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Vladimir Y. Chernyak

Publications and source records attributed to Vladimir Y. Chernyak.

At least 37 records · Page 2Linked to original sources

Ensemble Control of Cycling Energy Loads: Markov Decision Approach

A Markov decision process (MDP) framework is adopted to represent ensemble control of devices with cyclic energy consumption patterns, e.g., thermostatically controlled loads. Specifically we utilize and develop the class of MDP models previously coined linearly solvable MDPs, that describe optimal dynamics of the probability distribution of an ensemble of many cycling devices. Two principally different settings are discussed. First, we consider optimal strategy of the ensemble aggregator balancing between minimization of the cost of operations and minimization of the ensemble welfare penalty, where the latter is represented as a KL-divergence between actual and normal probability distributions of the ensemble. Then, second, we shift to the demand response setting modeling the aggregator's task to minimize the welfare penalty under the condition that the aggregated consumption matches the targeted time-varying consumption requested by the system operator. We discuss a modification of both settings aimed at encouraging or constraining the transitions between different states. The dynamic programming feature of the resulting modified MDPs is always preserved; however, `linear solvability' is lost fully or partially, depending on the type of modification. We also conducted some (limited in scope) numerical experimentation using the formulations of the first setting. We conclude by discussing future generalizations and applications.

eess.SY↗

Exciton Scattering via Algebraic Topology

This paper introduces an intersection theory problem for maps into a smooth manifold equipped with a stratification. We investigate the problem in the special case when the target is the unitary group and the domain is a circle. The first main result is an index theorem that equates a global intersection index with a finite sum of locally defined intersection indices. The local indices are integers arising from the geometry of the stratification. The result is used to study a well-known problem in chemical physics, namely, the problem of enumerating the electronic excitations (excitons) of a molecule equipped with scattering data. We provide a lower bound for this number. The bound is shown to be sharp in a limiting case.

math.AT↗

Multistate Landau-Zener models with all levels crossing at one point

We discuss common properties and reasons for integrability in the class of multistate Landau-Zener (MLZ) models with all diabatic levels crossing at one point. Exploring the Stokes phenomenon, we show that each previously solved model has a dual one, whose scattering matrix can be also obtained analytically. For applications, we demonstrate how our results can be used to study conversion of molecular into atomic Bose condensates during passage through the Feshbach resonance, and provide purely algebraic solutions of the bowtie and special cases of the driven Tavis-Cummings model (DTCM).

quant-ph↗

A higher Boltzmann distribution

We characterize the classical Boltzmann distribution as the unique solution to a certain combinatorial Hodge theory problem in homological degree zero on a finite graph. By substituting for the graph a CW complex and a degree d, we are able to define, by direct analogy, a higher dimensional Boltzmann distribution as a certain (d-1)-cycle on the real cellular chain complex which is characterized by appropriate constraints. We then give an explicit formula for this cycle. We explain how this circle of ideas relates to the authors' Higher Kirchhoff Network Theorem. We also give an improved version of the authors' Higher Matrix-Tree Theorems.

math.AT↗

The Quest for Solvable Multistate Landau-Zener Models

Recently, integrability conditions (ICs) in mutistate Landau-Zener (MLZ) theory were proposed [1]. They describe common properties of all known solved systems with linearly time-dependent Hamiltonians. Here we show that ICs enable efficient computer assisted search for new solvable MLZ models that span complexity range from several interacting states to mesoscopic systems with many-body dynamics and combinatorially large phase space. This diversity suggests that nontrivial solvable MLZ models are numerous. In addition, we refine the formulation of ICs and extend the class of solvable systems to models with points of multiple diabatic level crossing.

quant-ph↗

Discriminating Cascading Processes in Nonlinear Optics; A QED Analysis Based on Their Molecular and Geometric Origin

The nonlinear optical response of a system of molecules often contains contributions whereby the products of lower-order processes in two separate molecules give signals that appear on top of a genuine direct higher-order process with a single molecule. These many-body contributions are known as cascading and complicate the interpretation of multidimensional stimulated Raman and other nonlinear signals. In a quantum electrodynamic (QED) treatment, these cascading processes arise from second-order expansion in the molecular coupling to vacuum modes of the radiation field, i.e., single-photon exchange between molecules, which also gives rise to other collective effects. We predict the relative phase of the direct and cascading nonlinear signals and its dependence on the microscopic dynamics as well as the sample geometry. This phase may be used to identify experimental conditions for distinguishing the direct and cascading signals by their phase. Higher-order cascading processes involving the exchange of several photons between more than two molecules are discussed as well.

quant-ph↗

Excited-State Structure Modifications Due to Molecular Substituents and Exciton Scattering in Conjugated Molecules

Attachment of chemical substituents (such as polar moieties) constitutes an efficient and convenient way to modify physical and chemical properties of conjugated polymers and oligomers. Associated modifications in the molecular electronic states can be comprehensively described by examining scattering of excitons in the polymer's backbone at the scattering center representing the chemical substituent. Here, we implement effective tight-binding models as a tool to examine the analytical properties of the exciton scattering matrices in semi-infinite polymer chains with substitutions. We demonstrate that chemical interactions between the substitution and attached polymer are adequately described by the analytical properties of the scattering matrices. In particular, resonant and bound electronic excitations are expressed via the positions of zeros and poles of the scattering amplitude, analytically continued to complex values of exciton quasi-momenta. We exemplify the formulated concepts by analyzing excited states in conjugated phenylacetylenes substituted by perylene.

physics.chem-ph↗

Counting the number of excited states in organic semiconductor systems using topology

Exciton Scattering (ES) theory attributes excited electronic states to standing waves in quasi-one-dimensional molecular materials by assuming a quasi-particle picture of optical excitations. The quasi-particle properties at branching centers are described by the corresponding scattering matrices. Here we identify the topological invariant of scattering center, referred to as its winding number, and apply topological intersection theory to count the number of quantum states in a quasi-one-dimensional system.

physics.chem-ph↗

Stochastic Dynamics of Extended Objects in Driven Systems II: Current Quantization in the Low-Temperature Limit

Driven Langevin processes have appeared in a variety of fields due to the relevance of natural phenomena having both deterministic and stochastic effects. The stochastic currents and fluxes in these systems provide a convenient set of observables to describe their non-equilibrium steady states. Here we consider stochastic motion of a (k - 1)-dimensional object, which sweeps out a k-dimensional trajectory, and gives rise to a higher k-dimensional current. By employing the low-temperature (low-noise) limit, we reduce the problem to a discrete Markov chain model on a CW complex, a topological construction which generalizes the notion of a graph. This reduction allows the mean fluxes and currents of the process to be expressed in terms of solutions to the discrete Supersymmetric Fokker-Planck (SFP) equation. Taking the adiabatic limit, we show that generic driving leads to rational quantization of the generated higher dimensional current. The latter is achieved by implementing the recently developed tools, coined the higher-dimensional Kirchhoff tree and co-tree theorems. This extends the study of motion of extended objects in the continuous setting performed in the prequel to this manuscript.

physics.chem-ph↗

Stochastic Dynamics of Extended Objects in Driven Systems: I. Higher-Dimensional Currents in the Continuous Setting

The probability distributions, as well as the mean values of stochastic currents and fluxes, associated with a driven Langevin process, provide a good and topologically protected measure of how far a stochastic system is driven out of equilibrium. By viewing a Langevin process on a compact oriented manifold of arbitrary dimension m as a theory of a random vector field associated with the environment, we are able to consider stochastic motion of higher-dimensional objects, which allow new observables, called higher-dimensional currents, to be introduced. These higher dimensional currents arise by counting intersections of a k-dimensional trajectory, produced by a evolving (k-1)-dimensional cycle, with a reference cross section, represented by a cycle of complimentary dimension (m - k). We further express the mean fluxes in terms of the solutions of the Supersymmetric Fokker-Planck (SFP), thus generalizing the corresponding well-known expressions for the conventional currents.

physics.chem-ph↗

Linear PDEs and eigenvalue problems corresponding to ergodic stochastic optimization problems on compact manifolds

We consider long term average or `ergodic' optimal control poblems with a special structure: Control is exerted in all directions and the control costs are proportional to the square of the norm of the control field with respect to the metric induced by the noise. The long term stochastic dynamics on the manifold will be completely characterized by the long term density $ρ$ and the long term current density $J$. As such, control problems may be reformulated as variational problems over $ρ$ and $J$. We discuss several optimization problems: the problem in which both $ρ$ and $J$ are varied freely, the problem in which $ρ$ is fixed and the one in which $J$ is fixed. These problems lead to different kinds of operator problems: linear PDEs in the first two cases and a nonlinear PDE in the latter case. These results are obtained through through variational principle using infinite dimensional Lagrange multipliers. In the case where the initial dynamics are reversible we obtain the result that the optimally controlled diffusion is also symmetrizable. The particular case of constraining the dynamics to be reversible of the optimally controlled process leads to a linear eigenvalue problem for the square root of the density process.

math.OC↗

Non-linear non-local molecular electrodynamics with nano-optical fields

The interaction of optical fields sculpted on the nano-scale with matter may not be described by the dipole approximation since the fields vary appreciably across the molecular length scale. Rather than incrementally adding higher multipoles it is advantageous and more physically transparent to describe the optical process using non-local response functions that intrinsically include all multipoles. We present a semi-classical approach to the non-linear response functions based on the minimal coupling Hamiltonian. The first, second and third order non-local response functions are expressed in terms of correlation functions of the charge and the current densities. This approach is based on the gauge invariant current rather than the polarization, and on the vector potential rather than the electric and magnetic fields.

quant-ph↗

Low-Temperature Hopping Dynamics with Energy Disorder: Renormalization Group Approach

We formulate a real-space renormalization group (RG) approach for efficient numerical analysis of the low-temperature hopping dynamics in energy-disordered lattices. The approach explicitly relies on the time-scale separation of the trapping/escape dynamics. This time-scale separation allows to treat the hopping dynamics as a hierarchal process, an RG step being a transformation between the levels of the hierarchy. We apply the proposed RG approach to analyze hopping dynamics in one- and two-dimensional lattices with varying degree of energy disorder, and find the approach to be more accurate at low temperatures and computationally much faster, than the direct diagonalization. Applicability criteria of the proposed approach with respect to the time-scale separation and the maximum number of hierarchy levels are formulated. RG flows of energy distribution and preexponents of the Miller-Abrahams model are analyzed.

cond-mat.mes-hall↗

Stochastic Optimal Control as Non-equilibrium Statistical Mechanics: Calculus of Variations over Density and Current

In Stochastic Optimal Control (SOC) one minimizes the average cost-to-go, that consists of the cost-of-control (amount of efforts), cost-of-space (where one wants the system to be) and the target cost (where one wants the system to arrive), for a system participating in forced and controlled Langevin dynamics. We extend the SOC problem by introducing an additional cost-of-dynamics, characterized by a vector potential. We propose derivation of the generalized gauge-invariant Hamilton-Jacobi-Bellman equation as a variation over density and current, suggest hydrodynamic interpretation and discuss examples, e.g., ergodic control of a particle-within-a-circle, illustrating non-equilibrium space-time complexity.

cond-mat.stat-mech↗

Kirchhoff's theorems in higher dimensions and Reidemeister torsion

Using ideas from algebraic topology and statistical mechanics, we generalize Kirchhoff's network and matrix-tree theorems to finite CW complexes of arbitrary dimension. As an application, we give a formula expressing Reidemeister torsion as an enumeration of higher dimensional spanning trees.

math.AT↗

Algebraic topology and the quantization of fluctuating currents

We give a new approach to the study of statistical mechanical systems: algebraic topology is used to investigate the statistical distributions of stochastic currents generated in graphs. In the adiabatic and low temperature limits we will demonstrate that quantization of current generation occurs.

math.AT↗

Quantization and Fractional Quantization of Currents in Periodically Driven Stochastic Systems I: Average Currents

This article studies Markovian stochastic motion of a particle on a graph with finite number of nodes and periodically time-dependent transition rates that satisfy the detailed balance condition at any time. We show that under general conditions, the currents in the system on average become quantized or fractionally quantized for adiabatic driving at sufficiently low temperature. We develop the quantitative theory of this quantization and interpret it in terms of topological invariants. By implementing the celebrated Kirchhoff theorem we derive a general and explicit formula for the average generated current that plays a role of an efficient tool for treating the current quantization effects.

cond-mat.mes-hall↗