arXiv subjects

W. G. Clark

Publications and source records attributed to W. G. Clark.

14 recordsLinked to original sources

arXiv2014

Investigation of the magnetic dipole field at the atomic scale in quasi-one-dimensional paramagnetic conductor Li$_{0.9}$Mo$_{6}$O$_{17}$

We report magnetic dipole field investigation at the atomic scale in a single crystal of quasi-one-dimensional (Q1D) paramagnetic conductor Li$_{0.9}$Mo$_{6}$O$_{17}$, using a paramagnetic electron model and $^{7}$Li-NMR spectroscopy measurements with an externally applied magnetic field $B_{0}$ = 9 T. We find that the magnetic dipole field component ($B_{||}^{\text{dip}}$) parallel to $B_{0}$ at the Li site from the Mo electrons has no lattice axial symmetry; it is small around the middle between the lattice $c$ and $a$ axes in the $ac$-plane with the minimum at the field orientation angle $θ$ = +52.5$^{\circ}$, while the $B_{||}^{\text{dip}}$ maximum is at $θ$ = +142.5$^{\circ}$ when $B_{0}$ is applied perpendicular to $b$ ($B_{0}$ $\perp$ $b$), where $θ$ = 0$^{\circ}$ represents the direction of $B_{0}$ $\parallel$ $c$. Further estimate indicates that $B_{||}^{\text{dip}}$ has a maximum value of 0.35 G at $B_{0}$ = 9 T, and the Mo ions have a possible effective magnetic dipole moment 0.015 $μ_{\text{B}}$ per ion, which is significantly smaller than that of a spin 1/2 free electron. By minimizing potential magnetic contributions to the NMR spectrum satellites with the NMR spectroscopy measurements at the direction where the value of the magnetic dipole field is the smallest, the behavior of the independent charge contributions is observed. This work demonstrates that the magnetic dipole field from the Mo electrons is the dominant source of the local magnetic fields at the Li site, and it suggests that the mysterious "metal-insulator" crossover at low temperatures is not a charge effect. The work also reveals valuable local field information for further NMR investigation which is suggested recently [Phys. Rev. B $\bf{85}$, 235128 (2012)] to be key important to the understanding of many mysterious properties of this Q1D material of particular interest.

cond-mat.str-el↗

arXiv2014

Internal static electric and magnetic field at the copper cite in a single crystal of the electron-doped high-T$_{c}$ superconductor Pr$_{1.85}$Ce$_{0.15}$CuO$_{4-y}$

We report $^{63, 65}$Cu-NMR spectroscopy and Knight shift measurements on a single crystal of the electron-doped high-$T_{c}$ superconductor Pr$_{1.85}$Ce$_{0.15}$CuO$_{4-y}$ (PCCO) with an applied magnetic field ($H$) up to 26.42 T. A very small NQR frequency is obtained with the observation of the spectrum, which shows an extremely wide continuous distribution of it that becomes significant narrower below 20 K at $H$ $\parallel$ $c$ where the superconductivity is completely suppressed, indicating a significant change in the charge distribution at the Cu site, while the corresponding changes at $H$ $\perp$ $c$ is negligible when the superconductivity is present or not fully suppressed. The Knight shift and central linewidth are proportional to the applied magnetic field with a high anisotropy. We find that the magnitude of the internal static magnetic field at the copper is dominated by the anisotropic Cu$^{2+}$ 3$d$-orbital contributions, while its weak temperature-dependence is mainly determined by the isotropic contact hyperfine coupling to the paramagnetic Pr$^{3+}$ spins, which also gives rise to the full distribution of the internal static magnetic field at the copper for $H$ $\perp$ $c$. This internal static electric and magnetic field environment at the copper is very different from that in the hole-doped cuprates, and may provide new insight into the understanding of high-$T_{c}$ superconductivity. Other experimental techniques are needed to verify whether the observed significant narrowing of the charge distribution at the Cu site with $H$ $\parallel$ $c$ is caused by the charge ordering (CO) [E. H. da Silva Neto $et ~al.$, to be published in Science] \cite{ehdsn} or a new type of charge modulation.

cond-mat.supr-con↗

arXiv2014

Superconducting anisotropy in the electron-doped high-T$_{c}$ superconductors Pr$_{2-x}$Ce$_{x}$CuO$_{4-y}$

We report superconducting anisotropy measurements in the electron-doped high-$T_{c}$ superconductors (HTSCs) Pr$_{2-x}$Ce$_{x}$CuO$_{4-y}$ (PCCO, $x$ = 0.15 and 0.17) with applied magnetic field ($H_{0}$) up to 28 T. Our results show that the upper critical field [$H_{c2}(T)$] is highly anisotropic, and as temperature $T$ $\rightarrow$ 0 the value of it at $H_{0}$ $\parallel$ $c$ [$H_{c2,\parallel c}$(0)] is far less than the Pauli limit, which is very different from that at $H_{0}$ $\perp$ $c$. The $H_{c2}(0)$ character along with the evaluated zero $T$ coherence length $[ξ_{ab(c)}(0)]$ and penetration depth $[λ_{ab(c)}(0)]$ is compared with those of the hole-doped cuprate HTSCs and typical Fe-based superconductors. We find that the low temperature anisotropic character of PCCO is rather similar to that of hole-doped cuprate HTSCs, but apparently larger than that of typical Fe-based superconductors. This study also proves a new sensitive probe of detecting rich properties of unconventional superconductors with the use of the resonant frequency of a NMR probe circuit.

cond-mat.supr-con↗

arXiv2009

Critical properties of the S=1 spin dimer compound Ba3Mn2O8

Ba3Mn2O8 is a hexagonally coordinated Mn5+ S=1 spin dimer system with small uniaxial single-ion anisotropy. 135,137Ba NMR spectroscopy is used to establish the lower critical field Hc1 of distinct field-induced phases for H parallel to c,H perpendicular to c, and measure the longitudinal (Ml) and transverse (Mt) magnetizations in the vicinity of the quantum critical point (QCP). Ml_parallel (T, Hc1), Ml_perpendicular (T, Hc1) are reproduced by solving a low-energy model for a dilute gas of interacting bosons. Ml_parallel(T goes to 0, H = Hc1) (Ml_perpendicular(T goes to 0, H = Hc1)) follows the expectation for a BEC (Ising-like) QCP.

cond-mat.str-el↗

arXiv2007

$^{77}$Se NMR measurements of the $π-d$ exchange field in the organic conductor $λ-$(BETS)$_{2}$FeCl$_{4}$

$^{77}$Se-NMR spectrum and frequency shift measurements in the paramagnetic metal (PM) and antiferromagnetic insulating (AFI) phases are reported for a small single crystal of the organic conductor $λ-$(BETS)$_{2}$FeCl$_{4}$ as a function of temperature ($T$) and field alignment for an applied magnetic field $B_{0}$ = 9 T. The results show that in the low $T$ limit, where the localized Fe$^{3+}$ spins ($S_{d}$ = 5/2) are almost fully polarized, the conduction electrons (Se $π$-electrons, spin $s_π$ = 1/2) in the BETS molecules experience an exchange field ($\bf{B}$$_{πd}$) from the Fe$^{3+}$ spins with a value of $-$ 32.7 $\pm$ 1.5 T at 5 K and 9 T aligned opposite to $\bf{B}$$_{0}$. This large negative value of $\bf{B}$$_{πd}$ is consistent with that predicted by the resistivity measurements and supports the Jaccarino-Peter internal field-compensation mechanism being responsible for the origin of field-induced superconductivity.

cond-mat.str-el↗

arXiv2007

$^{1}$H-NMR spin-echo measurements of the static and dynamic spin properties in $λ$-(BETS)$_{2}$FeCl$_{4}$

$^{1}$H-NMR spin-echo measurements of the spin-echo decay $M(2τ)$ with a decay rate 1/$T_{2}$ and the frequency shift $Δν/ν_{0}$ under applied magnetic field $\mathbf{B}$$_{0}$ = 9 T along the a-axis over a temperature range 2.0$-$180 K are reported for a single crystal of the organic conductor $λ$-(BETS)$_{2}$FeCl$_{4}$. It provides the spin dynamic and static properties in the paramagnetic metal (PM) and antiferromagnetic insulator (AFI) states as well as across the PM$-$AFI phase transition. A large slow beat structure in the spin-echo decay is observed with a typical beat frequency of $f$ $\sim$ 7 kHz and it varies across the spectrum. Its origin is attributed to the $^{1}$H$-$$^{1}$H dipole interactions rather than to the much larger dipolar field contribution from the Fe$^{3+}$ electrons (spin $S$ = 5/2). A simple phenomenological model provides an excellent fit to the data. The dominant $^{1}$H-NMR frequency shift comes from the dipolar field from the 3d Fe$^{3+}$ ions, and the Fe$^{3+}$ $-$ Fe$^{3+}$ exchange interactions ($J_{0}$) ($J_{0} $ includes the d$-$d exchange interactions through the $π-$electrons) have a substantial effect to the local field at the proton sites expecially at low temperatures. A good fit is obtained with $J_{0}$ = - 1.7 K. The data of the spin-echo decay rate 1/$T_{2}$ indicates that there is a significant change in the slow fluctuations of the local magnetic field at the $^{1}$H-sites on traversing the PM to AFI phase. This evidence supports earlier reports that the PM$-$AFI phase transition in $λ$-(BETS)$_{2}% $FeCl$_{4} $ is driven magnetically and first order.

cond-mat.str-el↗

arXiv2006

Proton NMR measurements of the local magnetic field in the paramagnetic metal and antiferromagnetic insulator phases of $λ$-(BETS)$_{2}$FeCl$_{4}$

Measurements of the $^{1}$H-NMR spectrum of a small ($\sim$ 4 $μ$g) single crystal of the organic conductor $λ$-(BETS)$_{2}$FeCl$_{4}$ are reported with an applied magnetic field $\bf{B}$$_{0}$ = 9 T parallel to the a-axis in the $ac$-plane over a temperature $(T)$ range 2.0 $-$ 180 K. They provide the distribution of the static local magnetic field at the proton sites in the paramagnetic metal (PM) and antiferromagnetic insulator (AFI) phases, along with the changes that occur at the PM$-$AFI phase transition. The spectra have six main peaks that are significantly broadened and shifted at low $T$. The origin of these features is attributed to the large dipolar field from the 3d Fe$^{3+}$ ion moments (spin $S_{\rm{d}}$ = 5/2). Their amplitude and $T-$dependence are modeled using a modified Brillouin function that includes a mean field approximation for the total exchange interaction ($J_{0}$) between one Fe$^{3+}$ ion and its two nearest neighbors. A good fit is obtained using $J_{0}$ = $-$ 1.7 K. At temperatures below the PM$-$AFI transition temperature $T_{MI}$ = 3.5 K, an extra peak appears on the high frequency side of the spectrum and the details of the spectrum become smeared. Also, the rms linewidth and the frequency shift of the spectral distribution are discontinuous, consistent with the transition being first-order. These measurements verify that the dominant local magnetic field contribution is from the Fe$^{3+}$ ions and indicate that there is a significant change in the static local magnetic field distribution at the proton sites on traversing the PM to AFI phase transition.

cond-mat.str-el↗

arXiv2004

Self-Similar Evolution of Parabolic Pulses in a Laser

Self-similar propagation of ultrashort, parabolic pulses in a laser resonator is observed theoretically and experimentally. This constitutes a new type of pulse-shaping in modelocked lasers: in contrast to the well-known static (soliton-like) and breathing (dispersion-managed soliton) pulse evolutions, asymptotic solutions to the nonlinear wave equation that governs pulse propagation in most of the laser cavity are observed. Stable self-similar pulses exist with energies much greater than can be tolerated in soliton-like pulse shaping, and this will have implications for practical lasers.

physics.optics↗

arXiv2003

NMR Investigation of the Organic Conductor lambda-(BETS)2FeCl4

The two-dimensional organic conductor lambda-(BETS)2FeCl4 has an unusual phase diagram as a function of temperature and magnetic field that includes a paramagnetic metal (PM) phase, an antiferromagnetic insulating (AFI) phase, and a field-induced superconducting phase [S. Uji, H. Kobayashi, L. Balicas, and James S. Brooks, Adv. Mater. 14, 243 (2002), and cited references]. Here, we report a preliminary investigation of the PM and AFI phases at 9.0 T over the temperature range 2.0-180 K that uses proton NMR measurements of the spectrum, the spin-lattice relaxation rate (1/T1), and the spin echo decay rate (1/T2). The sample is asmall single crystal whose mass is approximately 3 micrograms (approximately 2E16 protons). Its small size creates several challenges that include detecting small signals and excluding parasitic proton signals that are not from the sample [H. N. Bachman and I. F. Silvera, J. Mag. Res. 162, 417 (2003)]. These strategies and other techniques used to obtain viable signals are described.

cond-mat.str-el↗

arXiv2003

Inhomogeneous electronic structure probed by spin-echo experiments in the electron doped high-Tc superconductor Pr_{1.85}Ce_{0.15}CuO_{4-y}

63Cu nuclear magnetic resonance (NMR) spin-echo decay rate (T_2^{-1}) measurements are reported for the normal and superconducting states of a single crystal of Pr_{1.85}Ce_{0.15}CuO_{4-y} (PCCO) in a magnetic field B_0=9T over the temperature range 2K<T<200K. The spin-echo decay rate is temperature-dependent for T<55K, and has a substantial dependence on the radio frequency (rf) pulse parameters below T~25K. This dependence indicates that T_2^{-1} is strongly effected by a local magnetic field distribution that can be modified by the rf pulses, including ones that are not at the nuclear Larmor frequency. The low-temperature results are consistent with the formation of a static inhomogeneous electronic structure that couples to the rf fields of the pulses.

cond-mat.supr-con↗

arXiv2002

Origin for the enhanced copper spin echo decay rate in the pseudogap regime of the multilayer high-T_c cuprates

We report measurements of the anisotropy of the spin echo decay for the inner layer Cu site of the triple layer cuprate, Hg_0.8Re_0.2Ba_2Ca_2Cu_3O_8 (T_c=126 K) in the pseudogap T regime below T_pg ~ 170 K and the corresponding analysis for their interpretation. As the field alignment is varied, the shape of the decay curve changes from Gaussian (H_0 \parallel c) to single exponential (H_0 \perp c). The latter characterizes the decay caused by the fluctuations of adjacent Cu nuclear spins caused by their interactions with electron spins. The angular dependence of the second moment (T_{2M}^{-2} \equiv <Δω^2>) deduced from the decay curves indicates that T_{2M}^{-2} for H_0 \parallel c, which is identical to T_{2G}^{-2} (T_{2G} is the Gaussian component), is substantially enhanced, as seen in the pseudogap regime of the bilayer systems. Comparison of T_{2M}^{-2} between H_0 \parallel c and H_0 \perp c indicates that this enhancement is caused by electron spin correlations between the inner and the outer CuO_2 layers. These results provide the answer to the long-standing controversy regarding the opposite T dependences of (T_1T)^{-1} and T_{2G}^{-2} in the pseudogap regime of bi- and trilayer systems.

cond-mat.str-el↗

arXiv2001

High Magnetic Field NMR Studies of LiVGe$_2$O$_6$, a quasi 1-D Spin $S = 1$ System

We report $^{7}$Li pulsed NMR measurements in polycrystalline and single crystal samples of the quasi one-dimensional S=1 antiferromagnet LiVGe$_2$O$_6$, whose AF transition temperature is $T_{\text{N}}\simeq 24.5$ K. The field ($B_0$) and temperature ($T$) ranges covered were 9-44.5 T and 1.7-300 K respectively. The measurements included NMR spectra, the spin-lattice relaxation rate ($T_1^{-1}$), and the spin-phase relaxation rate ($T_2^{-1}$), often as a function of the orientation of the field relative to the crystal axes. The spectra indicate an AF magnetic structure consistent with that obtained from neutron diffraction measurements, but with the moments aligned parallel to the c-axis. The spectra also provide the $T$-dependence of the AF order parameter and show that the transition is either second order or weakly first order. Both the spectra and the $T_1^{-1}$ data show that $B_0$ has at most a small effect on the alignment of the AF moment. There is no spin-flop transition up to 44.5 T. These features indicate a very large magnetic anisotropy energy in LiVGe$_2$O$_6$ with orbital degrees of freedom playing an important role. Below 8 K, $T_1^{-1}$ varies substantially with the orientation of $B_0$ in the plane perpendicular to the c-axis, suggesting a small energy gap for magnetic fluctuations that is very anisotropic.

cond-mat↗

arXiv2000

Superconducting Fluctuations and the Pseudogap in the Slightly-overdoped High-Tc Superconductor TlSr2CaCu2O6.8: High Magnetic Field NMR Studies

From measurements of the ^{63}Cu Knight shift (K) and the nuclear spin-lattice relaxation rate (1/T_{1}) under magnetic fields from zero up to 28 T in the slightly overdoped superconductor TlSr_{2}CaCu_{2}O_{6.8} (T_{c}=68 K), we find that the pseudogap behavior, {\em i.e.}, the reductions of 1/T_{1}T and K above T_{c} from the values expected from the normal state at high T, is strongly field dependent and follows a scaling relation. We show that this scaling is consistent with the effects of the Cooper pair density fluctuations. The present finding contrasts sharply with the pseudogap property reported previously in the underdoped regime where no field effect was seen up to 23.2 T. The implications are discussed.

cond-mat.supr-con↗

arXiv2000

Evidence from $^{77}$Se Knight shifts for triplet superconductivity in (TMTSF)$_2$PF$_6$

The layered quasi-one-dimensional molecular superconductor (TMTSF)$_2$PF$_6$ is a very exotic material with a superconducting order parameter whose ground state symmetry has remained ill-defined. Here we present a pulsed NMR Knight shift (K) study of $^{77}$Se measured simultaneously with transport in pressurized (TMTSF)$_2$PF$_6$. The Knight shift is linearly dependent on the electron spin susceptibility $χ_s$, and is therefore a direct measure of the spin polarization in the superconducting state. For a singlet superconductor, the spin contribution to the Knight shift, K$_s$, falls rapidly on cooling through the transition. The present experiments indicate no observable change in K between the metallic and superconducting states, and thus strongly support the hypothesis of triplet p-wave superconductivity in (TMTSF)$_2$PF$_6$.

cond-mat.supr-con↗