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Vittal Prakasam

Publications and source records attributed to Vittal Prakasam.

2 recordsLinked to original sources

A Heterogeneous 200 mm Silicon Nitride Photonics Platform for Visible-to-Near-Infrared Applications via Micro-Transfer Printing

The commercialization of next-generation technologies, including optical interconnects, quantum computing, AR/VR, and medical diagnostics, requires a low-loss photonic platform offering compact, multifunctional systems in the visible and near-infrared range. Although silicon nitride (SiN) is an excellent material due to its ultra-low loss and broad transparency window, integrating active components such as light sources, modulators and photodetectors from diverse material platforms in a scalable, reliable way remains challenging. Micro-transfer printing is an emerging wafer-scale heterogeneous integration technology that can be implemented as a back-end post-processing step without disrupting the primary in-line fabrication process. In this work, we present a dual LPCVD SiN layer platform fabricated in a 200 mm CMOS pilot line, that incorporates micro-transfer printing modules, allowing the integration of active components on well defined recesses. A hydrogenated amorphous silicon layer is also available to increase the versatility of the platform allowing for evanescently-coupled III-V lasers as well as other passive functionality in the near-infrared region. We report full wafer-scale measurements showing low optical SiN losses of 4 dB/cm and 0.23 dB/cm at a wavelength of 488 nm and 940 nm respectively. In addition, a transition loss of only 0.35 dB is obtained from the SiN to the a-Si:H layer, in good agreement with simulated values. Finally, to showcase more advanced functionality, GaAs-based gain sections are micro-transfer printed on several dies, achieving consistent die-to-die lasing at 970 nm with on-chip optical powers of approximately 1 mW. These results showcase the potential of the integrated photonics platform towards unlocking a wide range of new applications in the sub-1-$\mu$m spectral region.

physics.optics

Texture Formation in Polycrystalline Thin Films of All-Inorganic Lead Halide Perovskite

Controlling grain orientations within polycrystalline all-inorganic halide perovskite solar cells can help increase conversion efficiencies toward their thermodynamic limits, however the forces governing texture formation are ambiguous. Using synchrotron X-ray diffraction, we report meso-structure formation within polycrystalline CsPbI2.85Br0.15 powders as they cool from a high-temperature cubic perovskite (α-phase). Tetragonal distortions (\b{eta}-phase) trigger preferential crystallographic alignment within polycrystalline ensembles, a feature we suggest is coordinated across multiple neighboring grains via interfacial forces that select for certain lattice distortions over others. External anisotropy is then imposed on polycrystalline thin films of orthorhombic (γ-phase) CsPbI3-xBrx perovskite via substrate clamping, revealing two fundamental uniaxial texture formations; (i) I-rich films possess orthorhombic-like texture (<100> out-of-plane; <010> and <001> in-plane), while (ii) Br-rich films form tetragonal-like texture (<110> out-of-plane; <1-10> and <001> in-plane). In contrast to relatively uninfluential factors like the choice of substrate, film thickness and annealing temperature, Br incorporation modifies the γ-CsPbI3-xBrx crystal structure by reducing the orthorhombic lattice distortion (making it more tetragonal-like) and governs the formation of the different, energetically favored textures within polycrystalline thin films.

cond-mat.mtrl-sci