arXiv subjects

Vipin Kumar Singh

Publications and source records attributed to Vipin Kumar Singh.

9 recordsLinked to original sources

arXiv2026

Can Legal AI Know When It Is Wrong? And Do Students Know When It Is?

Integrating Large Language Models (LLMs) into the Indian judiciary promises access to justice but introduces severe risks. We identify the 'inertia of confidence'--an overconfidence phenomenon analogous to the Dunning-Kruger effect where LLMs provide incorrect legal verdicts with near-maximum confidence, driven by a hypothesized 'precedent overfitting' bias. Phase I of our socio-technical audit tested ChatGPT (GPT-5.2), Meta AI, and Perplexity AI on a 60-case battery regarding the Indian Contract Act, 1872, and the shift toward statutory enforcement of specific performance. We introduce the High-Confidence Error Rate (HCER) to quantify incorrect verdicts delivered with dangerous certainty (>= 9 on a 1-10 scale). All models struggled with statutory updates. Meta AI proved most vulnerable (31.7% HCER), frequently misapplying pre-amendment rules with a 9.1/10 mean confidence, followed by Perplexity (15.0%) and ChatGPT (6.7%). Phase II investigated human vulnerability to this overconfidence via a survey of Indian law students (N=380). Verification often functions as a reactive adaptation to machine hallucinations: students encountering fabricated citations reported higher verification scores (4.2/5) than those with no such encounters (2.8/5). Furthermore, while 81.6% knew submitting hallucinated cases can lead to contempt-of-court, 71.1% received no formal training on ethical AI use. We propose shifting toward adversarial legal research pedagogy and implementing source-grounded verification architectures to prevent systemic professional negligence.

cs.AI↗

arXiv2025

Magnetic Manipulation of Spatially Confined Multiferroic Heuslers by Martensitic Microstructure Engineering

Magnetic shape-memory (MSM) Heuslers show a strong coupling between magnetic and structural characteristics, evidencing a correlation between magnetic, thermal, and mechanical properties through a magnetostructural martensitic transformation. This functional aspect makes MSM Heuslers promising for integration into smart micro/nanodevices, including sensors, energy harvesters, and actuators. Controlling the martensitic microstructure, which determines the magnetic characteristics, is among the key points for optimization of the magnetic functional properties of these materials at different length scales. Here, we report a strategy for manipulating the magnetic properties of spatially confined epitaxial Ni-Mn-Ga films grown on Cr(001)//MgO(001) by twinning configuration engineering in the low-temperature ferromagnetic (martensitic) phase. We show how the twinning configurations in the continuous films and the micropatterned structures can be switched from Y-type (showing negligible magnetic stray field) into X-type (presenting significant magnetic stray field) by a post-annealing process. Advanced characterization techniques enable us to analyze the atomic structure and the surface quality of the annealed samples and to disentangle the twin-switching phenomenon. The martensitic microstructure engineering reported in this study introduces a simple method for promoting the magnetic stray-field contribution at the surface of Ni-Mn-Ga epitaxial thin films and micropatterns initially showing a negligible magnetic stray field.

cond-mat.mtrl-sci↗

arXiv2023

Bulk Electronic Structure of Ni2MnGa studied by Density Functional Theory and Hard X-ray Photoelectron Spectroscopy

A combined study employing density functional theory (DFT) using the experimentally determined modulated structures and bulk-sensitive hard x-ray photoelectron spectroscopy on single-crystalline Ni$_2$MnGa is presented in this work. For the aforementioned modulated structures, all of the characteristic features in the experimental valence band (VB) are in excellent agreement with the theoretical VB calculated from DFT, evincing that it is the true representation of Ni$_2$MnGa in the martensite phase. We establish the existence of a charge density wave (CDW) state in the martensite phase from the shape of the VB near $E_F$ that shows a transfer of spectral weight in excellent agreement with DFT. Furthermore, presence of a pseudogap is established by fitting the near $E_F$ region with a power law function predicted theoretically for the CDW phase. Thus, the present work emphasizes that the atomic modulation plays an important role in hosting the CDW phase in bulk stoichiometric Ni$_2$MnGa.

cond-mat.mtrl-sci↗

arXiv2022

Decagonal Sn clathrate on $d$-Al-Ni-Co

Decagonal quasiperiodic ordering of Sn thin film on $d$-Al-Ni-Co, is shown based on scanning tunneling microscopy (STM), low-energy electron diffraction and density functional theory (DFT). Interestingly, the decagonal structural correlations are partially retained up to a large film thickness of 10 nm grown at a 165$\pm$10 K. The nucleation centers called 'Sn white flowers' identified by STM at submonolayer thickness are recognized as valid patches of the decagonal clathrate structure with low adsorption energies. Due to the excellent lattice matching (to within 1%) between columns of Sn dodecahedra in the clathrate structure and pentagonal motifs at the $d$-Al-Ni-Co surface, the interfacial energy favors clathrate over the competing Sn crystalline forms. DFT study of the Sn/Al-Ni-Co composite model shows good mechanical stability, as shown by the work of separation of Sn from Al-Ni-Co slab that is comparable to clathrate self-separation energy. The relaxed surface terminations of the R$_2$T$_4$ clathrate approximant are in self-similarity correspondence with the motifs observed in the STM images from monolayer to thickest Sn film.

cond-mat.mtrl-sci↗

arXiv2022

Charge density wave induced nodal lines in LaTe$_3$

LaTe$_3$ is a noncentrosymmetric (NC) material with time reversal (TR) symmetry in which the charge density wave (CDW) is hosted by the Te bilayers. Here, we show that LaTe$_3$ hosts a Kramers nodal line (KNL), a twofold degenerate nodal line that connects the TR invariant momenta in NC achiral systems, using angle resolved photoemission spectroscopy (ARPES), density functional theory (DFT), effective band structure (EBS) calculated by band unfolding, and symmetry arguments. DFT incorporating spin-orbit coupling (SOC) reveals that the KNL -- protected by the TR and lattice symmetries -- imposes gapless crossings between the bilayer-split CDW-induced shadow bands and the main bands. In excellent agreement with the EBS, ARPES data corroborate the presence of the KNL and show that the crossings traverse the Fermi level. Furthermore, spinless nodal lines - entirely gapped out by the SOC - are formed by the linear crossings of the shadow and main bands with a high Fermi velocity.

cond-mat.mtrl-sci↗

arXiv2020

Quasiperiodic ordering in thick Sn layer on $i$-Al-Pd-Mn: A possible quasicrystalline clathrate

Realization of an elemental solid-state quasicrystal has remained a distant dream so far in spite of extensive work in this direction for almost two decades. Here, we report the discovery of quasiperiodic ordering in a thick layer of elemental Sn grown on icosahedral ($i$)-Al-Pd-Mn. The STM images and the LEED patterns of the Sn layer show specific structural signatures that portray quasiperiodicity but are distinct from the substrate. Photoemission spectroscopy reveals the existence of the pseudogap around the Fermi energy up to the maximal Sn thickness. The structure of the Sn layer is modeled as a novel form of quasicrystalline clathrate on the basis of the following: Firstly, from ab-initio theory, the energy of bulk Sn clathrate quasicrystal is lower than the high temperature metallic $β$-Sn phase, but higher than the low temperature $α$-Sn phase. A comparative study of the free slab energetics shows that surface energy favors clathrate over $α$-Sn up to about 4 nm layer thickness, and matches $β$-Sn for narrow window of slab thickness of 2-3 nm. Secondly, the bulk clathrate exhibits gap opening near Fermi energy, while the free slab form exhibits a pronouced pseudogap, which explains the pseudogap observed in photoemission. Thirdly, the STM images exhibit good agreement with clathrate model. We establish the adlayer-substrate compatibility based on very similar (within 1%) the cage-cage separation in the Sn clathrate and the pseudo-Mackay cluster-cluster separation on the $i$-Al-Pd-Mn surface. Furthermore, the nucleation centers of the Sn adlayer on the substrate are identified and these are shown to be a valid part of the Sn clathrate structure. Thus, based on both experiment and theory, we propose that 4 nm thick Sn adlayer deposited on 5-fold surface of $i$-Al-Pd-Mn substrate is in fact a metastable realization of elemental, clathrate family quasicrystal.

cond-mat.other↗

arXiv2019

Electronic structure of Au-Sn compounds grown on Au(111)

The electronic structure of Au-Sn intermetallic layers of different compositions grown on Au(111) to the thickness of several nanometers has been studied in this work. The layer, interface and the substrate related components in the Au 4$f$ and Sn 4$d$ core-level spectra obtained using x-ray photoelectron spectroscopy (XPS) vary with deposition parameters to reveal the details of the Au-Sn formation. While AuSn is grown by deposition at room temperature, Au rich compounds form as a result of heat treatment through inter diffusion of Au and Sn. Deposition at high temperature forms more Au rich compositions compared to post annealing at the same temperature due to the kinetic energy of the impinging Sn atoms in the former case. Post annealing, on the other hand, stabilizes the bulk phases such as AuSn and Au$_5$Sn and exhibits an activated behavior for transition from the former to the latter with increasing temperature. The XPS valence band spectra of AuSn and Au$_{5}$Sn layers show good agreement with the density functional theory calculation, indicating that these have the bulk structure reported in literature. However, the influence of anti-site defects is observed in Au$_5$Sn. Low energy electron diffraction study reveals that although the AuSn layer is ordered, its top surface is disordered at room temperature. Surface order is obtained by annealing or deposition at elevated temperatures and dispersing bands are observed by angle resolved photoemission spectroscopy. Both electron-like and hole-like bands are evident for the ($\sqrt{3}$$\times$$\sqrt{3}$)R30$^{\circ}$ phase, while a nearly free electron-like parabolic surface state is observed for the p(3$\times$3)R15$^{\circ}$ phase.

cond-mat.mtrl-sci↗

arXiv2018

Dirac cone in a non-honeycomb surface alloy

We demonstrate unexpected occurrence of linear bands resembling Dirac cone at the zone-center of Au$_2$Sn surface alloy with $\left( \begin{smallmatrix} 2&1\\ 1&3 \end{smallmatrix} \right)$ surface structure formed by deposition of about 0.9 ML Sn on Au(111) at elevated temperature. The surface exhibits an oblique symmetry with unequal lattice constants making it the first two dimensional surface alloy to exhibit Dirac cone with a non-honeycomb lattice.

cond-mat.mtrl-sci↗

arXiv2018

Influence of anti-site disorder and electron-electron correlations on the electronic structure of CeMnNi$_4$

CeMnNi$_4$ exhibits an unusually large spin polarization, but its origin has baffled researchers for more than a decade. We use bulk sensitive hard x-ray photoelectron spectroscopy (HAXPES) and density functional theory based on the Green's function technique to demonstrate the importance of electron-electron correlations of both the Ni 3$d$ ($U_{Ni}$) and Mn 3$d$ ($U_{Mn}$) electrons in explaining the valence band of this multiply correlated material. We show that Mn-Ni anti-site disorder as well as $U_{Ni}$ play crucial role in enhancing its spin polarization: anti-site disorder broadens a Ni 3$d$ minority-spin peak close to the Fermi level ($E_F$), while an increase in $U_{Ni}$ shifts it towards $E_F$, both leading to a significant increase of minority-spin states at $E_F$. Furthermore, rare occurrence of a valence state transition between the bulk and the surface is demonstrated highlighting the importance of HAXPES in resolving the electronic structure of materials unhindered by surface effects.

cond-mat.mtrl-sci↗