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V. Ihnatovych

Publications and source records attributed to V. Ihnatovych.

6 recordsLinked to original sources

On the incorrectness of the proof of the Gibbs theorem on the entropy of a mixture of ideal gases, which was given by J. W. Gibbs

There is the Gibbs theorem in thermodynamics, according to which the entropy of the mixture of ideal gases is equal to the sum of the entropies of the components of the mixture. J. W. Gibbs proved this by a mathematical derivation from the beginnings of thermodynamics and the laws of ideal gases, in particular Dalton's law. This message shows that this proof is mathematically incorrect. It is also shown that the Gibbs theorem cannot be derived mathematically from Dalton's law.

physics.hist-ph

Philosophical roots of the "eternal" questions in the XX-century theoretical physics

The evolution of theoretical physics in the XX century differs significantly from that in XVII-XIX centuries. While continuous progress is observed for theoretical physics in XVII-XIX centuries, modern physics contains many questions that have not been resolved despite many decades of discussion. Based upon the analysis of works by the founders of the XX-century physics, the conclusion is made that the roots of the "eternal" questions by the XX-century theoretical physics lie in the philosophy used by its founders. The conclusion is made about the need to use the ideas of philosophy that guided C. Huygens, I. Newton, W. Thomson (Lord Kelvin), J. K. Maxwell, and the other great physicists of the XVII-XIX centuries, in all areas of theoretical physics.

physics.hist-ph

The logical foundations of Gibbs' paradox in classical thermodynamics

The analysis of the arguments within the limits of the classical thermodynamics that lead to the Gibbs paradox was made. Features of preconditions used in the derivation of the entropy of mixing of ideal gases that caused the appearance of paradox were established. It was shown that the Gibbs paradox has not connection with the assumption of discrete differences between the parameters of different gases.

physics.hist-ph

Inconsistency of Carnot's theorem's proof by William Thomson

William Thomson proved Carnot's theorem basing on postulate: "It is impossible, by means of inanimate material agency, to derive mechanical effect from any portion of matter by cooling it below the temperature of the coldest of the surrounding objects". The present paper demonstrates that Carnot's theorem can be proved based on the contrary Thomson's postulate: "It is impossible to use the mechanical effect to the heating the coldest of surrounding objects". A conclusion that Carnot's theorem does not follow from the Thomson's postulate has been drawn.

physics.hist-ph

Inconsistency of Carnot's theorem's proof by R. Clausius

R. Clausius proved Carnot's theorem basing on postulate "Heat cannot, of itself, pass from a colder to a hotter body". Alexander Gukhman demonstrated that Carnot's theorem can be proved based on the postulate "Heat cannot, of itself, pass from a hotter to a colder body". He concluded that Carnot's theorem does not follow from Clausius' postulate. The following paper gives a detailed justification of Gukhman's derivation.

physics.hist-ph