Searcharxiv⌕ Search

arXiv subjects

Vadim A. Markel

Publications and source records attributed to Vadim A. Markel.

35 records · Page 2Linked to original sources
arXiv2008

Correct Definition of the Poynting Vector in Electrically and Magnetically Polarizable Medium Reveals that Negative Refraction is Impossible

I compute from first principles the local heating rate $q$ (the amount of electromagnetic energy converted to heat per unit time per unit volume) for electromagnetic waves propagating in magnetically and electrically polarizable media. I find that, in magnetic media, this rate has two separate contributions, $q^{(V)}$ and $q^{(S)}$, the first coming from the volume of the medium and the second from its surface. I argue that the second law of thermodynamics requires that the volume contribution be positive and that this requirement, in turn, prohibits negative refraction. This result holds for active or passive media and in the presence of anisotropy and spatial dispersion.

physics.optics↗
arXiv2006

Propagation of Surface Plasmons in Ordered and Disordered Chains of Metal Nanospheres

We report a numerical investigation of surface plasmon (SP) propagation in ordered and disordered linear chains of metal nanospheres. In our simulations, SPs are excited at one end of a chain by a near-field tip. We then find numerically the SP amplitude as a function of propagation distance. Two types of SPs are discovered. The first SP, which we call the ordinary or quasistatic, is mediated by short-range, near-field electromagnetic interaction in the chain. This excitation is strongly affected by Ohmic losses in the metal and by disorder in the chain. These two effects result in spatial decay of the quasistatic SP by means of absorptive and radiative losses, respectively. The second SP is mediated by longer range, far-field interaction of nanospheres. We refer to this SP as the extraordinary or non-quasistatic. The non-quasistatic SP can not be effectively excited by a near-field probe due to the small integral weight of the associated spectral line. Because of that, at small propagation distances, this SP is dominated by the quasistatic SP. However, the non-quasistatic SP is affected by Ohmic and radiative losses to a much smaller extent than the quasistatic one. Because of that, the non-quasistatic SP becomes dominant sufficiently far from the exciting tip and can propagate with little further losses of energy to remarkable distances. The unique physical properties of the non-quasistatic SP can be utilized in all-optical integrated photonic systems.

physics.optics↗
arXiv2006

Spectroscopic studies of fractal aggregates of silver nanospheres undergoing local restructuring

We present an experimental spectroscopic study of large random colloidal aggregates of silver nanoparticles undergoing local restructuring. We argue that such well-known phenomena as strong fluctuation of local electromagnetic fields, appearance of "hot spots" and enhancement of nonlinear optical responses depend on the local structure on the scales of several nanosphere diameters, rather that the large-scale fractal geometry of the sample.

physics.optics↗
arXiv2006

Comment on "Optical Response of Strongly Coupled Nanopraticles in Dimer Arrays" (Phys. Rev. B 71(4), 045404, 2005)

I have re-calculated the extinction spectra of aggregates of two silver nanospheres shown in Figs.~2 and 3 of Ref.~8. I have used the approximate method of images according to Ref.~8 and an exact numerical technique. I have found that the three sets of data (those I have obtained by the method of images, the numerical results, and the results published in Ref.~8) do not coincide. In this Comment, I discuss the reasons for these discrepancies and the general applicability of the method of images to the quasi-static electromagnetic problem of two interacting nanospheres.

physics.optics↗
arXiv2005

Coherently tunable third-order nonlinearity in a nanojunction

A possibility of tuning the phase of the third-order Kerr-type nonlinear susceptibility in a system consisting of two interacting metal nanospheres and a nonlinearly polarizable molecule is investigated theoretically and numerically. It is shown that by varying the relative inter-sphere separation, it is possible to tune the phase of the effective nonlinear susceptibility χ^{(3)}(ω;ω,ω,-ω)$ in the whole range from 0 to $2π$.

physics.optics↗
arXiv2005

Local anisotropy and giant enhancement of local electromagnetic fields in fractal aggregates of metal nanoparticles

We have shown within the quasistatic approximation that the giant fluctuations of local electromagnetic field in random fractal aggregates of silver nanospheres are strongly correlated with a local anisotropy factor S which is defined in this paper. The latter is a purely geometrical parameter which characterizes the deviation of local environment of a given nanosphere in an aggregate from spherical symmetry. Therefore, it is possible to predict the sites with anomalously large local fields in an aggregate without explicitly solving the electromagnetic problem. We have also demonstrated that the average (over nanospheres) value of S does not depend noticeably on the fractal dimension D, except when D approaches the trivial limit D=3. In this case, as one can expect, the average local environment becomes spherically symmetrical and S approaches zero. This corresponds to the well-known fact that in trivial aggregates fluctuations of local electromagnetic fields are much weaker than in fractal aggregates. Thus, we find that, within the quasistatics, the large-scale geometry does not have a significant impact on local electromagnetic responses in nanoaggregates in a wide range of fractal dimensions. However, this prediction is expected to be not correct in aggregates which are sufficiently large for the intermediate- and radiation-zone interaction of individual nanospheres to become important.

physics.optics↗
arXiv2005

Superresolution and Corrections to the Diffusion Approximation in Optical Tomography

We demonstrate that the spatial resolution of images in optical tomography is not limited to the fundamental length scale of one transport mean free path. This result is facilitated by the introduction of novel corrections to the standard integral equations of scattering theory within the diffusion approximation to the radiative transport equation.

physics.optics↗
arXiv2005

Multiple Projection Optical Diffusion Tomography with Plane Wave Illumination

We describe a new data collection scheme for optical diffusion tomography in which plane wave illumination is combined with multiple projections in the slab imaging geometry. Multiple projection measurements are performed by rotating the slab around the sample. The advantage of the proposed method is that the measured data can be much more easily fitted into the dynamic range of most commonly used detectors. At the same time, multiple projections improve image quality by mutually interchanging the depth and transverse directions, and the scanned (detection) and integrated (illumination) surfaces. Inversion methods are derived for image reconstructions with extremely large data sets. Numerical simulations are performed for fixed and rotated slabs.

physics.med-ph↗
arXiv2005

Comment on "Silver nanoparticle array structures that produce remarkably narrow plasmon lineshapes" [J. Chem. Phys. 120, 10871 (2004)]

In this Comment I discuss two incorrect statements which were made in the paper "Silver nanoparticle array structures that produce remarkably narrow plasmon line shapes" [J. Chem. Phys.120, 10871 (2004)] by Zou, Janel, and Schatz (ZJS). The first statement is about the use of quasistatic approximation in my earlier work on the similar subject, and the second statement concerns the possibility of exact cancellation of radiative relaxation in periodical chains of nanoparticles. The relationship between the quasistatic approximation, the dipole approximation, and the approximation due to Doyle [Phys. Rev. B39, 9852 (1989)] which was used by ZJS is clarified. It is shown that the exact cancellation of radiative relaxation cannot take place in the particular geometry considered by ZJS.

physics.chem-ph↗
arXiv2005

Divergence of Dipole Sums and the Nature of Non-Lorentzian Exponentially Narrow Resonances in One-Dimensional Periodic Arrays of Nanospheres

Origin and properties of non-Lorentzian spectral lines in linear chains of nanospheres are discussed. The lines are shown to be super-exponentially narrow with the characteristic width proportional to exp[-C(h/a)^3] where C is a numerical constant, h the spacing between the nanospheres in the chain and a the sphere radius. The fine structure of these spectral lines is also investigated.

physics.optics↗
arXiv2005

Radiative Transport Equation in Rotated Reference Frames

A novel method for solving the linear radiative transport equation (RTE) in a three-dimensional homogeneous medium is proposed and illustrated with numerical examples. The method can be used with an arbitrary phase function A(s,s') with the constraint that it depends only on the angle between the angular variables s and s'. This corresponds to spherically symmetric (on average) random medium constituents. Boundary conditions are considered in the slab and half-space geometries. The approach developed in this paper is spectral. It allows for the expansion of the solution to the RTE in terms of analytical functions of angular and spatial variables to relatively high orders. The coefficients of this expansion must be computed numerically. However, the computational complexity of this task is much smaller than in the standard method of spherical harmonics. The solutions obtained are especially convenient for solving inverse problems associated with radiative transfer.

math-ph↗
arXiv2001

Theory of Electron-Phonon Dynamics in Insulating Nanoparticles

We discuss the rich vibrational dynamics of nanometer-scale semiconducting and insulating crystals as probed by localized electronic impurity states, with an emphasis on nanoparticles that are only weakly coupled to their environment. Two principal regimes of electron-phonon dynamics are distinguished, and a brief survey of vibrational-mode broadening mechanisms is presented. Recent work on the effects of mechanical interaction with the environment is discussed.

cond-mat.mes-hall↗