arXiv subjects

V. A. Sidorov

Publications and source records attributed to V. A. Sidorov.

At least 19 recordsLinked to original sources

arXiv2026

The New High-entropy Compound RhMnFeCoGe4 with Cubic Non-centrosymmetric B20 Structure

A novel high-entropy compound, RhMnFeCoGe$_4$, with a cubic non-centrosymmetric B20 struc- ture, has been synthesized under conditions of high pressure and temperature. The electrical transport and magnetic properties of the obtained compound at both ambient and elevated pres- sures have been investigated. In addition, nuclear magnetic resonance (NMR) spectra were obtained at 4.2 K and ab initio calculations were performed. The new material exhibits ferromag- netic behavior with a critical temperature of $T_C$ = 146 K and a spontaneous moment of 2.5 $μ_B$ per formula unit. The magnetization data obtained at the critical region yielded the critical temperature and exponents, which were found to be $T_C$ = 146(1) K, $β$ = 0.337(1), $γ$ = 1.121(1), and $δ$ = 4.326(1). The magnetic moments of Mn and Co were determined from NMR spectra to be 2.2 $μ_B$ and 0.5 $μ_B$, respectively. Ab initio calculations yielded reasonable values for the lattice parameter and the magnetic moments of all constituents. The density of states and band structure are determined for both paramagnetic and ferromagnetic states. Lattice compression results in the increase in the $T_C$.

cond-mat.mtrl-sci↗

arXiv2026

SANS and magnetometry study of the magnetic phase diagram of the B20 helimagnet FeRhSi

This manuscript reports the first direct neutron-scattering evidence for long-period helimagnetism in the newly identified 4d-substituted B20 compound Fe0.5Rh0.5Si. By combining SANS with low-field magnetometry, we establish the magnetic modulation, construct a field-temperature phase diagram, and identify a candidate A-phase region supported by an independent structural signature. The work is important beyond this single compound because it expands the family of chiral B20 helimagnets into Rh-substituted materials, where spin-orbit coupling, disorder, and Dzyaloshinskii-Moriya interactions can be tuned. It will interest researchers in chiral magnetism, topological spin textures, magnetic neutron scattering, and quantum materials, and provides a foundation for future studies of emergent magnetic phases and topology-driven phenomena in chemically tuned chiral magnets.

cond-mat.str-el↗

arXiv2026

The analysis of heat capacity of MnGe metallic helimagnet

Zero-field heat capacity of metallic helimagnet MnGe was analyzed based on the results of resistivity decomposition published previously by our group for the same crystal. Current procedure allowed identifying along with ($i$) electronic ($\tildeγ$ $\approx$ 7 mJ/mol$\cdot$K$^2$) and ($ii$) phononic ($Θ_D$ $\approx$ 350 K) components ($iii$) the additional term, caused by the presence of spin fluctuations (SFs). The last contribution was found to exist in a wide range of temperatures in both paramagnetic (PM) and magnetically ordered states. However, its amplitude appears to be significantly lower in comparison with phononic component. The obtained value of spin fluctuation temperature $θ_{sf}$(MnGe) $\approx$ 330 K correlates well with previous estimations, as well as with results of various experiments, which predict the existence of SFs in MnGe at least up to 250 $-$ 300 K.

cond-mat.str-el↗

arXiv2022

Split of the magnetic and crystallographic states in Fe$_{1-x}$Rh$_{x}$Ge

We report on a comprehensive experimental and theoretical study of Fe$_{1-x}$Rh$_{x}$Ge compounds, within the entire concentration range $x \in \left[0.0 - 1.0\right]$, using X-Ray diffraction, small-angle neutron scattering, magnetometry and theoretical calculations. While FeGe and RhGe are single phase helimagnet and unconventional superconductor, respectively, an internal splitting of the crystallographic and magnetic states is found for intermediate compositions $x \in \left[0.2 - 0.9\right]$. A theoretical analysis of the stability of the two detected phases, together with the experimental data, indicate that this splitting preserves a common space group and occurs within single crystallites. Despite their apparent similarity, these two phases however display different magnetic structures, with distinct ferro- and helimagnetic character.

cond-mat.mtrl-sci↗

arXiv2022

Possible quadrupole-order-driven commensurate-incommensurate phase transition in B20 CoGe

The B20-type cobalt germanide CoGe was investigated by measuring the specific heat, resistivity, and $^{59}$Co nuclear magnetic resonance (NMR). We observed a phase transition at $T_Q=13.7$ K, evidenced by a very narrow peak of the specific heat and sharp changes of the nuclear spin-spin ($T_2^{-1}$) and spin-lattice ($T_1^{-1}$) relaxation rates. The fact that the entropy release is extremely small and the Knight shift is almost independent of temperature down to low temperatures as anticipated in a paramagnetic metal indicates that the $T_Q$ transition is of non-magnetic origin. In addition, we detected a crossover scale $T_0\sim30$ K below which the resistivity and the NMR linewidth increase, and $T_1^{-1}$ is progressively distributed in space, that is, a static and dynamical spatial inhomogeneity develops. While the order parameter for the $T_Q$ transition remains an open question, a group-theoretical analysis suggests that the finite electric quadrupole density arising from the low local site symmetry at cobalt sites could drive the crystal symmetry lowering from the P2$_1$3 symmetry that is commensurate to the R3 symmetry with an incommensurate wavevector, which fairly well accounts for the $T_Q$ transition. The quadrupole-order-driven commensurate-incommensurate phase transition may be another remarkable phenomenon arising from the structural chirality inherent in the noncentrosymmetric B20 family.

cond-mat.str-el↗

arXiv2020

Dualism of the 4f electrons and high-temperature antiferromagnetism of the heavy-fermion compound YbCoC$_{2}$

We report on the first study of the noncentrosymmetric ternary carbide YbCoC$_{2}$. Our magnetization, specific heat, resistivity and neutron diffraction measurements consistently show that the system behaves as a heavy-fermion compound, displaying an amplitude-modulated magnetic structure below the Néel temperature reaching $T_{N}$ = 33 K under pressure. Such a large value, being the highest among the Yb-based systems, is explained in the light of our ab initio calculations, which show that the 4f electronic states of Yb have a dual nature -- i.e., due to their strong hybridization with the 3d states of Co, 4f states expose both localized and itinerant properties.

cond-mat.str-el↗

arXiv2019

Theoretical and experimental study of high-pressure synthesized B20-type compounds Mn$_{1-x}$(Co,Rh)$_x$Ge

The search and exploration of new materials not found in nature is one of modern trends in pure and applied chemistry. In the present work, we report on experimental and \textit{ab initio} density-functional study of the high-pressure-synthesized series of compounds Mn$_{1-x}$(Co,Rh)$_x$Ge. These high-pressure phases remain metastable at normal conditions, therewith they preserve their inherent noncentrosymmetric B20-type structure and chiral magnetism. Of particular interest in these two isovalent systems is the comparative analysis of the effect of $3d$ (Co) and $4d$ (Rh) substitution for Mn, since the $3d$ orbitals are characterized by higher localization and electron interaction than the $4d$ orbitals. The behavior of Mn$_{1-x}$(Co,Rh)$_x$Ge systems is traced as the concentration changes in the range $0 \leq x \leq 1$. We applied a sensitive experimental and theoretical technique which allowed to refine the shape of the temperature dependencies of magnetic susceptibility $χ(T)$ and thereby provide a new and detailed magnetic phase diagram of Mn$_{1-x}$Co$_x$Ge. It is shown that both systems exhibit a helical magnetic ordering that very strongly depends on the composition $x$. However, the phase diagram of Mn$_{1-x}$Co$_x$Ge differs from that of Mn$_{1-x}$Rh$_x$Ge in that it is characterized by coexistence of two helices in particular regions of concentrations and temperatures.

physics.chem-ph↗

arXiv2018

Magnetic, electronic and transport properties of high-pressure-synthesized chiralmagnets Mn$_{1-x}$Rh$_x$Ge (B20)

We report on structural, magnetic and transport properties of a new set of the high-pressuresynthesized compounds Mn$_{1-x}$Rh$x$Ge ($0 \leq x \leq 1$) with the chiral magnetic ordering. The magnetic and transport properties depend substantially on the concentration of rhodium (x) and the pressure. The saturation magnetic moment corresponds to a known high-spin value for pristine MnGe (x = 0) and decreases almost linearly with increasing concentration $x$. In addition, XMCD spectra taken at 10 K and 2 T indicate magnetic polarization of the Rh 4d electron states and Ge $4p$ states, which decreases with $x$, too. In rhodium rich compounds ($x \geq 0.5$) the temperature of the magnetic ordering increases significantly with pressure, whereas in manganese rich compounds ($x < 0.5$) the temperature decreases. Three different tendencies are also found for several structural and transport properties. In the intermediate range ($0.3 \leq x \leq 0.7$) samples are semiconducting in the paramagnetic phase, but become metallic in the magnetically ordered state. We carried out ab initio density-functional calculations of Mn$_{1-x}$Rh$_x$Ge at various concentrations $x$ and traced the evolution of electronic and magnetic properties. The calculation results are in good agreement with the measured magnetic moments and qualitatively explain the observed trends in transport properties.

cond-mat.str-el↗

arXiv2015

Thermal expansion and compressibility of monogermanides of 3d-metals

Synchrotron diffraction as a function of temperature and pressure, specific heat, magnetic susceptibility and small-angle neutron scattering experiments have revealed an anomalous response of MnGe. Similar but less pronounced behavior has also been observed in Mn$_{1-x}$Co$_x$Ge and Mn$_{1-x}$Fe$_x$Ge solid solutions. Spin density fluctuations and Mn spin state instability are discussed as possible candidates for the observed effects.

cond-mat.mtrl-sci↗

arXiv2015

Superconductivity and Magnetism in Noncentrosymmetric RhGe

RhGe synthesized at high pressure is crystallized in noncentrosymmetric cubic structure of the B20 type. Measurements of the electrical resistivity and magnetization demonstrate a superconducting state below T$_c$ ~ 4.5 K and a weak ferromagnetism below T$_m$ ~ 140 K. Specific heat data confirm the bulk nature of superconductivity in this ferromagnetic superconductor. The superconducting region forms a dome on the P-T diagram with a maximum of T$_c$ near 4 GPa. Ab initio simulations suggest that the observed weak magnetization emerges from the pronounced spin polarization with magnetic quadrupole and toroidal moments located at Rh and Ge sites.

cond-mat.supr-con↗

arXiv2014

Two-channel point-contact tunneling theory of superconductors

We introduce a two-channel tunneling model to generalize the widely used BTK theory of point-contact conductance between a normal metal contact and superconductor. Tunneling of electrons can occur via localized surface states or directly, resulting in a Fano resonance in the differential conductance $G=dI/dV$. We present an analysis of $G$ within the two-channel model when applied to soft point-contacts between normal metallic silver particles and prototypical heavy-fermion superconductors CeCoIn$_5$ and CeRhIn$_5$ at high pressures. In the normal state the Fano line shape of the measured $G$ is well described by a model with two tunneling channels and a large temperature-independent background conductance. In the superconducting state a strongly suppressed Andreev reflection signal is explained by the presence of the background conductance. We report Andreev signal in CeCoIn$_5$ consistent with standard $d_{x^2-y^2}$-wave pairing, assuming an equal mixture of tunneling into [100] and [110] crystallographic interfaces. Whereas in CeRhIn$_5$ at 1.8 and 2.0 GPa the signal is described by a $d_{x^2-y^2}$-wave gap with reduced nodal region, i.e., increased slope of the gap opening on the Fermi surface. A possibility is that the shape of the high-pressure Andreev signal is affected by the proximity of a line of quantum critical points that extends from 1.75 to 2.3 GPa, which is not accounted for in our description of the heavy-fermion superconductor.

cond-mat.supr-con↗

arXiv2014

Hyperfine field assessment of the magnetic structure of ZrZn2

Time differential perturbed angular gamma-gamma-correlation (TDPAC) method on 111Cd nuclei probes inserted in ZrZn1.9 is used to measure the magnetic hyperfine fields (MHF) at Zr and Zn sites and the electric field gradient (EFG) Vzz at Zn sites as a function of temperature at various pressures and as a function of pressure at the temperature 4 K. Our data indicate that the local magnetic moment of Zr in the magnetically ordered state is substantially larger than its value obtained from the macroscopic measurements and that there is also an induced magnetic moment at the Zn site. We conclude that ZrZn2 is not a simple ferromagnet and discuss a possible type of its magnetic ordering.

cond-mat.mtrl-sci↗

arXiv2014

Disorder in a Quantum Critical Superconductor

In four classes of materials, the layered copper-oxides, organics, iron-pnictides and heavy-fermion compounds, an unconventional superconducting state emerges as a magnetic transition is tuned toward absolute zero temperature, that is, toward a magnetic quantum-critical point (QCP). In most materials, the QCP is accessed by chemical substitutions or applied pressure. CeCoIn5 is one of the few materials that are born as a quantum-critical superconductor and, therefore, offers the opportunity to explore the consequences of chemical disorder. Cadmium-doped crystals of CeCoIn5 are a particularly interesting case where Cd substitution induces long-range magnetic order, as in Zn-doped copper-oxides. Applied pressure globally supresses the Cd-induced magnetic order and restores bulk superconductivity. Here we show, however, that local magnetic correlations, whose spatial extent decreases with applied pressure, persist at the extrapolated QCP. The residual droplets of impurity-induced magnetic moments prevent the reappearance of conventional signatures of quantum criticality, but induce a heterogeneous electronic state. These discoveries show that spin droplets can be a source of electronic heterogeneity in classes of strongly correlated electron systems and emphasize the need for caution when interpreting the effects of tuning a correlated system by chemical substitution.

cond-mat.supr-con↗

arXiv2013

Thermodynamics of the ferromagnetic phase transition in nearly half metallic CoS2 at high pressures

The volume change and heat capacity at the ferromagnetic phase transition in CoS2 were measured at high pressures using X-rays generated by the Argonne synchrotron light source and by ac-calorimetry, respectively. The transition entropy, calculated on the basis of these experimental data, drops along the transition line due to quantum degradation, as required by Nernst law. The volume change increases strongly along the transition line, which is explained by specifics of the compressibility difference of coexisting phases that results from nearly half metallic nature of the ferromagnetic phase of CoS2.

cond-mat.str-el↗

arXiv2013

Comparative study of helimagnets MnSi and Cu2OSeO3 at high pressures

The heat capacity of helical magnets Cu2OSeO3 and MnSi has been investigated at high pressures by the ac-calorimetric technique. Despite the differing nature of their magnetic moments, Cu2OSeO3 and MnSi demonstrate a surprising similarity in behavior of their magnetic and thermodynamic properties at the phase transition. Two characteristic features of the heat capacity at the phase transitions of both substances (peak and shoulder) behave also in a similar way at high pressures if analyzed as a function of temperature. This probably implies that the longitudinal spin fluctuations typical of weak itinerant magnets like MnSi contribute little to the phase transition. The shoulders of the heat capacity curves shrink with decreasing temperature suggesting that they arise from classical fluctuations. In case of MnSi the sharp peak and shoulder at the heat capacity disappear simultaneously probably signifying the existence of a tricritical point and confirming the fluctuation nature of the first order phase transition in MnSi as well as in Cu2OSeO3.

cond-mat.str-el↗

arXiv2013

Pressure phase diagram and quantum criticality of CePt2In7 single crystals

We report the temperature-pressure (T-P) phase diagram of CePt2In7 single crystals, especially the pressure evolution of the antiferromagnetic order and the emergence of superconductivity, which have been studied by electrical resistivity and ac calorimetry under nearly hydrostatic environments. Compared with its polycrystalline counterpart, bulk superconductivity coexists with antiferromagnetism in a much narrower pressure region. The possible existence of textured superconductivity and local quantum criticality also are observed in CePt2In7, exhibiting a remarkable similarity with CeRhIn5.

cond-mat.str-el↗

arXiv2013

Effects of pressure on the ferromagnetic state of the CDW compound SmNiC2

We report the pressure response of charge-density-wave (CDW) and ferromagnetic (FM) phases of the rare-earth intermetallic SmNiC2 up to 5.5 GPa. The CDW transition temperature (T_{CDW}), which is reflected as a sharp inflection in the electrical resistivity, is almost independent of pressure up to 2.18 GPa but is strongly enhanced at higher pressures, increasing from 155.7 K at 2.2 GPa to 279.3 K at 5.5 GPa. Commensurate with the sharp increase in T_{CDW}, the first-order FM phase transition, which decreases with applied pressure, bifurcates into the upper (T_{M1}) and lower (T_c) phase transitions and the lower transition changes its nature to second order above 2.18 GPa. Enhancement both in the residual resistivity and the Fermi-liquid T^2 coefficient A near 3.8 GPa suggests abundant magnetic quantum fluctuations that arise from the possible presence of a FM quantum critical point.

cond-mat.str-el↗

arXiv2012

Pressure effects on the heavy-fermion antiferromagnet CeAuSb2

The f-electron compound CeAuSb2, which crystallizes in the ZrCuSi2-type tetragonal structure, orders antiferromagnetically between 5 and 6.8 K, where the antiferromagnetic transition temperature T_N depends on the occupancy of the Au site. Here we report the electrical resistivity and heat capacity of a high-quality crystal CeAuSb2 with T_N of 6.8 K, the highest for this compound. The magnetic transition temperature is initially suppressed with pressure, but is intercepted by a new magnetic state above 2.1 GPa. The new phase shows a dome shape with pressure and coexists with another phase at pressures higher than 4.7 GPa. The electrical resistivity shows a T^2 Fermi liquids behavior in the complex magnetic state, and the residual resistivity and the T^2 resistivity coefficient increases with pressure, suggesting the possibility of a magnetic quantum critical point at a higher pressure.

cond-mat.str-el↗