arXiv subjects

Volker Schmidt

Publications and source records attributed to Volker Schmidt.

48 records · Page 3Linked to original sources

arXiv2018

Estimation of geodesic tortuosity and constrictivity in stationary random closed sets

We investigate the problem of estimating geodesic tortuosity and constrictivity as two structural characteristics of stationary random closed sets. They are of central importance for the analysis of effective transport properties in porous or composite materials. Loosely speaking, geodesic tortuosity measures the windedness of paths whereas the notion of constrictivity captures the appearance of bottlenecks resulting from narrow passages within a given materials phase. We first provide mathematically precise definitions of these quantities and introduce appropriate estimators. Then, we show strong consistency of these estimators for unboundedly growing sampling windows. In order to apply our estimators to real datasets, the extent of edge effects needs to be controlled. This is illustrated using a model for a multi-phase material that is incorporated in solid oxid fuel cells.

math.ST↗

arXiv2018

Characterization of the 3D microstructure of Ibuprofen tablets by means of synchrotron tomography

We present a methodology to characterize the 3D microstructure of Ibuprofen tablets, which strongly influences the strength and solubility kinetics of the final formulation, by means of synchrotron tomography. A physically coherent trinarization for greyscale images of Ibuprofen tablets consisting of the three phases microcrystalline cellulose, Ibuprofen and pores is presented. For this purpose, a hybrid approach is developed combining a trinarization by means of statistical learning with a trinarization based on a watershed algorithm. This hybrid approach allows us to compute microstructure characteristics of tablets using image analysis. A comparison with experimental results shows that there is a significant amount of pores which is below the resolution limit and results from image analysis let us conjecture that these pores make up the major part of the surface between pores and solid. Furthermore, we compute microstructure characteristics, which are experimentally not accessible such as local percolation probabilities and chord length distribution functions. Both characteristics are meaningful in order to quantify the influence of tablet compaction on its microstructure. The presented approach can be used to get better insights into the relationship between production parameters and microstructure characteristics based on 3D image data of Ibuprofen tablets manufactured under different conditions.

cond-mat.mtrl-sci↗

arXiv2018

Description of ore particles from XMT images, supported by SEM-based image analysis

In this paper, 3D image data of ore particle systems is investigated. By combining X-ray micro tomography (XMT) with scanning electron microscope (SEM) based image analysis additional information about the mineralogical composition from certain planar sections can be gained. For the analysis of tomographic images of particle systems the extraction of single particles is essential. This is performed with a marker-based watershed algorithm and a post-processing step utilizing a neural network to reduce oversegmentation. The results are validated by comparing the 3D particle-wise segmentation empirically with 2D SEM images which have been obtained with a different imaging process and segmentation algorithm. Finally, a stereological application is shown, in which planar SEM images are embedded into the tomographic 3D image. This allows the estimation of local X-ray attenuation coefficients, which are material-specific quantities, in the entire tomographic image.

eess.IV↗

arXiv2018

MULTIBAT: Unified workflow for fast electrochemical 3D simulations of lithium-ion cells combining virtual stochastic microstructures, electrochemical degradation models and model order reduction

We present a simulation workflow for efficient investigations of the interplay between 3D lithium-ion electrode microstructures and electrochemical performance, with emphasis on lithium plating. Our approach addresses several challenges. First, the 3D microstructures of porous electrodes are generated by a parametric stochastic model, in order to significantly reduce the necessity of tomographic imaging. Secondly, we integrate a consistent microscopic, 3D spatially-resolved physical model for the electrochemical behavior of the lithium-ion cells taking lithium plating and stripping into account. This highly non-linear mathematical model is solved numerically on the complex 3D microstructures to compute the transient cell behavior. Due to the complexity of the model and the considerable size of realistic microstructures even a single charging cycle of the battery requires several hours computing time. This renders large scale parameter studies extremely time consuming. Hence, we develop a mathematical model order reduction scheme. We demonstrate how these aspects are integrated into one unified workflow, which is a step towards computer aided engineering for the development of more efficient lithium-ion cells.

math.NA↗

arXiv2018

Stochastic model for the 3D microstructure of pristine and cyclically aged cathodes in Li-ion batteries

It is well-known that the microstructure of electrodes in lithium-ion batteries strongly affects their performance. Vice versa, the microstructure can exhibit strong changes during the usage of the battery due to aging effects. For a better understanding of these effects, mathematical analysis and modeling has turned out to be of great help. In particular, stochastic 3D microstructure models have proven to be a powerful and very flexible tool to generate various kinds of particle-based structures. Recently, such models have been proposed for the microstructure of anodes in lithium-ion energy and power cells. In the present paper, we describe a stochastic modeling approach for the 3D microstructure of cathodes in a lithium-ion energy cell, which differs significantly from the one observed in anodes. The model for the cathode data enhances the ideas of the anode models, which have been developed so far. It is calibrated using 3D tomographic image data from pristine as well as two aged cathodes. A validation based on morphological image characteristics shows that the model is able to realistically describe both, the microstructure of pristine and aged cathodes. Thus, we conclude that the model is suitable to generate virtual, but realistic microstructures of lithium-ion cathodes.

cond-mat.mtrl-sci↗

arXiv2015

Fitting Laguerre tessellation approximations to tomographic image data

The analysis of polycrystalline materials benefits greatly from accurate quantitative descriptions of their grain structures. Laguerre tessellations approximate such grain structures very well. However, it is a quite challenging problem to fit a Laguerre tessellation to tomographic data, as a high-dimensional optimization problem with many local minima must be solved. In this paper, we formulate a version of this optimization problem that can be solved quickly using the cross-entropy method, a robust stochastic optimization technique that can avoid becoming trapped in local minima. We demonstrate the effectiveness of our approach by applying it to both artificially generated and experimentally produced tomographic data.

cond-mat.mtrl-sci↗

arXiv2014

Asymptotic goodness-of-fit tests for the Palm mark distribution of stationary point processes with correlated marks

We consider spatially homogeneous marked point patterns in an unboundedly expanding convex sampling window. Our main objective is to identify the distribution of the typical mark by constructing an asymptotic $χ^2$-goodness-of-fit test. The corresponding test statistic is based on a natural empirical version of the Palm mark distribution and a smoothed covariance estimator which turns out to be mean square consistent. Our approach does not require independent marks and allows dependences between the mark field and the point pattern. Instead we impose a suitable $β$-mixing condition on the underlying stationary marked point process which can be checked for a number of Poisson-based models and, in particular, in the case of geostatistical marking. In order to study test performance, our test approach is applied to detect anisotropy of specific Boolean models.

math.ST↗

arXiv2012

Non-parametric asymptotic statistics for the Palm mark distribution of β-mixing marked point processes

We consider spatially homogeneous marked point patterns in an unboundedly expanding convex sampling window. Our main objective is to identify the distribution of the typical mark by constructing an asymptotic χ^2-goodness-of-fit test. The corresponding test statistic is based on a natural empirical version of the Palm mark distribution and a smoothed covariance estimator which turns out to be mean-square consistent. Our approach does not require independent marks and allows dependences between the mark field and the point pattern. Instead we impose a suitable β-mixing condition on the underlying stationary marked point process which can be checked for a number of Poisson-based models and, in particular, in the case of geostatistical marking. Our method needs a central limit theorem for β-mixing random fields which is proved by extending Bernstein's blocking technique to non-cubic index sets and seems to be of interest in its own right. By large-scale model-based simulations the performance of our test is studied in dependence of the model parameters which determine the range of spatial correlations.

math.ST↗

arXiv2009

Scaling limits for shortest path lengths along the edges of stationary tessellations - Supplementary material

We consider spatial stochastic models, which can be applied e.g. to telecommunication networks with two hierarchy levels. In particular, we consider two Cox processes concentrated on the edge set of a random tessellation, where the points can describe the locations of low-level and high-level network components, respectively, and the edge set the underlying infrastructure of the network, like road systems, railways, etc. Furthermore, each low-level component is marked with the shortest path along the edge set to the nearest high-level component. We investigate the typical shortest path length of the resulting marked point process, which is an important characteristic e.g. in performance analysis and planning of telecommunication networks. In particular, we show that its distribution converges to simple parametric limit distributions if a certain scaling factor converges to zero and infinity, respectively. This can be used to approximate the density of the typical shortest path length by analytical formulae.

math.PR↗

arXiv2007

Limit theorems for functionals on the facets of stationary random tessellations

We observe stationary random tessellations $X=\{Ξ_n\}_{n\ge1}$ in $\mathbb{R}^d$ through a convex sampling window $W$ that expands unboundedly and we determine the total $(k-1)$-volume of those $(k-1)$-dimensional manifold processes which are induced on the $k$-facets of $X$ ($1\le k\le d-1$) by their intersections with the $(d-1)$-facets of independent and identically distributed motion-invariant tessellations $X_n$ generated within each cell $Ξ_n$ of $X$. The cases of $X$ being either a Poisson hyperplane tessellation or a random tessellation with weak dependences are treated separately. In both cases, however, we obtain that all of the total volumes measured in $W$ are approximately normally distributed when $W$ is sufficiently large. Structural formulae for mean values and asymptotic variances are derived and explicit numerical values are given for planar Poisson--Voronoi tessellations (PVTs) and Poisson line tessellations (PLTs).

math.PR↗

arXiv2007

Scaling limits for random fields with long-range dependence

This paper studies the limits of a spatial random field generated by uniformly scattered random sets, as the density $λ$ of the sets grows to infinity and the mean volume $ρ$ of the sets tends to zero. Assuming that the volume distribution has a regularly varying tail with infinite variance, we show that the centered and renormalized random field can have three different limits, depending on the relative speed at which $λ$ and $ρ$ are scaled. If $λ$ grows much faster than $ρ$ shrinks, the limit is Gaussian with long-range dependence, while in the opposite case, the limit is independently scattered with infinite second moments. In a special intermediate scaling regime, there exists a nontrivial limiting random field that is not stable.

math.PR↗

arXiv2006

Central limit theorems for Poisson hyperplane tessellations

We derive a central limit theorem for the number of vertices of convex polytopes induced by stationary Poisson hyperplane processes in $\mathbb{R}^d$. This result generalizes an earlier one proved by Paroux [Adv. in Appl. Probab. 30 (1998) 640--656] for intersection points of motion-invariant Poisson line processes in $\mathbb{R}^2$. Our proof is based on Hoeffding's decomposition of $U$-statistics which seems to be more efficient and adequate to tackle the higher-dimensional case than the ``method of moments'' used in [Adv. in Appl. Probab. 30 (1998) 640--656] to treat the case $d=2$. Moreover, we extend our central limit theorem in several directions. First we consider $k$-flat processes induced by Poisson hyperplane processes in $\mathbb{R}^d$ for $0\le k\le d-1$. Second we derive (asymptotic) confidence intervals for the intensities of these $k$-flat processes and, third, we prove multivariate central limit theorems for the $d$-dimensional joint vectors of numbers of $k$-flats and their $k$-volumes, respectively, in an increasing spherical region.

math.PR↗