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V. V. Smith

Publications and source records attributed to V. V. Smith.

At least 19 recordsLinked to original sources

Chemical Abundances of the Bioessential Elements C, O and S, and the Refractory Elements Fe and Ni, in Solar-type Exoplanet-hosting Stars from HARPS North and South

We determined atmospheric and evolutionary parameters, along with chemical abundances of C, O, S, Fe, and Ni for 290 solar-type exoplanet hosting stars using high-resolution HARPS-North and HARPS-South spectra, and radii for 373 exoplanets using literature transit depths. We find that stars hosting giant exoplanets (R$_{\text{pl}}>4\ \text{R}_{\oplus}$) show enhanced [X/H] abundances compared to small exoplanet hosts for all elements analyzed. When considering only exoplanets with $P_{\text{orb}}\leq30$ days, there is a statistically significant anti-correlation between host star [Fe/H] and $P_{\text{orb}}$. However, [Fe/H] does not continue to decline as the orbital period increases, but rather rises again for exoplanets with larger orbital periods. Stars hosting only small exoplanets or hosting at least one sub-Saturn show significant differences between the populations of hot and warm exoplanets for all elements. In contrast, stars hosting at least one Jupiter-sized planet show no abundance differences. The host star C/O ratios obtained vary from 0.17 to 0.95, with giant exoplanet hosts exhibiting the lowest median C/O ratios (0.43$^{+0.02}_{-0.03}$), while the 3 -- 4 R$_\oplus$ sub-Neptune hosts in our sample exhibit the highest median C/O ratios (0.55$^{+0.05}_{-0.01}$). Our sample has 199 exoplanets with estimated masses and we find correlations between host star [O/H] and [S/H] and $\log(M_{\text{pl}}/\text{M}_\oplus)$. When segregating the sample into hot and warm exoplanet hosts, these trends are only found for warm exoplanets. Dividing the sample between low- (91 exoplanets) and high-[$\alpha$/Fe] (20 exoplanets) stars, there are trends between host star [O/H], [S/H], [Fe/H] and [Ni/H] and $\log(M_{\text{pl}}/\text{M}_\oplus)$ only for the low-[$\alpha$/Fe] sample.

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Chemical radial gradients for the bulge-bar stellar populations from the APOGEE survey

The Milky Way bulge-bar is composed of multiple populations. Using chemical and kinematical planes, we segregate six populations in a bulge-bar sample observed by the APOGEE survey: two with bar-driven orbits, two with eccentric orbits, and two with low-eccentricity orbits, each composed of low- and high-[Mg/Fe] stars. Our sample spans $-2.0\lesssim$[Fe/H]$\lesssim+0.5$ and Galactocentric distance $R_{Gal}$ $<6$ kpc. We use chemical abundances from APOGEE DR17 for the elements Mg, Si, Ca, Al, K, Mn, Co, Ni, and Fe, and from the BAWLAS catalog for Ce and Nd. We find that the low- and high-[Mg/Fe] stars with low-eccentricity orbits, which exhibit chemical and orbital characteristics similar to those of the low- and high-[$α$/Fe] disks, display slightly negative and positive metallicity gradients, respectively. This result for the low-[Mg/Fe] low-eccentricity stars indicates a break in the global thin disk metallicity gradient. The high eccentricity populations with both low- and high-[Mg/Fe] show approximately flat metallicity gradients. In general, the [X/H] gradients of all elements for all populations follow Fe, except for the neutron-capture elements Ce and Nd. For all elements, the high-[Mg/Fe] bar population shows a much steeper positive [X/H] gradient than the nearly flat gradient for the low-[Mg/Fe] bar stars. The positive [X/H] gradients observed among our high-[Mg/Fe] bar stars probably reflect an age variation along the peanut structure. This interpretation agrees with the N-body simulations. Such steep positive gradients have also been reported in some high-redshift (z$\sim$4--10) galaxies.

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Stellar characterization, Magnesium Abundances and Chromospheric Activity Analysis of Stars with Confirmed Exoplanets from the K2 mission

We present a homogeneous spectroscopic analysis of confirmed K2 mission exoplanet-hosting stars, comprising 301 targets with high-resolution optical spectra from HIRES and TRES taken from ExoFOP. We derived effective temperatures, surface gravities, and iron and magnesium abundances in LTE by measuring the equivalent widths of Fe I, Fe II, and Mg I lines. Three estimates of stellar masses and radii were obtained via Stefan-Boltzmann and isochrone methods using the codes PARAM and isochrones. These were used to derive exoplanetary radii reaching internal precisions of 2.5%, 2.6%, and 6.6%, respectively, and the radius gap being consistently detected near 1.9 R$_{\oplus}$. We measured chromospheric activity from the Ca II H & K and H$α$ lines. Within the low-activity range ($\log R^{\prime}_{HK} < -4.75$), stellar activity appears to decrease with increasing planetary radius from super-Earths, sub-Neptunes, sub-Saturns, into the Jupiter regime. According to the [Mg/Fe] measurements, most of our K2 planet hosts belong to the Galactic thin disk, but our sample has a population from the thick disk (high-alpha sequence). Most stars show consistent chemo-dynamical behavior. We find that the [Mg/Fe] ratios are indistinguishable between systems containing Large or Small exoplanets, as well as Single- or Multi-exoplanetary systems. Both the [Fe/H] and [Mg/H] distributions reveal that stars hosting large planets are more iron- and magnesium-enhanced than those having only small planets, further confirming the link between stellar abundances and exoplanetary size, but no significant differences are found between the Single- versus Multi-exoplanetary systems.

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Abundances of P, S, and K in 58 bulge spheroid stars from APOGEE

We have previously studied several elements in 58 selected bulge spheroid stars, based on spectral lines in the H-band. We now derive the abundances of the less-studied elements phosphorus (P; Z=15), sulphur (S; Z=16), and potassium (K; Z=19). The abundances of P, S, and K in 58 bulge spheroid stars are compared both with the results of a previous analysis of the data from the Apache Point Observatory Galactic Evolution Experiment (APOGEE), and with a few available studies of these elements. We derive the individual abundances through spectral synthesis, using the stellar physical parameters available for our sample from the DR17 release of the APOGEE project. We provide recommendations for the best lines to be used for the studied elements among those in the H-band. We also compare the present results, together with literature data, with chemical-evolution models. Finally, the neutrino-process was taken into account for the suitable fit to the odd-Z elements P and K. We confirm that the H-band has useful lines for the derivation of the elements P, S, and K in moderately metal-poor stars. The abundances, plotted together with literature results from high-resolution spectroscopy, indicate that: moderately enhanced phosphorus stars are found, reminiscent results obtained for thick disk and halo stars of metallicity [Fe/H]~-1.0. Therefore, for the first time, we identify this effect to occur in the old stars from the bulge spheroid. Sulphur is an alpha-element and behaves as such. Potassium and sulphur both exhibit some star-to-star scatter, but fit within the expectations from chemical evolution models.

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Open cluster members in APOGEE DR17 I. Dynamics and star members

Context. Open clusters (OCs) are groups of stars formed from the same cloud of gas and cosmic dust. They play an important role in studies of star formation and evolution and our understanding of galaxy structure and dynamics. Aims. The main objective of this work is to identify stars that belong to OCs using astrometric data from Gaia EDR3 and spectroscopic data from APOGEE DR17. Furthermore, we investigate the metallicity gradients and orbital properties of the OCs in our sample. Methods. By applying the HDBSCAN clustering algorithm to these data, we identified observed stars in our galaxy with similar dynamics, chemical compositions, and ages. The orbits of the OCs were also calculated using the GravPot16 code. Results. We find 1,987 stars that tentatively belong to 49 OCs; 941 of these stars have probabilities above 80 \% of belonging to OCs. Our metallicity gradient presents a two-slope shape for two measures of different Galactic center distances -- the projected Galactocentric distance and the guiding center radius to the Galactic center -- as already reported in previous work. However, when we separate the OCs by age, we observe no significant difference in the metallicity gradient slope beyond a certain distance from the Galactic center. Our results show a shallower gradient for clusters younger than 2 Gyr than those older than 2 Gyr. All our OCs dynamically assemble the disk-like population very well, and they are in prograde orbits, which is typical for disk-like populations. Some OCs resonate with the Galactic bar at the Lagrange points L4 and L5.

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Abundances of iron-peak elements in 58 bulge spheroid stars from APOGEE

Stars presently identified in the bulge spheroid are probably very old, and their abundances can be interpreted as due to the fast chemical enrichment of the early Galactic bulge. The abundances of the iron-peak elements are important tracers of nucleosynthesis processes, in particular oxygen burning, silicon burning, the weak s-process, and alpha-rich freeze-out. Aims. The aim of this work is to derive the abundances of V, Cr, Mn, Co, Ni, and Cu in 58 bulge spheroid stars and to compare them with the results of a previous analysis of data from APOGEE. We selected the best lines for V, Cr, Mn, Co, Ni, and Cu located within the H-band of the spectrum, identifying the most suitable ones for abundance determination, and discarding severe blends. Using the stellar physical parameters available for our sample from the DR17 release of the APOGEE project, we derived the individual abundances through spectrum synthesis. We then complemented these measurements with similar results from different bulge field and globular cluster stars, in order to define the trends of the individual elements and compare with the results of chemical-evolution models. We verify that the H-band has useful lines for the derivation of the elements V, Cr, Mn, Co, Ni, and Cu in moderately metal-poor stars. The resulting abundances indicate that: V, Cr, and Ni vary in lockstep with Fe; Co tends to vary in lockstep with Fe, but could be showing a slight decrease with decreasing metallicity; and Mn and Cu decrease with decreasing metallicity. These behaviours are well reproduced by chemical-evolution models except for Cu, which appears to drop faster than the models predict for moderate metallicities. Finally, abundance indicators combined with kinematical and dynamical criteria appear to show that our 58 sample stars are likely to have originated in situ.

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A perspective on the Milky Way Bulge-Bar as seen from the neutron-capture elements Cerium and Neodymium with APOGEE

This study probes the chemical abundances of the neutron-capture elements cerium and neodymium in the inner Milky Way from an analysis of a sample of $\sim$2000 stars in the Galactic Bulge/bar spatially contained within $|X_{Gal}|<$5 kpc, $|Y_{Gal}|<$3.5 kpc, and $|Z_{Gal}|<$1 kpc, and spanning metallicities between $-$2.0$\lesssim$[Fe/H]$\lesssim$+0.5. We classify the sample stars into low- or high-[Mg/Fe] populations and find that, in general, values of [Ce/Fe] and [Nd/Fe] increase as the metallicity decreases for the low- and high-[Mg/Fe] populations. Ce abundances show a more complex variation across the metallicity range of our Bulge-bar sample when compared to Nd, with the r-process dominating the production of neutron-capture elements in the high-[Mg/Fe] population ([Ce/Nd]$<$0.0). We find a spatial chemical dependence of Ce and Nd abundances for our sample of Bulge-bar stars, with low- and high-[Mg/Fe] populations displaying a distinct abundance distribution. In the region close to the center of the MW, the low-[Mg/Fe] population is dominated by stars with low [Ce/Fe], [Ce/Mg], [Nd/Mg], [Nd/Fe], and [Ce/Nd] ratios. The low [Ce/Nd] ratio indicates a significant contribution in this central region from r-process yields for the low-[Mg/Fe] population. The chemical pattern of the most metal-poor stars in our sample suggests an early chemical enrichment of the Bulge dominated by yields from core-collapse supernovae and r-process astrophysical sites, such as magneto-rotational supernovae.

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Chemical abundances of the young inner-disk open cluster NGC 6705 observed by APOGEE: sodium-rich and not $α$-enhanced

Previous results in the literature have found the young inner-disk open cluster NGC 6705 to be mildly $α$-enhanced. We examined this possibility via an independent chemical abundance analysis for 11 red-giant members of NGC 6705. The analysis is based on near-infrared APOGEE spectra and relies on LTE calculations using spherical model atmospheres and radiative transfer. We find a mean cluster metallicity of $\rm [Fe/H] = +0.13 \pm 0.04$, indicating that NGC 6705 is metal-rich, as may be expected for a young inner-disk cluster. The mean $α$-element abundance relative to iron is $\rm \langle [α/Fe]\rangle =-0.03 \pm 0.05$, which is not at odds with expectations from general Galactic abundance trends. NGC 6705 also provides important probes for studying stellar mixing, given its turn-off mass of M$\sim$3.3 M$_\odot$. Its red giants have low $^{12}$C abundances ([$^{12}$C/Fe]=$-$0.16) and enhanced $^{14}$N abundances ([$^{14}$N/Fe]=+0.51), which are key signatures of the first dredge-up on the red giant branch. An additional signature of dredge-up was found in the Na abundances, which are enhanced by [Na/Fe]=+0.29, with a very small non-LTE correction. The $^{16}$O and Al abundances are found to be near-solar. All of the derived mixing-sensitive abundances are in agreement with stellar models of approximately 3.3 M$_{\odot}$ evolving along the red giant branch and onto the red clump. As found in young open clusters with similar metallicities, NGC 6705 exhibits a mild excess in the s-process element cerium, with $\rm [Ce/Fe] = +0.13\pm0.07$.

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Abundance analysis of APOGEE spectra for 58 metal-poor stars from the bulge spheroid

The central part of the Galaxy host a multitude of stellar populations, including the spheroidal bulge stars, stars moved to the bulge through secular evolution of the bar, inner halo, inner thick disk, inner thin disk, as well as debris from past accretion events. We identified a sample of 58 candidate stars belonging to the stellar population of the spheroidal bulge, and analyse their abundances. The present calculations of Mg, Ca, and Si lines are in agreement with the APOGEE-ASPCAP abundances, whereas abundances of C, N, O, and Ce are re-examined. We find normal $α$-element enhancements in oxygen, similar to magnesium, Si, and Ca abundances, which are typical of other bulge stars surveyed in the optical in Baade's Window. The enhancement of [O/Fe] in these stars suggests that they do not belong to accreted debris. No spread in N abundances is found, and none of the sample stars is N-rich, indicating that these stars are not second generation stars originated in globular clusters. Ce instead is enhanced in the sample stars, which points to an s-process origin such as due to enrichment from early generations of massive fast rotating stars, the so-called spinstars

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Exploring the s-process history in the Galactic disk: Cerium abundances and gradients in Open Clusters from the OCCAM/APOGEE sample

The APOGEE Open Cluster Chemical Abundances and Mapping (OCCAM) survey is used to probe the chemical evolution of the s-process element cerium in the Galactic disk. Cerium abundances were derived from measurements of Ce II lines in the APOGEE spectra using the Brussels Automatic Code for Characterizing High Accuracy Spectra (BACCHUS) in 218 stars belonging to 42 open clusters. Our results indicate that, in general, for Ages $<$ 4 Gyr, younger open clusters have higher [Ce/Fe] and [Ce/$α$-element] ratios than older clusters. In addition, metallicity segregates open clusters in the [Ce/X]-Age plane (where X can be H, Fe, and the $α$-elements O, Mg, Si, or Ca). These metallicity-dependant relations result in [Ce/Fe] and [Ce/$α$] ratios with age that are not universal clocks. Radial gradients of [Ce/H] and [Ce/Fe] ratios in open clusters, binned by age, were derived for the first time, with d[Ce/H]dR$_{GC}$ being negative, while d[Ce/Fe]/dR$_{GC}$ is positive. [Ce/H] and [Ce/Fe] gradients are approximately constant over time, with the [Ce/Fe] gradient becoming slightly steeper, changing by $\sim$+0.009 dex-kpc$^{-1}$-Gyr$^{-1}$. Both the [Ce/H] and [Ce/Fe] gradients are shifted to lower values of [Ce/H] and [Ce/Fe] for older open clusters. The chemical pattern of Ce in open clusters across the Galactic disk is discussed within the context of s-process yields from AGB stars, $\sim$Gyr time delays in Ce enrichment of the interstellar medium, and the strong dependence of Ce nucleosynthesis on the metallicity of its AGB stellar sources.

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On producers of cosmic organic compounds: exploring the boron abundance in lithium-rich K giant stars

The element boron belongs, together with lithium and beryllium, to a known trio of important elements for the study of evolutionary processes in low mass stars. Because B is the least fragile of this trio to be destroyed in the stellar interiors, it can be used to test if the Li enrichment is of planetary origin. Here, for the first time, boron lines are examined in the UV for four giants with different degrees of large Li enrichment by means of observations with the Hubble telescope. Two main results are found in our study. One is that to first approximation B abundances appear not to be in excess, invalidating the planet engulfment mechanism. The second one is that the two stars with very large Li abundances present emission lines indicating that quite strong active chromospheres are acting in these very Li-rich giants. These new results obtained from the UV complement our recent studies in the mid-IR (de la Reza et al. 2015) where strong emission-line features of organic material were found in the spectra of some Li-rich stars.

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Lithium in red giant stars: Constraining non-standard mixing with large surveys in the Gaia era

Lithium is extensively known to be a good tracer of non-standard mixing processes occurring in stellar interiors. We present the results of a new large Lithium survey in red giant stars and combine it with surveys from the literature to probe the impact of rotation-induced mixing and thermohaline double-diffusive instability along stellar evolution. We determined the surface Li abundance for a sample of 829 giant stars with accurate Gaia parallaxes for a large sub-sample (810 stars) complemented with accurate Hipparcos parallaxes (19 stars). The spectra of our sample of northern and southern giant stars were obtained in three ground-based observatories (OHP, ESO-La Silla, Mc Donald). We determined the atmospheric parameters (Teff, log(g), [Fe/H]), and the Li abundance. We used Gaia parallaxes and photometry to determine the luminosity of our objects and we estimated the mass and evolution status of each sample star with a maximum-likelihood technique using stellar evolution models computed with the STAREVOL code. We compared the observed Li behaviour with predictions from stellar models, including rotation and thermohaline mixing. The same approach was used for stars from selected Li surveys from the literature. Rotation-induced mixing accounts nicely for the lithium behaviour in stars warmer than about 4200K, independently of the mass domain. For stars with masses lower than 2Msun thermohaline mixing leads to further Li depletion below the Teff of the RGB bump (about 4000K), and on the early AGB, as observed. Depending on the definition we adopt, we find between 0.8 and 2.2% of Li-rich giants in our new sample. Gaia puts a new spin on the understanding of mixing processes in stars, and our study confirms the importance of rotation-induced processes and of thermohaline mixing. However asteroseismology is required to definitively pinpoint the actual evolution status of Li-rich giants.

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A comprehensive comparison between APOGEE and LAMOST: Radial Velocities and Atmospheric Stellar Parameters

We undertake a critical and comprehensive comparison of the radial velocities and the main stellar atmospheric parameters for stars in common between the latest data releases from the APOGEE and the LAMOST surveys. There is a total of 42,420 dwarfs/giants stars in common between the APOGEE DR14 - LAMOST DR3 stellar catalogs. A comparison between the RVs shows an offset of 4.54 $\pm$ 0.03 km/s, with a dispersion of 5.8 km/s, in the sense that APOGEE RVs are larger. We observe a small offset in the Teff of about 13 K, with a scatter of 155 K. Small offset in [Fe/H] of about 0.06 dex together with a scatter of 0.13 dex is also observed. We notice that the largest offset between the surveys occurs in the surface gravities. Using only surface gravities in calibrated red giants from APOGEE DR14, where there are 24,074 stars in common, a deviation of 0.14 dex is found with substantial scatter. There are 17,482 red giant stars in common between APOGEE DR14 and those in LAMOST tied to APOGEE DR12 via the Cannon. There is generally good agreement between the two data-sets. However, we find dependencies of the differences of the stellar parameters on effective temperature. For metal-rich stars, a different trend for the [Fe/H] discrepancies is found. Surprisingly, we see no correlation between the internal APOGEE DR14 - DR12 differences in Teff and those in DR14 - LAMOST tied to DR12, where a correlation should be expected since LAMOST has been calibrated to APOGEE DR12. We also find no correlation between the [Fe/H] discrepancies, suggesting that LAMOST/Cannon is not well coupled to the APOGEE DR12 stellar parameters scale. A [Fe/H] dependence between the stellar parameters in APOGEE DR12 and those in DR14 is reported. We find a weak correlation in the differences between APOGEE DR14 - DR12 and LAMOST on DR12 surface gravity for stars hotter than 4800 K and in the log g range between 2.0 and 2.8.

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A chemical and kinematical analysis of the intermediate-age open cluster IC 166 from APOGEE and Gaia DR2

IC 166 is an intermediate-age open cluster ($\sim 1$ Gyr) which lies in the transition zone of the metallicity gradient in the outer disc. Its location, combined with our very limited knowledge of its salient features, make it an interesting object of study. We present the first high-resolution spectroscopic and precise kinematical analysis of IC 166, which lies in the outer disc with $R_{GC} \sim 12.7$ kpc. High resolution \textit{H}-band spectra were analyzed using observations from the SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. We made use of the Brussels Automatic Stellar Parameter (BACCHUS) code to provide chemical abundances based on a line-by-line approach for up to eight chemical elements (Mg, Si, Ca, Ti, Al, K, Mn and Fe). The $α-$element (Mg, Si, Ca and whenever available Ti) abundances, and their trends with Fe abundances have been analysed for a total of 13 high-likelihood cluster members. No significant abundance scatter was found in any of the chemical species studied. Combining the positional, heliocentric distance, and kinematic information we derive, for the first time, the probable orbit of IC 166 within a Galactic model including a rotating boxy bar, and found that it is likely that IC 166 formed in the Galactic disc, supporting its nature as an unremarkable Galactic open cluster with an orbit bound to the Galactic plane.

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Target Selection for the SDSS-IV APOGEE-2 Survey

APOGEE-2 is a high-resolution, near-infrared spectroscopic survey observing roughly 300,000 stars across the entire sky. It is the successor to APOGEE and is part of the Sloan Digital Sky Survey IV (SDSS-IV). APOGEE-2 is expanding upon APOGEE's goals of addressing critical questions of stellar astrophysics, stellar populations, and Galactic chemodynamical evolution using (1) an enhanced set of target types and (2) a second spectrograph at Las Campanas Observatory in Chile. APOGEE-2 is targeting red giant branch (RGB) and red clump (RC) stars, RR Lyrae, low-mass dwarf stars, young stellar objects, and numerous other Milky Way and Local Group sources across the entire sky from both hemispheres. In this paper, we describe the APOGEE-2 observational design, target selection catalogs and algorithms, and the targeting-related documentation included in the SDSS data releases.

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New H-band Stellar Spectral Libraries for the SDSS-III/APOGEE survey

The Sloan Digital Sky Survey--III (SDSS--III) Apache Point Observatory Galactic Evolution Experiment (APOGEE) has obtained high resolution (R $\sim$ 22,500), high signal-to-noise ratio ($>$ 100) spectra in the H$-$band ($\sim$1.5$-$1.7 $μ$m) for about 146,000 stars in the Milky Way galaxy. We have computed spectral libraries with effective temperature ($T\rm{_{eff}}$) ranging from 3500 to 8000 K for the automated chemical analy\-sis of the survey data. The libraries, used to derive stellar parameters and abundances from the APOGEE spectra in the SDSS--III data release 12 (DR12), are based on ATLAS9 model atmospheres and the ASS$ε$T spectral synthesis code. We present a second set of libraries based on MARCS model atmospheres and the spectral synthesis code Turbospectrum. The ATLAS9/ASS$ε$T ($T\rm{_{eff}}$ = 3500$-$8000 K) and MARCS/Turbospectrum ($T\rm{_{eff}}$ = 3500$-$5500 K) grids cover a wide range of metallicity ($-$2.5 $\leq$ [M/H] $\leq$ $+$0.5 dex), surface gravity (0 $\leq$ log $g$ $\leq$ 5 dex), microturbulence (0.5 $\leq$ $ξ$ $\leq$ 8 km~s$^{-1}$), carbon ($-$1 $\leq$ [C/M] $\leq$ $+$1 dex), nitrogen ($-$1 $\leq$ [N/M] $\leq$ $+$1 dex), and $α$-element ($-$1 $\leq$ [$α$/M] $\leq$ $+$1 dex) variations, having thus seven dimensions. We compare the ATLAS9/ASS$ε$T and MARCS/Turbospectrum libraries and apply both of them to the analysis of the observed H$-$band spectra of the Sun and the K2 giant Arcturus, as well as to a selected sample of well-known giant stars observed at very high-resolution. The new APOGEE libraries are publicly available and can be employed for chemical studies in the H$-$band using other high-resolution spectrographs.

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The Chemical Evolution of Fluorine in the Bulge - High-resolution K-band spectra of giants in three fields

Possible main formation sites of F in the Universe include AGB stars, the ν-process in Type II SNe, and/or W-R stars. The importance of the W-R stars has theoretically been questioned and they are probably not needed in the modelling of the chemical evolution of F in the solar neighborhood. It has, however, been suggested that W-R stars are indeed needed to explain the chemical evolution of F in the Bulge. The molecular spectral data of the often used HF-molecule has not been presented in a complete and consistent way and has recently been debated in the literature. In this article we determine the [F/O] vs. [O/H] trend in the Bulge to investigate the possible contribution from W-R stars. Additionally, we present here a HF line list for the K- and L-bands (including the often used 23358.33 Å line) and an accompanying partition function. The F abundances were determined using spectral fitting from hi-res NIR spectra of eight K giants recorded by the spectrograph CRIRES. We have also re-analyzed five previously published Bulge giants using our new HF molecular data. We find that the F-O abundance in the Bulge probably cannot be explained with chemical evolution models including only AGB-stars and the ν-process in SNe Type II, i.e. a significant amount of F production in W-R stars is likely needed to explain the F abundance in the Bulge. Concerning the HF line list, we find that a possible reason for the inconsistencies in the literature, with two different excitation energies being used, is two different definitions of the zero-point energy for the HF molecule and therefore also two accompanying different dissociation energies. Both line lists are correct, as long as the corresponding consistent partition function is used in the spectral synthesis. However, we suspect this has not been the case in several earlier works leading to F abundances 0.3 dex too high.

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Chemodynamics of the Milky Way. I. The first year of APOGEE data

We investigate the chemo-kinematic properties of the Milky Way disc by exploring the first year of data from the Apache Point Observatory Galactic Evolution Experiment (APOGEE), and compare our results to smaller optical high-resolution samples in the literature, as well as results from lower resolution surveys such as GCS, SEGUE and RAVE. We start by selecting a high-quality sample in terms of chemistry ($\sim$ 20.000 stars) and, after computing distances and orbital parameters for this sample, we employ a number of useful subsets to formulate constraints on Galactic chemical and chemodynamical evolution processes in the Solar neighbourhood and beyond (e.g., metallicity distributions -- MDFs, [$α$/Fe] vs. [Fe/H] diagrams, and abundance gradients). Our red giant sample spans distances as large as 10 kpc from the Sun. We find remarkable agreement between the recently published local (d $<$ 100 pc) high-resolution high-S/N HARPS sample and our local HQ sample (d $<$ 1 kpc). The local MDF peaks slightly below solar metallicity, and exhibits an extended tail towards [Fe/H] $= -$1, whereas a sharper cut-off is seen at larger metallicities. The APOGEE data also confirm the existence of a gap in the [$α$/Fe] vs. [Fe/H] abundance diagram. When expanding our sample to cover three different Galactocentric distance bins, we find the high-[$α$/Fe] stars to be rare towards the outer zones, as previously suggested in the literature. For the gradients in [Fe/H] and [$α$/Fe], measured over a range of 6 $ < $ R $ <$ 11 kpc in Galactocentric distance, we find a good agreement with the gradients traced by the GCS and RAVE dwarf samples. For stars with 1.5 $<$ z $<$ 3 kpc, we find a positive metallicity gradient and a negative gradient in [$α$/Fe].

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