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Victor G. Karpov

Publications and source records attributed to Victor G. Karpov.

15 recordsLinked to original sources

Revisiting the barometric equation and the extent of a planetary atmosphere

The barometric equation predicts the molecular concentration $n(z)$ exponentially decaying with altitude $z$. Because the mean free path $l=1/nσ$ increases exponentially, at high altitudes $z$, the equation is no longer within the domain of applicability of the standard kinetic theory. \cite{grimsditch} Here, we predict the dependence $n(z)\propto z^{-2}$ for the case $l\gg L$ in uniform gravity and $n(z)\propto [\ln(1+z/R_0)]^{-2}$ when $z\gg R_0$ for a planet of radius $R_0$. It corresponds to a non-stationary planetary atmosphere with hydrogen accretion. The accretion is accompanied by a release of gravitational potential energy that could be the elusive source driving the formation of stellar coronas. Other consequences include slowly decaying tails of planetary atmospheres and periodical hydrogen explosions of white dwarfs.

astro-ph.EP↗

Modification of Tin (Sn) Metal Surfaces by Surface Plasmon Polariton Excitation

We report on the modification of tin (Sn) film surfaces under a laser beam irradiation that triggers surface plasmon polariton (SPP) excitations. The observed surface features in the form of small raised grains, with well-defined rooting, look similar to tin whisker nodules. We attribute the appearance of those features to the field-induced nucleation caused by the SPP related strong electric field. Possible implications of our findings include accelerated-life testing for tin whisker growth-related reliability as well as applications to nanoparticle nucleation.

cond-mat.mtrl-sci↗

Threshold Switching in CdTe Photovoltaics

With the ubiquitous acceptance of PVs, the number of devices manufactured annually is following an exponential trend. Yet, the manufacturing process of important brands of thin film solar cells involves a tedious and expensive step of laser scribing. The time-consuming and technologically involved laser scribing method remains widely used to contact the device electrodes. This work examines an alternative method (threshold switching phenomenon) to create an enduring conductive path in cadmium telluride (CdTe) PV, which eliminates the pitfalls in conventional scribing technology. The samples undergoing threshold switching show a promising sign of the conductive path compared to the control samples. This method could potentially lead to the manufacturing technology saving time, money, and raw materials along with added reliability and efficiency.

cond-mat.mtrl-sci↗

Cultivating Metal Whiskers by Surface Plasmon Polariton Excitation

This work presents a preliminary experimental study on the possibility to initiate growth of whiskers on the surfaces of some technologically important metals utilizing the enhanced electric field of surface plasmon polaritons (SPPs). The results provide evidence that a relatively high concentration of what appear to be whisker nuclei form in the region where SPPs were excited, whereas no such changes are observed on the untreated surface.

cond-mat.mtrl-sci↗

Metal whisker growth induced by localized, high-intensity DC electric fields

In this work, a very high, locally applied electric field was used to induce whisker nucleation on an Sn film. The field was generated by using a conductive AFM tip and applying a voltage bias between the sample and the conductive cantilever>The tip-sample separation distance was thus controllable, and any dielectric breakdown could be avoided. At locations where the AFM tip was positioned for an extended period, minuscule whiskers were observed, whose growth direction matched vertical orientation of the field.

cond-mat.mtrl-sci↗

Threshold switching in solar cells and a no-scribe photovoltaic technology

We show that thin film CdTe solar cells exhibit the phenomenon of threshold switching similar to that in phase change and resistive memory. It creates a conductive filament (shunt) through the solar cell reaching the buried electrode, such as the transparent conductive oxide (TCO) in CdTe based photovoltaics (PV). While in the existing PV the buried electrode was routinely contacted via laser scribe filled metals, our work paves a way to an alternative technology of no-scribe PV.

cond-mat.other↗

Electrostatically accelerated tin whisker development under x- and gamma-rays

We observed the accelerated tin whisker development under non-destructive gamma-ray and x-ray irradiation and determined the characteristic range of radiation doses 20-30 KGy, for which that effect becomes significant. We were able to change the radiation induced whisker growth by electrically disconnecting some parts of our experimental setup thus demonstrating the electrostatic nature of the accelerated whisker development. The observed acceleration factors make the ionizing radiation a potential non-destructive and readily implementable accelerated life testing tool.

physics.app-ph↗

Whisker growth on Sn thin film accelerated under gamma-ray irradiation

We report on growth of tin (Sn) metal whiskers that is significantly accelerated under gamma-ray irradiation. The studied Sn thin film, evaporated on glass substrate, was subjected to a total of ~60 hours of irradiation over the course of 30 days. The irradiated sample demonstrated the enhanced development, in both whisker densities and lengths, resulting in an acceleration factor of ~50. This makes gamma-ray irradiation a candidate tool for accelerated testing of whisker propensity. We attribute the observed enhancement to electrostatic fields created by charged defects in the glass substrate under ionizing radiation of gamma-rays.

cond-mat.mtrl-sci↗

The stochastic growth of metal whiskers

The phenomenon of spontaneously growing metal whiskers (MW) raises significant reliability concerns due to its related arcing and shorting in electric equipment. The growth kinetics of MW remains poorly predictable. Here we present a theory describing the earlier observed intermittent growth of MW as caused by local energy barriers related to variations in the random electric fields generated by surface imperfections. We find the probabilistic distribution of MW stopping times, during which MW growth halts, which is important for reliability projections.

cond-mat.soft↗

Heat transfer and SET voltage in filamentary RRAM devices

We study the heat transport in filamentary RRAM nano-sized devices by comparing the accurate results of COMSOL modeling with simplified analytical models for two complementary mechanisms: one neglecting the radial heat transfer from the filament to the insulating host, while the other describing the radial transport through the dielectric in the absence of the filament heat transfer. For the former, we find that the earlier assumed simplification of the electrodes being ideal heat conductors is insufficient; a more adequate approximation is derived where the heat transport is determined by the adjacent proximities of the filament tips in the electrodes.We find that both complementary mechanisms overestimate the maximum temperature yet offering acceptable results. However, the two in parallel provide a better analytical approximation. In addition, we show that the Wiedemann-Franz-Lorenz law helps the analysis when the Lorenz parameter is chosen from the actual data. We present an approximate expression for the SET voltage possessing a high degree of universality and predicting that filament materials with low Lorenz numbers can be good candidates for the future low set voltage devices.

cond-mat.mtrl-sci↗

Understanding the movements of metal whiskers

Metal whiskers often grow across leads of electric equipment and electronic package causing current leakage or short circuits and raising significant reliability issues. The nature of metal whiskers remains a mystery after several decades of research. In addition, metal whiskers exhibit a rather unusual dynamic property of relatively high amplitude movements under gentle air flow or, according to some testimonies, without obvious stimuli. Understanding the physics behind that motion would give additional insights into the nature of metal whiskers. Here, we quantitatively analyze several possible mechanisms potentially responsible for the observed movements: (1) minute air currents, (2) Brownian motion due to random bombardments with the air molecules, (3) mechanically caused movements, such as (a) externally transmitted vibrations of the sample, and (b) torque exerted due to material propagation along curved whiskers responsible for the whisker growth (similar to the known garden hose oscillations), (4) time dependent electric fields due to diffusion of ions across the metal surface, and (5) nonequilibrium electric field configurations making it possible for {\it some} whiskers to move. For all these scenarios we provide numerical estimates. Our conclusion is that the observed movements are likely due to the minor air currents, intentional or ill-controlled, and that external mechanical vibrations could force such movements in a rather harsh environment or/and for whiskers with severe constrictions. We argue that under non-steady state conditions, such as caused by changes in the external light intensity, some whiskers can exercise spontaneous oscillations.

cond-mat.soft↗

Plasmon mediated non-photochemical nucleation of nanoparticles by circularly polarized light

We predict nucleation of pancake shaped metallic nanoparticles having plasmonic frequencies in resonance with a non-absorbed circularly polarized electromagnetic field. We show that the same field can induce nucleation of randomly oriented needle shaped particles. The probabilities of these shapes are estimated vs. field frequency and strength, material parameters, and temperature. This constitutes a quantitative model of non-photochemical laser induced nucleation (NPLIN) consistent with the observed particle geometry. Our results open a venue to nucleation of nanoparticles of desirable shapes controlled by the field frequency and polarization.

cond-mat.mes-hall↗

Hot spots spontaneously emerging in thin film photovoltaics

We present data exhibiting hot spots spontaneously emerging in forward biased thin film photovoltaics based on a-Si:H technology. These spots evolve over time shrinking in their diameter and increasing temperature up to approximately 300 $^o$C above that of the surrounding area. Our numerical approach explores a system of many identical diodes in parallel connected through the resistive electrode and through thermal connectors, a model which couples electric and thermal processes. The modeling results show that hot spots emerge collapsing from a rather large area of nonuniform temperature, then collapse to local entities. Finally, we present a simplified analytical treatment establishing relations between the hot spot parameters.

cond-mat.dis-nn↗

Nucleation of plasmonic resonance nanoparticles

We predict the electromagnetic field driven nucleation of nanoparticles that provide plasmonic oscillations in resonance with the field frequency. The oscillations assume a phase that maximizes the particle polarization and energy gain due to nucleation. We derive closed form expressions for the corresponding nucleation barrier and particle shape vs. field frequency and strength, metal plasma frequency, conductivity, and the host dielectric permittivity. We show that the plasmonic polarization allows for nucleation of particles that would not be stable in zero field.

cond-mat.mes-hall↗

A phenomenological theory of nonphotochemical laser induced nucleation

Our analysis of the experimental data related to nonphotochemical laser induced nucleation in solutions leads to the inevitable conclusion that the phase transformation is initiated by particles that are metallic in nature. This conclusion appears paradoxical because the final products are dielectric crystals. We show that the experimental results are well accounted for by the theory of electric field induced nucleation of metallic particles that are elongated in the direction of the field. However, new physical and chemical insights are required to understand the structure of the metallic precursor particles and the kinetics of subsequent dielectric crystallization.

cond-mat.stat-mech↗