arXiv subjects

Vijay Kumar Sharma

Publications and source records attributed to Vijay Kumar Sharma.

3 recordsLinked to original sources

arXiv2026

Bandedge-state-limited single-photon emission from volumetric quantum design of 2D colloidal quantum wells

Present-day solution-processable single-photon sources are dominated by three-dimensionally confined colloidal quantum dot emitters, yet their particle-to-particle variation in single-exciton properties limits reproducibility and scalability. Here, to avoid such heterogeneity, we demonstrate reliable room-temperature single-photon emission from atomically flat two-dimensional (2D) colloidal quantum wells (CQWs) with inherently uniform one-dimensional quantum confinement, despite their long-standing limitations of efficient multiexciton emission and pronounced exciton-surface susceptibility. We resolve these challenges through volumetric quantum design (VQD) of CQWs, yielding a highly localized, single bandedge state. This design laterally confines the bandedge excitonic domain within the exciton coherent area and vertically decouples it from surface states via a thick, strain-relieved quantum-barrier shell that preserves strong confinement, overcoming the daunting thickness-confinement trade-off in 2D CQWs. Statistical single-particle spectroscopy reveals that VQD-CQWs deliver near-blinking-free (on-time >99.5%) and fluence-insensitive antibunching (g(2)(0): 0.041), protected by a bandedge-state-filling bottleneck, together with linear polarization of up to 73% under cavity-free conditions, originating from synergistic transition-dipole and electric-field anisotropies. These advances establish 2D CQWs as a viable, homogenous and scalable platform for quantum technologies.

physics.app-ph↗

arXiv2023

Near-Unity Emitting, Widely Tailorable and Stable Exciton Concentrators Built from Doubly Gradient 2D Semiconductor Nanoplatelets

The strength of electrostatic interactions (EI) between electrons and holes within semiconductor nanocrystals profoundly impact the performance of their optoelectronic systems, and different optoelectronic devices demand distinct EI strength of the active medium. However, achieving a broad range, fine-tuning of the EI strength for specific optoelectronic applications is a daunting challenge, especially in quasi 2-dimensional core-shell semiconductor nanoplatelets (NPLs), as the epitaxial growth of the inorganic shell along the direction of the thickness that solely contributes to the quantum confined effect significantly undermines the strength of the EI. Herein we propose and demonstrate a novel doubly-gradient (DG) core-shell architecture of semiconductor NPLs for on-demand tailoring of the EI strength by controlling the localized exciton concentration via in-plane architectural modulation, demonstrated by a wide tuning of radiative recombination rate and exciton binding energy. Moreover, these exciton-concentration-engineered DG NPLs also exhibit a near-unity quantum yield, remarkable thermal and photo stability, as well as considerably suppressed self-absorption. As proof-of-concept demonstrations, highly efficient color converters and high-performance light-emitting diodes (external quantum efficiency: 16.9%, maximum luminance: 43,000 cd/m2) have been achieved based on the DG NPLs. This work thus opens up new avenues for developing high-performance colloidal optoelectronic device applications.

physics.optics↗

arXiv2017

Temperature-dependent Optoelectronic Properties of Quasi-2D Colloidal Cadmium Selenide Nanoplatelets

Colloidal Cadmium Selenide (CdSe) nanoplatelets (NPLs) are a recently developed class of efficient luminescent nanomaterial suitable for optoelectronic device applications. A change in temperature greatly affects their electronic bandstructure and luminescence properties. It is important to understand how-and-why the characteristics of NPLs are influenced, particularly at elevated temperature, where both reversible and irreversible quenching processes come into picture. Here we present a study on the effect of elevated temperature on the characteristics of colloidal CdSe NPLs. We used an effective-mass envelope function theory based 8-band k$\cdot$p model and density-matrix theory considering exciton-phonon interaction. We observed the photoluminescence (PL) spectra at various temperatures for their photon emission energy, PL linewidth and intensity by considering the exciton-phonon interaction with both acoustic and optical phonons using Bose-Einstein statistical factors. With rise in temperature we observed a fall in the transition energy (emission redshift), matrix element, Fermi factor and quasi Fermi separation, with reduction in intraband state gaps and increased interband coupling. Also, there was a fall in the PL intensity, along with spectral broadening due to an intraband scattering effect. The predicted transition energy values and simulated PL spectra at varying temperatures exhibit appreciable consistency with experimental results. Our findings have important implications for application of NPLs in optoelectronic devices, such as NPL lasers and LEDs, operating much above room temperature.

cond-mat.mes-hall↗