arXiv subjects

Usman Khan

Publications and source records attributed to Usman Khan.

11 recordsLinked to original sources

arXiv2026

Precise Photon Arrival Time Measurement via Time to Frequency Demultiplexing

We demonstrate a nonlinear-optics approach to precise measurement of photon arrival time, by translating the temporal information of single photons to a wavelength distribution of frequency conversion followed by de-multiplexed detection. It uses a multi-color, pulse-delayed pump laser to drive multiplexed frequency conversion, transducing photons to various frequency channels according to their arrival time. By photon detection in each channel, the measurement resolution and accuracy can reach picosecond level, much lower than the detectors' naive resolution and significantly beating the shot-noise limited direct detection. Distinct to any method relying on repeated, multiple sampling, our approach supports event-ready operations, capable of detecting randomly arriving single photons with no dead window. It is thus particularly suitable for practical applications of ranging, sensing, and communications in the dynamic, photon-starving environment.

physics.optics↗

arXiv2024

Hidden phase uncovered by ultrafast carrier dynamics in thin Bi2O2Se

Bi2O2Se has attracted intensive attention due to its potential in electronics, optoelectronics, as well as ferroelectric applications. Despite that, there have only been a handful of experimental studies based on ultrafast spectroscopy to elucidate the carrier dynamics in Bi2O2Se thin films, Different groups have reported various ultrafast timescales and associated mechanisms across films of different thicknesses. A comprehensive understanding in relation to thickness and fluence is still lacking. In this work, we have systematically explored the thickness-dependent Raman spectroscopy and ultrafast carrier dynamics in chemical vapor deposition (CVD)-grown Bi2O2Se thin films on mica substrate with thicknesses varying from 22.44 nm down to 4.62 nm at both low and high pump fluence regions. Combining the thickness dependence and fluence dependence of the slow decay time, we demonstrate a ferroelectric transition in the thinner (< 8 nm) Bi2O2Se films, influenced by substrate-induced compressive strain and non-equilibrium states. Moreover, this transition can be manifested under highly non-equilibrium states. Our results deepen the understanding of the interplay between the ferroelectric phase and semiconducting characteristics of Bi2O2Se thin films, providing a new route to manipulate the ferroelectric transition.

cond-mat.mtrl-sci↗

arXiv2021

Catalyst-Free Growth of Atomically-thin Bi2O2Se Nanoribbons for High-performance Electronics and Optoelectronics

One-dimensional (1D) materials have attracted significant research interest due to their unique quantum confinement effects and edge-related properties. Atomically thin 1D nanoribbon is particularly interesting because it is a valuable platform with physical limits of both thickness and width. Here, we develop a catalyst-free growth method and achieves the growth of Bi2O2Se nanostructures with tunable dimensionality. Significantly, Bi2O2Se nanoribbons with thickness down to 0.65 nm, corresponding to monolayer, are successfully grown for the first time. Electrical and optoelectronic measurements show that Bi2O2Se nanoribbons possess decent performance in terms of mobility, on/off ratio, and photoresponsivity, suggesting their promising for devices. This work not only reports a new method for the growth of atomically thin nanoribbons but also provides a platform to study properties and applications of such nanoribbon materials at thickness limit.

cond-mat.mtrl-sci↗

arXiv2020

High-Fidelity Transfer of 2D Bismuth Oxyselenide and its Mechanical Properties

Two-dimensional (2D) bismuth oxyselenide (Bi2O2Se) with high electron mobility is advantageous in future high-performance and flexible electronic and optoelectronic devices. However, transfer of thin Bi2O2Se flakes is rather challenging, restricting measurements of its mechanical properties and application exploration in flexible devices. Here, we develop a reliable and effective polydimethylsiloxane (PDMS)-mediated method that allows transferring thin Bi2O2Se flakes from grown substrates onto target substrates like micro-electro-mechanical system substrates. The high fidelity of the transferred thin flakes stems from the high adhesive energy and flexibility of PDMS film. For the first time, the mechanical properties of 2D Bi2O2Se are experimentally acquired with nanoindentation method. We found that few-layer Bi2O2Se exhibits a large intrinsic stiffness of 18-23 GPa among 2D semiconductors, and a Young' s modulus of 88.7 +- 14.4 GPa which is consistent with the theoretical values. Furthermore, few-layer Bi2O2Se can withstand a high radial strain of more than 3%, demonstrating excellent flexibility. The development of the reliable transfer method and documentation of mechanical properties of 2D Bi2O2Se jointly fill the gap between theoretical prediction and experimental verification of mechanical properties of this emerging material, and will promote flexible electronics and optoelectronics based on 2D Bi2O2Se.

cond-mat.mtrl-sci↗

arXiv2020

Synthesis of ultrahigh-quality monolayer molybdenum disulfide through in-situ defect healing with thiol molecules

Monolayer transition metal dichalcogenides (TMDCs) are two-dimensional (2D) materials with many potential applications. Chemical vapour deposition (CVD) is a promising method to synthesize these materials. However, CVD-grown materials generally have poorer quality than mechanically exfoliated ones and contain more defects due to the difficulties in controlling precursors' distribution and concentration during growth where solid precursors are used. Here, we propose to use thiol as a liquid precursor for CVD growth of high quality and uniform 2D MoS2. Atomic-resolved structure characterizations indicate that the concentration of sulfur vacancies in the MoS2 grown from thiol is the lowest among all reported CVD samples. Low temperature spectroscopic characterization further reveals the ultrahigh optical quality of the grown MoS2. Density functional theory simulations indicate that thiol molecules could interact with sulfur vacancies in MoS2 and repair these defects during the growth of MoS2, resulting in high quality MoS2. This work provides a facile and controllable method for the growth of high-quality 2D materials with ultralow sulfur vacancies and high optical quality, which will benefit their optoelectronic applications.

cond-mat.mtrl-sci↗

arXiv2020

Unsaturated Single Atoms on Monolayer Transition Metal Dichalcogenides for Ultrafast Hydrogen Evolution

Large scale implementation of electrochemical water splitting for hydrogen evolution requires cheap and efficient catalysts to replace expensive platinum. Molybdenum disulfide is one of the most promising alternative catalysts but its intrinsic activity is still inferior to platinum. There is therefore a need to explore new active site origins in molybdenum disulfide with ultrafast reaction kinetics and to understand their mechanisms. Here, we report a universal cold hydrogen plasma reduction method for synthesizing different single atoms sitting on two-dimensional monolayers. In case of molybdenum disulfide, we design and identify a new type of active site, i.e., unsaturated Mo single atoms on cogenetic monolayer molybdenum disulfide. The catalyst shows exceptional intrinsic activity with a Tafel slope of 35.1 mV dec-1 and a turnover frequency of ~10^3 s-1 at 100 mV, based on single flake microcell measurements. Theoretical studies indicate that coordinately unsaturated Mo single atoms sitting on molybdenum disulfide increase the bond strength between adsorbed hydrogen atoms and the substrates through hybridization, leading to fast hydrogen adsorption/desorption kinetics and superior hydrogen evolution activity. This work shines fresh light on preparing highly-efficient electrocatalysts for water splitting and other electrochemical processes, as well as provides a general method to synthesize single atoms on two-dimensional monolayers.

cond-mat.mtrl-sci↗

arXiv2019

On the Complexity of Minimum-Cost Networked Estimation of Self-Damped Dynamical Systems

In this paper, we consider the optimal design of networked estimators to minimize the communication/measurement cost under the networked observability constraint. This problem is known as the minimum-cost networked estimation problem, which is generally claimed to be NP-hard. The main contribution of this work is to provide a polynomial-order solution for this problem under the constraint that the underlying dynamical system is self-damped. Using structural analysis, we subdivide the main problem into two NP-hard subproblems known as (i) optimal sensor selection, and (ii) minimum-cost communication network. For self-damped dynamical systems, we provide a polynomial-order solution for subproblem (i). Further, we show that the subproblem (ii) is of polynomial-order complexity if the links in the communication network are bidirectional. We provide an illustrative example to explain the methodologies.

eess.SY↗

arXiv2019

Digital synthesis of multistage etalons for enhancing the FSR

Fabry-Perot fiber etalons (FPE) built from three or more reflectors are attractive for a variety of applications including communications and sensing. For accelerating a research and development work, one often desires to use off-the-shelf components to build an FPE with a required transmission profile for a particular application. Usually, multistage FPEs are designed with equal lengths of cavities followed by determination of the required reflectivities for realizing a desired transmission profile. As seen in previous works, fabricated reflectors are usually slightly different from the designed ones leading to departure from the desired transmission profile of the FPE. Here, we show a novel digital synthesis of multistage etalons with off-the-shelf reflectors and unequal lengths of involved cavities. We find that, in contrast to equal cavity lengths, unequal lengths of cavities provide more number of poles in the $z$-domain to achieve a desired multicavity FPE transmission response. For given reflectivities and by determining correct unequal lengths of cavities with our synthesis technique, we demonstrate a design example of increasing the FSR followed by its experimental validation. This work is generalizable to ring resonators, mirrored, and fiber Bragg grating based cavities; enabling the design and optimization of cavity systems for a wide range of applications including lasers, sensors, and filters.

eess.SP↗

arXiv2017

Observational Equivalence in System Estimation: Contractions in Complex Networks

Observability of complex systems/networks is the focus of this paper, which is shown to be closely related to the concept of contraction. Indeed, for observable network tracking it is necessary/sufficient to have one node in each contraction measured. Therefore, nodes in a contraction are equivalent to recover for loss of observability, implying that contraction size is a key factor for observability recovery. Here, using a polynomial order contraction detection algorithm, we analyze the distribution of contractions, studying its relation with key network properties. Our results show that contraction size is related to network clustering coefficient and degree heterogeneity. Particularly, in networks with power-law degree distribution, if the clustering coefficient is high there are less contractions with smaller size on average. The implication is that estimation/tracking of such systems requires less number of measurements, while their observational recovery is more restrictive in case of sensor failure. Further, in Small-World networks higher degree heterogeneity implies that there are more contractions with smaller size on average. Therefore, the estimation of representing system requires more measurements, and also the recovery of measurement failure is more limited. These results imply that one can tune the properties of synthetic networks to alleviate their estimation/observability recovery.

eess.SY↗

arXiv2017

An opportunistic linear-convex algorithm for localization in mobile robot networks

In this paper, we develop a \textcolor{black}{\emph{distributed}} algorithm to localize a network of robots moving arbitrarily in a bounded region. In the case of such mobile networks, the main challenge is that the robots may not be able to find nearby robots to implement a distributed algorithm. We address this issue by providing an opportunistic algorithm that only implements a location update when there are nearby robots and does not update otherwise. We assume that each robot measures a noisy version of its motion and the distances to the nearby robots. To localize a network of mobile robots in~$\mathbb{R}^m$, we provide a simple \emph{linear} update, which is based on barycentric coordinates and is linear-convex. We abstract the corresponding localization algorithm as a Linear Time-Varying (LTV) system and show that it asymptotically converges to the true locations~of~the robots. We first focus on the noiseless case, where the distance and motion vectors are known (measured) perfectly, and provide sufficient conditions on the convergence of the algorithm. We then evaluate the performance of the algorithm in the presence of noise and provide modifications to counter the undesirable effects of noise. \textcolor{black}{We further show that our algorithm precisely tracks a mobile network as long as there is at least one known beacon (a node whose location is perfectly known).

cs.RO↗

arXiv2016

Magnetic fingerprint of interfacial coupling between CoFe and nanoscale ferroelectric domain walls

Magnetoelectric coupling in ferromagnet/multiferroic systems is often manifested in the exchange bias effect, which may have combined contributions from multiple sources, such as domain walls, chemical defects or strain. In this study we magnetically "fingerprint" the coupling behavior of CoFe grown on epitaxial BiFeO3 (BFO) thin films by magnetometry and first-order-reversal-curves (FORC). The contribution to exchange bias from 71°, 109° and charged ferroelectric domain walls (DWs) was elucidated by the FORC distribution. CoFe samples grown on BFO with 71° DWs only exhibit an enhancement of the coercivity, but little exchange bias. Samples grown on BFO with 109° DWs and mosaic DWs exhibit a much larger exchange bias, with the main enhancement attributed to 109° and charged DWs. Based on the Malozemoff random field model, a varying-anisotropy model is proposed to account for the exchange bias enhancement. This work sheds light on the relationship between the exchange bias effect of the CoFe/BFO heterointerface and the ferroelectric DWs, and provides a path for multiferroic device analysis and design.

cond-mat.mtrl-sci↗