arXiv subjects

W. -C. Chen

Publications and source records attributed to W. -C. Chen.

5 recordsLinked to original sources

arXiv2020

Surface-state Coulomb repulsion accelerates a metal-insulator transition in topological semimetal nanofilms

The emergence of quantization at the nanoscale, the quantum size effect (QSE), allows flexible control of matter and is a rich source of advanced functionalities. A QSE-induced transition into an insulating phase in semimetallic nanofilms was predicted for bismuth a half-century ago and has regained new interest with regard to its surface states exhibiting nontrivial electronic topology. Here, we reveal an unexpected mechanism of the transition by high-resolution angle-resolved photoelectron spectroscopy combined with theoretical calculations. Anomalous evolution and degeneracy of quantized energy levels indicate that increased Coulomb repulsion from the surface states deforms a quantum confinement potential with decreasing thickness. The potential deformation drastically modulates spatial distributions of quantized wave functions, which leads to acceleration of the transition even beyond the original QSE picture. This discovery establishes a complete picture of the long-discussed problem in bismuth and highlights the new class of size effects dominating nanoscale transport in systems with metallic surface states.

cond-mat.mtrl-sci↗

arXiv2018

Alkali-metal induced band structure deformation investigated by angle-resolved photoemission spectroscopy and first-principles calculations

Alkali-metal adsorption on the surface of materials is widely used for in situ surface electron doping, particularly for observing unoccupied band structures by angle-resolved photoemission spectroscopy (ARPES). However, the effects of alkali-metal atoms on the resulting band structures have yet to be fully investigated, owing to difficulties in both experiments and calculations. Here, we combine ARPES measurements on cesium-adsorbed ultrathin bismuth films with first-principles calculations of the electronic charge densities and demonstrate a simple method to evaluate alkali-metal induced band deformation. We reveal that deformation of bismuth surface bands is directly correlated with vertical charge-density profiles at each electronic state of bismuth. In contrast, a change in the quantized bulk bands is well described by a conventional rigid-band-shift picture. We discuss these two aspects of the band deformation holistically, considering spatial distributions of the electronic states and cesium-bismuth hybridization, and provide a prescription for applying alkali-metal adsorption to a wide range of materials.

cond-mat.mtrl-sci↗

arXiv2017

Anisotropy in the thermal hysteresis of resistivity and charge density wave nature of single crystal SrFeO3-delta: X-ray absorption and photoemission studies

The local electronic and atomic structures of the high-quality single crystal of SrFeO3-{delta} ({delta}~0.19) were studied using temperature-dependent x-ray absorption and valence-band photoemission spectroscopy (VB-PES) to investigate the origin of anisotropic resistivity in the ab-plane and along the c-axis close to the region of thermal hysteresis (near temperature for susceptibility maximum, Tm~78 K). All experiments herein were conducted during warming and cooling processes. The Fe L3,2-edge X-ray linear dichrois results show that during cooling from room temperature to below the transition temperature, the unoccupied Fe 3d eg states remain in persistently out-of-plane 3d3z2-r2 orbitals. In contrast, in the warming process below the transition temperature, they change from 3d3z2-r2 to in-plane 3dx2-y2 orbitals. The nearest-neighbor (NN) Fe-O bond lengths also exhibit anisotropic behavior in the ab-plane and along the c-axis below Tm. The anisotropic NN Fe-O bond lengths and Debye-Waller factors stabilize the in-plane Fe 3dx2-y2 and out-of-plane 3d3z2-r2 orbitals during warming and cooling, respectively. Additionally, a VB-PES study further confirms that a relative band gap opens at low temperature in both the ab-plane and along the c-axis, providing the clear evidence of the charge-density-wave nature of SrFeO3-{delta} ({delta}~ 0.19) single crystal.

cond-mat.str-el↗

arXiv2016

Proving Nontrivial Topology of Pure Bismuth by Quantum Confinement

The topology of pure Bi is controversial because of its very small ($\sim$10 meV) band gap. Here we perform high-resolution angle-resolved photoelectron spectroscopy measurements systematically on 14$-$202 bilayers Bi films. Using high-quality films, we succeed in observing quantized bulk bands with energy separations down to $\sim$10 meV. Detailed analyses on the phase shift of the confined wave functions precisely determine the surface and bulk electronic structures, which unambiguously show nontrivial topology. The present results not only prove the fundamental property of Bi but also introduce a capability of the quantum-confinement approach.

cond-mat.mtrl-sci↗

arXiv2011

Helium star evolutionary channel to super-Chandrasekhar mass type Ia supernovae

Recent discovery of several overluminous type Ia supernovae (SNe Ia) indicates that the explosive masses of white dwarfs may significantly exceed the canonical Chandrasekhar mass limit. Rapid differential rotation may support these massive white dwarfs. Based on the single-degenerate scenario, and assuming that the white dwarfs would differentially rotate when the accretion rate $\dot{M}>3\times 10^{-7}M_{\odot}\rm yr^{-1}$, employing Eggleton's stellar evolution code we have performed the numerical calculations for $\sim$ 1000 binary systems consisting of a He star and a CO white dwarf (WD). We present the initial parameters in the orbital period - helium star mass plane (for WD masses of $1.0 M_{\odot}$ and $1.2 M_{\odot}$, respectively), which lead to super-Chandrasekhar mass SNe Ia. Our results indicate that, for an initial massive WD of $1.2 M_{\odot}$, a large number of SNe Ia may result from super-Chandrasekhar mass WDs, and the highest mass of the WD at the moment of SNe Ia explosion is 1.81 $M_\odot$, but very massive ($>1.85M_{\odot}$) WDs cannot be formed. However, when the initial mass of WDs is $1.0 M_{\odot}$, the explosive masses of SNe Ia are nearly uniform, which is consistent with the rareness of super-Chandrasekhar mass SNe Ia in observations.

astro-ph.HE↗