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Valla Fatemi

Publications and source records attributed to Valla Fatemi.

At least 19 recordsLinked to original sources

Fabrication-free assessment of microwave losses in germanium-based dielectrics and superconductors

We present a flip-chip-based sensing scheme to measure effective microwave losses associated with target materials for quantum technologies, without requiring any device fabrication on the material under test. Using this approach, we quantify the microwave losses of a strain-engineered Ge/SiGe quantum well heterostructure and investigate losses arising from its Ge substrate and intermediate layers. The quality factors of the fabricated microwave resonators agree with the losses of dielectric materials independently extracted from flip-chip sensing measurements. We further study the superconductor platinum silicon germanide (PtSiGe) prepared by thermal reaction with a deposited Pt film, finding high microwave losses that limit the suitability of the films studied here as the sole superconductor for high-quality resonator applications. By coating Pt with Nb prior to the reaction, we observe a substantial reduction in microwave loss and a nearly three-fold enhancement of the transport critical temperature. The temperature dependence of the microwave loss is consistent with gap inhomogeneity in both superconducting films. These results identify constraints on material choices, provide design guidance for microwave circuits on planar Ge heterostructures, and demonstrate a fast-turnaround testing method for new materials for superconducting quantum circuits.

quant-ph

Exponential quantum advantage for learning signals with a single qubit

Quantum technology has the potential to transform scientific discovery, but quantum advantages often require processing capabilities well beyond the reach of experimental platforms. We show that coupling a single controllable qubit to an otherwise conventional sensor can exponentially reduce the number of measurements required to learn classical signals. These rigorous quantum advantages apply to fundamental sensing tasks, including learning Fourier coefficients, extracting temporal correlations from time-varying signals, and estimating transformations of physical observables. Using a superconducting cavity--qubit architecture, we experimentally demonstrate $10^7$-fold reductions in the number of measurements required for Fourier-amplitude and time-varying signal learning. Our $\textit{quantum feature sensing}$ algorithms further enable orders-of-magnitude improvements in simulations of weak-signal dark matter detection and wireless communication applications. These quantum advantages are derived from Quantum Phase-Space Inference (Q$\Psi$), a unifying theory of quantum-enhanced experiments that simultaneously converts a set of experimental objectives and constraints into tight lower bounds and optimal quantum-enhanced learning algorithms while producing a certificate of quantum advantage. Q$\Psi$ extends beyond the regimes captured by quantum Fisher information and provides a framework for systematically identifying rigorous quantum advantages in practical experimental tasks. Together, our results establish that near-term quantum technology can exponentially enhance our ability to learn from classical signals.

quant-ph

High-Q superconducting microwave resonators using MBE titanium nitride

Using molecular beam epitaxy, we have realized thin films of titanium nitride (TiN) on c-plane sapphire that exhibit the lowest observed full-width at half maximum X-ray rocking curve width of 18 arcsec. Though the (111) oriented TiN exhibits an abrupt and crystalline interface with sapphire, for the first time we observe sub-surface defects in the sapphire substrate, which nucleate structural defects in the epitaxial TiN layer. Using quarter-wavelength coplanar waveguide (CPW) resonators in a 3 \textmu m/6 \textmu m/3 \textmu m gap/strip/gap lines in a hanger geometry, we find the internal quality factor of the TiN resonators to be $>10^{6}$ in the single-photon $\langle n \rangle \sim 1$ limit at 5.8 GHz and 10 mK, rising to $>20 \times 10^{6}$ at $\langle n \rangle \sim 10^{6}$. The results are of high interest for applications of superconducting TiN in several areas, and provide a path towards epitaxial Josephson junctions with crystalline barriers in the future for high coherence qubits.

cond-mat.supr-con

Bosonic Cyclic Codes: Trading Stabilizers for Gaussian Non-Clifford Phase Gates

Bosonic codes offer hardware-efficient approaches to quantum error correction, with the best encodings offering effective protection of idle quantum information against loss and dephasing - particularly rotation-symmetric codes, which include the cat and binomial code families. However, rotation-symmetric codes are only naturally endowed with a single logical Pauli gate, while other logical gates require the use of non-linear operations, obstructing the utility of these codes for realizing quantum algorithms. Here, we balance error protection with controllability by introducing bosonic cyclic codes: a generalization of rotation-symmetric codes that enable the measured tradeoff of error protection properties for fault-tolerant logical phase gates. Through our general construction, we find that sacrificing the detectability of a single photon loss relative to a rotation-symmetric code can yield a number of logical phase gates commensurate with the original rotation symmetry order of the code, all achievable via passive Gaussian rotations. Giving the corresponding generalizations of cat and binomial codes - which we dub cyclic cat and Vandermonde codes, respectively - we further find that many of the desirable properties of these codes transfer to the bosonic cyclic code setting. We go on to discuss the larger $SU(2)$ symmetry and rotation gates of the codes, which yield additional stabilizers and logical Pauli gates, as well as new non-Clifford gates for the smallest `kitten' binomial code, and provide a new error detection protocol. Finally, we introduce a general paradigm for converting higher-order stabilizers to logical gates, as in our generalization of rotation-symmetric codes, and apply it to several multimode bosonic codes.

quant-ph

Strain engineering of Andreev spin qubits in Germanium

Planar germanium heterostructures are promising hosts for hybrid quantum devices due to their compatibility with superconductors, low material disorder, and relaxed fabrication constraints. Also, the potentially low density of nuclear spins and strong spin-orbit interaction make germanium attractive for coherent spin physics. However, recent microwave spectroscopy experiments were unable to resolve a spin-splitting of bound states in germanium Josephson junctions, the prerequisite for defining and controlling Andreev spin qubits. Here, we argue that compressive strain is the key mechanism suppressing spin splitting in current devices. Furthermore, we propose unstrained and tensile-strained heterostructures, fully compatible with state-of-the-art growth technology, that significantly enhance the relevant spin-orbit effect. By numerically simulating ballistic Josephson junctions, we predict spin splittings comfortably in the GHz range, more than 2 orders of magnitude larger than compressively strained cases, and all-electric quantum gates in a hundred nanoseconds. Our results establish strain engineering as a key design principle for realizing Andreev spin qubits in germanium-based devices.

cond-mat.mes-hall

Quantum computational displacement sensing

Quantum computational sensing (QCS) combines quantum sensing with quantum computing to extract task-relevant information from the physical world. QCS can in principle achieve an accuracy advantage for specific tasks versus the alternative of raw-signal estimation using conventional quantum sensing followed by task-specific classical postprocessing. Here we report the experimental demonstration of quantum computational displacement sensing (QCDS) with a superconducting circuit comprising a qubit coupled to an oscillator. We consider binary classification sensing tasks, where the goal is to predict the class label of a single complex-valued displacement sensed once by the oscillator. Rather than estimating the displacement, our computational-sensing protocol -- using parameterized quantum circuits before and after sensing -- attempts to determine the binary class label using quantum processing and map it onto the ground or excited state of the qubit. A single measurement of the qubit directly outputs the prediction. We implemented circuits with up to 24 entangling gates and 38 free parameters, which were trained in silico. We show that increasing the circuit depth systematically improves expressivity and classification accuracy. We experimentally obtained an accuracy advantage over a suite of protocols that first use conventional quantum sensing to estimate the displacement before using classical postprocessing to perform prediction. For certain tasks, our protocol achieves a 15-percentage-points higher classification accuracy than most conventional approaches considered. Our results establish the feasibility of quantum computational sensing with noisy superconducting hardware and illustrate how integrating quantum computation with quantum sensing can enhance performance when the goal is to estimate a property or function of a signal rather than to estimate the signal.

quant-ph

Resist-free shadow deposition using silicon trenches for Josephson junctions in superconducting qubits

Superconducting qubit fabrication innovations continue to be explored to achieve higher performance. Despite improvements to base layer fabrication and processing, resist-based Josephson junction (JJ) schemes have largely remained unchanged. The polymer mask during deposition causes chemical contamination and limits in situ and ex situ surface preparation, junction materials, and scalability. Here, we demonstrate a resist-free approach to junction fabrication based on etched silicon trenches that is CMOS compatible and easily integrated into existing innovations in qubit base layer fabrication and chemical processing. We fabricate Al-AlOx-Al JJs and qubits using this method, measuring median energy relaxation times up to 184 microseconds. We find minimal contamination at the substrate-metal interface and fluctuations of energy relaxation on a 35 hour timescale that are narrow and normally distributed. The method widens the process window for substrate preparation and new materials platforms.

quant-ph

Error semitransparent universal control of a bosonic logical qubit

Bosonic codes offer hardware-efficient approaches to logical qubit construction and hosted the first demonstration of beyond-break even logical quantum memory. However, such accomplishments were done for idling information, and realization of fault-tolerant logical operations remains a critical bottleneck for universal quantum computation in scaled systems. Error-transparent (ET) gates offer an avenue to resolve this issue, but experimental demonstrations have been limited to phase gates. Here, we introduce a framework based on dynamic encoding subspaces that enables simple linear drives to accomplish universal gates that are error semi-transparent (EsT) to oscillator photon loss. With an EsT logical gate set of {X, H, T}, we observe a five-fold reduction in infidelity conditioned on photon loss, demonstrate extended active-manipulation lifetimes with quantum error correction, and construct a composite EsT non-Clifford operation using a sequence of eight gates from the set. Our approach is compatible with methods for detectable ancilla errors, offering an approach to error-mitigated universal control of bosonic logical qubits with the standard quantum control toolkit.

quant-ph

Fabrication effects on Niobium oxidation and surface contamination in Niobium-metal bilayers using X-ray photoelectron spectroscopy

Superconducting resonators and qubits are limited by dielectric losses from surface oxides. Surface oxides are mitigated through various strategies such as the addition of a metal capping layer, surface passivation, and acid processing. In this study, we demonstrate the use of X-ray photoelectron spectroscopy (XPS) as a rapid characterization tool to study the effectiveness cap layers for niobium for further device fabrication. We non-destructively evaluate 17 capping layers to characterize their ability to prevent oxygen diffusion, and the effects of standard fabrication processes -- annealing, resist stripping, and acid cleaning. We downselect for resilient capping layers and test their microwave resonator performance.

cond-mat.mtrl-sci

Krypton-sputtered tantalum films for scalable high-performance quantum devices

Superconducting qubits based on tantalum (Ta) thin films have demonstrated the highest-performing microwave resonators and qubits. This makes Ta an attractive material for superconducting quantum computing applications, but, so far, direct deposition has largely relied on high substrate temperatures exceeding \SI{400}{\celsius} to achieve the body-centered cubic phase, BCC (\textalpha-Ta). This leads to compatibility issues for scalable fabrication leveraging standard semiconductor fabrication lines. Here, we show that changing the sputter gas from argon (Ar) to krypton (Kr) promotes BCC Ta synthesis on silicon (Si) at temperatures as low as \SI{200}{\celsius}, providing a wide process window compatible with back-end-of-the-line fabrication standards. Furthermore, we find these films to have substantially higher electronic conductivity, consistent with clean-limit superconductivity. We validated the microwave performance through coplanar waveguide resonator measurements, finding that films deposited at \SI{250}{\celsius} and \SI{350}{\celsius} exhibit a tight performance distribution at the state of the art. Higher temperature-grown films exhibit higher losses, in correlation with the degree of Ta/Si intermixing revealed by cross-sectional transmission electron microscopy. Finally, with these films, we demonstrate transmon qubits with a relatively compact, \SI{20}{\micro\meter} capacitor gap, achieving a median quality factor up to 14 million.

quant-ph

Loopless multiterminal quantum circuits at odd parity

We theoretically investigate loopless multiterminal hybrid superconducting devices at odd fermion parity with time-reversal symmetry. We find that the energy-phase relationship has a double minimum corresponding to opposite windings of the superconducting phases. Spin-orbit coupling adds multi-axial spin splittings, which contrasts with two-terminal devices where spin dependence is uniaxial. Capacitive shunting localizes quantum circuit states in the wells and exponentially suppresses their splitting. For weak spin-orbit strength, the system has a four-dimensional spin-chirality low-energy subspace which can be universally controlled with electric fields only.

cond-mat.mes-hall

Andreev spin qubits bound to Josephson vortices in spin-orbit coupled planar Josephson junctions

We propose a variant of Andreev spin qubits (ASQs) defined in planar Josephson junctions based on spin-orbit coupled two-dimensional electron gases (2DEGs) in a weak out-of-plane magnetic field. The magnetic field induces a linear phase gradient across the junction, generating Josephson vortices that can host low-energy Andreev bound states (ABSs). We show that, in certain parameter regimes, the combined effect of the phase gradient and spin-orbit coupling stabilizes an odd-fermion parity ground state, where a single Josephson vortex binds a spinful low-energy degree of freedom that is energetically separated from the other ABSs. This low-energy degree of freedom can be exploited to define a special type of ASQ, which we dub the vortex spin qubit (VSQ). We show that single-qubit gates for VSQs can be performed via flux driving, while readout can be achieved by adapting standard circuit quantum electrodynamics (cQED) techniques developed for conventional ASQs. We further outline how an entangling two-qubit gate can be performed using an ac current drive. We argue that VSQs offer prospects for a substantial reduction in device complexity and hardware overhead compared to conventional ASQ implementations, while preserving key advantages such as supercurrent-based readout, single-qubit gates, and long-range two-qubit gates.

cond-mat.mes-hall

Spectroscopy and Coherent Control of Two-Level System Defect Ensembles Using a Broadband 3D Waveguide

Defects in solid-state materials play a central role in determining coherence, stability, and performance in quantum technologies. Although narrowband techniques can probe specific resonances with high precision, a broadband spectroscopic approach captures the full spectrum of defect properties and dynamics. Two-level system (TLS) defects in amorphous dielectrics are a particularly important example because they are major sources of decoherence and energy loss in superconducting quantum devices. However, accessing and characterizing their collective dynamics remains far more challenging than probing individual TLS defects. Building on our previously developed Broadband Cryogenic Transient Dielectric Spectroscopy (BCTDS) technique, we study the coherent control and time-resolved dynamics of TLS defect ensembles over a wide frequency range of 3-5 GHz without requiring full device fabrication, revealing quantum interference effects, memory-dependent dynamics, and dressed-state evolution within the TLS defect bath. The spectral response reveals distinct V-shaped structures corresponding to the bare eigenmode frequencies. Using these features, we extract a TLS defect spectral density of 84 GHz^-1 for a silicon sample, across a 4.1-4.6 GHz span. Furthermore, we systematically investigate amplitude- and phase-controlled interference fringes for multiple temperatures and inter-pulse delays, providing direct evidence of coherent dynamics and control. A driven minimal spin model with dipole-dipole interactions that qualitatively capture the observed behavior is presented. Our results establish BCTDS as a versatile platform for broadband defect spectroscopy, offering new capabilities for diagnosing and mitigating sources of decoherence, engineering many-body dynamics, and exploring non-equilibrium phenomena in disordered quantum systems.

quant-ph

Active-Learning Inspired $\textit{Ab Initio}$ Theory-Experiment Loop Approach for Management of Material Defects: Application to Superconducting Qubits

Surface oxides are associated with two-level systems (TLSs) that degrade the performance of niobium-based superconducting quantum computing devices. To address this, we introduce a predictive framework for selecting metal capping layers that inhibit niobium oxide formation. Using DFT-calculated oxygen interstitial and vacancy energies as thermodynamic descriptors, we train a logistic regression model on a limited set of experimental outcomes to successfully predict the likelihood of oxide formation beneath different capping materials. This approach identifies Zr, Hf, and Ta as effective diffusion barriers. Our analysis further reveals that the oxide formation energy per oxygen atom serves as an excellent standalone descriptor for predicting barrier performance. By combining this new descriptor with lattice mismatch as a secondary criterion to promote structurally coherent interfaces, we identify Zr, Ta, and Sc as especially promising candidates. This closed-loop strategy integrates first-principles theory, machine learning, and limited experimental data to enable rational design of next-generation materials.

cond-mat.mtrl-sci

Low barrier ZrO$_x$-based Josephson junctions

The Josephson junction is a crucial element in superconducting devices, and niobium is a promising candidate for the superconducting material due to its large energy gap relative to aluminum. AlO$_x$ has long been regarded as the highest quality oxide tunnel barrier and is often used in niobium-based junctions. Here we propose ZrO$_x$ as an alternative tunnel barrier material for Nb electrodes. We theoretically estimate that zirconium oxide has excellent oxygen retention properties and experimentally verify that there is no significant oxygen diffusion leading to NbO$_x$ formation in the adjacent Nb electrode. We develop a top-down, subtractive fabrication process for Nb/Zr-ZrO$_x$/Nb Josephson junctions, which enables scalability and large-scale production of superconducting electronics. Using cross sectional scanning transmission electron microscopy, we experimentally find that depending on the Zr thickness, ZrO$_x$ tunnel barriers can be fully crystalline with chemically abrupt interfaces with niobium. Further analysis using electron energy loss spectroscopy reveals that ZrO$_x$ corresponds to tetragonal ZrO$_2$. Room temperature characterization of fabricated junctions using Simmons' model shows that ZrO$_2$ exhibits a low tunnel barrier height, which is promising in merged-element transmon applications. Low temperature transport measurements reveal sub-gap structure, while the low-voltage sub-gap resistance remains in the megaohm range.

cond-mat.supr-con

Fast readout of quantum dot spin qubits via Andreev spins

Spin qubits in semiconducting quantum dots are currently limited by slow readout processes, which are orders of magnitude slower than gate operations. In contrast, Andreev spin qubits benefit from fast measurement schemes enabled by the large resonator couplings of superconducting qubits but suffer from reduced coherence during qubit operations. Here, we propose fast and high-fidelity measurement protocols based on an electrically-tunable coupling between quantum dot and Andreev spin qubits. In realistic devices, this coupling can be made sufficiently strong to enable high-fidelity readout well below microseconds, potentially enabling mid-circuit measurements. Crucially, the electrical tunability of our coupler permits to switch it off during idle periods, minimizing crosstalk and measurement back-action. Our approach is fully compatible with germanium-based devices and paves the way for scalable quantum computing architectures by leveraging the advantages of heterogeneous qubit implementations.

cond-mat.mes-hall

Full characterization of measurement-induced transitions of a superconducting qubit

Repeated quantum non-demolition measurement is a cornerstone of quantum error correction protocols. In superconducting qubits, the speed of dispersive state readout can be enhanced by increasing the power of the readout tone. However, such an increase has been found to result in additional qubit state transitions that violate the desired quantum non-demolition character of the measurement. Recently, the readout of a transmon superconducting qubit was improved by using a tone with frequency much larger than the qubit frequency. Here, we experimentally identify the mechanisms of readout-induced transitions in this regime. In the dominant mechanism, the energy of an incoming readout photon is partially absorbed by the transmon and partially returned to the transmission line as a photon with lower frequency. Other mechanisms involve the excitation of unwanted package modes, decay via material defects, and, at higher qubit frequencies, the activation of undesired resonances in the transmon spectrum. Our work provides a comprehensive characterization of superconducting qubit state transitions caused by a strong drive.

quant-ph

Mixed spin-boson coupling for qubit readout with suppressed residual shot-noise dephasing

Direct dipole coupling between a two-level system and a bosonic mode describes the interactions present in a wide range of physical platforms. In this work, we study a coupling that is mixed between two pairs of quadratures of a bosonic mode and a spin. In this setting, we can suppress the dispersive shift while retaining a nonzero Kerr shift, which results in a quadratic relationship between shot-noise dephasing and thermal photons in the oscillator. We demonstrate this configuration with a simple toy model, quantify the expected improvements to photon shot-noise dephasing of the spin, and describe an approach to fast qubit readout via the Kerr shift. Further, we show how such a regime is achievable in superconducting circuits because magnetic and electric couplings can be of comparable strength, using two examples: the Cooper pair transistor and the fluxonium molecule.

quant-ph