arXiv subjects

V. A. Malyshev

Publications and source records attributed to V. A. Malyshev.

89 records · Page 5Linked to original sources

arXiv2004

Phase coherence in tight-binding models with nonrandom long-range hopping

The density of states, even for a perfectly ordered tight-binding model, can exhibit a tail-like feature at the top of the band, provided the hopping integral falls off in space slowly enough. We apply the coherent potential approximation to study the eigenstates of a tight-binding Hamiltonian with uncorrelated diagonal disorder and long-range hopping, falling off as a power $μ$ of the intersite distance. For a certain interval of hopping range exponent $μ$, we show that the phase coherence length is infinite for the outermost state of the tail, irrespectively of the strength of disorder. Such anomalous feature can be explained by the smallness of the phase-space volume for the disorder scattering from this state. As an application of the theory, we mention that ballistic regime can be realized for Frenkel excitons in two-dimensional molecular aggregates, affecting to a large extent the optical response and energy transport.

cond-mat.dis-nn↗

arXiv2003

Low-temperature dynamics of weakly localized Frenkel excitons in disordered linar chains

We calculate the temperature dependence of the fluorescence Stokes shift and the fluorescence decay time in linear Frenkel exciton systems resulting from the thermal redistribution of exciton population over the band states. The following factors, relevant to common experimental conditions, are accounted for in our kinetic model: (weak) localization of the exciton states by static disorder, coupling of the localized excitons to vibrations in the host medium, a possible non-equilibrium of the subsystem of localized Frenkel excitons on the time scale of the emission process, and different excitation conditions (resonant or non resonant). A Pauli master equation, with microscopically calculated transition rates, is used to describe the redistribution of the exciton population over the manifold of localized exciton states. We find a counterintuitive non-monotonic temperature dependence of the Stokes shift. In addition, we show that depending on experimental conditions, the observed fluorescence decay time may be determined by vibration-induced intra-band relaxation, rather than radiative relaxation to the ground state. The model considered has relevance to a wide variety of materials, such as linear molecular aggregates, conjugated polymers, and polysilanes.

cond-mat.dis-nn↗

arXiv2003

Temperature dependent fluorescence in disordered Frenkel chains: interplay of equilibration and local band-edge level structure

We model the optical dynamics in linear Frenkel exciton systems governed by scattering on static disorder and lattice vibrations, and calculate the temperature dependent fluorescence spectrum and lifetime. The fluorescence Stokes shift shows a nonmonotonic behavior with temperature, which derives from the interplay of the local band-edge level structure and thermal equilibration. The model yields excellent fits to experiments performed on linear dye aggregates.

cond-mat.dis-nn↗

arXiv2003

Superradiance from an ultrathin film of three-level V-type atoms: Interplay between splitting, quantum coherence and local-field effects

We carry out a theoretical study of the collective spontaneous emission (superradiance) from an ultrathin film comprised of three-level atoms with $V$-configuration of the operating transitions. As the thickness of the system is small compared to the emission wavelength inside the film, the local-field correction to the averaged Maxwell field is relevant. We show that the interplay between the low-frequency quantum coherence within the subspace of the upper doublet states and the local-field correction may drastically affect the branching ratio of the operating transitions. This effect may be used for controlling the emission process by varying the doublet splitting and the amount of low-frequency coherence.

quant-ph↗

arXiv2003

Low-temperature quenching of one-dimensional localised Frenkel excitons

We present a theoretical analysis of low-temperature quenching of one-dimensional Frenkel excitons that are localised by moderate on-site (diagonal) uncorrelated disorder. Exciton diffusion is considered as an incoherent hopping over localization segments and is probed by the exciton fluorescence quenching at point traps. The rate equation is used to calculate the temperature dependence of the exciton quenching. The activation temperature of the diffusion is found to be of the order of the width of the exciton absorption band. We demonstrate that the intra-segment scattering is extremely important for the exciton diffusion. We discuss also experimental data on the fast exciton-exciton annihilation in linear molecular aggregates at low temperatures.

cond-mat.dis-nn↗

arXiv2003

On the low-temperature diffusion of localized Frenkel excitons in linear molecular aggregates

We study theoretically diffusion of one-dimensional Frenkel excitons in J-aggregates at temperatures that are smaller or of the order of the J-band width. We consider an aggregate as an open linear chain with uncorrelated on-site (diagonal) disorder that localizes the exciton at chain segments of size smaller than the full chain length. The exciton diffusion over the localization segments is considered as incoherent hopping. The diffusion is probed by the exciton fluorescence quenching which is due to the presence of point traps in the aggregate. The rate equation for populations of the localized exciton states is used to describe the exciton diffusion and trapping. We show that there exist two regimes of the exciton diffusion at low temperatures. The first, slower one, involves only the states of the very tail of the density of states, while the second, much faster one, also involves the higher states that are close to the bottom of the exciton band. The activation energy for the first regime of diffusion is of the order of one fifth of the J-band width, while for the second one it is of the order of the full J-band width. We discuss also the experimental data on the fast low-temperature exciton-exciton annihilation reported recently by I. G. Scheblykin {\em et al}, J. Phys. Chem. B {\bf 104}, 10949 (2000).

cond-mat.dis-nn↗

arXiv2002

Anderson transition in low-dimensional disordered systems driven by nonrandom long-range hopping

The single-parameter scaling hypothesis predicts the absence of delocalized states for noninteracting quasiparticles in low-dimensional disordered systems. We show analytically and numerically that extended states may occur in the one- and two-dimensional Anderson model with a nonrandom hopping falling off as some power of the distance between sites. The different size scaling of the bare level spacing and the renormalized magnitude of the disorder seen by the quasiparticles finally results in the delocalization of states at one of the band edges of the quasiparticle energy spectrum. The delocalized nature of those eigenstates is investigated by numerical diagonalization of the Hamiltonian and by the supersymmetric method for disorder averaging, combined with a renormalization group analysis.

cond-mat.dis-nn↗

arXiv2002

Absence of weak localization in two-dimensional disordered Frenkel lattices

The standard one-parameter scaling theory predicts that all eigenstates in two-dimensional random lattices are weakly localized. We show that this claim fails in two-dimensional dipolar Frenkel exciton systems. The linear energy dispersion at the top of the exciton band, originating from the long-range inter-site coupling of dipolar nature, yields the same size-scaling law for the level spacing and the effective disorder seen by the exciton. This finally results in the delocalization of those eigenstates in the thermodynamic limit. Large scale numerical simulations allow us to perform a detailed multifractal analysis and to elucidate the nature of the excitonic eigenstates.

cond-mat.dis-nn↗

arXiv2001

Gibbs and Quantum Discrete Spaces

Gibbs measure is one of the central objects of the modern probability, mathematical statistical physics and euclidean quantum field theory. Here we define and study its natural generalization for the case when the space, where the random field is defined is itself random. Moreover, this randomness is not given apriori and independently of the configuration, but rather they depend on each other, and both are given by Gibbs procedure; We call the resulting object a Gibbs family because it parametrizes Gibbs fields on different graphs in the support of the distribution. We study also quantum (KMS) analog of Gibbs families. Various applications to discrete quantum gravity are given.

gr-qc↗

arXiv2001

Nonlinear resonance reflection from and transmission through a dense glassy system built up of oriented linear Frenkel chains: two-level models

A theoretical study of the resonance optical response of assemblies of oriented short (as compared to an optical wavelength) linear Frenkel chains is carried out using a two-level model. We show that both transmittivity and reflectivity of the film may behave in a bistable fashion and analyze how the effects found depend on the film thickness and on the inhomogeneous width of the exciton optical transition.

physics.chem-ph↗

arXiv2001

Low-temperature kinetics of exciton-exciton annihilation of weakly localized one-dimensional Frenkel excitons

We present results of numerical simulations of the kinetics of exciton-exciton annihilation of weakly localized one-dimensional Frenkel excitons at low temperatures. We find that the kinetics is represented by two well-distinguished components: a fast short-time decay and a very slow long-time tail. The former arises from excitons that initially reside in states belonging to the same localization segment of the chain, while the slow component is caused by excitons created on different localization segments. We show that the usual bi-molecular theory fails in the description of the behavior found. We also present a qualitative analytical explanation of the non-exponential behavior observed in both the short- and the long-time decay components.

cond-mat.dis-nn↗

arXiv2000

Critical Behaviour in a Planar Dynamical Triangulation Model with a Boundary

We consider a canonical ensemble of dynamical triangulations of a 2-dimensional sphere with a hole where the number $N$ of triangles is fixed. The Gibbs factor is $\exp (-μ\sum °v)$ where $°v$ is the degree of the vertex $v$ in the triangulation $T$. Rigorous proof is presented that the free energy has one singularity, and the behaviour of the length $m$ of the boundary undergoes 3 phases: subcritical $m=O(1)$, supercritical (elongated) with $m$ of order $N$ and critical with $m=O(\sqrt{N})$. In the critical point the distribution of $m$ strongly depends on whether the boundary is provided with the coordinate system or not. In the first case $m$ is of order $\sqrt{N}$, in the second case $m$ can have order $N^α$ for any $0<α<{1/2}$.

gr-qc↗

arXiv1999

Motional narrowing effect in one-dimensional Frenkel chains with configurational disorder

We analyze the peculiarities of the motional narrowing effect in disordered one-dimensional Frenkel chains with off-diagonal disorder, induced by uncorrelated Gaussian fluctuations in the positions of the host units. A clear difference in the scaling laws with respect to the magnitude of the positional disorder and the chain size is found, as compared to those for uncorrelated diagonal disorder as well as for off-diagonal disorder modeled by uncorrelated randomness in the nearest-neighbor couplings. The origin of such a difference is discussed in detail.

cond-mat.dis-nn↗

arXiv1999

Linear optical properties of one-dimensional Frenkel exciton systems with intersite energy correlations

We analyze the effects of intersite energy correlations on the linear optical properties of one-dimensional disordered Frenkel exciton systems. The absorption line width and the factor of radiative rate enhancement are studied as a function of the correlation length of the disorder. The absorption line width monotonously approaches the seeding degree of disorder on increasing the correlation length. On the contrary, the factor of radiative rate enhancement shows a non-monotonous trend, indicating a complicated scenario of the exciton localization in correlated systems. The concept of coherently bound molecules is exploited to explain the numerical results, showing good agreement with theory. Some recent experiments are discussed in the light of the present theory.

cond-mat.dis-nn↗

arXiv1999

KMS states on Quantum Grammars

We consider quantum (unitary) continuous time evolution of spins on a lattice together with quantum evolution of the lattice itself. In physics such evolution was discussed in connection with quantum gravity. It is also related to what is called quantum circuits, one of the incarnations of a quantum computer. We consider simpler models for which one can obtain exact mathematical results. We prove existence of the dynamics in both Schroedinger and Heisenberg pictures, construct KMS states on appropriate C*-algebras. We show (for high temperatures) that for each system where the lattice undergoes quantum evolution, there is a natural scaling leading to a quantum spin system on a fixed lattice, defined by a renormalized Hamiltonian.

math-ph↗

arXiv1998

Probability around the Quantum Gravity. Part 1: Pure Planar Gravity

In this paper we study stochastic dynamics which leaves quantum gravity equilibrium distribution invariant. We start theoretical study of this dynamics (earlier it was only used for Monte-Carlo simulation). Main new results concern the existence and properties of local correlation functions in the thermodynamic limit. The study of dynamics constitutes a third part of the series of papers where more general class of processes were studied (but it is self-contained), those processes have some universal significance in probability and they cover most concrete processes, also they have many examples in computer science and biology. At the same time the paper can serve an introduction to quantum gravity for a probabilist: we give a rigorous exposition of quantum gravity in the planar pure gravity case. Mostly we use combinatorial techniques, instead of more popular in physics random matrix models, the central point is the famous $α=-7/2$ exponent.

math-ph↗

arXiv1998

Zero-energy peak of the density of states and localization properties of a one-dimensional Frenkel exciton: Off-diagonal disorder

We study a one-dimensional Frenkel Hamiltonian with off-diagonal disorder, focusing our attention on the physical nature of the zero-energy peak of the density of states. The character of excitonic states (localized or delocalized) is also examined in the vicinity of this peak. It is shown that the state being responsible for the peak is localized. A detailed comparison of the nearest-neighbor approach with the long-range dipole-dipole coupling is performed.

cond-mat.dis-nn↗