Large Nernst effect in chemically derived multilayer graphene at millitesla magnetic fields
Simple synthesis of graphitic compounds, their high conductivity, and integrability with other materials motivate the effort toward graphite-based thermoelectric generators. At the same time, semimetallic nature of graphite and graphene results in nearly-zero thermopower due to electron-hole compensation. Here, we observe large transverse thermopower in chemically derived multilayer graphene films with strong fluctuations of thickness and carrier density at low magnetic fields $B$. Using the scanning laser-induced heating of macroscopic film, we find that transverse (Nernst) thermoelectric voltage becomes comparable to the longitudinal thermoelectric voltage at the metal-doped graphene contact at $B^*\approx4$ mT and ambient conditions. Estimates of transverse thermopower $S_{xy}$ based on the known laser-induced temperature show that it is as large as $\sim 10$ $\mu$V/K at $B^*$, and raises in a sub-linear fashion to 250 $\mu$V/K at $B\approx315$ mT, the maximum field we reach with centimeter-sized permanent magnet. Extra increase in thermoelectric signal is achieved upon voltage measurement at Hall probes when the dc field lines are co-directional with local Nernst current. Our results show the promise of large-scale multilayer graphene for thermoelectricity generation.