Photoemission insights into lanthanide-based crystals
The interplay of strongly localized 4$f$ electrons with itinerant spd-valence states gives rise to a wide range of correlated phenomena and properties that place lanthanide materials at the focus of considerable research efforts. Beyond the bulk, their surfaces are of particular interest, where the reduced coordination, a modified crystal electric field, broken inversion symmetry in combination with strong spin-orbit coupling, and the emergence of surface states and resonances considerably reshape 4$f$-driven electronic and magnetic properties. This, in turn, enables novel functionalities of particular relevance for low-dimensional systems and their applications. This review summarizes how advances in photoelectron spectroscopies, together with improved crystal growth, have enabled detailed insights into bulk and surface phenomena of lanthanide-based crystals. After a brief overview of key developments from the 1970s to the 1990s, we discuss recent progress, focusing on systematic studies by the authors and collaborators that form a coherent line of research. These include the unveiling of $k$-resolved $f-spd$ hybridization, the formation and evolution with temperature of $f$-derived Fermi surface in Kondo lattices, layer-dependent 4$f$ magnetic anisotropy, the emergence of ferromagnetically ordered surfaces in systems with non-magnetic bulk ground state. This coherent line of research addresses core questions in the physics of 4$f$ systems and opens opportunities for engineering novel lanthanide-based architectures, including heterostructures and supramolecular complexes with novel physical properties and functionalities.