arXiv subjects

V. Williams

Publications and source records attributed to V. Williams.

2 recordsLinked to original sources

arXiv2021

Low Temperature Domain Wall Freezing and Non-Equilibrium Dynamics in the Transverse-Field Ising Model Material CoNb$_2$O$_6$

CoNb$_2$O$_6$ is a rare realization of the transverse field Ising model (TFIM), making it a useful tool for studying both equilibrium and non-equilibrium many-body quantum physics. Despite a large body of work dedicated to characterizing this material, details of the ordered states in the presence of relatively weak transverse fields have not been discussed in detail. Here, we present a detailed study of CoNb$_2$O$_6$ via ac susceptibility measurements in order to further characterize its low temperature behavior in the presence of a transverse field. Specifically, we call attention to an unconventional freezing transition in zero-field below T$_F$ = 1.2~K, occurring \emph{within} the well-known commensurate antiferromagnetic (CAFM) state that onsets at $T_{N2}$ = 1.9~K. We performed a series of transverse-field quenches into this frozen state, which resulted in a slowly relaxing susceptibility, $\chi^{\prime}(t)$, that followed a logarithmic decay within the time range measured. We discuss the frozen state in the context of the freezing of previously discussed "free" chains arising from domain walls between the four degenerate sublattices of the CAFM state. We also attempted to observe Kibble-Zurek scaling by quenching the transverse field into the frozen state at different rates. This produced a null result; the behavior can be fully explained by coarsening of domains over the timescale of the quenches. The absence of a clear Kibble-Zurek scaling is itself surprising, given the proposed ubiquity of the phenomenon for general second order phase transitions.

cond-mat.str-el↗

arXiv2020

Hot Hydride Superconductivity above 550 K

The search for room temperature superconductivity has accelerated dramatically in the last few years driven largely by theoretical predictions that first indicated alloying dense hydrogen with other elements could produce conventional phonon-mediated superconductivity at very high temperatures and at accessible pressures, and more recently, with the success of structure search methods that have identified specific candidates and pressure-temperature (P-T) conditions for synthesis. These theoretical advances have prompted improvements in experimental techniques to test these predictions. As a result, experimental studies of simple binary hydrides under pressure have yielded high critical superconducting transition temperatures (Tc), of 260 K in LaH10, close to the commonly accepted threshold for room temperature, 293 K, at pressures near 180 GPa. We successfully synthesized a metallic La-based superhydride from La metal and ammonia borane, NH3BH3, and find a multi-step transition with a Tc of 294 K for the highest onset. When subjected to subsequent thermal excursions to higher temperatures that promoted a chemical reaction to what we believe is a ternary or higher order system, the transition temperature was driven to higher temperatures. Although the reaction does not appear to be complete, the onset temperature was pushed from 294 K to 556 K before the experiments had to be terminated. The results provide evidence for hot superconductivity well above room temperature, in line with recent predictions for a higher order hydride under pressure.

cond-mat.supr-con↗