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V. Kocsis

Publications and source records attributed to V. Kocsis.

17 recordsLinked to original sources

Thermal transport and low-temperature specific heat in 4Hb-TaS$_2$

We investigate the low-energy excitation spectrum of the van der Waals heterostructure superconductor 4Hb-TaS$_2$ using ultra-low-temperature specific-heat and thermal-conductivity measurements with magnetic fields applied parallel and perpendicular to the crystallographic $c$ axis. The specific heat is broadly consistent with a nodeless superconducting gap, but retains a finite residual linear contribution, indicating a small residual low-energy density of states in the superconducting state. In addition, a pronounced upturn appears below approximately 0.3K. Its weak magnetic-field dependence, together with the absence of a corresponding feature in thermal transport, supports an interpretation in terms of localized degrees of freedom, most likely a nuclear Schottky contribution. In contrast to the finite residual thermodynamic density of states, the thermal conductivity extrapolates to a vanishing zero-field electronic linear term within experimental uncertainty for both field orientations. Thus, the residual low-energy states do not form a detectable itinerant heat-conduction channel. In finite magnetic field, the electronic heat transport grows rapidly. For out-of-plane fields, this response is broadly consistent with previous thermal-conductivity measurements and with the behavior commonly associated with multigap nodeless superconductivity. The even steeper increase observed for in-plane fields suggests that the field-induced quasiparticle response of 4Hb-TaS$_2$ is more complicated than the standard multigap picture alone.

cond-mat.supr-con

Imaging antiferromagnetic domains in LiCoPO$_4$ via the optical magnetoelectric effect

Antiferromagnetic (AFM) materials are considered as promising building blocks of novel data storage devices, still, detecting and manipulating AFM domains have remained challenging. Here, we demonstrate that the two antiphase domains of the magnetoelectric antiferromagnet LiCoPO$_4$ can be distinguished by their light absorption difference. Using visible and infrared spectroscopy, we observed spontaneous non-reciprocal absorption, also termed as directional dichroism, at the crystal field excitations of Co$^{2+}$ ions coordinated by distorted oxygen octahedra. This absorption contrast is particularly pronounced near the telecommunication wavelength of 1550 nm. These findings allowed us to image the AFM domains in LiCoPO$_4$ using a simple transmission light microscopy setup. Our findings suggest that optical magnetoelectric effects offer promising routes for probing the AFM order parameter in non-centrosymmetric transition metal compounds.

cond-mat.mtrl-sci

Magnetic phase diagram and spin Hamiltonian of antiferromagnet Cs$_2$CoI$_4$

We report comprehensive thermodynamic and neutron scattering measurements on the $S$ = 3/2 antiferromagnet Cs$_2$CoI$_4$, a member of the thoroughly studied family of frustrated magnets Cs$_2MX_4$ ($M$ = Cu, Co, Ru, $X$ = Br, Cl, I, O). Unlike previously studied members, Cs$_2$CoI$_4$ undergoes a structural phase transition, for which we determine the low-temperature crystallographic structure. The resulting symmetry reduction strongly affects both the magnetic exchange interactions and single-ion anisotropy. Despite the large parameter space, we propose a minimal magnetic Hamiltonian that reasonably captures the observed excitation spectrum, analyzed using extended SU(4) linear spin-wave theory.

cond-mat.str-el

Chiral anomaly in the Weyl semimetal TaRhTe$_4$

TaRhTe$_4$ is a type-IIWeyl semimetal, exhibiting fourWeyl points in proximity to the Fermi level. In this article, we report our results of a systematic study of longitudinal magnetoresistance in TaRhTe$_4$. Our findings indicate that magnetoresistance becomes negative only when the magnetic field is applied parallel to the electric field. By rotating E (as well as B), we show that its origin is consistent with the prediction of the chiral anomaly, while the current jetting effect and weak localization could be excluded. The negative magnetoresistance persists up to room temperature, suggesting that TaRhTe4 exhibits distinctive properties within the family of Weyl semimetals.

cond-mat.str-el

Large Nernst effect in Te-based van der Waals materials

Layered van der Waals tellurides reveal topologically non-trivial properties that give rise to unconventional magneto-transport phenomena. Additionally, their semimetallic character with high mobility makes them promising candidates for large magneto-thermoelectric effects. Remarkable studies on the very large and unconventional Nernst effect in WTe$_2$ have been reported, raising questions about whether this property is shared across the entire family of van der Waals tellurides. In this study, systematic measurements of the Nernst effect in telluride van der Waals Weyl semimetals are presented. Large linear Nernst coefficients in WTe$_2$ and MoTe$_2$ are identified, and moderate Nernst coefficients with non-linear behavior in magnetic fields are observed in W$_{0.65}$Mo$_{0.35}$Te$_2$, TaIrTe$_4$, and TaRhTe$_4$. Within this sample set, a correlation between the dominant linear-in-magnetic-field component of the Nernst coefficient and mobility is established, aligning with the established Nernst scaling framework, though with a different scaling factor compared to existing literature. This enhancement might be caused by the shared favorable electronic band structure of this family of materials. Conversely, the non-linear component of the Nernst effect in a magnetic field could not be correlated with mobility. This non-linear term is almost absent in the binary compounds, suggesting a multiband origin and strong compensation between electron-like and hole-like carriers. This comprehensive study highlights the potential of van der Waals tellurides for thermoelectric conversion.

cond-mat.mtrl-sci

Anomalous quasielastic scattering contribution in the centrosymmetric multi-$\mathbf{q}$ helimagnet SrFeO$_3$

Centrosymmetric compounds which host three-dimensional topological spin structures comprise a distinct subclass of materials in which multiple-$\mathbf{q}$ magnetic order is stabilized by anisotropy and bond frustration in contrast to the more common path of antisymmetric exchange interactions. Here we investigate static and dynamic magnetic properties of the cubic perovskite SrFeO$_3$ $\unicode{x2013}$ a rare example of a centrosymmetric material hosting two types of topological spin textures: skyrmion- and hedgehog-lattice phases. Our detailed magnetization and dilatometry measurements describe the domain selection processes and phase transitions in SrFeO$_3$. Spin excitations are investigated using inelastic neutron scattering for all three zero-field phases. In the higher-temperature ordered phases, high-energy magnons increasingly lose coherence, so that spin fluctuations are dominated by a distinct quasielastic component at low energies. We anticipate that this could be generic to symmetric helimagnets in which the chiral symmetry is spontaneously broken by the magnetic order.

cond-mat.str-el

Refining magnetic interactions from the magnetic field dependence of spin-wave excitations in magnetoelectric LiFePO$_4$

We investigated the spin excitations of magnetoelectric $\text{LiFePO}_4$ by THz absorption spectroscopy in magnetic fields up to 33$\,$T. By studying their selection rules, we found not only magnetic-dipole, but also electric-dipole active (electromagnons) and magnetoelectric resonances. The magnetic field dependence of four strong low-energy modes is reproduced well by our four-sublattice spin model for fields applied along the three orthorhombic axes. From the fit, we refined the exchange couplings, single-ion anisotropies, and the Dzyaloshinskii-Moriya interaction parameters. Additional spin excitations not described by the mean-field model are observed at higher frequencies. Some of them shows a strong shift with magnetic field, up to 4$\,\text{cm}^{-1}/\text{T}$, when the field is applied along the easy axis. Based on this field dependence, we attribute these high frequency resonances to excitation of higher spin multipoles and of two magnons, which become THz-active due to the low symmetry of the magnetically ordered state.

cond-mat.str-el

Frustration model and spin excitations in the helimagnet FeP

The metallic compound FeP belongs to the class of materials that feature a complex noncollinear spin order driven by magnetic frustration. While its double-helix magnetic structure with a period $λ_{\text{s}} \approx 5c$, where $c$ is the lattice constant, was previously well determined, the relevant spin-spin interactions that lead to that ground state remain unknown. By performing extensive inelastic neutron scattering measurements, we obtained the spin-excitation spectra in a large part of the momentum-energy space. The spectra show that the magnons are gapped with a gap energy of $\sim$5 meV. Despite the 3D crystal structure, the magnon modes display strongly anisotropic dispersions, revealing a quasi-one-dimensional character of the magnetic interactions in FeP. The physics of the material, however, is not determined by the dominating exchange, which is ferromagnetic. Instead, the weaker two-dimensional antiferromagnetic interactions between the rigid ferromagnetic spin chains drive the magnetic frustration. Using linear spin-wave theory, we were able to construct an effective Heisenberg Hamiltonian with an anisotropy term capable of reproducing the observed spectra. This enabled us to quantify the exchange interactions in FeP and determine the mechanism of its magnetic frustration.

cond-mat.str-el

In-situ electric field control of THz non-reciprocal directional dichroism in the multiferroic Ba$_2$CoGe$_2$O$_7$

Non-reciprocal directional dichroism, also called the optical-diode effect, is an appealing functional property inherent to the large class of non-centrosymmetric magnets. However, the in-situ electric control of this phenomenon is challenging as it requires a set of conditions to be fulfilled: Special symmetries of the magnetic ground state, spin-excitations with comparable magnetic- and electric-dipole activity and switchable electric polarization. We demonstrate the isothermal electric switch between domains of Ba$_2$CoGe$_2$O$_7$ possessing opposite magnetoelectric susceptibilities. Combining THz spectroscopy and multiboson spin-wave analysis, we show that unbalancing the population of antiferromagnetic domains generates the non-reciprocal light absorption of spin excitations.

cond-mat.str-el

Field-induced phase transitions of the Kitaev material $α$-RuCl$_3$ probed by thermal expansion and magnetostriction

High-resolution thermal expansion and magnetostriction measurements were performed on single crystals of $α$-RuCl$_3$ in magnetic fields applied parallel to the Ru-Ru bonds. The length changes were measured in the direction perpendicular to the honeycomb planes. Our data show clear thermodynamic characteristics for the field-induced phase transition at the critical field $μ_0H_{c1} = 7.8(2)$ T where the antiferromagnetic zigzag order is suppressed. At higher fields, a kink in the magnetostriction coefficient signals an additional phase transition around $μ_0H_{c2} \approx 11$ T. The extracted Grüneisen parameter shows typical hallmarks for quantum criticality near $H_{c1}$, but also displays anomalous behavior above $H_{c1}$. We compare our experimental data with linear spin-wave calculations employing a minimal Kitaev-Heisenberg model in the semiclassical limit. Most of the salient features are in agreement with each other, however, the peculiar features in the high-field region above $H_{c1}$ cannot be accounted for in our modelling and hence suggest a genuine quantum nature. We construct a phase diagram for $α$-RuCl$_3$ showing two low-temperature transitions induced by an in-plane field along the Ru-Ru bonds.

cond-mat.str-el

Directional dichroism in the paramagnetic state of multiferroics: a case study of infrared light absorption in Sr2CoSi2O7 at high temperatures

The coexisting magnetic and ferroelectric orders in multiferroic materials give rise to a handful of novel magnetoelectric phenomena, such as the absorption difference for the opposite propagation directions of light called the non-reciprocal directional dichroism (NDD). Usually these effects are restricted to low temperature, where the multiferroic phase develops. In this paper we report the observation of NDD in the paramagnetic phase of Sr2CoSi2O7 up to temperatures more than ten times higher than its Néel temperature (7 K) and in fields up to 30 T. The magnetically induced polarization and NDD in the disordered paramagnetic phase is readily explained by the single-ion spin-dependent hybridization mechanism, which does not necessitate correlation effects between magnetic ions. The Sr2CoSi2O7 provides an ideal system for a theoretical case study, demonstrating the concept of magnetoelectric spin excitations in a paramagnet via analytical as well as numerical approaches. We applied exact diagonalization of a spin cluster to map out the temperature and field dependence of the spin excitations, as well as symmetry arguments of the single ion and lattice problem to get the spectrum and selection rules.

cond-mat.str-el

Competing Exchange Interactions in the Multiferroic and Ferrimagnetic CaBaCo$_4$O$_7$

Competing exchange interactions can produce complex magnetic states together with spin-induced electric polarizations. With competing interactions on alternating triangular and kagome layers, the swedenborgite CBO may have one of the largest measured spin-induced polarizations of about 1700 nC/cm$^2$ below its ferrimagnetic transition temperature at 70 K. Powder neutron-diffraction data, magnetization measurements, and spin-wave resonance frequencies in the THz range reveal that the complex spin order of multiferroic CBO can be described as a triangular array of c-axis chains ferrimagnetically coupled to each other in the ab plane. Magnetostriction on bonds that couple those chains produces the large spin-induced polarization of CBO.

cond-mat.mtrl-sci

Unidirectional terahertz light absorption in the pyroelectric ferrimagnet CaBaCo4O7

Spin excitations were studied by absorption spectroscopy in CaBaCo4O7 which is a type-I multiferroic compound with the largest magnetic-order induced ferroelectric polarization (ΔP=17mC/m2) reported, so far. We observed two optical magnon branches: a solely electric dipole allowed one and a mixed magnetoelectric resonance. The entangled magnetization and polarization dynamics of the magnetoelectric resonance gives rise to unidirectional light absorption, i.e. that magnon mode absorbs the electromagnetic radiation for one propagation direction but not for the opposite direction. Our systematic study of the magnetic field and temperature dependence of magnon modes provides information about the energies and symmetries of spin excitations, which is required to develop a microscopic spin model of CaBaCo4O7.

cond-mat.str-el

Simultaneously Magnetic- and Electric-dipole Active Spin Excitations Govern the Static Magnetoelectric Effect in Multiferroic Materials

We derive a sum rule to demonstrate that the static magnetoelectric (ME) effect is governed by optical transitions that are simultaneously excited via the electric and magnetic components of light. By a systematic analysis of magnetic point groups, we show that the ME sum rule is applicable to a broad variety of non-centrosymmetric magnets including ME multiferroic compounds. Due to the dynamical ME effect, the optical excitations in these materials can exhibit directional dichroism, i.e. the absorption coefficient can be different for counter-propagating light beams. According to the ME sum rule, the magnitude of the linear ME effect of a material is mainly determined by the directional dichroism of its low-energy optical excitations. Application of the sum rule to the multiferroic Ba$_2$CoGe$_2$O$_7$, Sr$_2$CoSi$_2$O$_7$ and Ca$_2$CoSi$_2$O$_7$ shows that in these compounds the static ME effect is mostly governed by the directional dichroism of the spin-wave excitations in the GHz-THz spectral range. On this basis, we argue that the studies of directional dichroism and the application of ME sum rule can promote the synthesis of new materials with large static ME effect.

cond-mat.mtrl-sci

Magnetoelasticity in ACr2O4 spinel oxides

Dynamical properties of the lattice structure was studied by optical spectroscopy in ACr2O4 chromium spinel oxide magnetic semiconductors over a broad temperature region of T=10-335K. The systematic change of the A-site ions (A=Mn, Fe, Co, Ni and Cu) showed that the occupancy of 3d orbitals on the A-site, has strong impact on the lattice dynamics. For compounds with orbital degeneracy (FeCr2O4, NiCr2O4 and CuCr2O4), clear splitting of infrared-active phonon modes and/or activation of silent vibrational modes have been observed upon the Jahn-Teller transition and at the onset of the subsequent long-range magnetic order. Although MnCr2O4 and CoCr2O4 show multiferroic and magnetoelectric character, no considerable magnetoelasticity was found in spinel compounds without orbital degeneracy as they closely preserve the high-temperature cubic spinel structure even in their magnetic ground state. Besides lattice vibrations, intra-atomic 3d-3d transitions of the A$^{2+}$ ions were also investigated to determine the crystal field and Racah parameters and the strength of the spin-orbit coupling.

cond-mat.str-el

Malaria pigment crystals as magnetic micro-rotors: key for high-sensitivity diagnosis

The need to develop new methods for the high-sensitivity diagnosis of malaria has initiated a global activity in medical and interdisciplinary sciences. Most of the diverse variety of emerging techniques are based on research-grade instruments, sophisticated reagent-based assays or rely on expertise. Here, we suggest an alternative optical methodology with an easy-to-use and cost-effective instrumentation based on unique properties of malaria pigment reported previously and determined quantitatively in the present study. Malaria pigment, also called hemozoin, is an insoluble microcrystalline form of heme. These crystallites show remarkable magnetic and optical anisotropy distinctly from any other components of blood. As a consequence, they can simultaneously act as magnetically driven micro-rotors and spinning polarizers in suspensions. These properties can gain importance not only in malaria diagnosis and therapies, where hemozoin is considered as drug target or immune modulator, but also in the magnetic manipulation of cells and tissues on the microscopic scale.

physics.bio-ph

Giant magneto-optical response in non-magnetic semiconductor BiTeI driven by bulk Rashba spin splitting

We study the magneto-optical (MO) response of polar semiconductor BiTeI with giant bulk Rashba spin splitting at various carrier densities. Despite being non-magnetic, the material is found to yield a huge MO activity in the infrared region under moderate magnetic fields (<3 T). By comparison with first-principles calculations, we show that such an enhanced MO response is mainly due to the intraband transitions between the Rashba-split bulk conduction bands in BiTeI, which give rise to distinct novel features and systematic doping dependence of the MO spectra. We further predict an even more pronounced enhancement in the low-energy MO response and dc Hall effect near the crossing (Dirac) point of the conduction bands.

cond-mat.str-el