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Volker Hoffmann

Publications and source records attributed to Volker Hoffmann.

4 recordsLinked to original sources

Production of Upgraded Metallurgical Grade (UMG) silicon for a low-cost high-efficiency and reliable PV technology

UMG-Si has the potential to reduce the cost of PV technology and to improve its environmental profile. In this contribution, we summarize the extensive work made in the research and development of UMG technology for PV, which has led to the demonstration of UMG-Si as a competitive alternative to polysilicon for the production of high-efficiency multicrystalline solar cells and modules. The tailoring of the processing steps along the complete Ferrosolar's UMG-Si manufacturing value chain has been addressed, commencing with the purification stage that results in a moderately compensated material due to the presence of phosphorous and boron. Gallium is added as a dopant at the crystallization stage to obtain a uniform resistivity profile 1 Ohm*cm along the ingot height. Defect engineering techniques based on phosphorus diffusion gettering have been optimized to improve the bulk electronic quality of UMG-Si wafers. Black silicon texturing, compatible with subsequent gettering and surface passivation, has been successfully implemented. Industrial-type BSF and PERC solar cells have been fabricated, achieving cell efficiencies in the range of those obtained with conventional polysilicon substrates. TOPCon solar cell processing key steps have also been tested to further evaluate the potential of the material in advanced device architectures beyond PERC. Degradation mechanisms related to light exposure and operation temperature have been shown not to be significant in UMG PERC solar cells when a regeneration step is implemented, and PV modules with several years of outdoor operation have demonstrated similar performance to reference ones based on poly-Si. LCA has been carried out to evaluate the environmental impact of UMG-based PV technology when compared to the poly-Si-based one, considering different scenarios both for the manufacturing sites and the PV installations.

cond-mat.mtrl-sci

Stochasticity & Predictability in Terrestrial Planet Formation

Terrestrial planets are thought to be the result of a vast number of gravitational interactions and collisions between smaller bodies. We use numerical simulations to show that practically identical initial conditions result in a wide array of final planetary configurations. This is a result of the chaotic evolution of trajectories which are highly sensitive to minuscule displacements. We determine that differences between systems evolved from virtually identical initial conditions can be larger than the differences between systems evolved from very different initial conditions. This implies that individual simulations lack predictive power. For example, there is not a reproducible mapping between the initial and final surface density profiles. However, some key global properties can still be extracted if the statistical spread across many simulations is considered. Based on these spreads, we explore the collisional growth and orbital properties of terrestrial planets which assemble from different initial conditions (we vary the initial planetesimal distribution, planetesimal masses, and giant planet orbits). Confirming past work, we find that the resulting planetary systems are sculpted by sweeping secular resonances. Configurations with giant planets on eccentric orbits produce fewer and more massive terrestrial planets on tighter orbits than those with giants on circular orbits. This is further enhanced if the initial mass distribution is biased to the inner regions. In all cases, the outer edge of the system is set by the final location of the $ν_6$ resonance and we find that the mass distribution peaks at the $ν_5$ resonance. Using existing observations, we find that extrasolar systems follow similar trends. Although differences between our numerical modelling and exoplanetary systems remain, we suggest that CoRoT-7, HD 20003, and HD 20781 may host undetected giant planets.

astro-ph.EP

The effect of ISM turbulence on the gravitational instability of galactic discs

We investigate the gravitational instability of galactic discs, treating stars and cold interstellar gas as two distinct components, and taking into account the phenomenology of turbulence in the interstellar medium (ISM), i.e. the Larson-type scaling relations observed in the molecular and atomic gas. Besides deriving general properties of such systems, we analyse a large sample of galaxies from The HI Nearby Galaxy Survey (THINGS), and show in detail how interstellar turbulence affects disc instability in star-forming spirals. We find that turbulence has a significant effect on both the inner and the outer regions of the disc. In particular, it drives the inner gas disc to a regime of transition between two instability phases and makes the outer disc more prone to star-dominated instabilities.

astro-ph.CO

Direct Low Temperature Nano-Graphene Synthesis over a Dielectric Insulator

Graphene ranks highly as a possible material for future high-speed and flexible electronics. Current fabrication routes, which rely on metal substrates, require post synthesis transfer of the graphene onto a Si wafer or in the case of epitaxial growth on SiC, temperatures above 1000 °C are required. Both the handling difficulty and high temperatures are not best suited to present day silicon technology. We report a facile chemical vapor deposition approach in which nano-graphene and few layer graphene is directly formed over magnesium oxide and can be achieved at temperatures as low as 325 °C.

cond-mat.mes-hall