that, near the transition point, different dynamical modes contribute to the specific heat in the classical and the quantum liquids.

cond-mat.stat-mech↗

arXiv2025

Tagged particle dynamics in supercooled quantum liquid

We analyze dynamics of quantum supercooled liquids in terms of tagged particle dynamics. Unlike the classical case, uncertainty in the position of a particle in quantum liquid leads to qualitative changes. We demonstrate these effects in the dynamics of the first two moments of displacements, namely, the mean-squared displacement, $\langle Δr^2(t)\rangle$, and $\langle Δr^4(t)\rangle$. Results are presented for a hard sphere liquid using mode-coupling theory (MCT) formulation and simulation on a binary Lennard-Jones liquid. As the quantumness (controlled by the de-Broglie thermal wavelength) is increased, a non-zero value of the moments at zero time leads to significant deviations from the classical behavior in the initial dynamics. Initial displacement shows ballistic behavior $\langle Δr^2(t)\rangle\sim t^2$, but, as a result of large uncertainty in the position, the dynamical effects become weaker with increasing quantumness over this time scale.

cond-mat.stat-mech↗

arXiv2024

Two-dimensional spectroscopy of open quantum systems

Two-dimensional spectroscopy is discussed for open quantum systems with multiple simultaneously measurable fluxes. In particular, we discuss a junction where optical measurements of photon flux are complemented with simultaneous transport measurements of electron currents. Theory of two-dimensional spectroscopy in both fluxes is developed employing non-self-consistent nonequilibrium Green's function formulation. Theoretical derivations are illustrated with numerical simulations within generic junction model.

cond-mat.mes-hall↗

arXiv2024

Nonlinear optical spectroscopy of open quantum systems

Development of experimental techniques at nanoscale resulted in ability to perform spectroscopic measurements on single-molecule current carrying junctions. These experiments are natural meeting point for research fields of optical spectroscopy and molecular electronics. We present a pedagogical comparison between perturbation theory expansion of standard nonlinear optical spectroscopy and (non-self-consistent) perturbative diagrammatic formulation of the nonequilibrium Green's functions method (NEGF is widely used in molecular electronics) indicating their similarities and differences. Comparing the two approaches we argue that optical spectroscopy of open quantum systems has to be analyzed within the more general Green's function formulation.

cond-mat.mes-hall↗

arXiv2023

Stochastic dynamics of a non-Markovian random walk in the presence of resetting

The discrete stochastic dynamics of a random walker in the presence of resetting and memory is analyzed. Resetting and memory effects may compete for certain parameter regime and lead to significant changes in the long time dynamics of the walker. Analytic exact results are obtained for a model memory where the walker remembers all the past events equally. In most cases, resetting effects dominate at long times and dictate the asymptotic dynamics. We discuss the full phase diagram of the asymptotic dynamics and the resulting changes due to the resetting and the memory effects.

cond-mat.stat-mech↗

arXiv2022

Counting statistics of energy transport across squeezed thermal reservoirs

A general formalism for computing the full counting statistics of energy exchanged between 'N' squeezed thermal photon reservoirs weakly coupled to a cavity with 'M' photon modes is presented. The formalism is based on the two-point measurement scheme and is applied to two simple special cases, the relaxation dynamics of a single mode cavity in contact with a single squeezed thermal photon reservoir and the steady-state energy transport between two squeezed thermal photon reservoirs coupled to a single cavity mode. Using analytical results, it is found that the short time statistics is significantly affected by noncommutivity of the initial energy measurements with the reservoirs squeezed states, and may lead to negative probabilities if not accounted properly. Furthermore, it is found that for the single reservoir setup, generically there is no transient or steady-state fluctuation theorems for energy transport. In contrast, for the two reservoir case, although there is no generic transient fluctuation theorem, steady-state fluctuation theorem with a non-universal affinity is found to be valid. Statistics of energy currents are further discussed.

cond-mat.stat-mech↗

arXiv2020

Structural relaxation in quantum supercooled liquids: A mode-coupling approach

We study supercooled dynamics in quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to strongly quantum regime, where tunneling overcomes classical caging, leading to faster relaxation. As a result, the glass transition critical density can become significantly higher than for the classical liquids. Perturbative approach is used to solve time dependent quantum mode-coupling equations to study in detail the dynamics of the supercooled liquid in moderate quantum regime. Similar to the classical case, relaxation time shows power-law increase with increasing density in the supercooled regime. However, the power-law exponent is found to be dependent on the quantumness; it increases linearly as the quantumness is increased in the moderate quantum regime.

cond-mat.stat-mech↗

arXiv2019

Statistics of work done in degenerate parametric amplification process

We study statistics of work done by two classical electric field pumps (two-photon and one-photon resonant pumps) on a quantum optical oscillator. We compute moment generating function for the energy change of the oscillator, interpreted as work done by the classical drives on the quantum oscillator starting out in a thermalized Boltzmann state. The moment generating function is inverted, analytically when only one of the pumps is turned on and numerically when both the pumps are turned on, to get the probability function for the work. The resulting probability function for the work done by the classical drive is shown to satisfy transient detailed and integral work fluctuation theorems. Interestingly, we find that, in order for the work distribution function to satisfy the fluctuation theorem in presence of both the drivings, relative phase of drivings need to be shifted by $π$, this is related to the broken time reversal symmetry of the Hamiltonian.

cond-mat.stat-mech↗

arXiv2019

Statistics of heat transport across capacitively coupled double quantum dot circuit

We study heat current and the full statistics of heat fluctuations in a capacitively-coupled double quantum dot system. This work is motivated by recent theoretical studies and experimental works on heat currents in quantum dot circuits. As expected intuitively, within the (static) mean-field approximation, the system at steady-state decouples into two single-dot equilibrium systems with renormalized dot energies, leading to zero average heat flux and fluctuations. This reveals that dynamic correlations induced between electrons on the dots is solely responsible for the heat transport between the two reservoirs. To study heat current fluctuations, we compute steady-state cumulant generating function for heat exchanged between reservoirs using two approaches : Lindblad quantum master equation approach, which is valid for arbitrary coulomb interaction strength but weak system-reservoir coupling strength, and the saddle point approximation for Schwinger-Keldysh coherent state path integral, which is valid for arbitrary system-reservoir coupling strength but weak coulomb interaction strength. Using thus obtained generating functions, we verify steady-state fluctuation theorem for stochastic heat flux and study the average heat current and its fluctuations. We find that the heat current and its fluctuations change non-monotonically with the coulomb interaction strength ($U$) and system-reservoir coupling strength ($Γ$) and are suppressed for large values of $U$ and $Γ$.

cond-mat.mes-hall↗

arXiv2018

Current in nanojunctions : Effects of reservoir coupling

We study the effect of system reservoir coupling on currents flowing through quantum junctions. We consider two simple double-quantum dot configurations coupled to two external fermionic reservoirs and study the net current flowing between the two reservoirs. The net current is partitioned into currents carried by the eigenstates of the system and by the coherences between the eigenstates induced due to coupling with the reservoirs. We find that current carried by populations is always positive whereas current carried by coherences are negative for large couplings. This results in a non-monotonic dependence of the net current on the coupling strength. We find that in certain cases, the net current can vanish at large couplings due to cancellation between currents carried by the eigenstates and by the coherences. These results provide new insights into the non-trivial role of system-reservoir couplings on electron transport through quantum dot junctions. In the presence of weak coulomb interactions, net current as a function of system reservoir coupling strength shows similar trends as for the non-interacting case.

cond-mat.mes-hall↗

arXiv2017

A memory based random walk model to understand diffusion in crowded heterogeneous environment

We study memory based random walk models to understand diffusive motion in crowded heterogeneous environment. The models considered are non-Markovian as the current move of the random walk models is determined by randomly selecting a move from history. At each step, particle can take right, left or stay moves which is correlated with the randomly selected past step. There is a perfect stay-stay correlation which ensures that the particle does not move if the randomly selected past step is a stay move. The probability of traversing the same direction as the chosen history or reversing it depends on the current time and the time or position of the history selected. The time or position dependent biasing in moves implicitly corresponds to the heterogeneity of the environment and dictates the long-time behavior of the dynamics that can be diffusive, sub or super diffusive. A combination of analytical solution and Monte Carlo simulation of different random walk models gives rich insight on the effects of correlations on the dynamics of a system in heterogeneous environment.

cond-mat.stat-mech↗

arXiv2016

Controlling local currents in molecular junctions

The effect of non-equilibrium constraints and dephasing on the circulating currents in molecular junctions are analyzed. Circulating currents are manifestations of quantum effects and can be induced either by externally applied bias or an external magnetic field through the molecular system. In symmetric Aharonov-Bohm ring, bond currents have two contributions, bias driven and magnetic field driven. We analyze the competition between these two contributions and show that, as a consequence, current through one of the branches can be completely suppressed. We then study the effect of asymmetry (as a result of chemical substitution) on the current pathways inside the molecule and study asymmetry induced circulating currents (without magnetic field) by tuning the coupling strength of the substituent (at finite bias).

cond-mat.mes-hall↗

arXiv2016

Geometric effects in non-equilibrium electron transfer statistics in adiabatically driven quantum junctions

Cyclic Pancharatnam-Berry (PB) and adiabatic noncyclic geometric (ANG) effects are investigated in a single electron orbital system connected to two metal contacts with externally driven chemical potential and/or temperatures.The PB contribution does not affect the density matrix evolution, but has quantitative effect on the statistics (fluctuations) of electron transfer. The ANG contribution, on the other hand, affects the net flux across the junction. Unlike the PB, the ANG contribution is non-zero when two parameters are identically driven. Closed analytical expressions are derived for the ANG contribution to the flux, and the PB contribution to the first two leading order fluctuations. Fluctuations can be modified by manipulating the relative phases of the drivings. Interestingly, we find that the fluctuations of the pumped charge do not satisfy the steady state fluctuation theorem in presence of nonzero geometric contribution, but can be recovered for a vanishing geometric contribution even in presence of the external driving.

cond-mat.stat-mech↗

arXiv2015

Statistics of an adiabatic charge pump

We investigate the effect of time-dependent cyclic-adiabatic driving on the charge transport in quantum junction. We propose a nonequilibrium Greens function formalism to study statistics of the charge pumped (at zero bias) through the junction. The formulation is used to demonstrate charge pumping in a single electronic level coupled to two (electronic) reservoirs with time dependent couplings. Analytical expression for the average pumped current for a general cyclic driving is derived. It is found that for zero bias, for a certain class of driving, the Berry phase contributes only to the odd cumulants. To contrast, a quantum master equation formulation does not show Berry-phase effect at all.

cond-mat.stat-mech↗

arXiv2014

An integral fluctuation theorem for systems with unidirectional transitions

The fluctuations of a Markovian jump process with one or more unidirectional transitions, where $R_{ij} >0$ but $R_{ji} =0$, are studied. We find that such systems satisfy an integral fluctuation theorem. The fluctuating quantity satisfying the theorem is a sum of the entropy produced in the bidirectional transitions and a dynamical contribution which depends on the residence times in the states connected by the unidirectional transitions. The convergence of the integral fluctuation theorem is studied numerically, and found to show the same qualitative features as in systems exhibiting microreversibility.

cond-mat.stat-mech↗

arXiv2014

Descending from infinity: Convergence of tailed distributions

We investigate the relaxation of long-tailed distributions under stochastic dynamics that do not support such tails. Linear relaxation is found to be a borderline case in which long tails are exponentially suppressed in time but not eliminated. Relaxation stronger than linear suppresses long tails immediately, but may lead to strong transient peaks in the probability distribution. A delta function initial distribution under stronger than linear decay displays not one but two different regimes of diffusive spreading.

cond-mat.stat-mech↗