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Vladimir Yu. Rudyak

Publications and source records attributed to Vladimir Yu. Rudyak.

5 recordsLinked to original sources

Rank-dependent optimal resetting in multiparticle search

In many soft-matter and biological systems, task completion relies on the cumulative arrival of multiple searchers rather than the speed of a single pioneer. The completion kinetics are therefore set not only by the first arrival, but by the full ordered sequence of first-passage times. Here, we determine how stochastic resetting optimizes these ordered arrivals for all arrival ranks. We construct an exact finite-$N$ reference for non-interacting Brownian searchers and obtain the mean ordered first-passage time $\langle T_{(k)} \rangle$ and its optimal resetting rate $r_k^*$. For searchers with identical initial conditions, $r_k^*$ increases monotonically with arrival rank and, with increasing population size, approaches the known large-$N$ quantile limit where a finite optimum appears only above a critical rank fraction $ϕ_c \simeq 0.412$. Spatial heterogeneity qualitatively reorganizes this sequence, shifting its maximum from late to early ranks even without particle interactions. We then compare this baseline with Brownian colloid experiments, interacting active Brownian particles, and a collective autochemotactic search with persistent environmental memory. Across these systems, sensitivity to resetting increases strongly with arrival rank, while deviations from appropriate non-interacting references reveal the influence of direct interactions, finite return overhead, and environmental memory. Our results show that optimal resetting in multiparticle search is governed by the required completion rank and must be evaluated relative to protocol- and geometry-matched baselines.

cond-mat.stat-mech

Spatiotemporal Hierarchy of Slow Avalanches During Creep

Far from equilibrium, amorphous solids exhibit structural relaxations that span a vast range of timescales such as physical aging and creep. Recently, it has been shown that such relaxations are driven by via intermittent, scale-free, yet anomalously slow cascades of local rearrangements, termed 'thermal avalanches.' Here, we investigate the spatio-temporal dynamics of these avalanches during logarithmic creep, using simulations of a model amorphous solid. By systematically disentangling mechanical and thermal activation events, we reveal that thermal avalanches have a hierarchical spatio-temporal structure: localized rearrangement events group into fast and compact cascades, which then promote the thermal activation of subsequent cascades via long-range, noise-mediated facilitation. This process results in heavy-tailed temporal correlations reminiscent of seismic activity. We validate these findings using experiments on slow relaxation of crumpled matter. Our work provides a framework for identifying noise-mediated correlations and elucidates the rich structural dynamics underlying slow relaxation of amorphous solids.

cond-mat.soft

Channel Formation Enhances Target Consumption by Chemotactic Active Brownian Particles

In many situations, simply finding a target during a search is not enough. It is equally important to be able to return to that target repeatedly or to enable a larger community to locate and utilize it. While first passage time is commonly used to measure search success, relatively little is known about increasing the average rate of target encounters over time. Here, using an active Brownian particle model with chemotaxis, we demonstrate that when a searcher has no memory and there is no communication among multiple searchers, encoding information about the target's location in the environment outperforms purely memoryless strategies by boosting the overall hit rate. We further show that this approach reduces the impact of target size on a successful search and increases the total utilization time of the target.

cond-mat.soft

Optimal Entanglement of Polymers Promotes Formation of Highly Oriented Fibers

Polymer fibers consist of macromolecules oriented along the fiber axis. Better alignment of chains leads to an increased strength of the fiber. It is believed that the key factor preventing formation of a perfectly oriented fiber is entanglement of polymers. We performed large-scale computer simulations of uniaxial stretching of semicrystalline ultrahigh molecular weight polyethylene. We discovered that there is an optimal number of entanglements per macromolecule necessary to maximize chain orientation in a fiber. Polymers that were entangled too strongly formed less oriented fibers. On the other hand, when polymers had too few entanglements per chain, they disentangled during stretching, and the strong fiber was not formed. We constructed a microscopic analytical theory describing both the fiber formation and disentanglement processes. Our work presents a novel view on the role of entanglements during fiber production and predicts the existence of a single universal optimal number of entanglements per chain maximizing the fiber quality: approximately $10^2$ entanglements.

cond-mat.soft

Core-shell microgels via precipitation polymerization: computer simulations

In this work we presented a novel computational model of precipitation polymerization allowing one to obtain core-shell microgels via a realistic cross-linking process based on the experimental procedure. We showed that the cross-linker-monomer reactivity ratios r are responsible for the microgel internal structure. Values of r lower than 1 correspond to the case when alternating sequences occur at the early reaction stages; this leads to the formation of microgels with pronounced core-shell structure. The distribution of dangling ends for small values of r becomes bimodal with two well-distinguished peaks, which correspond to the core (short dangling ends) and corona (long dangling ends) regions. The density profiles confirm the existence of two distinct regions for small r: a densely cross-linked core and a loose corona entirely consisting of dangling ends with no cross-linker. The consumption of the cross-linker in the course in the microgel formation was found to be in a perfect agreement with the predictions of Monte Carlo (MC) model in the sequence space.

cond-mat.soft