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Varazdat Stepanyan

Publications and source records attributed to Varazdat Stepanyan.

3 recordsLinked to original sources

Nonlocal Electrostatic Field Theory from Microscopic Description

The study of electric fields in soft materials converges either to the study of point-like particles (local) in nonlinear theories or to the use of particles with finite sizes in nonlocal linear theories. In this work we start from the microscopic equations of motion and construct a unified mean field Fokker-Planck equation that describes the non-equilibrium electrostatics of nonlocal nonlinear systems. We obtain a generalized Poisson-Boltzmann equation for such systems as well as their electrostatic free energy expression. In the linear approximation we obtain an anisotropic susceptibility in an isotropic fluid which allows for local linear response inversion in electrostatics.

cond-mat.soft

Negative thermodynamic pressure: no-go theorem and yes-go examples

Theory and experiment have long discussed negative thermodynamic pressure states, but their microscopic origins are unclear. I address this problem within the framework of quantum thermodynamics. I show that the pressure exerted on the boundary is positive when there is no interaction with the boundary. This is formalized by a no-go theorem that holds for any quantum state with finite motion. As a consequence of this analysis, I deduce a general formula for quantum non-equilibrium pressure. It is believed that stable negative pressure states cannot exist in gases. I provide solvable examples of quantum and classical gases, where negative pressure is achieved due to a suitable coupling with the boundary walls.

quant-ph

Thermal transitions in a one-dimensional, finite-size Ising model

We revisit the one-dimensional ferromagnetic Ising spin-chain with a finite number of spins and periodic boundaries and derive analytically and verify numerically its various stationary and dynamical properties at different temperatures. In particular, we determine the probability distributions of magnetization, the number of domain walls, and the corresponding residence times for different chain lengths and magnetic fields. While we study finite systems at thermal equilibrium, we identify several temperatures similar to the critical temperatures for first-order phase transitions in the thermodynamic limit. We illustrate the utility of our results by their application to structural transitions in biopolymers having non-trivial intermediate equilibrium states.

cond-mat.stat-mech