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Vatsal Sanjay

Publications and source records attributed to Vatsal Sanjay.

At least 19 recordsLinked to original sources

Singularities in Soft Matter Systems

When a liquid thread pinches off, its neck thins as it separates into two unconnected regions. Using continuum mechanics, we can predict that the neck reaches zero radius in finite time while its curvature grows without bound. Together, the vanishing neck and diverging curvature form a finite-time singularity. However, a real fluid does not realise these mathematical limits as molecular or material physics takes over once the neck becomes sufficiently small. Similar singularities arise throughout soft matter whenever a smooth continuum description is used at vanishing length scales. This review asks what the shrinking region forgets, what it retains, and which material length, time, or stress cuts off the apparent divergence. The dynamics near a singularity often become self-similar, with profiles at different times collapsing onto one shape when rescaled by the shrinking local length. Sometimes that collapse is universal enough that the surrounding geometry and forcing no longer determine the local dynamics. Nonetheless, the measured output could still depend on how the shrinking region is fed by the surrounding flow and on the small-scale physics that finally replaces the ideal divergence. Complex fluids and active matter change the same local balance by bringing their own timescales into the shrinking region. Beyond interfaces, the same logic applies when the localised object is a stress concentration or a defect in geometry or order rather than a moving surface. Singularities matter because they show where continuum theory stops being the relevant description and how the small-scale cutoff sets the outputs that count in printing, coating, aerosols, and stretchable solids.

cond-mat.soft

Self-similar Worthington jets

When a micron-sized bubble bursts, capillary waves deform the cavity into a cone that ejects a Worthington jet. The jet is born by inertial focusing, and the local collapse follows self-similar Euler solutions set by the semiangle $β$. Writing $r_j$ and $v_j$ for the dimensionless jet-base radius and velocity, the local Weber number $We_j=r_j v^2_j$ measures inertia relative to capillarity. The theory, supported by accurate numerical simulations gives $r_j\proptoτ^{α(β)}$ with $α\simeq0.63$ and, hence $We_j\gg1$, with $We_j\to\infty$ as $r_j\to0$, so inertia increasingly overwhelms capillarity. In simulations, the interface collapses onto a universal shape for more than two decades in dimensionless time when lengths are scaled using our prediction for $r_j$. For water, this gives incipient radii of $\mathcal{O}(1)$ nm, predicting nanometric sea-spray aerosols.

physics.flu-dyn

Confinement-Induced Suppression of Jet Drop Size by Bubble Bursting in Shallow Liquids

Bubble bursting is a major source of aerosol generation in a wide range of natural and industrial systems. While the resulting jet dynamics have been extensively studied in deep liquid pools, bubble bursting often occurs in shallow liquid layers where the influence of the nearby solid boundary remains poorly understood. Here, we show numerically that a shallow liquid layer produces smaller and more numerous jet drops, even when the initial bubble shape is unchanged. We identify a wall-induced viscous sticking effect that suppresses the upward motion of the cavity bottom, leading to a steeper cavity geometry during capillary-wave focusing. We further develop a semi-empirical scaling law that predicts the jet drop radius as a function of the Ohnesorge number and the initial bubble-wall distance. Our results establish geometric confinement as a governing factor in bubble bursting and provide a framework for predicting and controlling aerosol generation in shallow liquid environments.

physics.flu-dyn

Rheology of Two-Dimensional Dilute Emulsions

The single droplet under shear is a foundational problem in fluid mechanics. In computational fluid dynamics, the two-dimensional (2D) formulation offers advantages in both computational efficiency and relevance, yet its theoretical treatment remains relatively underdeveloped. In this brief note, we present an analytical treatment of this problem, beginning with a derivation of the Lamb solution for 2D Stokes flows, which in turn is used to obtain the flow fields around a droplet in a purely extensional flow. Using these flow fields, expressions are obtained for the apparent viscosity, $μ^*$, of a dilute emulsion as well as a small deformation theory. We show that $μ^* = μ( 1 + f(λ) ϕ) + \mathcal{O}(ϕ^2)$ with $f(λ) = (2λ+ 1)/(λ+ 1)$ where $λ$ is the ratio of the droplet viscosity to the matrix viscosity and $ϕ$ is the area fraction covered by the suspended phase. Also the steady state value of the Taylor deformation parameter $D_T^\infty$, in the capillarity-dominated regime, obeys $D_T^\infty = g(λ)\,\text{Ca}$, where Ca is the capillary number and $g(λ) = 1$. This contrasts with the 3D case, where $g(λ)$ depends on $λ$. These results are then validated through direct numerical simulations across a wide range of viscosity ratios ($0.01 < λ< 100$). Our results provide a basic theoretical framework for interpreting 2D droplet simulations and provide clear benchmarks for computational fluid dynamics.

physics.flu-dyn

How elasticity affects bubble pinch-off

The pinch-off of bubbles in viscoelastic liquids is a fundamental process that has received little attention compared to viscoelastic drop pinch-off. While these processes exhibit qualitative similarities, the dynamics of the pinch-off process are significantly different. When a drop of a dilute polymer solution pinches off, a thread is known to develop that prevents breakup due the diverging polymer stresses. Conversely, our experiments reveal that this thread is absent for bubble pinch-off in dilute polymer solutions. We show that a thread becomes apparent only for high polymer concentrations, where the pinch-off dynamics become very sensitive to the size of the needle from which the bubble detaches. The experiments are complemented by numerical simulations and analytical modeling using the Oldroyd-B model, which capture the dilute regime. The model shows that polymer stresses are still singular during bubble pinch-off, but the divergence is much weaker as compared to drop pinch-off. This explains why, in contrast to droplets, viscoelastic bubble-threads do not appear for dilute suspensions but require large polymer concentrations

cond-mat.soft

Holes in Sheets: Double-Threshold Rupture of Draining Liquid Films

Classical rupture is attributed to molecular (van der Waals) forces acting at nanometric thicknesses. Nonetheless, micron-thick liquid sheets routinely perforate far above the scale where these molecular forces act, yet the mechanism that selects opening versus healing has remained unclear. Using direct numerical simulations of a draining sheet with an entrained air bubble (cavity), we show that irreversible rupture occurs only when a deterministic double-threshold is crossed: (i) the outward driving (from airflow or inertia) is strong enough and (ii) the cavity is distorted enough. If either condition falls short, surface tension heals the cavity and the sheet reseals. The time for this process is set by the balance between inertia and viscosity -- fast for inertia-dominated sheets and slower for viscous ones. This double-threshold mechanism explains why micrometer-thick films perforate and offers practical control options -- driving strength and defect geometry -- for predicting and controlling breakup in spray formation processes, wave breaking, and respiratory films.

physics.flu-dyn

Impacting spheres: from liquid drops to elastic beads

A liquid drop impacting a non-wetting rigid substrate laterally spreads, then retracts, and finally jumps off again. An elastic solid, by contrast, undergoes a slight deformation, contacts briefly, and bounces. The impact force on the substrate - crucial for engineering and natural processes - is classically described by Wagner's (liquids) and Hertz's (solids) theories. This work bridges these limits by considering a generic viscoelastic medium. Using direct numerical simulations, we study a viscoelastic sphere impacting a rigid, non-contacting surface and quantify how the elasticity number ($El$, dimensionless elastic modulus) and the Weissenberg number ($Wi$, dimensionless relaxation time) dictate the impact force. We recover the Newtonian liquid response as either $El \to 0$ or $Wi \to 0$, and obtain elastic-solid behavior in the limit $Wi \to \infty$ and $El \ne 0$. In this elastic-memory limit, three regimes emerge - capillary-dominated, Wagner scaling, and Hertz scaling - with a smooth transition from the Wagner to the Hertz regime. Sweeping $Wi$ from 0 to $\infty$ reveals a continuous shift from materials with no memory to materials with permanent memory of deformation, providing an alternate, controlled route from liquid drops to elastic beads. The study unifies liquid and solid impact processes and offers a general framework for the liquid-to-elastic transition relevant across systems and applications.

cond-mat.soft

Stood-up drop to measure receding contact angles

The wetting behavior of drops on natural and industrial surfaces is determined by the advancing and receding contact angles. They are commonly measured by the sessile drop technique, also called goniometry, which doses liquid through a solid needle. Consequently, this method requires substantial drop volumes, long contact times, tends to be user-dependent, and is difficult to automate. Here, we propose the stood-up drop (SUD) technique as an alternative to measure receding contact angles. The method consists of depositing a liquid drop on a surface by a short liquid jet, at which it spreads radially forming a pancake-shaped film. Then the liquid retracts, forming a spherical cap drop shape (stood-up drop). At this quasi-equilibrium state, the contact angle ($θ_\text{SUD}$) closely resembles the receding contact angle measured by goniometry. Our method is suitable for a wide variety of surfaces from hydrophilic to hydrophobic, overcoming typical complications of goniometry such as needle-induced distortion of the drop shape, and it reduces user dependence. We delineate when the receding contact angle can be obtained by the stood-up method using Volume-of-Fluid (VoF) simulations that systematically vary viscosity, contact angle, and deposited drop volume. Finally, we provide simple scaling criteria to predict when the stood-up drop technique works.

physics.flu-dyn

Implementation of integral surface tension formulations in a volume of fluid framework and their applications to Marangoni flows

Accurate numerical modeling of surface tension has been a challenging aspect of multiphase flow simulations. The integral formulation for modeling surface tension forces is known to be consistent and conservative, and to be a natural choice for the simulation of flows driven by surface tension gradients along the interface. This formulation was introduced by Popinet and Zaleski [1] for a front-tracking method and was later extended to level set methods by Al-Saud et al. [2]. In this work, we extend the integral formulation to a volume of fluid (VOF) method for capturing the interface. In fact, we propose three different schemes distinguished by the way we calculate the geometric properties of the interface, namely curvature, tangent vector and surface fraction from VOF representation. We propose a coupled level set volume of fluid (CLSVOF) method in which we use a signed distance function coupled with VOF, a height function (HF) method in which we use the height functions calculated from VOF, and a height function to distance (HF2D) method in which we use a sign-distance function calculated from height functions. For validation, these methods are rigorously tested for several problems with constant as well as varying surface tension. It is found that from an accuracy standpoint, CLSVOF has the least numerical oscillations followed by HF2D and then HF. However, from a computational speed point of view, HF method is the fastest followed by HF2D and then CLSVOF. Therefore, the HF2D method is a good compromise between speed and accuracy for obtaining faster and correct results. Keywords: Multiphase flows; Surface tension modeling; Marangoni flows

physics.flu-dyn

To jump or not to jump: Adhesion and viscous dissipation dictate the detachment of coalescing wall-attached bubbles

Bubble coalescence can promote bubble departure at much smaller sizes compared to buoyancy. This can critically enhance the efficiency of gas-evolving electrochemical processes, such as water electrolysis. In this study, we integrate high-speed imaging experiments and direct numerical simulations to dissect how and under which conditions bubble coalescence on surfaces leads to detachment. Our transparent electrode experiments provide new insights into contact line dynamics, demonstrating that the bubble neck generally does not contact the surface during coalescence. We reveal that whether coalescence leads to bubble departure or not is determined by the balance between surface energy, adhesion forces, and viscous dissipation. For the previously unexplored regime at low effective Ohnesorge number, a measure of viscosity that incorporates the effect of asymmetry between the coalescing bubbles, we identify a critical dimensionless adhesion energy threshold of $\approx$15% of the released surface energy, below which bubbles typically detach. We develop a global energy balance model that successfully predicts coalescence outcomes across diverse experimental conditions.

physics.flu-dyn

Viscoelastic Worthington jets & droplets produced by bursting bubbles

Bubble bursting and subsequent collapse of the open cavity at free surfaces of contaminated liquids can generate aerosol droplets, facilitating pathogen transport. After film rupture, capillary waves focus at the cavity base, potentially generating fast Worthington jets that are responsible for ejecting the droplets away from the source. While extensively studied for Newtonian fluids, the influence of non-Newtonian rheology on this process remains poorly understood. Here, we employ direct numerical simulations to investigate the bubble cavity collapse in viscoelastic media, such as polymeric liquids. We find that the jet and drop formation are dictated by two dimensionless parameters: the elastocapillary number $Ec$ (the ratio of the elastic modulus and the Laplace pressure) and the Deborah number $De$ (the ratio of the relaxation time and the inertio-capillary timescale). We show that for low values of $Ec$ and $De$, the viscoelastic liquid adopts a Newtonian-like behavior, where the dynamics are governed by the solvent Ohnesorge number $Oh_s$ (the ratio of visco-capillary and inertio-capillary timescales). In contrast, for large values $Ec$ and $De$, the enhanced elastic stresses completely suppress the formation of the jet. For some cases with intermediate values of $Ec$ and $De$, smaller droplets are produced compared to Newtonian fluids, potentially enhancing aerosol dispersal. By mapping the phase space spanned by $Ec$, $De$, and $Oh_s$, we reveal three distinct flow regimes: (i) jets forming droplets, (ii) jets without droplet formation, and (iii) absence of jet formation. Our results elucidate the mechanisms underlying aerosol suppression versus fine spray formation in polymeric liquids, with implications for pathogen transmission and industrial processes involving viscoelastic fluids.

physics.flu-dyn

Bouncing microdroplets on hydrophobic surfaces

Intuitively, slow droplets stick to a surface and faster droplets splash or bounce. However, recent work suggests that on non-wetting surfaces, whether microdroplets stick or bounce depends only on their size and fluid properties, but not on the incoming velocity. Here, we show using theory and experiments that even poorly wetting surfaces have a velocity-dependent criterion for bouncing of aqueous droplets, which is as high as 6 m/s for diameters of 30-50 microns on hydrophobic surfaces such as Teflon. We quantify this criterion by analyzing the interplay of dissipation, surface adhesion, and incoming kinetic energy, and describe a wealth of associated phenomena, including air bubbles and satellite droplets. Our results on inertial microdroplets elucidate fundamental processes crucial to aerosol science and technology.

physics.flu-dyn

Unifying theory of scaling in drop impact: Forces & maximum spreading diameter

The dynamics of drop impact on a rigid surface -- omnipresent in nature and technology -- strongly depends on the droplet's velocity, its size, and its material properties. The main characteristics are the droplet's force exerted on the surface and its maximal spreading radius. The crucial question is: How do they depend on the (dimensionless) control parameters, which are the Weber number $We$ (non-dimensionalized kinetic energy) and the Ohnesorge number $Oh$ (dimensionless viscosity)? Here we perform direct numerical simulations over the huge parameter range $1\le We \le 10^3$ and $10^{-3}\le Oh \le 10^2$ and in particular develop a unifying theoretical approach, which is inspired by the Grossmann-Lohse theory for wall-bounded turbulence [J. Fluid Mech. 407, 27 (2000); PRL 86, 3316 (2001)]. The key idea is to split the energy dissipation rate into the different phases of the impact process, in which different physical mechanisms dominate. The theory can consistently and quantitatively account for the $We$ and $Oh$ dependences of the maximal impact force and the maximal spreading diameter over the huge parameter space. It also clarifies why viscous dissipation plays a significant role during impact, even for low-viscosity droplets (low $Oh$), in contrast to what had been assumed in prior theories.

physics.flu-dyn

The role of viscosity on drop impact forces on non-wetting surfaces

A liquid drop impacting a rigid substrate undergoes deformation and spreading due to normal reaction forces, which are counteracted by surface tension. On a non-wetting substrate, the drop subsequently retracts and takes off. Our recent work (Zhang et al., \textit{Phys. Rev. Lett.}, vol. 129, 2022, 104501) revealed two peaks in the temporal evolution of the normal force $F(t)$ -- one at impact and another at jump-off. The second peak coincides with a Worthington jet formation, which vanishes at high viscosities due to increased viscous dissipation affecting flow focusing. In this article, using experiments, direct numerical simulations, and scaling arguments, we characterize both the peak amplitude $F_1$ at impact and the one at take off ($F_2$) and elucidate their dependency on the control parameters: the Weber number $We$ (dimensionless impact kinetic energy) and the Ohnesorge number $Oh$ (dimensionless viscosity). The first peak amplitude $F_1$ and the time $t_1$ to reach it depend on inertial timescales for low viscosity liquids, remaining nearly constant for viscosities up to 100 times that of water. For high viscosity liquids, we balance the rate of change in kinetic energy with viscous dissipation to obtain new scaling laws: $F_1/F_ρ\sim \sqrt{Oh}$ and $t_1/τ_ρ\sim 1/\sqrt{Oh}$, where $F_ρ$ and $τ_ρ$ are the inertial force and time scales, respectively, which are consistent with our data. The time $t_2$ at which the amplitude $F_2$ appears is set by the inertio-capillary timescale $τ_γ$, independent of both the viscosity and the impact velocity of the drop. However, these properties dictate the magnitude of this amplitude.

physics.flu-dyn

Focusing of concentric free-surface waves

Gravito-capillary waves at free-surfaces are ubiquitous in several natural and industrial processes involving quiescent liquid pools bounded by cylindrical walls. These waves emanate from the relaxation of initial interface distortions, which often take the form of a cavity (depression) centred on the symmetry axis of the container. These surface waves reflect from the container walls leading to a radially inward propagating wave-train converging (focussing) onto the symmetry axis. Under the inviscid approximation and for sufficiently shallow cavities, the relaxation is well-described by the linearised potential-flow equations. Naturally, adding viscosity to such a system introduces viscous dissipation that enervates energy and dampens the oscillations at the symmetry axis. However, for viscous liquids and deeper cavities, these equations are qualitatively inaccurate. In this study, we elucidate a modal approach to study the initial-value problem for concentric gravito-capillary waves generated on a free-surface for inviscid as well as viscous liquids. For a sufficiently deep cavity, the inward focusing of waves results in large interfacial oscillations at the axis, necessitating a second-order nonlinear theory. We demonstrate that this theory effectively models the interfacial behavior and highlights the crucial role of nonlinearity near the symmetry axis. Contrary to expectations, the addition of slight viscosity further intensifies the oscillations at the symmetry axis. This finding underscores the limitations of the potential flow model and suggests avenues for more accurate modelling of such complex free-surface flows.

physics.flu-dyn

Electrolyte spraying within H$_2$ bubbles during water electrolysis

Electrolytically generated gas bubbles can significantly hamper the overall electrolysis efficiency. Therefore it is crucial to understand their dynamics in order to optimise water electrolyzer systems. Here we demonstrate a distinct transport mechanism where coalescence with microbubbles drives electrolyte droplets, resulting from the fragmentation of the Worthington jet, into the gas phase during hydrogen evolution reaction, both in normal and microgravity environments. This indicates that the H$_2$ bubble is not only composed of hydrogen gas and vapor but also includes electrolyte fractions. Reminiscent of bursting bubbles on a liquid-gas interface, this behavior results in a flow inside the bubble, which is further affected by Marangoni convection at the gas-electrolyte interface, highlighting interface mobility. In the case of electrode-attached bubbles, the sprayed droplets form electrolyte puddles at the bubble-electrode contact area, affecting the dynamics near the three-phase contact line and favoring bubble detachment from the electrode. The results of this work unravel important insights into the physicochemical aspects of electrolytic gas bubbles, integral for optimizing gas-evolving electrochemical systems. Besides, our findings are essential for studying the limits of jet formation and rupture relevant to acid mist formation in electrowinning, generation of sea spray aerosols, impact of droplets on liquid surfaces, etc.

physics.flu-dyn

When does an impacting drop stop bouncing?

Non-wetting substrates allow impacting liquid drops to spread, recoil, and takeoff, provided they are not too heavy (Biance et al. 2006) or too viscous (Jha et al. 2020). In this article, using direct numerical simulations with the volume of fluid method, we investigate how viscous stresses and gravity conspire against capillarity to inhibit drop rebound. Close to the bouncing to non-bouncing transition, we evidence that the initial spreading stage can be decoupled from the later retraction and takeoff, allowing to understand the rebound as a process converting the surface energy of the spread liquid into kinetic energy. Drawing an analogy with coalescence induced jumping, we propose a criterion for the transition from the bouncing to the non-bouncing regime, namely by the condition $Oh_c + Bo_c \sim 1$, where $Oh_c$ and $Bo_c$ are the Ohnesorge number and Bond number at the transition, respectively. This criterion is in excellent agreement with the numerical results. We also elucidate the mechanisms of bouncing inhibition in the heavy and viscous drops limiting regimes by calculating the energy budgets and relating them to the drop's shape and internal flow.

physics.flu-dyn

Drop impact on viscous liquid films

When a liquid drop falls on a solid substrate, the air layer in between them delays the occurrence of liquid--solid contact. For impacts on smooth substrates, the air film can even prevent wetting, allowing the drop to bounce off with dynamics identical to that observed for impacts on superamphiphobic materials. In this article, we investigate similar bouncing phenomena, occurring on viscous liquid films, that mimic atomically smooth substrates, with the goal to probe their effective repellency. We elucidate the mechanisms associated to the bouncing to non-bouncing (floating) transition using experiments, simulations, and a minimal model that predicts the main characteristics of drop impact, the contact time, and the coefficient of restitution. In the case of highly viscous or very thin films, the impact dynamics is not affected by the presence of the viscous film. Within this substrate--independent limit, bouncing is suppressed once the drop viscosity exceeds a critical value as on superamphiphobic substrates. For thicker or less viscous films, both the drop and film properties influence the rebound dynamics and conspire to inhibit bouncing above a critical film thickness. This substrate--dependent regime also admits a limit, for low viscosity drops, in which the film properties alone determine the limits of repellency.

physics.flu-dyn