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V. Vakula

Publications and source records attributed to V. Vakula.

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Universal method of selective detection of a wide range of pollutants in liquids using conductance quantization

The primary objective of research in modern sensor technologies is to develop innovative detection methods for the rapid analysis of complex molecular systems. The present work demonstrates that the quantum mechanism of selective detection, based on conductance quantization, can be effectively employed to create a universal method for detecting a broad spectrum of agents in liquid media, including heavy metals and organic solvents. The efficacy of this approach is illustrated through the use of quantum point-contact sensors, which utilize dendritic Yanson point contacts undergoing quantum transformations during the cyclic switchover effect. These sensors have proven capable of detecting copper, zinc, and lead ions in liquid media across a wide range of concentrations, including trace levels as low as a few parts per billion (ppb). Furthermore, they can identify organic solvents, as demonstrated with acetic acid. The use of innovative quantum detection principles paves the way for the development of a comprehensive array of next-generation devices, offering promising solutions for advanced environmental monitoring applications.

physics.ins-det

Abnormally large changes in anharmonicity of intramolecular vibrations in free clusters of nitrogen

Cathodoluminescence VUV spectra of free pure nitrogen clusters produced by condensation of gas mixtures in supersonic jets expanding into vacuum were studied. The clusters were of icosahedral structure, as evidenced by our electron diffraction measurements, i.e., quasicrystals, and contained about 1000 atoms. The cluster temperature was about 40 K. The luminescence spectra measured in the range of 45,000-75,000 cm^-1 clearly showed three vibronic w -> X series of transitions from the excited 'w' to the ground 'X' state, which are intrinsic to nitrogen molecules. All the transitions revealed a strong dependence of the matrix shift of their peak positions on vibration quantum number, while for bulk samples of N2 the matrix shift is known to remain unchanged. Our analysis showed that in clusters the vibrational anharmonicity parameter changes drastically for both the upper and lower states, while the change in the vibrational frequencies is much less prominent. The results obtained provide information about an abnormally strong influence of cluster environment on the nonlinear contribution to the vibrations of nitrogen molecules.

physics.atm-clus