V. Smolyaninova | Searcharxiv

arXiv1999

Electrical transport in the ferromagnetic state of manganites: Small-polaron metallic conduction at low temperatures

We report measurements of the resistivity in the ferromagnetic state of epitaxial thin films of La_{1-x}Ca_{x}MnO_{3} and the low temperature specific heat of a polycrystalline La_{0.8}Ca_{0.2}MnO_{3}. The resistivity below 100 K can be well fitted by ρ- ρ_{o} = E ω_{s}/sinh^{2}(\hbar ω_{s}/2k_{B}T) with \hbar ω_{s}/k_{B} \simeq 100 K and E being a constant. Such behavior is consistent with small-polaron coherent motion which involves a relaxation due to a soft optical phonon mode. The specific heat data also suggest the existence of such a phonon mode. The present results thus provide evidence for small-polaron metallic conduction in the ferromagnetic state of manganites.

cond-mat.str-el↗

arXiv1999

Properties of the ferrimagnetic double-perovskite A_{2}FeReO_{6} (A=Ba and Ca)

Ceramics of A_{2}FeReO_{6} double-perovskite have been prepared and studied for A=Ba and Ca. Ba_{2}FeReO_{6} has a cubic structure (Fm3m) with $a\approx $8.0854(1) Åwhereas Ca_{2}FeReO_{6} has a distorted monoclinic symmetry with $a\approx 5.396(1) Å, b\approx 5.522(1) Å, c\approx 7.688(2) Å$ and $β=90.4^{\circ} (P21/n)$. The barium compound is metallic from 5 K to 385 K, i.e. no metal-insulator transition has been seen up to 385 K, and the calcium compound is semiconducting from 5 K to 385 K. Magnetization measurements show a ferrimagnetic behavior for both materials, with T_{c}=315 K for Ba_{2}FeReO_{6} and above 385 K for Ca_{2}FeReO_{6}. A specific heat measurement on the barium compound gave an electron density of states at the Fermi level, N(E_{F}) equal to 6.1$\times 10^{24} eV^{-1}mole^{-1}$. At 5 K, we observed a negative magnetoresistance of 10 % in a magnetic field of 5 T, but only for Ba_{2}FeReO_{6}. Electrical, thermal and magnetic properties are discussed and compared to the analogous compounds Sr_{2}Fe(Mo,Re)O_{6}.

cond-mat.mtrl-sci↗