arXiv subjects

Vladimir Pomjakushin

Publications and source records attributed to Vladimir Pomjakushin.

41 records · Page 3Linked to original sources

arXiv2013

Microscopic studies of the normal and superconducting state of Ca3Ir4Sn13

We report on muon spin rotation (muSR) studies of the superconducting and magnetic properties of the ternary intermetallic stannide Ca3Ir4Sn13. This material has recently been the focus of intense research activity due to a proposed interplay of ferromagnetic spin fluctuations and superconductivity. In the temperature range T=1.6-200 K, we find that the zero-field muon relaxation rate is very low and does not provide evidence for spin fluctuations on the muSR time scale. The field-induced magnetization cannot be attributed to localized magnetic moments. In particular, our muSR data reveal that the anomaly observed in thermal and transport properties at T*~38 K is not of magnetic origin. Results for the transverse-field muon relaxation rate at T=0.02-12 K, suggest that superconductivity emerges out of a normal state that is not of a Fermi-liquid type. This is unusual for an electronic system lacking partially filled f-electron shells. The superconducting state is dominated by a nodeless order parameter with a London penetration depth of lambda=385(1) nm and the electron-phonon pairing interaction is in the strong-coupling limit.

cond-mat.supr-con↗

arXiv2011

The effect of compressive strain on the Raman modes of the dry and hydrated BaCe0.8Y0.2O3 proton conductor

The BaCe0.8Y0.2O3-δ proton conductor under hydration and under compressive strain has been analyzed with high pressure Raman spectroscopy and high pressure x-ray diffraction. The pressure dependent variation of the Ag and B2g bending modes from the O-Ce-O unit is suppressed when the proton conductor is hydrated, affecting directly the proton transfer by locally changing the electron density of the oxygen ions. Compressive strain causes a hardening of the Ce-O stretching bond. The activation barrier for proton conductivity is raised, in line with recent findings using high pressure and high temperature impedance spectroscopy. The increasing Raman frequency of the B1g and B3g modes thus implies that the phonons become hardened and increase the vibration energy in the a-c crystal plane upon compressive strain, whereas phonons are relaxed in the b-axis, and thus reveal softening of the Ag and B2g modes. Lattice toughening in the a-c crystal plane raises therefore a higher activation barrier for proton transfer and thus anisotropic conductivity. The experimental findings of the interaction of protons with the ceramic host lattice under external strain may provide a general guideline for yet to develop epitaxial strained proton conducting thin film systems with high proton mobility and low activation energy.

cond-mat.mtrl-sci↗

arXiv2011

Structural Evolution of One-dimensional Spin Ladder Compounds Sr14-xCaxCu24O41 with Ca doping and Related Hole Redistribution Evidence

Incommensurate crystal structures of spin ladder series Sr14-xCaxCu24O41 (x=3, 7, 11, 12.2) were characterized by powder neutron scattering method and refined using the superspace group Xmmm(00γ)ss0 (equivalent to superspace group Fmmm(0,0,1+γ)ss0); X stands for non-standard centering (0,0,0,0), (0,1/2,1/2,1/2), (1/2,1/2,0,0), (1/2,0,1/2,1/2)) with a modulated structure model. The Ca doping effects on the lattice parameters, atomic displacement, Cu-O distances, Cu-O bond angles and Cu bond valence sum were characterized. The refined results show that the CuO4 planar units in both chain and ladder sublattices become closer to square shape with an increase of Ca doping. The Cu bond valence sum calculation provided new evidence for the charge transfer from the chains to ladders (approximately 0.16 holes per Cu from x=0 to 12.2). The charge transfer was attributed to two different mechanisms: (a) the Cu-O bond distance shrinkage on the ladder; (b) increase of the interaction between two sublattices, resulting in Cu-O bonding between the chains and ladders. The low temperature structural refinement resulted in the similar conclusion, with a slight charge backflow to the chains.

cond-mat.supr-con↗

arXiv2009

Synthesis, crystal structure and chemical stability of the superconductor FeSe_{1-x}

We report on a comparative study of the crystal structure and the magnetic properties of FeSe1-x (x= 0.00 - 0.15) superconducting samples by neutron powder diffraction and magnetization measurements. The samples were synthesized by two different methods: a 'low-temperature' one using powders as a starting material at T =700 C and a "high-temperature' method using solid pieces of Fe and Se at T= 1070 C. The effect of a starting (nominal) stoichiometry on the phase purity of the obtained samples, the superconducting transition temperature Tc, as well as the chemical instability of FeSe1-x at ambient conditions were investigated. It was found that in the Fe-Se system a stable phase exhibiting superconductivity at Tc~8K exists in a narrow range of selenium concentration (FeSe0.974(2)).

cond-mat.supr-con↗

arXiv2006

Absence of Long Range Magnetic Order in the La1.4Sr0.8Ca0.8Mn2O7 Bilayered Manganite

In this work we studied, by means of high-resolution neutron diffraction as a function of temperature, the La1.4Sr0.8Ca0.8Mn2O7 bilayered manganite for two different annealing treatments. Out data allowed us to shown, for the first time, the absence of long-range magnetic order in this optimally doped bilayered manganite where the A-site of the structure is doped with equal proportions of different isovalent cations (Ca and Sr). The system, however, presents defined IM transitions which suggest that the transport properties are not linked to the evolution of long-range order and that two dimensional spin ordering in the layers of the perovskite blocks may be sufficient to 'assist' the hole hopping. Possible reason for the suppression of magnetic order induced by the Ca doping is a size effect coupled to the cation size mismatch between the Sr and Ca ions.

cond-mat.mtrl-sci↗